$**************************************************************************
$
$ mc_fe_bainite_v1.01.tdb
$
$************************RELEASE VERSION***********************************
$ MatCalc thermodynamic steel database, version 2.060, created 2017-03-06
$
$ This database contains edited and newly assessed thermodynamic data for steel.
$ Thermodynamic parameters have been assessed at TU Wien
$ by Povoden-Karadeniz Erwin and Jacob Aurelie.
$
$ ##########################################################################
$
$ use with MatCalc version 6.00 or higher
$
$ ##########################################################################
$
$ Copyright holder and editor: Erwin Povoden-Karadeniz
$ (erwin.povoden-karadeniz@tuwien.ac.at)
$ Update by: Aurélie Jacob
$
$ This database mc_fe_bainite_v1.01.tdb is made available under the
$ Open Database License: http://opendatacommons.org/licenses/odbl/1.0/.
$ Any rights in individual contents of the database are licensed under the
$ Database Contents License: http://opendatacommons.org/licenses/dbcl/1.0/.
$
$ ##########################################################################
$
$ Update from previous database mc_fev2.060 (v 1.0):
$ - Optimization of FCC/BCC FeCrNi for duplex stainless steel
$ - G-phase for duplex stainless steel and reactor pressure vessel steel
$ -> Elements: Mn,Ni,Si,Fe,Cr,Mo optimized
$ - Related phases to G-phase
$ -> C15 and C14 Laves phase
$ -> MnNiSi ternary phases: T4 and T7
$ -> B2 phase
$ -> L12-ordered
$ Update v1.01
$ corrected - re-implement HMVA and debug (E. Povoden-Karadeniz)
$ unify reference formatting (E. Povoden-Karadeniz)
$ merged with reassessed MX carbonitride assessments (A, Jacob)
$ Note that other phases and their parametrisations have not been validated
$ or reassessed, associated with the present fcc - bcc optimisations by ref 293.
$
$ The following assessments are incorporated in this database:
$
$ ... see list of publications in the reference section
$ at the end of this file ...
$ The following elements are included in this database:
$
$ Fe, Al, B, C, Co, Cr, Cu, H, Hf, La, Mn, Mo, N, Nb, Ni, O, P, Pd, S, Si,
$ Ti, V, W, Y
$ This database has been optimised inside the following limits:
$ Temperature: 673 K - 2000 K
$
$ Alloy composition (wt.%): Al<3 B<0.5 C<0.5 Co<3 Cr<25 Cu<1 Hf<0.5
$ La<0.5 Mn<25 Mo<5 N<1 Nb<1 Ni<26 O<0.5 P<0.005 Pd<4 S<0.5 Si<3.5
$ Ti<0.5 V<0.5 W<3 Y<0.5
$
$ Particular focus: appropriate T0 temperatures assessed and implemented
$ according to Ref 293
$ H: Only binary Fe-H parameters in fcc and bcc are edited.
$ Typical applications: Bainitic steels.
$ The following phases are included in this database:
$ They are listed in the order of their appearance in
$ part D) Thermodynamic model parameters for phases.
$ For their documentation see part D).
$ Documentation and priority rankings suggested by the editor are visible
$ in the MatCalc databases window after reading the database
$ and marking the phase of interest.
$
$ LIQUID
$
$ FCC_A1
$ BCC_A2
$ HCP_A3
$
$ ALPHA_MN
$ BETA_MN
$ BETA_RHOMBO_B
$ DIAMOND_A4
$ GRAPHITE
$
$ Ordered phases (split model used)
$ BCC_B2
$
$ Intermetallic phases
$ CHI_A12 CO3MO CO3V COV3 CR3MN5 G_PHASE GAMMA_PRIME LAVES_PHASE MNNI
$ MNNI2 MNNI_T3 MU_PHASE MU_PHASE_I ETA NITI2 R_PHASE SIGMA FE17Y2
$ NI5Y PDFE_L12 PDMN_AF PDMN_P PDMN_B2 PD2MN PD3MN Pd5MN3 PD6FE5MN2
$
$ Carbides
$ CEMENTITE CR2VC2 K_CARB KSI_CARBIDE M3C2 M6C
$ M7C3 M12C M23C6 MOC_ETA V3C2 WC
$
$ Metastable transition carbides
$ EPS_CARB ETA_CARB FE24C10 KSI_FE5C2
$
$ Nitrides
$ ALN ALN_EQU BN_HP4 FE4N MN6N4 MN6N5 MNSIN2 SI3N4 ZET
$
$ Borides
$ CRB CR2B CR5B3 FEB FENBB FE3NB3B4 M2B MNB2 MNB4 O_MN2B MN3B4
$ MOB MOB2 MO2M1B2 NBB NB3B2 M5B6 TIB TIB2 TI3B4
$
$ Sulfides
$ A_CHALC ANILITE B_CHALC COVELLITE CU2S DIGENITE
$ DISULF DJURLEITE FC_MONO FC_ORTHO FES_P MNS_Q PYRR TIS
$
$ Carbo-sulfides
$ TI4C2S2
$
$ Oxides
$ Simple oxide models without considering of
$ cation and oxygen nonstoichiometries are used.
$ CORUND HALITE HF1O2_M HF1O2_T HF1O2_C LA2O3_A LA2O3_H LA2O3_C SIO2
$ SPINEL TI2O3 TIO2 TRID Y2O3_H Y2O3_C YALO3 Y4AL2O9 Y2TIO5 Y2TI2O7
$
$ Phosphides
$ M2P M3P
$
$ Special phases
$ BCC_DISL
$
$ This database has been revised for the low temperature applications
$ Can be used for bainite and martensite calculations
$
$***************************************************************************
$
$ A) Definition of elements
$ From A. T. Dinsdale, SGTE data for pure elements (REF 0)
$
$***************************************************************************
$
$Element Standard state mass [g/mol] enthalpy_298 entropy_298
ELEMENT VA VACUUM 0.0 0.00 0.00 !
ELEMENT AL FCC_A1 26.98154 4540.0 28.30 !
ELEMENT B BETA_RHOMBO_B 10.811 1222.0 5.90 !
ELEMENT C HEX_A9 12.011 1054.0 5.7423 !
ELEMENT CO HCP_A3 58.933 4765.567 30.03 !
ELEMENT CR BCC_A2 51.996 4050.0 23.5429 !
ELEMENT CU FCC_A1 63.546 5004.0 33.15 !
ELEMENT FE BCC_A2 55.847 4489.0 27.2797 !
ELEMENT H 1/2_MOLE_H2(GAS) 1.0079 4234.0 65.285 !
ELEMENT HF HCP_A3 178.49 5845.0 43.56 !
ELEMENT LA DOUBLE_HCP(ABAC) 138.91 6665.1 56.902 !
ELEMENT MN BCC_A12 54.9380 4995.696 32.2206 !
ELEMENT MO BCC_A2 95.94 4589.0 28.56 !
ELEMENT N 1/2_MOLE_N2(G) 14.007 4335.0 95.751 !
ELEMENT NB BCC_A2 92.9064 5220.0 36.27 !
ELEMENT NI FCC_A1 58.69 4787.0 29.7955 !
ELEMENT O 1/2_MOLE_O2(GAS) 15.999 4341.0 102.5200 !
ELEMENT P WHITE_P 30.974 5360.0 41.09 !
ELEMENT PD FCC_A1 106.42 5468.5 37.8234 !
ELEMENT S FC_ORTHORH 32.066 4412.0 32.054 !
ELEMENT SI DIA_A4 28.0855 3217.0 18.81 !
ELEMENT TI HCP_A3 47.88 4824.0 30.72 !
ELEMENT V BCC_A2 50.9415 4507.0 30.89 !
ELEMENT W BCC_A2 183.85 4970.0 32.6176 !
ELEMENT Y HCP_A3 88.9059 5966.384 44.4341 !
$
$***************************************************************************
$
$ B) MatCalc specific commands
$
$***************************************************************************
$
$ Defines Fe as reference element
REFERENCE_ELEMENT FE !
$
$ if phase FCC_A1 is selected, add composition set for carbonitrides ...
ADD_COMPOSITION_SET FCC_A1 :TI,NB,V:C,N: !
ADD_COMPOSITION_SET FCC_A1 :CU:VA: !
$ simple carbide/nitride phases derived from parent are defined
$ by MatCalc syntax (5.44.0.008)
$ CREATE_NEW_PHASE parent_phase_name c :El1,El2,...:El3,El4,...: new_name
$
$ if phase HCP_A3 is selected, add composition set for carbides and nitrides
ADD_COMPOSITION_SET HCP_A3 :CR:N: !
ADD_COMPOSITION_SET HCP_A3 :MO:C: !
ADD_COMPOSITION_SET HCP_A3 :CR,V:C: !
$
$ if phase M6C is selected, add composition set for eta-nitride Cr3Ni2SiN
ADD_COMPOSITION_SET M6C :CR:NI:SI:C,N: !
$
$
ADD_COMPOSITION_SET LAVES_PHASE :CO:MO: !
ADD_COMPOSITION_SET LAVES_PHASE :FE:W: !
$
$ MatCalc syntax (MatCalc 5.31.1053)
$ATTACH_CONTRIBUTION BCC_DISL BCC_A2 PARENT_PHASE !
$
$ ##############################################################
$ Enthalpies of vacancy formation - FCC_A1
$ ##############################################################
$
$ default is Fe
PARAMETER HMVA(FCC_A1,*;0)
273.00 +175000; 6000.00 N
REF:pov12 !
PARAMETER HMVA(FCC_A1,AL:*;0)
273.00 +64200; 6000.00 N
REF:pov10 !
PARAMETER HMVA(FCC_A1,CO:*;0)
273.00 +165000; 6000.00 N
REF:pov15 !
PARAMETER HMVA(FCC_A1,CU:*;0)
273.00 +125000; 6000.00 N
REF:pov10 !
PARAMETER HMVA(FCC_A1,FE:*;0)
273.00 +175000; 6000.00 N
REF:pov12 !
PARAMETER HMVA(FCC_A1,HF:*;0)
273.00 +200000; 6000.00 N
REF:pov15 !
PARAMETER HMVA(FCC_A1,LA:*;0)
273.00 +140000; 6000.00 N
REF:pov15 !
PARAMETER HMVA(FCC_A1,MN:*;0)
273.00 +230000; 6000.00 N
REF:pov15 !
PARAMETER HMVA(FCC_A1,NI:*;0)
273.00 +134000; 6000.00 N
REF:pov15 !
PARAMETER HMVA(FCC_A1,PD:*;0)
273.00 +178000; 6000.00 N
REF:pov14 !
PARAMETER HMVA(FCC_A1,TI:*;0)
273.00 +188000; 6000.00 N
REF:pov15 !
PARAMETER HMVA(FCC_A1,W:*;0)
273.00 +160000; 6000.00 N
REF:pov15 !
PARAMETER HMVA(FCC_A1,ZR:*;0)
273.00 +195000; 6000.00 N
REF:pov15 !
$
$ ##############################################################
$ Enthalpies of vacancy formation - BCC_A2
$ ##############################################################
$
$ default is Fe
PARAMETER HMVA(BCC_A2,*;0)
273.00 +163000; 6000.00 N
REF:pov10 !
PARAMETER HMVA(BCC_A2,CR:*;0)
273.00 +203000; 6000.00 N
REF:pov10 !
PARAMETER HMVA(BCC_A2,FE:*;0)
273.00 +163000; 6000.00 N
REF:pov10 !
PARAMETER HMVA(BCC_A2,MN:*;0)
273.00 +101000; 6000.00 N
REF:pov10 !
PARAMETER HMVA(BCC_A2,MO:*;0)
273.00 +286000; 6000.00 N
REF:pov10 !
PARAMETER HMVA(BCC_A2,NB:*;0)
273.00 +290000; 6000.00 N
REF:pov10 !
PARAMETER HMVA(BCC_A2,V:*;0)
273.00 +204000; 6000.00 N
REF:pov10 !
PARAMETER HMVA(BCC_A2,W:*;0)
273.00 +378000; 6000.00 N
REF:pov10 !
$
$***************************************************************************
$
$ C) Gibbs energy functions
$
$***************************************************************************
$
$ ###########################################################
$ SER (Standard elements references)
$ ###########################################################
$
FUNCTION GHSERAL
273.00 -7976.15+137.093038*T-24.3671976*T*LN(T)
-1.884662E-3*T**2-0.877664E-6*T**3+74092*T**(-1); 700.00 Y
-11276.24+223.048446*T-38.5844296*T*LN(T)
+18.531982E-3*T**2-5.764227E-6*T**3+74092*T**(-1); 933.47 Y
-11278.378+188.684153*T-31.748192*T*LN(T)-1.231E+28*T**(-9); 6000.00 N
REF:0 !
FUNCTION GHSERBB
273.00 -7735.284+107.111864*T-15.6641*T*LN(T)
-0.006864515*T**2+6.18878E-07*T**3+370843*T**(-1); 1100.00 Y
-16649.474+184.801744*T-26.6047*T*LN(T)-7.9809E-04*T**2
-2.556E-08*T**3+1748270*T**(-1); 2348.00 Y
-36667.582+231.336244*T-31.5957527*T*LN(T)-0.00159488*T**2
+1.34719E-07*T**3+11205883*T**(-1); 3000.00 Y
-21530.653+222.396264*T-31.4*T*LN(T); 6000.00 N
REF:0 !
$ low T part of next function from REF 156
FUNCTION GHSERCC
273.00 -988.25091-7.39898691*T+1.76583*T*LN(T)-0.01706952*T**2; 350.00 Y
-17368.441+170.73*T-24.3*T*LN(T)
-4.723E-4*T**2+2562600*T**(-1)-2.643E+8*T**(-2)+1.2E+10*T**(-3); 6000.00 N
REF:0 !
FUNCTION GHSERCO
273.00 +310.241+133.36601*T-25.0861*T*LN(T)
-2.6547387E-3*T**2-1.7348E-07*T**3+72526.9*T**(-1); 1768.00 Y
-17197.666+253.28374*T-40.5*T*LN(T)+9.3488E+30*T**(-9); 6000.00 N
REF:0 !
FUNCTION GHSERCR
273.00 -8856.94+157.48*T-26.908*T*LN(T)
+0.00189435*T**2-1.47721E-6*T**3+139250*T**(-1); 2180.00 Y
-34869.344+344.18*T-50*T*LN(T)-2.88526E+32*T**(-9); 6000.00 N
REF:0 !
FUNCTION GHSERCU
273.00 -7770.458+130.485235*T-24.112392*T*LN(T)
-2.65684E-03*T**2+0.129223E-06*T**3+52478*T**(-1); 1357.77 Y
-13542.026+183.803828*T-31.38*T*LN(T)+3.642E+29*T**(-9); 6000.00 N
REF:0 !
FUNCTION GHSERFE
273.00 +1225.7+124.134*T-23.5143*T*LN(T)-0.00439752*T**2
-5.89269E-8*T**3+77358.5*T**(-1); 1811.00 Y
-25383.581+299.31255*T-46*T*LN(T)+2.2960305E+31*T**(-9); 6000.00 N
REF:0 !
FUNCTION GHSERHF
273.00 -6987.297+110.744026*T-22.7075*T*LN(T)-4.146145E-3*T**2
-0.000477E-6*T**3-22590*T**(-1); 2506.00 Y
-1446776.329+6193.609991*T-787.5363829*T*LN(T)+173.5215E-3*T**2
-7.575759E-6*T**3+501742495*T**(-1); 6000.00 N
REF:0 !
FUNCTION GHSERHH
273.00 -9522.97393+78.5273873*T-31.35707*T*LN(T)
+0.0027589925*T**2-7.46390667E-07*T**3+56582.3*T**(-1); 1000.00 Y
+180.10884-15.6128262*T-17.84857*T*LN(T)-.00584168*T**2
+3.14618667E-07*T**3-1280036*T**(-1); 2100.00 Y
-18840.1661+92.3120249*T-32.05082*T*LN(T)-.0010728235*T**2
+1.14281783E-08*T**3+3561002.5*T**(-1); 6000.00 N
REF:223 !
FUNCTION GHSERLA
273.00 -7968.403+120.284604*T-26.34*T*LN(T)-.001295165*T**2; 550.00 Y
-3381.413+59.06113*T-17.1659411*T*LN(T)-.008371705*T**2
+6.8932E-07*T**3-399448*T**(-1); 2000.00 Y
-15608.882+181.390071*T-34.3088*T*LN(T); 6000.00 N
REF:0 !
FUNCTION GHSERMN
273.00 -8115.28+130.059*T-23.4582*T*LN(T)
-7.34768E-3*T**2+69827.1*T**(-1); 1519.00 Y
-28733.41+312.2648*T-48.0*T*LN(T)+1.656847E+30*T**(-9); 6000.00 N
REF:0 !
FUNCTION GHSERMO
273.00 -7746.302+131.9197*T-23.56414*T*LN(T)
-0.003443396*T**2+5.662834E-7*T**3-1.309265E-10*T**4
+65812.39*T**(-1); 2896.00 Y
-30556.41+283.559746*T-42.63829*T*LN(T)-4.849315E+33*T**(-9); 5000.00 N
REF:0 !
$ 1/2N2 gas
FUNCTION GHSERNN
273.00 -3750.675-9.45425*T-12.7819*T*LN(T)
-0.00176686*T**2+2.680735E-09*T**3-32374*T**(-1); 950.00 Y
-7358.85+17.2003*T-16.3699*T*LN(T)
-6.5107E-04*T**2+3.0097E-8*T**3+563070*T**(-1); 3350.00 Y
-16392.8+50.26*T-20.4695*T*LN(T)
+2.39754E-04*T**2-8.3331E-9*T**3+4596375*T**(-1); 6000.00 N
REF:0 !
FUNCTION GHSERNB
273.00 -8519.353+142.045475*T-26.4711*T*LN(T)
+0.203475E-3*T**2-0.35011E-6*T**3+93399*T**(-1); 2750.00 Y
-37669.3+271.720843*T-41.77*T*LN(T)+1.52824E+32*T**(-9); 6000.00 N
REF:0 !
FUNCTION GHSERNI
273.00 -5179.159+117.854*T-22.096*T*LN(T)-4.8407E-3*T**2; 1728.00 Y
-27840.655+279.135*T-43.10*T*LN(T)+1.12754E+31*T**(-9); 6000.00 N
REF:0 !
FUNCTION GHSEROO
273.00 -3480.87226-25.5028601*T
-11.1355068*T*LN(T)-.005098873*T**2+6.6184604E-07*T**3
-38364.8742*T**(-1); 1000.00 Y
-6568.76015+12.6600017*T-16.8138015*T*LN(T)-5.9579637E-04*T**2
+6.78055555E-09*T**3+262904.778*T**(-1); 3300.00 Y
-13986.728+31.259625*T-18.9536*T*LN(T)-4.25243E-04*T**2
+1.0721E-08*T**3+4383200*T**(-1); 6000.00 N
REF:0 !
FUNCTION GHSERPD
273.00 -10204.027+176.076315*T-32.211*T*LN(T)
+0.007120975*T**2-1.919875E-06*T**3+168687*T**(-1); 900.00 Y
+917.062+49.659892*T-13.5708*T*LN(T)-0.00717522*T**2+1.91115E-07*T**3
-1112465*T**(-1); 1828.00 Y
-67161.018+370.102147*T-54.2067086*T*LN(T)
+0.002091396*T**2-6.2811E-08*T**3+18683526*T**(-1); 6000.00 N
REF:0 !
FUNCTION GHSERPP
273.00 -43821.799+1026.69389*T-178.426*T*LN(T)+.290708*T**2
-1.04022667E-04*T**3+1632695*T**(-1); 317.30 Y
-9587.448+152.341487*T-28.7335301*T*LN(T)+.001715669*T**2
-2.2829E-07*T**3+172966*T**(-1); 1000.00 Y
-8093.075+135.876831*T-26.326*T*LN(T); 3000.00 N
REF:0 !
FUNCTION GHSERSI
273.00 -8162.609+137.236859*T-22.8317533*T*LN(T)
-1.912904E-3*T**2-0.003552E-6*T**3+176667*T**(-1); 1687.00 Y
-9457.642+167.281367*T-27.196*T*LN(T)-4.2037E+30*T**(-9); 3600.00 N
REF:0 !
FUNCTION GHSERSS
273.00 -5228.956+55.417762*T-11.007*T*LN(T)
-0.026529*T**2+7.754333E-06*T**3; 368.30 Y
-6513.769+94.692922*T-17.941839*T*LN(T)-0.010895125*T**2
+1.402558E-06*T**3+39910*T**(-1); 3000.00 N
REF:0 !
FUNCTION GHSERTI
273.00 -8059.921+133.615208*T-23.9933*T*LN(T)
-4.777975E-3*T**2+1.06716E-07*T**3+72636*T**(-1); 900.00 Y
-7811.815+132.988068*T-23.9887*T*LN(T)
-4.2033E-3*T**2-9.0876E-08*T**3+42680*T**(-1); 1155.00 Y
+908.837+66.976538*T-14.9466*T*LN(T)
-8.1465E-3*T**2+2.02715E-07*T**3-1477660*T**(-1); 1941.00 Y
-124526.786+638.806871*T-87.2182461*T*LN(T)
+8.204849E-3*T**2-3.04747E-07*T**3+36699805*T**(-1); 4000.00 N
REF:0 !
FUNCTION GHSERVV
273.00 -7930.43+133.346053*T-24.134*T*LN(T)
-3.098E-3*T**2+1.2175E-07*T**3+69460*T**(-1); 790.00 Y
-7967.842+143.291093*T-25.9*T*LN(T)+0.0625E-3*T**2-0.68E-6*T**3; 2183.00 Y
-41689.864+321.140783*T-47.43*T*LN(T)+6.44389E+31*T**(-9); 4000.00 N
REF:0 !
FUNCTION GHSERWW
273.00 -7646.311+130.4*T-24.1*T*LN(T)
-1.936E-3*T**2+2.07E-7*T**3-5.33E-11*T**4+44500*T**(-1); 3695.00 Y
-82868.801+389.362335*T-54.0*T*LN(T)+1.528621E+33*T**(-9); 6000.00 N
REF:0 !
FUNCTION GHSERYY
273.00 -7347.055+117.532124*T-23.8685*T*LN(T)
-3.845475E-3*T**2+0.011125E-6*T**3-16486*T**(-1); 1500.00 Y
-15802.62+229.831717*T-40.2851*T*LN(T)+6.8095E-3*T**2
-1.14182E-6*T**3; 1799.00 Y
-72946.216+393.885821*T-58.2078433*T*LN(T)+2.436461E-3*T**2
-0.072627E-6*T**3+20866567*T**(-1); 6000.00 N
REF:0 !
$
$ ###########################################################
$ Gibbs energy functions other than SER
$ ###########################################################
$
FUNCTION GHSERNIA
273.00 -5179.159+117.854*T-22.096*T*LN(T)-4.8407E-3*T**2; 6000.00 N
REF:pov12 !
FUNCTION GHSERTIA
273.00 -8059.921+133.615208*T-23.9933*T*LN(T)
-4.777975E-3*T**2+1.06716E-07*T**3+72636*T**(-1); 6000.00 N
REF:pov12 !
FUNCTION GDHCNI
273.00 +0.5*GNIHCP#+0.5*GHSERNI#; 6000.00 N
REF:160 !
FUNCTION GDHCTI
273.00 +0.5*GHSERTI#+0.5*GTIFCC#; 6000.00 N
REF:160 !
FUNCTION GDHCNIA
273.00 +0.5*GNIHCPA#+0.5*GHSERNIA#; 6000.00 N
REF:pov12 !
FUNCTION GDHCTIA
273.00 +0.5*GHSERTIA#+0.5*GTIFCCA#; 6000.00 N
REF:pov12 !
FUNCTION GTI2NI
273.00 +0.33333*GHSERNIA#+0.66666667*GHSERTIA#-27514.218
+2.85345219*T; 6000.00 N
REF:160 !
FUNCTION DGLAV
273.00 +5000; 6000.00 N
REF:160 !
FUNCTION GLAVNI
273.00 +GHSERNI#+DGLAV#; 6000.00 N
REF:160 !
FUNCTION GLAVTI
273.00 +GHSERTI#+DGLAV#; 6000.00 N
REF:160 !
FUNCTION GTIFCCA
273.00 +6000-0.1*T+GHSERTIA#; 6000.00 N
REF:pov12 !
FUNCTION GNIHCPA
273.00 +1046+1.2552*T+GHSERNIA#; 6000.00 N
REF:pov12 !
$ bcc
FUNCTION GALBCC
273.00 +10083-4.813*T+GHSERAL#; 6000.00 N
REF:0 !
FUNCTION GCOBCC
273.00 +2938-0.7138*T+GHSERCO#; 6000.00 N
REF:0 !
FUNCTION GCUBCC
273.00 +4017-1.255*T+GHSERCU#; 6000.00 N
REF:0 !
FUNCTION GHFBCC
273.00 +5370.703+103.836026*T-22.8995*T*LN(T)-4.206605E-3*T**2
+0.871923E-6*T**3-22590*T**(-1)-0.1446E-9*T**4; 2506.00 Y
+1912456.771-8624.20573*T+1087.6141247*T*LN(T)-286.857065E-3*T**2
+13.427829E-6*T**3-610085091*T**(-1); 6000.00 N
REF:0 !
FUNCTION GLABCC
273.00 -3952.161+88.072353*T-21.7919*T*LN(T)
-.004045175*T**2-5.25865E-07*T**3; 800.00 Y
+321682.673-3565.08252*T+513.440708*T*LN(T)-.387295093*T**2
+4.9547989E-05*T**3-36581228*T**(-1); 1134.00 Y
-16377.894+218.492988*T-39.5388*T*LN(T); 1193.00 Y
-136609.91+1123.34397*T-163.413074*T*LN(T)+.053968535*T**2
-4.056395E-06*T**3+21167204*T**(-1); 2000.00 Y
-8205.988+174.836315*T-34.3088*T*LN(T); 6000.00 N
REF:0 !
FUNCTION GMNBCC
273.00 -3235.3+127.85*T-23.7*T*LN(T)
-0.00744271*T**2+60000*T**(-1); 1519.00 Y
-23188.83+307.7043*T-48*T*LN(T)+1.265152E+30*T**(-9); 6000.00 N
REF:0 !
FUNCTION GNIBCC
273.00 +8715.084-3.556*T+GHSERNI#; 6000.00 N
REF:0 !
FUNCTION GPBCC
273.00 +18792.241+135.412002*T-25.55*T*LN(T)+3.4121E-3*T**2
-2.418867E-6*T**3+160095*T**(-1); 500.00 Y
+23045.079+64.411737*T-14.368*T*LN(T)-9.57685E-3*T**2
+0.393917E-6*T**3-141375*T**(-1); 852.35 Y
-74639.613+1012.76962*T-149.4495562*T*LN(T)+67.272364E-3*T**2
-6.651929E-6*T**3+12495943*T**(-1); 1500.00 Y
+20244.681+140.579181*T-26.326*T*LN(T); 3000.00 N
REF:0 !
FUNCTION GPDBCC
273.00 +GHSERPD#+10500-1.8*T; 6000.00 N
REF:0 !
FUNCTION GSIBCC
273.00 +47000-22.5*T+GHSERSI#; 6000.00 N
REF:0 !
FUNCTION GTIBCC
273.00 +6787.856+1.098972*T-1.5835*T*LN(T)
+4.11413E-3*T**2-0.385519E-6*T**3-65428*T**(-1)+GHSERTI#; 900.00 Y
+6539.750+1.726111*T-1.5881*T*LN(T)
+3.539455E-3*T**2-0.187927E-6*T**3-35472*T**(-1)+GHSERTI#; 1155.00 Y
+5758.548+38.389841*T-7.4305*T*LN(T)
+9.363570E-3*T**2-1.048055E-6*T**3-525090*T**(-1)+GHSERTI#; 1941.00 Y
+151010.046-821.233343*T+106.3083366*T*LN(T)
-30.213169E-3*T**2+1.533611E-6*T**3-35299304*T**(-1)+GHSERTI#; 4000.00 N
REF:0 !
FUNCTION GYYBCC
273.00 +5485.858-20.009726*T+2.927924*T*LN(T)
-4.150358E-3*T**2+0.747591E-6*T**3-37863*T**(-1)+GHSERYY#; 1500.00 Y
+13941.422-132.309319*T+19.344524*T*LN(T)
-14.805333E-3*T**2+1.900536E-6*T**3-54349*T**(-1)+GHSERYY#; 1752.00 Y
+5594.895-34.089733*T+5.265*T*LN(T)
-6.8095E-3*T**2+1.14182E-6*T**3+GHSERYY#; 1799.00 Y
+177760.169-780.053385*T+98.0154419*T*LN(T)
-22.3552E-3*T**2+0.913936E-6*T**3-52416530*T**(-1)+GHSERYY#; 6000.00 N
REF:0 !
$ fcc
FUNCTION GCOFCC
273.00 +427.591-0.61525*T+GHSERCO#; 6000.00 N
REF:0 !
FUNCTION GCRFCC
273.00 +7284+0.163*T+GHSERCR#; 6000.00 N
REF:0 !
FUNCTION GFEFCC
273.00 -1462.4+8.282*T-1.15*T*LN(T)+6.4E-04*T**2+GHSERFE#; 1811.00 Y
-27098.266+300.25256*T-46*T*LN(T)+2.78854E+31*T**(-9); 6000.00 N
REF:0 !
FUNCTION GHFFCC
273.00 +3012.703+108.544*T-22.7075*T*LN(T)
-0.004146*T**2-0.000477E-6*T**3-22590*T**(-1); 2506.00 Y
-1436776.329+6191.409991*T-787.5363829*T*LN(T)+173.5215E-3*T**2
-7.575759E-6*T**3+501742495*T**(-1); 3000.00 N
REF:0 !
FUNCTION GLAFCC
273.00 -6109.797+89.878761*T-21.7919*T*LN(T)-0.004045175*T**2
-5.25865E-07*T**3; 1134.00 Y
-124598.976+955.878375*T-139.346741*T*LN(T)+0.042032405*T**2
-3.066199E-06*T**3+20994153*T**(-1); 2000.00 Y
-12599.386+178.54399*T-34.3088*T*LN(T); 6000.00 N
REF:0 !
FUNCTION GMNFCC
273.00 -3439.3+131.884*T-24.5177*T*LN(T)
-0.006*T**2+69600*T**(-1); 1519.00 Y
-26070.1+309.6664*T-48*T*LN(T)+3.86196E+30*T**(-9); 6000.00 N
REF:0 !
FUNCTION GMOFCC
273.00 +15200+0.63*T+GHSERMO#; 6000.00 N
REF:63 !
FUNCTION GPFCC
273.00 +10842.441+135.534002*T-25.55*T*LN(T)+3.4121E-3*T**2
-2.418867E-6*T**3+160095*T**(-1); 500.00 Y
+15095.279+64.533737*T-14.368*T*LN(T)-9.57685E-3*T**2
+0.393917E-6*T**3-141375*T**(-1); 852.35 Y
-82589.413+1012.89162*T-149.4495562*T*LN(T)+67.272364E-3*T**2
-6.651929E-6*T**3+12495943*T**(-1); 1500.00 Y
+12294.881+140.701181*T-26.326*T*LN(T); 3000.00 N
REF:pov14 !
FUNCTION GSIFCC
273.00 +51000-21.8*T+GHSERSI#; 6000.00 N
REF:0 !
FUNCTION GTIFCC
273.00 +6000-0.1*T+GHSERTI#; 6000.00 N
REF:0 !
FUNCTION GWFCC
273.00 +19300+.63*T+GHSERWW#; 6000.00 N
REF:0 !
$ hcp
FUNCTION GALHCP
273.00 +5481-1.8*T+GHSERAL#; 6000.00 N
REF:0 !
FUNCTION GFEHCP
273.00 -2480.08+136.725*T-24.6643*T*LN(T)
-0.00375752*T**2-5.8927E-8*T**3+77358.5*T**(-1); 1811.00 Y
-29340.78+304.56206*T-46*T*LN(T)+2.78854E+31*T**(-9); 6000.00 N
REF:0 !
FUNCTION GMOHCP
273.00 +3803.698+131.9197*T-23.56414*T*LN(T)
-3.443396E-3*T**2+0.566283E-6*T**3
+65812*T**(-1)-0.130927E-9*T**4; 2896.00 Y
-19006.41+283.559746*T-42.63829*T*LN(T)
-4849.315E30*T**(-9); 5000.00 N
REF:92 !
FUNCTION GNIHCP
273.00 +1046+1.2552*T+GHSERNI#; 6000.00 N
REF:0 !
FUNCTION GHEXTNB
273.00 -8519.35+142.048*T-26.4711*T*LN(T)
+0.203475E-3*T**2-0.350119E-6*T**3+93398.8*T**(-1); 6000.00 N
REF:19 !
FUNCTION GPRED
273.00 -25976.559+148.672002*T-25.55*T*LN(T)+3.4121E-3*T**2
-2.418867E-6*T**3+160095*T**(-1); 500.00 Y
-21723.721+77.671736*T-14.368*T*LN(T)-9.57685E-3*T**2
+0.393917E-6*T**3-141375*T**(-1); 852.35 Y
-119408.413+1026.02962*T-149.4495562*T*LN(T)+67.272364E-3*T**2
-6.651929E-6*T**3+12495943*T**(-1); 1500.00 Y
-24524.119+153.839181*T-26.326*T*LN(T); 3000.00 N
REF:0 !
FUNCTION GFECEM
273.00 -10195.860754+690.949887637*T-118.47637*T*LN(T)
-0.0007*T**2+590527*T**(-1); 6000.00 N
REF:156 !
FUNCTION GCOM23C6
273.00 +23*GHSERCO#+6*GHSERCC#+145000+116*T; 6000.00 N
REF:73 !
FUNCTION GCRM23C6
273.00 -521983+3622.24*T-620.965*T*LN(T)
-0.126431*T**2; 6000.00 N
REF:11 !
FUNCTION GFEM23C6
273.00 +7.666667*GFECEM#-1.666667*GHSERCC#+66920-40*T; 6000.00 N
REF:15 !
FUNCTION GMNM23C6
273.00 -308065+50.966*T+23*GHSERMN#+6*GHSERCC#; 6000.00 N
REF:15 !
FUNCTION GNIM23C6
273.00 +23*GHSERNI#+6*GHSERCC#+210000-84.71*T; 6000.00 N
REF:11 !
FUNCTION GVM23C6
273.00 -990367+4330.63*T-728.829*T*LN(T)+5003425*T**(-1); 6000.00 N
REF:15 !
FUNCTION GCRM7C3
273.00 -201690+1103.128*T-190.177*T*LN(T)-0.0578207*T**2; 6000.00 N
REF:11 !
FUNCTION GCRM3C2
273.00 -100823.8+530.66989*T-89.6694*T*LN(T)-0.0301188*T**2; 6000.00 N
REF:68 !
FUNCTION ETCFESI
273.00 +63; 6000.00 N
REF:92 !
FUNCTION GTIN
273.00 -357905+330.4982*T-52.458723*T*LN(T)-9.2840476E-4*T**2
+871489.25*T**(-1)-2.4139721E+9*T**(-3); 6000.00 N
REF:16 !
FUNCTION GSSLIQ
273.00 -4001.549+77.905686*T-15.504*T*LN(T)-1.8629E-2*T**2
-2.4942E-7*T**3-113945*T**(-1); 388.36 Y
-5285183.35+118449.601*T-19762.4*T*LN(T)+32.79275*T**2
-1.0221416667E-2*T**3+264673500*T**(-1); 428.15 Y
-8174995.226+319914.094*T-57607.3*T*LN(T)+135.3045*T**2
-5.2997333333E-2*T**3; 432.25 Y
-219408.801+7758.85593*T-1371.85*T*LN(T)+2.845035*T**2
-1.013803333E-3*T**3; 453.15 Y
+92539.872-1336.35027*T+202.958*T*LN(T)-0.2531915*T**2
+51.8835E-6*T**3-8202200*T**(-1); 717.00 Y
-6889.972+176.37082*T-32*T*LN(T); 6000.00 N
REF:0 !
FUNCTION GDHCFE
273.00 +0.5*GFEHCP#+0.5*GFEFCC#; 6000.00 N
REF:160 !
FUNCTION GDIG
273.00 +2*GHSERCU#+GHSERSS#-73851.5-97.82124*T+8.1715*T*LN(T); 3000.00 N
REF:82 !
FUNCTION GHFC
273.00 -226447+272.916*T-45.61482*T*LN(T)-.00299726*T**2+501495*T**(-1)
-9.58263E8*T**(-3); 4000.00 N
REF:194 !
FUNCTION GTIC
273.00 -175000+258*T-42.248*T*LN(T)
-0.0044617*T**2+31263*T**(-1)+6.96E+9*T**(-3); 6000.00 N
REF:pov15 !
$ Functions for ordered bcc
FUNCTION B2ALNI
273.00 -152397.88+26.40575*T; 6000.00 N
REF:89 !
FUNCTION LB2ALNI
273.00 -52440.88+11.30117*T; 6000.00 N
REF:89 !
$ Functions for ordered fcc
FUNCTION UALNI
273.00 -22212.8931+4.39570389*T; 6000.00 N
REF:89 !
FUNCTION U1ALNI
273.00 +0.666666667*UALNI#; 6000.00 N
REF:89 !
FUNCTION U3ALNI
273.00 +1e-8; 6000.00 N
REF:89 !
FUNCTION U4ALNI
273.00 +7203.60609-3.74273030*T; 6000.00 N
REF:89 !
FUNCTION L04ALNI
273.00 +U3ALNI#; 6000.00 N
REF:89 !
FUNCTION L14ALNI
273.00 +U4ALNI#; 6000.00 N
REF:89 !
FUNCTION ALNI3
273.00 +3*U1ALNI#; 6000.00 N
REF:89 !
FUNCTION AL2NI2
273.00 +4*U1ALNI#; 6000.00 N
REF:89 !
FUNCTION AL3NI
273.00 +3*U1ALNI#; 6000.00 N
REF:89 !
$
FUNCTION FESIW1
273.00 +10476.27; 6000.00 N
REF:24 !
FUNCTION LFESIB0
273.00 -27809+11.62*T; 6000.00 N
REF:24 !
FUNCTION LFESIB1
273.00 -23088; 6000.00 N
REF:24 !
FUNCTION LFESIB2
273.00 +3890; 6000.00 N
REF:24 !
$
FUNCTION B2NIVA
273.00 +162397.3-27.40575*T; 6000.00 N
REF:244 !
FUNCTION LB2NIVA
273.00 -64024.38+26.49419*T; 6000.00 N
REF:244 !
FUNCTION LF0
273.00 -20455.7462-11.7930695*T; 6000.00 N
REF:244 !
FUNCTION LF1
273.00 +15581.5125-8.49116947*T; 6000.00 N
REF:244 !
FUNCTION GMNNI3
273.00 -21016.3924; 6000.00 N
REF:244 !
FUNCTION GMN2NI2
273.00 -30156.6806; 6000.00 N
REF:244 !
FUNCTION GMN3NI
273.00 -20080.5831; 6000.00 N
REF:244 !
FUNCTION LRMNNI
273.00 -6829.00181; 6000.00 N
REF:244 !
FUNCTION MCEX
273.00 +355000+75*T-6*T*LN(T)+0.005*T**2-1e-005*T**3
+950000*T**(-1); 1000.00 N
REF:pov15 !
$ Oxide functions
FUNCTION GAL2O3
273.00 -1707351.3+448.021092*T-67.4804*T*LN(T)
-0.06747*T**2+1.4205433E-05*T**3+938780*T**(-1); 600.00 Y
-1724886.06+754.856573*T-116.258*T*LN(T)
-0.0072257*T**2+2.78532E-07*T**3+2120700*T**(-1); 1500.00 Y
-1772163.19+1053.4548*T-156.058*T*LN(T)
+0.00709105*T**2-6.29402E-07*T**3+12366650*T**(-1); 6000.00 N
REF:200 !
FUNCTION GCR2O3
273.00 -1164542+728.56*T-119.8*T*LN(T)
-0.00497*T**2+1050000*T**(-1); 6000.00 N
REF:198 !
$
FUNCTION GCR3O4
273.00 +1.5*GCR2O3#-0.5*GHSEROO#+280045-93.76*T; 6000.00 N
REF:198 !
$
FUNCTION GFEO
273.00 -279318+252.848*T-46.12826*T*LN(T)
-0.0057403*T**2; 6000.00 N
REF:199 !
FUNCTION GFE2O3
273.00 -858683+827.946*T-137.0089*T*LN(T)
+1453810*T**(-1); 6000.00 N
REF:221 !
FUNCTION GHF1O2_S
273.00 -1144500+446.1053*T-74.15647*T*LN(T)
-0.00297849*T**2+630000*T**(-1); 6000.00 N
REF:219 !
$
FUNCTION GLA2O3D
273.00 -1833257+692.9664*T-120.629*T*LN(T)
-.006854*T**2+808000*T**(-1)-10000000*T**(-2); 6000.00 N
REF:204 !
$
FUNCTION GLA2O3X
273.00 +43192-18.555*T+GLA2O3D#; 6000.00 N
REF:204 !
$
FUNCTION GLA2O3H
273.00 +32350-13.986*T+GLA2O3D#; 6000.00 N
REF:204 !
$
FUNCTION GNIO
273.00 -254927.2+276.208*T-46.0391*T*LN(T)
-0.00931454*T**2+1.29092E-06*T**3+382916*T**(-1); 1000.00 Y
-256835.2+340.043*T-56.36068*T*LN(T)
+0.00254106*T**2-8.11809E-07*T**3+1270*T**(-1); 1800.00 Y
-259131.4+337.305*T-55.75758*T*LN(T)
+0.00220246*T**2-7.80093E-07*T**3; 6000.00 N
REF:199 !
$
FUNCTION GSIO2
273.00 -900936.64-360.892175*T+61.1323*T*LN(T)
-0.189203605*T**2+4.9509742E-05*T**3-854401*T**(-1); 540.00 Y
273.00 -1091466.54+2882.67275*T-452.1367*T*LN(T)
+0.428883845*T**2-9.09177E-05*T**3+12476689*T**(-1); 770.00 Y
-1563481.44+9178.58655*T-1404.5352*T*LN(T)
+1.28404426*T**2-2.35047657E-04*T**3+56402304*T**(-1); 848.00 Y
-928732.923+356.218325*T-58.4292*T*LN(T)
-0.00515995*T**2-2.47E-10*T**3-95113*T**(-1); 1800.00 Y
-924076.574+281.229013*T-47.451*T*LN(T)
-0.01200315*T**2+6.78127E-7*T**3+665385*T**(-1); 2900.00 Y
-957997.4+544.992084*T-82.709*T*LN(T); 6000.00 N
REF:201 !
$
FUNCTION GTI2O3
273.00 -1543640+185.96227*T-30.3934128*T*LN(T)
-0.099958898*T**2-5.93279345E-06*T**3-117799.056*T**(-1); 470.00 Y
-1585377.8+937.087*T-147.673862*T*LN(T)
-0.00173711312*T**2-1.53383348E-10*T**3+2395423.68*T**(-1); 6000.00 N
REF:203 !
$
FUNCTION GTRID
273.00 -918008.73+140.55925*T-25.1574*T*LN(T)
-0.0148714*T**2-2.2791833E-05*T**3+66331*T**(-1); 388.00 Y
-921013.31+224.53808*T-37.8701*T*LN(T)
-0.02368535*T**2-1.6835E-07*T**3; 433.00 Y
-919633.42+210.51651*T-35.605*T*LN(T)
-0.03049985*T**2+4.6255E-06*T**3-162026*T**(-1); 900.00 Y
-979377.7+848.3098*T-128.434*T*LN(T)
+0.03387055*T**2-3.786883E-06*T**3+7070800*T**(-1); 1668.00 Y
-943685.26+493.58035*T-77.5875*T*LN(T)
+0.003040245*T**2-4.63118E-07*T**3+2227125*T**(-1); 3300.00 Y
-974449.74+587.37585*T-87.373*T*LN(T); 6000.00 N
REF:201 !
$
FUNCTION GY2O3C
273.00 -1984291+763.71851*T-125.692*T*LN(T)-0.00558*T**2
+2344020.5*T**(-1)-1.1730556E+08*T**(-2); 6000.00 N
REF:211 !
$
FUNCTION GY2O3H
273.00 -1959291+754.10313*T-125.692*T*LN(T)-0.00558*T**2
+2344020.5*T**(-1)-1.1730556E+08*T**(-2); 6000.00 N
REF:211 !
$
FUNCTION UNDEF
273.00 +1e-8; 6000.00 N !
$
$***************************************************************************
$***************************************************************************
$
$ D) Thermodynamic model parameters for phases
$
$***************************************************************************
$***************************************************************************
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: LIQUID
$###########################################################################
$
PHASE LIQUID % 1 1.0 > >> 6 !
CONSTITUENT LIQUID : AL,B,C,CO,CR,CU,FE,HF,LA,MN,MO,N,NB,NI,P,PD,S,SI,
TI,V,W,Y : !
$-------------------------------------------------------------------
$ liquid pure elements
$-------------------------------------------------------------------
PARAMETER G(LIQUID,AL;0)
273.00 +11005.029-11.841867*T+7.934E-20*T**7+GHSERAL#; 933.47 Y
+10482.382-11.253974*T+1.231E+28*T**(-9)+GHSERAL#; 2900.00 N
REF:0 !
PARAMETER G(LIQUID,B;0) 273.00 +40723.275+86.843839*T-15.6641*T*LN(T)
-0.006864515*T**2+6.18878E-07*T**3+370843*T**(-1); 500.00 Y
+41119.703+82.101722*T-14.9827763*T*LN(T)
-0.007095669*T**2+5.07347E-07*T**3+335484*T**(-1); 2348.00 Y
+28842.012+200.94731*T-31.4*T*LN(T); 6000.00 N
REF:0 !
PARAMETER G(LIQUID,C;0)
273.00 +117369-24.63*T+GHSERCC#; 6000.00 N
REF:0 !
PARAMETER G(LIQUID,CO;0)
273.00 +15085.037-8.931932*T-2.19801E-21*T**(7)+GHSERCO#; 1768.00 Y
+16351.056-9.683796*T-9.3488E+30*T**(-9)+GHSERCO#; 6000.00 N
REF:73 !
PARAMETER G(LIQUID,CR;0)
273.00 +24339.955-11.420225*T+2.37615E-21*T**7+GHSERCR#; 2180.00 Y
+18409.36-8.563683*T+2.88526E+32*T**(-9)+GHSERCR#; 6000.00 N
REF:0 !
PARAMETER G(LIQUID,CU;0)
273.00 +12964.736-9.511904*T-5.849E-21*T**7+GHSERCU#; 1357.77 Y
+13495.481-9.922344*T-3.642E+29*T**(-9)+GHSERCU#; 3200.00 N
REF:0 !
PARAMETER G(LIQUID,FE;0)
273.00 +12040.17-6.55843*T-3.6751551E-21*T**7+GHSERFE#; 1811.00 Y
-10839.7+291.302*T-46*T*LN(T); 6000.00 N
REF:64 !
PARAMETER G(LIQUID,LA;0)
273.00 +5332.653+18.23012*T-11.0188191*T*LN(T)-0.020171603*T**2
+2.93775E-06*T**3-133541*T**(-1); 1134.00 Y
-3942.004+171.018431*T-34.3088*T*LN(T); 6000.00 N
REF:0 !
PARAMETER G(LIQUID,HF;0)
273.00 +20414.959+99.790933*T-22.7075*T*LN(T)-4.146145E-3*T**2
-0.000477E-6*T**3-22590*T**(-1); 1000.00 Y
+49731.499-149.91739*T+12.116812*T*LN(T)-21.262021E-3*T**2
+1.376466E-6*T**3-4449699*T**(-1); 2506.00 Y
-4247.217+265.470523*T-44*T*LN(T); 6000.00 N
REF:0 !
PARAMETER G(LIQUID,MN;0)
273.00 +17859.91-12.6208*T-4.419297E-21*T**7+GHSERMN#; 1519.00 Y
+18739.51-13.2288*T-1.656847E+30*T**(-9)+GHSERMN#; 6000.00 N
REF:0 !
PARAMETER G(LIQUID,MO;0)
273.00 +41831.347-14.694912*T+4.24519E-22*T**7+GHSERMO#; 2896.00 Y
+34095.373-11.890046*T+4.849315E+33*T**(-9)+GHSERMO#; 5000.00 N
REF:0 !
PARAMETER G(LIQUID,N;0)
273.00 +29950+59.02*T+GHSERNN#; 6000.00 N
REF:0 !
PARAMETER G(LIQUID,NB;0)
273.00 +29781.555-10.816417*T-3.06098E-23*T**7+GHSERNB#; 2750.00 Y
+30169.901-10.964695*T-1.528238E+32*T**(-9)+GHSERNB#; 6000.00 N
REF:0 !
PARAMETER G(LIQUID,NI;0)
273.00 +16414.686-9.397*T-3.82318E-21*T**7+GHSERNI#; 1728.00 Y
+18290.88-10.537*T-1.12754E+31*T**(-9)+GHSERNI#; 6000.00 N
REF:0 !
PARAMETER G(LIQUID,P;0)
273.00 -26316.111+434.930931*T-70.7440584*T*LN(T)
-2.898936E-3*T**2+39.049371E-6*T**3+1141147*T**(-1); 317.30 Y
-7232.449+135.291873*T-26.326*T*LN(T); 3000.00 N
REF:0 !
PARAMETER G(LIQUID,PD;0)
273.00 +1302.731+170.964153*T-32.211*T*LN(T)+0.007120975*T**2
-1.919875E-06*T**3+168687*T**(-1); 600.00 Y
+23405.778-116.918419*T+10.8922031*T*LN(T)-27.266568E-03*T**2
+2.430675E-06*T**3-1853674*T**(-1); 1828.00 Y
-12373.637+251.416903*T-41.17*T*LN(T); 6000.00 N
REF:0 !
PARAMETER G(LIQUID,S;0)
273.00 +GSSLIQ#; 6000.00 N
REF:0 !
PARAMETER G(LIQUID,SI;0)
273.00 +50696.36-30.099439*T+2.0931E-21*T**7+GHSERSI#; 1687.00 Y
+49828.165-29.559068*T+4.2037E+30*T**(-9)+GHSERSI#; 3600.00 N
REF:0 !
PARAMETER G(LIQUID,TI;0)
273.00 +12194.415-6.980938*T+GHSERTI#; 1300.00 Y
+368610.36-2620.9995038*T+357.005867*T*LN(T)
-155.262855E-3*T**2+12.254402E-6*T**3-65556856*T**(-1)+GHSERTI#; 1941.00 Y
+111400-340.070171*T+40.9282461*T*LN(T)
-0.01*T**2+0.304747E-6*T**3-36699805*T**(-1)+GHSERTI#; 4000.00 N
REF:pov14 !
PARAMETER G(LIQUID,V;0)
273.00 +20764.117-9.455552*T-5.19136E-22*T**7+GHSERVV#; 2183.00 Y
+22072.353-10.0848*T-6.4439E+31*T**(-9)+GHSERVV#; 4000.00 N
REF:0 !
PARAMETER G(LIQUID,W;0)
273.00 +52160.584-14.10999*T-2.713468E-24*T**7+GHSERWW#; 3695.00 Y
+52432.75-14.187335*T-1.528621E+33*T**(-9)+GHSERWW#; 6000.00 N
REF:0 !
PARAMETER G(LIQUID,Y;0)
273.00 +3934.121+59.921688*T-14.8146562*T*LN(T)-15.623487E-3*T**2
+1.442946E-6*T**3-140695*T**(-1); 1799.00 Y
-13337.609+258.004539*T-43.0952*T*LN(T); 6000.00 N
REF:0 !
$-------------------------------------------------------------------
$ liquid binary interactions
$-------------------------------------------------------------------
PARAMETER L(LIQUID,AL,C;0) 273.00 +40861.02-33.21138*T; 6000.00 N
REF:155 !
PARAMETER L(LIQUID,AL,CR;0) 273.00 -29000; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,AL,CR;1) 273.00 -11000; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,AL,CU;0) 273.00 -66622+8.1*T; 6000.00 N
REF:107 !
PARAMETER L(LIQUID,AL,CU;1) 273.00 +46800-90.8*T+10*T*LN(T); 6000.00 N
REF:107 !
PARAMETER L(LIQUID,AL,CU;2) 273.00 -2812; 6000.00 N
REF:107 !
PARAMETER L(LIQUID,AL,FE;0) 273.00 -91976.5+22.1314*T; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,AL,FE;1) 273.00 -5672.58+4.8728*T; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,AL,FE;2) 273.00 +121.9; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,AL,HF;0) 273.00 -207000+43*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,AL,HF;1) 273.00 -22600+11*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,AL,HF;2) 273.00 +57000-8*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,AL,MN;0) 273.00 -66174+27.0988*T; 6000.00 N
REF:155 !
PARAMETER L(LIQUID,AL,MN;1) 273.00 -7509+5.4836*T; 6000.00 N
REF:155 !
PARAMETER L(LIQUID,AL,MN;2) 273.00 -2639; 6000.00 N
REF:155 !
PARAMETER L(LIQUID,AL,MO;0) 273.00 -100000+35*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,AL,MO;1) 273.00 -15000+6.3*T; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,AL,N;0) 273.00 -336826.61+103.22478*T; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,AL,NB;0) 273.00 -91000+25*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,AL,NB;1) 273.00 +6000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,AL,NB;2) 273.00 +15000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,AL,NI;0) 273.00 -207109.28+41.31501*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,AL,NI;1) 273.00 -10185.79+5.8714*T; 6000.00 N
REF:89 !
PARAMETER L(LIQUID,AL,NI;2) 273.00 +81204.81-31.95713*T; 6000.00 N
REF:89 !
PARAMETER L(LIQUID,AL,NI;3) 273.00 +4365.35-2.51632*T; 6000.00 N
REF:89 !
PARAMETER L(LIQUID,AL,NI;4) 273.00 -22101.64+13.16341*T; 6000.00 N
REF:89 !
PARAMETER L(LIQUID,AL,P;0) 273.00 +7322-8.368*T; 6000.00 N
REF:234 !
PARAMETER L(LIQUID,AL,SI;0) 273.00 -11655.93-0.92934*T; 6000.00 N
REF:101 !
PARAMETER L(LIQUID,AL,SI;1) 273.00 -2873.45+0.2945*T; 6000.00 N
REF:101 !
PARAMETER L(LIQUID,AL,SI;2) 273.00 +2520; 6000.00 N
REF:101 !
PARAMETER L(LIQUID,AL,SI;3) 273.00 +8698.25-8.57643*T; 6000.00 N
REF:128 !
PARAMETER L(LIQUID,AL,TI;0) 273.00 -118048+41.972*T; 6000.00 N
REF:159 !
PARAMETER L(LIQUID,AL,TI;1) 273.00 -23613+19.704*T; 6000.00 N
REF:159 !
PARAMETER L(LIQUID,AL,TI;2) 273.00 -34757-13.844*T; 6000.00 N
REF:159 !
PARAMETER L(LIQUID,AL,V;0) 273.00 -50725+9*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,AL,V;1) 273.00 -15000+8*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,B,C;1) 273.00 +200000; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,B,CR;0) 273.00 -134482+26.8*T; 6000.00 N
REF:114 !
PARAMETER L(LIQUID,B,CR;1) 273.00 +14347; 6000.00 N
REF:114 !
PARAMETER L(LIQUID,B,CR;2) 273.00 -1674; 6000.00 N
REF:114 !
PARAMETER L(LIQUID,B,CR;3) 273.00 -43361; 6000.00 N
REF:114 !
PARAMETER L(LIQUID,B,CU;0) 273.00 -3156.2; 6000.00 N
REF:227 !
PARAMETER L(LIQUID,B,CU;1) 273.00 +14390.26-9.98*T; 6000.00 N
REF:227 !
PARAMETER L(LIQUID,B,CU;2) 273.00 +42620-20*T; 6000.00 N
REF:227 !
PARAMETER L(LIQUID,B,FE;0) 273.00 -140000+42.834*T; 6000.00 N
REF:192 !
PARAMETER L(LIQUID,B,FE;1) 273.00 -1500; 6000.00 N
REF:192 !
PARAMETER L(LIQUID,B,FE;2) 273.00 +20000; 6000.00 N
REF:192 !
PARAMETER L(LIQUID,B,MN;0) 273.00 -134141.3-15.7142*T; 6000.00 N
REF:245 !
PARAMETER L(LIQUID,B,MN;1) 273.00 +32025.1-21.7659*T; 6000.00 N
REF:245 !
PARAMETER L(LIQUID,B,MN;2) 273.00 +59907.4; 6000.00 N
REF:245 !
PARAMETER L(LIQUID,B,MN;3) 273.00 -8723.6; 6000.00 N
REF:245 !
PARAMETER L(LIQUID,B,MO;0) 273.00 -148828.2+10.9*T; 6000.00 N
REF:118 !
PARAMETER L(LIQUID,B,MO;1) 273.00 -17793.3; 6000.00 N
REF:118 !
PARAMETER L(LIQUID,B,MO;2) 273.00 +21053.3; 6000.00 N
REF:118 !
PARAMETER L(LIQUID,B,N;0) 273.00 +3.0E+04-4.0*T; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,B,NB;0) 273.00 -182227+5.092*T; 6000.00 N
REF:117 !
PARAMETER L(LIQUID,B,NB;1) 273.00 +13667-27.617*T; 6000.00 N
REF:117 !
PARAMETER L(LIQUID,B,NB;2) 273.00 +8815; 6000.00 N
REF:117 !
PARAMETER L(LIQUID,B,NI;0) 273.00 -157542.283+53.0152309*T; 6000.00 N
REF:161 !
PARAMETER L(LIQUID,B,NI;1) 273.00 +63254.0561-21.9049039*T; 6000.00 N
REF:161 !
PARAMETER L(LIQUID,B,NI;2) 273.00 +94942.9034-37.9327311*T; 6000.00 N
REF:161 !
PARAMETER L(LIQUID,B,SI;0) 273.00 -68220.33+41.76042*T; 6000.00 N
REF:190 !
PARAMETER L(LIQUID,B,SI;1) 273.00 +10902.63-11.10014*T; 6000.00 N
REF:190 !
PARAMETER L(LIQUID,B,SI;2) 273.00 +39692.79-17.31724*T; 6000.00 N
REF:190 !
PARAMETER L(LIQUID,B,TI;0) 273.00 -240892+13.510*T; 6000.00 N
REF:117 !
PARAMETER L(LIQUID,B,TI;1) 273.00 -33241-21.867*T; 6000.00 N
REF:117 !
PARAMETER L(LIQUID,B,TI;2) 273.00 +42976+3.875*T; 6000.00 N
REF:117 !
PARAMETER L(LIQUID,B,TI;3) 273.00 +38759; 6000.00 N
REF:117 !
PARAMETER L(LIQUID,B,V;0) 273.00 -210000+40*T; 6000.00 N
REF:235 !
PARAMETER L(LIQUID,B,V;1) 273.00 -20000; 6000.00 N
REF:235 !
PARAMETER L(LIQUID,B,V;2) 273.00 +40000; 6000.00 N
REF:235 !
PARAMETER L(LIQUID,C,CO;0) 273.00 -107940.6+24.956*T; 6000.00 N
REF:73 !
PARAMETER L(LIQUID,C,CO;1) 273.00 -9805.5; 6000.00 N
REF:73 !
PARAMETER L(LIQUID,C,CR;0) 273.00 -90526-25.9116*T; 6000.00 N
REF:11 !
PARAMETER L(LIQUID,C,CR;1) 273.00 +80000; 6000.00 N
REF:11 !
PARAMETER L(LIQUID,C,CR;2) 273.00 +80000; 6000.00 N
REF:11 !
PARAMETER L(LIQUID,C,CU;0) 273.00 +75000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,HF;0) 273.00 -395564+42.9738*T; 6000.00 N
REF:194 !
PARAMETER L(LIQUID,C,HF;1) 273.00 -67417.5; 6000.00 N
REF:194 !
PARAMETER L(LIQUID,C,HF;2) 273.00 +225427-44.5905*T; 6000.00 N
REF:194 !
PARAMETER L(LIQUID,C,HF;3) 273.00 +231368-29.9471*T; 6000.00 N
REF:194 !
PARAMETER G(LIQUID,C,FE;0) 273.00 -123320+28.5*T; 6000 N
REF:293 !
PARAMETER G(LIQUID,C,FE;1) 273.00 +19300; 6000 N
REF14 !
PARAMETER G(LIQUID,C,FE;2) 273.00 +49260-19*T; 6000 N
REF14 !
PARAMETER L(LIQUID,C,MN;0) 273.00 -168240+35.635*T; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,MN;1) 273.00 -91760+50*T; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,MO;0) 273.00 -217800+38.41*T; 6000.00 N
REF:17 !
PARAMETER L(LIQUID,C,MO;1) 273.00 +30000; 6000.00 N
REF:17 !
PARAMETER L(LIQUID,C,MO;2) 273.00 +47000; 6000.00 N
REF:17 !
PARAMETER L(LIQUID,C,N;0) 273.00 +1E-7; 6000.00 N
REF:26 !
$PARAMETER L(LIQUID,C,NB;0) 273.00 -317748+35*T; 6000.00 N
$REF:pov09 !
$PARAMETER L(LIQUID,C,NB;1) 273.00 +1000; 6000.00 N
$REF:pov09 !
$PARAMETER L(LIQUID,C,NB;2) 273.00 +55982; 6000.00 N
$REF:19 !
PARAMETER L(LIQUID,C,NB;0) 273.00 -291000+30*T; 6000.00 N
REF:pov23 !
PARAMETER L(LIQUID,C,NB;1) 273.00 +8000; 6000.00 N
REF:pov23 !
PARAMETER L(LIQUID,C,NB;2) 273.00 +25000; 6000.00 N
REF:pov23 !
PARAMETER L(LIQUID,C,NI;0) 273.00 -111479+35.2685*T; 6000.00 N
REF:11 !
PARAMETER L(LIQUID,C,SI;0) 273.00 -133000+30.97*T; 6000.00 N
REF:24 !
PARAMETER L(LIQUID,C,TI;0) 273.00 -127500-44.4*T; 6000.00 N
REF:pov15 !
PARAMETER L(LIQUID,C,V;0) 273.00 -284196+38.952*T; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,V;1) 273.00 +96335-17.775*T; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,V;2) 273.00 +102050; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,W;0) 273.00 -107920+6.38*T; 6000.00 N
REF:19 !
PARAMETER L(LIQUID,C,W;1) 273.00 +173900-34.25*T; 6000.00 N
REF:19 !
PARAMETER L(LIQUID,C,W;2) 273.00 +83700; 6000.00 N
REF:19 !
PARAMETER L(LIQUID,CO,CR;0) 273.00 -3034-5.624*T; 6000.00 N
REF:73 !
PARAMETER L(LIQUID,CO,CR;1) 273.00 +909; 6000.00 N
REF:73 !
PARAMETER L(LIQUID,CO,CU;0) 273.00 +35200-4.945*T; 6000.00 N
REF:85 !
PARAMETER L(LIQUID,CO,CU;1) 273.00 -1000+0.083*T; 6000.00 N
REF:85 !
PARAMETER L(LIQUID,CO,FE;0) 273.00 -9753.82; 6000.00 N
REF:152 !
PARAMETER L(LIQUID,CO,FE;2) 273.00 +2757.96; 6000.00 N
REF:152 !
PARAMETER L(LIQUID,CO,HF;0) 273.00 -131500; 6000.00 N
REF:195 !
PARAMETER L(LIQUID,CO,MN;0) 273.00 -29476; 6000.00 N
REF:86 !
PARAMETER L(LIQUID,CO,MO;0) 273.00 -68756.05+31.8*T+0.2*T*LN(T); 6000.00 N
REF:77 !
PARAMETER L(LIQUID,CO,MO;1) 273.00 +2184.77+1.5*T; 6000.00 N
REF:77 !
PARAMETER L(LIQUID,CO,N;0) 273.00 -7700; 6000.00 N
REF:135 !
PARAMETER L(LIQUID,CO,NB;0) 273.00 -85028+14.284*T; 6000.00 N
REF:136 !
PARAMETER L(LIQUID,CO,NB;1) 273.00 -9936; 6000.00 N
REF:136 !
PARAMETER L(LIQUID,CO,NI;0) 273.00 +1331; 6000.00 N
REF:79 !
PARAMETER L(LIQUID,CO,V;0) 273.00 -69768.831+29.582*T; 6000.00 N
REF:134 !
PARAMETER L(LIQUID,CO,W;0) 273.00 -57700+22.8*T; 6000.00 N
REF:243 !
PARAMETER L(LIQUID,CO,W;1) 273.00 +2505.9; 6000.00 N
REF:243 !
PARAMETER L(LIQUID,CR,CU;0) 273.00 +83730-105.12*T+10*T*LN(T); 6000.00 N
REF:225 !
PARAMETER L(LIQUID,CR,CU;1) 273.00 -1371.45; 6000.00 N
REF:225 !
PARAMETER L(LIQUID,CR,CU;2) 273.00 -1271.47; 6000.00 N
REF:225 !
PARAMETER G(LIQUID,CR,FE;0) 273.00 -5.257*T; 6000 N
REF:287 !
PARAMETER G(LIQUID,CR,FE;1) 273.00 -5419.8; 6000 N
REF:287 !
PARAMETER L(LIQUID,CR,HF;0) 273.00 -20000; 6000.00 N
REF:196 !
PARAMETER L(LIQUID,CR,HF;1) 273.00 +6000; 6000.00 N
REF:196 !
PARAMETER L(LIQUID,CR,LA;0) 273.00 +39000; 6000.00 N
REF:205 !
PARAMETER L(LIQUID,CR,LA;1) 273.00 +14000; 6000.00 N
REF:205 !
PARAMETER L(LIQUID,CR,LA;2) 273.00 -5000; 6000.00 N
REF:205 !
PARAMETER L(LIQUID,CR,MN;0) 273.00 -15009+13.6587*T; 6000.00 N
REF:22 !
PARAMETER L(LIQUID,CR,MN;1) 273.00 +504+0.9479*T; 6000.00 N
REF:22 !
PARAMETER L(LIQUID,CR,MO;0) 273.00 +15810-6.714*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,CR,MO;1) 273.00 -6220; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,CR,N;0) 273.00 -161800-22.5*T; 6000.00 N
REF:pov12 !
PARAMETER L(LIQUID,CR,N;1) 273.00 +62400; 6000.00 N
REF:pov12 !
PARAMETER L(LIQUID,CR,NB;0) 273.00 -10304.91+0.60618*T; 6000.00 N
REF:45 !
PARAMETER L(LIQUID,CR,NB;1) 273.00 -8513.45+0.50080*T; 6000.00 N
REF:45 !
PARAMETER L(LIQUID,CR,NI;0) 273.00 +318-7.3318*T; 6000.00 N
REF:11 !
PARAMETER L(LIQUID,CR,NI;1) 273.00 +16941-6.3696*T; 6000.00 N
REF:11 !
PARAMETER L(LIQUID,CR,P;0) 273.00 -200000; 6000.00 N
REF:230 !
PARAMETER L(LIQUID,CR,P;1) 273.00 +79000; 6000.00 N
REF:230 !
PARAMETER L(LIQUID,CR,P;2) 273.00 -65000; 6000.00 N
REF:230 !
PARAMETER L(LIQUID,CR,SI;0) 273.00 -119217.90+16.11445*T; 6000.00 N
REF:46 !
PARAMETER L(LIQUID,CR,SI;1) 273.00 -47614.70+12.17363*T; 6000.00 N
REF:46 !
PARAMETER L(LIQUID,CR,TI;0) 273.00 +5250; 6000.00 N
REF:21 !
PARAMETER L(LIQUID,CR,TI;1) 273.00 +1500; 6000.00 N
REF:21 !
PARAMETER L(LIQUID,CR,V;0) 273.00 -9874-2.6964*T; 6000.00 N
REF:68 !
PARAMETER L(LIQUID,CR,V;1) 273.00 -1720-2.5237*T; 6000.00 N
REF:68 !
PARAMETER L(LIQUID,CR,W;0) 273.00 -16800+10*T; 6000.00 N
REF:138 !
PARAMETER L(LIQUID,CR,W;1) 273.00 +9000; 6000.00 N
REF:138 !
PARAMETER L(LIQUID,CR,Y;0) 273.00 +32000; 6000.00 N
REF:205 !
PARAMETER L(LIQUID,CR,Y;1) 273.00 +8500; 6000.00 N
REF:205 !
PARAMETER L(LIQUID,CU,FE;0) 273.00 +74500-143.5*T
+15.82*T*ln(T); 6000.00 N
REF:pov15 !
PARAMETER L(LIQUID,CU,FE;1) 273.00 +8500-6*T; 6000.00 N
REF:pov15 !
PARAMETER L(LIQUID,CU,FE;2) 273.00 +3000; 6000.00 N
REF:pov15 !
PARAMETER L(LIQUID,CU,FE;3) 273.00 -233.62; 6000.00 N
REF:80 !
PARAMETER L(LIQUID,CU,HF;0) 273.00 -61680+11*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,CU,HF;1) 273.00 -8800+5*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,CU,MN;0) 273.00 +1118.55-5.6225*T; 6000.00 N
REF:84 !
PARAMETER L(LIQUID,CU,MN;1) 273.00 -10915.375; 6000.00 N
REF:84 !
PARAMETER L(LIQUID,CU,NB;0) 273.00 +204361.19-89.93141*T; 6000.00 N
REF:44 !
PARAMETER L(LIQUID,CU,NB;1) 273.00 -105148.17+57.81653*T; 6000.00 N
REF:44 !
PARAMETER L(LIQUID,CU,NI;0) 273.00 +11760+1.084*T; 6000.00 N
REF:123 !
PARAMETER L(LIQUID,CU,NI;1) 273.00 -1672; 6000.00 N
REF:123 !
PARAMETER L(LIQUID,CU,S;0) 273.00 +100000-130*T; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,CU,S;1) 273.00 -25000; 6000.00 N
REF:pov15 !
PARAMETER L(LIQUID,CU,S;2) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(LIQUID,CU,SI;0) 273.00 -39688.86+14.27467*T; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,CU,SI;1) 273.00 -49937.13+29.78960*T; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,CU,SI;2) 273.00 -31810.16+18.00804*T; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,CU,V;0) 273.00 +37900; 6000.00 N
REF:131 !
PARAMETER L(LIQUID,CU,V;1) 273.00 +18500; 6000.00 N
REF:131 !
PARAMETER L(LIQUID,FE,HF;0) 273.00 -92100+23*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,FE,HF;1) 273.00 -14700+12*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,FE,HF;2) 273.00 -2700; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,FE,LA;0) 273.00 -41+15.2*T; 6000.00 N
REF:197 !
PARAMETER L(LIQUID,FE,LA;1) 273.00 -7837+4.9*T; 6000.00 N
REF:197 !
PARAMETER L(LIQUID,FE,MN;0) 273.00 -3950+0.489*T; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,FE,MN;1) 273.00 +1145; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,FE,MO;0) 273.00 -6973-0.37*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,MO;1) 273.00 -9424+4.502*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,N;0) 273.00 -19930-12.01*T; 6000.00 N
REF:22 !
$PARAMETER L(LIQUID,FE,NB;0) 273.00 -56553+10.828*T; 6000.00 N
$REF:113 !
$PARAMETER L(LIQUID,FE,NB;1) 273.00 +13400; 6000.00 N
$REF:113 !
PARAMETER L(LIQUID,FE,NB;0) 273.00 -74257+99.67*T-10*T*LN(T);
6000.00 N
REF:262 !
PARAMETER L(LIQUID,FE,NB;1) 273.00 +17624 -10.805*T; 6000 N
REF:262 !
PARAMETER L(LIQUID,FE,NI;0) 273.00 -18378.86+6.03912*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,FE,NI;1) 273.00 +9228.1-3.54642*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,FE,P;0) 273.00 -220300+66.36*T; 6000.00 N
REF:230 !
PARAMETER L(LIQUID,FE,P;1) 273.00 -24904; 6000.00 N
REF:230 !
PARAMETER L(LIQUID,FE,P;2) 273.00 +69825-25.9*T; 6000.00 N
REF:230 !
PARAMETER G(LIQUID,FE,PD;0) 273.00 +10666.2262-45.9291*T; 6000.00 N
REF:242 !
PARAMETER G(LIQUID,FE,PD;1) 273.00 +5171.3739+17.9258*T; 6000.00 N
REF:242 !
PARAMETER L(LIQUID,FE,S;0) 273.00 -105000-49*T; 6000.00 N
REF:jac17 !
PARAMETER L(LIQUID,FE,S;1) 273.00 +204150-21.612*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,S;2) 273.00 -76784+2.415*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,S;3) 273.00 -3376+8.529*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,SI;0) 273.00 -164435+41.977*T; 6000.00 N
REF:25 !
PARAMETER L(LIQUID,FE,SI;1) 273.00 -21.523*T; 6000.00 N
REF:25 !
PARAMETER L(LIQUID,FE,SI;2) 273.00 +5220+5.726*T; 6000.00 N
REF:25 !
PARAMETER L(LIQUID,FE,SI;3) 273.00 -28955+26.275*T; 6000.00 N
REF:25 !
PARAMETER L(LIQUID,FE,TI;0) 273.00 -71347+8.25*T; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,FE,TI;1) 273.00 +7434-4.5*T; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,FE,TI;2) 273.00 +12155+0.25*T; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,FE,V;0) 273.00 -34679+1.895*T; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,FE,V;1) 273.00 +10209; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,FE,W;0) 273.00 -3607+5.65*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,FE,W;1) 273.00 -5450; 6000.00 N
REF:79 !
PARAMETER L(LIQUID,FE,Y;0) 273.00 -35000-0.25*T; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,FE,Y;1) 273.00 -20*T; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,FE,Y;2) 273.00 -10*T; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,HF,MO;0) 273.00 -23413-2.27*T; 6000.00 N
REF:215 !
PARAMETER L(LIQUID,HF,MO;1) 273.00 +46500-28*T; 6000.00 N
REF:215 !
PARAMETER L(LIQUID,HF,MO;2) 273.00 -0.5*T; 6000.00 N
REF:215 !
PARAMETER L(LIQUID,HF,NB;0) 273.00 +25391.87; 6000.00 N
REF:216 !
PARAMETER L(LIQUID,HF,NB;1) 273.00 +10123.61; 6000.00 N
REF:216 !
PARAMETER L(LIQUID,HF,NI;0) 273.00 -200000+14*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,HF,NI;1) 273.00 -40000+2*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,HF,NI;2) 273.00 +20000-9*T; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,HF,TI;0) 273.00 -4993.5-7.10316*T; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,HF,W;0) 273.00 -21247.1+4*T; 6000.00 N
REF:215 !
PARAMETER L(LIQUID,HF,W;1) 273.00 -6000; 6000.00 N
REF:215 !
PARAMETER L(LIQUID,LA,NI;0) 273.00 -116299+19.815*T; 6000.00 N
REF:222 !
PARAMETER L(LIQUID,LA,NI;1) 273.00 +63813-40.941*T; 6000.00 N
REF:222 !
PARAMETER L(LIQUID,MN,MO;0) 273.00 -14000; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,MN,MO;1) 273.00 +9000; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,MN,N;0) 273.00 -142308+6.0759*T; 6000.00 N
REF:22 !
PARAMETER L(LIQUID,MN,N;1) 273.00 +32906; 6000.00 N
REF:22 !
PARAMETER L(LIQUID,MN,NI;0) 273.00 -44423.1238-2.353*T; 6000.00 N
REF:244 !
PARAMETER L(LIQUID,MN,NI;1) 273.00 +11941.36-6.8522*T; 6000.00 N
REF:244 !
PARAMETER L(LIQUID,MN,PD;0) 273.00 -30000-23*T; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,MN,PD;1) 273.00 -10000; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,MN,PD;2) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,MN,SI;0) 273.00 -139817+29.861*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,MN,SI;1) 273.00 -34917+3.205*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,MN,SI;2) 273.00 +46782-18.19*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,MN,SI;3) 273.00 +16168; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,MN,TI;0) 273.00 -34000+21.5*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,MN,TI;1) 273.00 +1400; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,MN,V;0) 273.00 -11399; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,MO,N;0) 273.00 -198280+37.49*T; 6000.00 N
REF:47 !
PARAMETER L(LIQUID,MO,NB;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,MO,NI;0) 273.00 -46540+19.53*T; 6000.00 N
REF:39 !
PARAMETER L(LIQUID,MO,NI;1) 273.00 +2915; 6000.00 N
REF:39 !
PARAMETER L(LIQUID,MO,SI;0) 273.00 -146600+16.5*T; 6000.00 N
REF:132 !
PARAMETER L(LIQUID,MO,SI;1) 273.00 +7100-3*T; 6000.00 N
REF:132 !
PARAMETER L(LIQUID,MO,SI;2) 273.00 +8000+12*T; 6000.00 N
REF:132 !
PARAMETER L(LIQUID,MO,TI;0) 273.00 -17494.7-3.57111*T; 6000.00 N
REF:125 !
PARAMETER L(LIQUID,MO,TI;1) 273.00 -463.9+9.0476*T; 6000.00 N
REF:125 !
PARAMETER L(LIQUID,MO,V;0) 273.00 +17784; 6000.00 N
REF:38 !
PARAMETER L(LIQUID,N,NB;0) 273.00 -292101; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,N,NB;1) 273.00 -105406; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,N,NI;0) 273.00 +14981; 6000.00 N
REF:67 !
PARAMETER L(LIQUID,N,SI;0) 273.00 -87631.311+22.359*T; 6000.00 N
REF:158 !
PARAMETER L(LIQUID,N,TI;0) 273.00 -376354; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,N,TI;1) 273.00 -98242; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,N,V;0) 273.00 -239000; 6000.00 N
REF:48 !
PARAMETER L(LIQUID,N,V;1) 273.00 -8380; 6000.00 N
REF:48 !
PARAMETER L(LIQUID,N,W;0) 273.00 -120000; 6000.00 N
REF:140 !
PARAMETER L(LIQUID,NB,NI;0) 273.00 -80037.3-6.31498*T; 6000.00 N
REF:54 !
PARAMETER L(LIQUID,NB,NI;1) 273.00 +97884.9-19.01069*T; 6000.00 N
REF:54 !
PARAMETER L(LIQUID,NB,NI;2) 273.00 +13500; 6000.00 N
REF:pov12 !
PARAMETER L(LIQUID,NB,P;0) 273.00 -350000+20*T; 6000.00 N
REF:232 !
PARAMETER L(LIQUID,NB,P;1) 273.00 +70000; 6000.00 N
REF:232 !
PARAMETER L(LIQUID,NB,SI;0) 273.00 -197000+17*T; 6000.00 N
REF:128 !
PARAMETER L(LIQUID,NB,SI;1) 273.00 -17000; 6000.00 N
REF:128 !
PARAMETER L(LIQUID,NB,SI;2) 273.00 +34000; 6000.00 N
REF:128 !
PARAMETER L(LIQUID,NB,TI;0) 273.00 +8500; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,NB,V;0) 273.00 +1e-7; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,NB,W;0) 273.00 -34043+3.603*T; 6000.00 N
REF:19 !
PARAMETER L(LIQUID,NB,Y;0) 273.00 +188000-61.3*T; 6000.00 N
REF:213 !
PARAMETER L(LIQUID,NB,Y;1) 273.00 +39500; 6000.00 N
REF:213 !
PARAMETER L(LIQUID,NI,P;0) 273.00 -381589+79.1144*T; 6000.00 N
REF:231 !
PARAMETER L(LIQUID,NI,P;1) 273.00 +104201.3-90.7228*T; 6000.00 N
REF:231 !
PARAMETER L(LIQUID,NI,P;2) 273.00 +78364.1; 6000.00 N
REF:231 !
PARAMETER L(LIQUID,NI,S;0) 273.00 -108895-24.526*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,NI,S;1) 273.00 +48062+25.687*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,NI,S;2) 273.00 -59106+15.353*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,NI,SI;0) 273.00 -208402.55+27.13099*T; 6000.00 N
REF:193 !
PARAMETER L(LIQUID,NI,SI;1) 273.00 -121913.4+18.80198*T; 6000.00 N
REF:193 !
PARAMETER L(LIQUID,NI,SI;3) 273.00 +145580.2-69.55691*T; 6000.00 N
REF:193 !
PARAMETER L(LIQUID,NI,TI;0) 273.00 -155117+39.058*T; 6000.00 N
REF:253 !
PARAMETER L(LIQUID,NI,TI;1) 273.00 -83164+31.448*T; 6000.00 N
REF:253 !
PARAMETER L(LIQUID,NI,TI;2) 273.00 -6.349*T; 6000.00 N
REF:253 !
PARAMETER L(LIQUID,NI,V;0) 273.00 -68170; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,NI,V;1) 273.00 +5000; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,NI,W;0) 273.00 +16290-10.25*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,NI,W;1) 273.00 -22450; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,NI,Y;0) 273.00 -155496+38.932*T; 6000.00 N
REF:213 !
PARAMETER L(LIQUID,NI,Y;1) 273.00 -52904+6.785*T; 6000.00 N
REF:213 !
PARAMETER L(LIQUID,P,TI;0) 273.00 -276200+50.25*T; 6000.00 N
REF:233 !
PARAMETER L(LIQUID,P,TI;1) 273.00 -12950+17.57*T; 6000.00 N
REF:233 !
PARAMETER L(LIQUID,P,TI;2) 273.00 -11100+18*T; 6000.00 N
REF:233 !
PARAMETER L(LIQUID,SI,TI;0) 273.00 -244329.45+29.01807*T; 6000.00 N
REF:191 !
PARAMETER L(LIQUID,SI,TI;1) 273.00 +69588.28-32.30618*T; 6000.00 N
REF:191 !
PARAMETER L(LIQUID,SI,TI;2) 273.00 +53629.71; 6000.00 N
REF:191 !
PARAMETER L(LIQUID,SI,V;0) 273.00 -190326.8+44.06262*T; 6000.00 N
REF:129 !
PARAMETER L(LIQUID,SI,V;1) 273.00 +6265.4; 6000.00 N
REF:129 !
PARAMETER L(LIQUID,SI,V;2) 273.00 +39546.5; 6000.00 N
REF:129 !
PARAMETER L(LIQUID,TI,V;0) 273.00 +1400; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,TI,V;1) 273.00 +4100; 6000.00 N
REF:12 !
$-------------------------------------------------------------------
$ liquid ternary interactions
$-------------------------------------------------------------------
PARAMETER L(LIQUID,AL,B,TI;0) 273.00 +422100-188.6*T; 6000.00 N
REF:160 !
PARAMETER L(LIQUID,AL,B,TI;1) 273.00 +243800; 6000.00 N
REF:160 !
PARAMETER L(LIQUID,AL,B,TI;2) 273.00 -171815; 6000.00 N
REF:160 !
PARAMETER L(LIQUID,AL,C,FE;0) 273.00 -49000; 6000.00 N
REF:155 !
PARAMETER L(LIQUID,AL,CR,NI;0) 273.00 +16000; 6000.00 N
REF:91 !
PARAMETER L(LIQUID,AL,CU,SI;0) 273.00 +129758.274-152.551977*T; 6000.00 N
REF:147 !
PARAMETER L(LIQUID,AL,CU,SI;1) 273.00 +154448.454-8.5615*T; 6000.00 N
REF:147 !
PARAMETER L(LIQUID,AL,CU,SI;2) 273.00 -88726.6292+40*T; 6000.00 N
REF:147 !
PARAMETER L(LIQUID,AL,FE,NI;0) 273.00 -306100+180*T; 6000.00 N
REF:95 !
PARAMETER L(LIQUID,AL,FE,NI;1) 273.00 +416900-120*T; 6000.00 N
REF:95 !
PARAMETER L(LIQUID,AL,FE,NI;2) 273.00 +14790-6.7*T; 6000.00 N
REF:95 !
PARAMETER L(LIQUID,AL,FE,SI;0) 273.00 -1866.9-0.17024*T; 6000.00 N
REF:100 !
PARAMETER L(LIQUID,AL,FE,SI;1) 273.00 -343716.1+2.53085*T; 6000.00 N
REF:100 !
PARAMETER L(LIQUID,AL,FE,SI;2) 273.00 +106280.7-1.28055*T; 6000.00 N
REF:100 !
PARAMETER L(LIQUID,AL,HF,NI;0) 273.00 +100000; 6000.00 N
REF:217 !
PARAMETER L(LIQUID,AL,MN,SI;0) 273.00 -72818; 6000.00 N
REF:149 !
PARAMETER L(LIQUID,AL,MN,SI;1) 273.00 -16967; 6000.00 N
REF:149 !
PARAMETER L(LIQUID,AL,MN,SI;2) 273.00 -55992; 6000.00 N
REF:149 !
PARAMETER L(LIQUID,AL,NI,SI;0) 273.00 +133699.59; 6000.00 N
REF:93 !
PARAMETER L(LIQUID,AL,NI,SI;1) 273.00 +102978.23; 6000.00 N
REF:93 !
PARAMETER L(LIQUID,AL,NI,SI;2) 273.00 +33204.48; 6000.00 N
REF:93 !
PARAMETER L(LIQUID,B,C,FE;0) 273.00 -200000; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,B,C,FE;1) 273.00 +200000; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,B,C,FE;2) 273.00 -200000; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,B,C,HF;0) 273.00 +133208; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,B,C,HF;1) 273.00 +39102.9; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,B,C,HF;2) 273.00 -313626; 6000.00 N
REF:92 !
PARAMETER L(LIQUID,B,CR,FE;0) 273.00 -70000; 6000.00 N
REF:145 !
PARAMETER L(LIQUID,B,CR,FE;1) 273.00 -30000; 6000.00 N
REF:145 !
PARAMETER L(LIQUID,B,CR,FE;2) 273.00 +120000; 6000.00 N
REF:145 !
PARAMETER L(LIQUID,B,CR,NI;0) 273.00 -5312-89.2*T; 6000.00 N
REF:114 !
PARAMETER L(LIQUID,B,CR,NI;1) 273.00 +3520.3; 6000.00 N
REF:114 !
PARAMETER L(LIQUID,B,CR,NI;2) 273.00 +246657; 6000.00 N
REF:114 !
PARAMETER L(LIQUID,B,FE,NB;0) 273.00 +1e-8; 6000.00 N
REF:146 !
PARAMETER L(LIQUID,B,FE,NB;1) 273.00 -300000; 6000.00 N
REF:146 !
PARAMETER L(LIQUID,B,FE,NB;2) 273.00 +1e-8; 6000.00 N
REF:146 !
PARAMETER L(LIQUID,B,FE,NI;0) 273.00 +56000-20*T; 6000.00 N
REF:192 !
PARAMETER L(LIQUID,B,FE,NI;1) 273.00 -40000; 6000.00 N
REF:192 !
PARAMETER L(LIQUID,B,FE,NI;2) 273.00 +1e-8; 6000.00 N
REF:192 !
PARAMETER L(LIQUID,B,NI,SI;0) 273.00 +50000; 6000.00 N
REF:190 !
PARAMETER L(LIQUID,B,NI,SI;1) 273.00 -80000; 6000.00 N
REF:190 !
PARAMETER L(LIQUID,B,NI,SI;2) 273.00 +50000; 6000.00 N
REF:190 !
PARAMETER L(LIQUID,C,CO,CR;0) 273.00 -302180; 6000.00 N
REF:73 !
PARAMETER L(LIQUID,C,CO,CR;1) 273.00 +35575; 6000.00 N
REF:73 !
PARAMETER L(LIQUID,C,CO,CR;2) 273.00 +35575; 6000.00 N
REF:73 !
PARAMETER L(LIQUID,C,CO,FE;0) 273.00 +11646-5.657*T; 6000.00 N
REF:75 !
PARAMETER L(LIQUID,C,CO,NI;0) 273.00 +50462-27.562*T; 6000.00 N
REF:76 !
PARAMETER L(LIQUID,C,CO,W;0) 273.00 +12770-22.9*T; 6000.00 N
REF:243 !
PARAMETER L(LIQUID,C,CR,FE;0) 273.00 -514037; 6000.00 N
REF:58 !
PARAMETER L(LIQUID,C,CR,FE;1) 273.00 +73286; 6000.00 N
REF:58 !
PARAMETER L(LIQUID,C,CR,FE;2) 273.00 +66921; 6000.00 N
REF:58 !
PARAMETER L(LIQUID,C,CR,MN;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,CR,MO;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,CR,NI;0) 273.00 +1E-7; 6000.00 N
REF:11 !
PARAMETER L(LIQUID,C,CR,TI;0) 273.00 -543844; 6000.00 N
REF:21 !
PARAMETER L(LIQUID,C,CR,TI;1) 273.00 -165916; 6000.00 N
REF:21 !
PARAMETER L(LIQUID,C,CR,TI;2) 273.00 +1e-8; 6000.00 N
REF:21 !
PARAMETER L(LIQUID,C,CR,V;0) 273.00 -769497; 6000.00 N
REF:52 !
PARAMETER L(LIQUID,C,CR,V;1) 273.00 +263981; 6000.00 N
REF:52 !
PARAMETER L(LIQUID,C,CR,V;2) 273.00 +3599; 6000.00 N
REF:52 !
PARAMETER L(LIQUID,C,CU,FE;0) 273.00 -76019; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,FE,MN;0) 273.00 -45675; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,FE,MN;1) 273.00 -12379; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,FE,MN;2) 273.00 -12379; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,FE,MO;0) 273.00 -37800; 6000.00 N
REF:27 !
PARAMETER L(LIQUID,C,FE,N;0) 273.00 +490996-109.135*T; 6000.00 N
REF:26 !
PARAMETER L(LIQUID,C,FE,N;1) 273.00 +192167-109.135*T; 6000.00 N
REF:26 !
PARAMETER L(LIQUID,C,FE,N;2) 273.00 +490996-109.135*T; 6000.00 N
REF:26 !
PARAMETER L(LIQUID,C,FE,NB;0) 273.00 -40000; 6000.00 N
REF:113 !
PARAMETER L(LIQUID,C,FE,NI;0) 273.00 +122200-58.8*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,C,FE,NI;1) 273.00 +92200-58.8*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,C,FE,NI;2) 273.00 +152200-58.8*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,C,FE,P;0) 273.00 -4100.5; 6000.00 N
REF:229 !
PARAMETER L(LIQUID,C,FE,P;1) 273.00 -251801.8+144.9988*T; 6000.00 N
REF:229 !
PARAMETER L(LIQUID,C,FE,P;2) 273.00 +5200.5; 6000.00 N
REF:229 !
PARAMETER L(LIQUID,C,FE,S;0) 273.00 +330000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,FE,S;1) 273.00 +160000-100*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,FE,S;2) 273.00 +330000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,FE,SI;0) 273.00 +400000; 6000.00 N
REF:25 !
PARAMETER L(LIQUID,C,FE,SI;1) 273.00 -55000; 6000.00 N
REF:25 !
PARAMETER L(LIQUID,C,FE,SI;2) 273.00 +450000; 6000.00 N
REF:25 !
$PARAMETER L(LIQUID,C,FE,TI;0) 273.00 -140000; 6000.00 N
$REF:16 !
PARAMETER L(LIQUID,C,FE,TI;0) 273.00 -255000; 6000.00 N
REF:jac24 !
PARAMETER L(LIQUID,C,FE,V;0) 273.00 -60000; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,FE,V;1) 273.00 -60000; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,FE,V;2) 273.00 +100000; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,FE,W;0) 273.00 -60600-71*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,C,FE,W;1) 273.00 +6400-71*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,C,FE,W;2) 273.00 +73400-71*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,C,HF,MO;0) 273.00 +5000; 6000.00 N
REF:pov10 !
PARAMETER L(LIQUID,C,HF,MO;1) 273.00 -5000; 6000.00 N
REF:pov10 !
PARAMETER L(LIQUID,C,HF,MO;2) 273.00 +5000; 6000.00 N
REF:pov10 !
PARAMETER L(LIQUID,C,MN,V;0) 273.00 +1E-7; 6000.00 N
REF:15 !
PARAMETER L(LIQUID,C,MO,TI;0) 273.00 -402258.4; 6000.00 N
REF:125 !
PARAMETER L(LIQUID,C,MO,TI;1) 273.00 -40675.2; 6000.00 N
REF:125 !
PARAMETER L(LIQUID,C,MO,TI;2) 273.00 +24292.1; 6000.00 N
REF:125 !
PARAMETER L(LIQUID,C,MO,V;0) 273.00 +120000; 6000.00 N
REF:38 !
PARAMETER L(LIQUID,C,NB,TI;0) 273.00 +140812; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,C,NB,W;0) 273.00 -195015; 6000.00 N
REF:19 !
PARAMETER L(LIQUID,C,NB,W;1) 273.00 +60769; 6000.00 N
REF:19 !
PARAMETER L(LIQUID,C,NB,W;2) 273.00 +176422; 6000.00 N
REF:19 !
PARAMETER L(LIQUID,C,NI,W;0) 273.00 +1100000-300*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,C,NI,W;1) 273.00 -235500; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,C,NI,W;2) 273.00 +480000-150*T; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,CO,CU,FE;0) 273.00 +22000; 6000.00 N
REF:228 !
PARAMETER L(LIQUID,CO,CU,FE;1) 273.00 -32000; 6000.00 N
REF:228 !
PARAMETER L(LIQUID,CO,CU,FE;2) 273.00 -1500; 6000.00 N
REF:228 !
PARAMETER L(LIQUID,CO,CU,MN;0) 273.00 -14000; 6000.00 N
REF:87 !
PARAMETER L(LIQUID,CO,CU,MN;1) 273.00 +41625-42.5*T; 6000.00 N
REF:87 !
PARAMETER L(LIQUID,CO,CU,MN;2) 273.00 -29000; 6000.00 N
REF:87 !
PARAMETER L(LIQUID,CO,FE,MO;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,CO,FE,MO;1) 273.00 -60000; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,CO,FE,MO;2) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,CO,FE,W;0) 273.00 +1E-7; 6000.00 N
REF:79 !
PARAMETER L(LIQUID,CO,FE,W;1) 273.00 +11287; 6000.00 N
REF:79 !
PARAMETER L(LIQUID,CO,FE,W;2) 273.00 +1E-7; 6000.00 N
REF:79 !
PARAMETER L(LIQUID,CO,NI,W;0) 273.00 -77000; 6000.00 N
REF:79 !
PARAMETER L(LIQUID,CO,NI,W;1) 273.00 -67282; 6000.00 N
REF:79 !
PARAMETER L(LIQUID,CO,NI,W;2) 273.00 +1E-7; 6000.00 N
REF:79 !
PARAMETER L(LIQUID,CR,CU,FE;0) 273.00 -115799+61.673*T; 6000.00 N
REF:225 !
PARAMETER L(LIQUID,CR,CU,FE;1) 273.00 -89317+55.011*T; 6000.00 N
REF:225 !
PARAMETER L(LIQUID,CR,CU,FE;2) 273.00 +30000; 6000.00 N
REF:pov15 !
PARAMETER L(LIQUID,CR,CU,NB;0) 273.00 +5000; 6000.00 N
REF:130 !
PARAMETER L(LIQUID,CR,CU,NB;1) 273.00 +50000; 6000.00 N
REF:130 !
PARAMETER L(LIQUID,CR,CU,NB;2) 273.00 +5000; 6000.00 N
REF:130 !
PARAMETER L(LIQUID,CR,CU,NI;0) 273.00 +50000; 6000.00 N
REF:pov15 !
PARAMETER L(LIQUID,CR,FE,MN;0) 273.00 +2378; 6000.00 N
REF:22 !
PARAMETER L(LIQUID,CR,FE,N;0) 273.00 -127121+68.6*T; 6000.00 N
REF:22 !
PARAMETER L(LIQUID,CR,FE,NB;0) 273.00 -10000; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,CR,FE,NI;0) 273.00 +140000-50*T; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,CR,FE,NI;1) 273.00 +5000-12*T; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,CR,FE,NI;2) 273.00 +75000; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,CR,FE,P;0) 273.00 +80000; 6000.00 N
REF:230 !
PARAMETER L(LIQUID,CR,FE,P;1) 273.00 +80000; 6000.00 N
REF:230 !
PARAMETER L(LIQUID,CR,FE,P;2) 273.00 -350000; 6000.00 N
REF:230 !
PARAMETER L(LIQUID,CR,FE,S;0) 273.00 -420000+100*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,CR,FE,S;1) 273.00 -230000+100*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,CR,FE,S;2) 273.00 -420000+100*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,CR,FE,SI;0) 273.00 +60000-50*T; 6000.00 N
REF:28 !
PARAMETER L(LIQUID,CR,FE,TI;0) 273.00 -90000; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,CR,FE,TI;1) 273.00 +70000; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,CR,FE,TI;2) 273.00 -90000; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,CR,FE,V;0) 273.00 +14881; 6000.00 N
REF:52 !
PARAMETER L(LIQUID,CR,FE,V;1) 273.00 +17968; 6000.00 N
REF:52 !
PARAMETER L(LIQUID,CR,FE,V;2) 273.00 -7692; 6000.00 N
REF:52 !
PARAMETER L(LIQUID,CR,MN,N;0) 273.00 +86690; 6000.00 N
REF:22 !
PARAMETER L(LIQUID,CR,MO,NI;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,CR,N,NI;0) 273.00 -89400; 6000.00 N
REF:36 !
PARAMETER L(LIQUID,CR,NB,NI;0) 273.00 -59943; 6000.00 N
REF:237 !
PARAMETER L(LIQUID,CR,NB,NI;1) 273.00 -220439; 6000.00 N
REF:237 !
PARAMETER L(LIQUID,CR,NB,NI;2) 273.00 -14828; 6000.00 N
REF:237 !
PARAMETER L(LIQUID,CR,NI,W;0) 273.00 +41500; 6000.00 N
REF:138 !
PARAMETER L(LIQUID,CU,FE,MN;0) 273.00 +241298-140*T; 6000.00 N
REF:87 !
PARAMETER L(LIQUID,CU,FE,MN;1) 273.00 +82096-40*T; 6000.00 N
REF:87 !
PARAMETER L(LIQUID,CU,FE,MN;2) 273.00 +25901.5-20*T; 6000.00 N
REF:87 !
PARAMETER L(LIQUID,CU,FE,N;0) 273.00 +27927; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,CU,FE,NI;0) 273.00 -68786+30.9*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,CU,FE,S;0) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,CU,FE,SI;0) 273.00 +23000-19.5*T; 6000.00 N
REF:228 !
PARAMETER L(LIQUID,CU,FE,SI;1) 273.00 +50000-19.5*T; 6000.00 N
REF:228 !
PARAMETER L(LIQUID,CU,FE,SI;2) 273.00 +23000-19.5*T; 6000.00 N
REF:228 !
PARAMETER L(LIQUID,CU,FE,V;0) 273.00 -85000; 6000.00 N
REF:228 !
PARAMETER L(LIQUID,CU,FE,V;1) 273.00 +5000; 6000.00 N
REF:228 !
PARAMETER L(LIQUID,CU,FE,V;2) 273.00 -80000; 6000.00 N
REF:228 !
PARAMETER L(LIQUID,CU,HF,TI;0) 273.00 +24000; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,CU,HF,TI;1) 273.00 -29000; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,CU,HF,TI;2) 273.00 +24000; 6000.00 N
REF:pov11 !
PARAMETER L(LIQUID,CU,MN,NI;0) 273.00 -42780; 6000.00 N
REF:244 !
PARAMETER L(LIQUID,CU,MN,NI;1) 273.00 -67310; 6000.00 N
REF:244 !
PARAMETER L(LIQUID,CU,MN,NI;2) 273.00 -56060; 6000.00 N
REF:244 !
PARAMETER L(LIQUID,FE,MN,MO;0) 273.00 +75000; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,FE,MN,N;0) 273.00 -15211+18.43*T; 6000.00 N
REF:22 !
PARAMETER L(LIQUID,FE,MN,NI;0) 273.00 +1E-7; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,FE,MN,PD;0) 273.00 -30000; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,FE,MN,PD;1) 273.00 -150000; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,FE,MN,PD;2) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(LIQUID,FE,MN,S;0) 273.00 -280000+100*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,MN,S;1) 273.00 -700000+100*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,MN,S;2) 273.00 -700000+100*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,MN,SI;0) 273.00 -180473; 6000.00 N
REF:53 !
PARAMETER L(LIQUID,FE,MN,SI;1) 273.00 -95027; 6000.00 N
REF:53 !
PARAMETER L(LIQUID,FE,MN,SI;2) 273.00 +180386; 6000.00 N
REF:293 !
PARAMETER L(LIQUID,FE,MN,V;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,MO,N;0) 273.00 +1E-7; 6000.00 N
REF:40 !
PARAMETER L(LIQUID,FE,MO,NI;0) 273.00 +50000; 6000.00 N
REF:41 !
PARAMETER L(LIQUID,FE,MO,S;0) 273.00 -33000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,MO,SI;0) 273.00 +110000; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,FE,N,NB;0) 273.00 -160000; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,FE,N,S;0) 273.00 -46238; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,N,SI;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,N,TI;0) 273.00 -300000; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,FE,N,V;0) 273.00 -228000; 6000.00 N
REF:32 !
PARAMETER L(LIQUID,FE,N,V;1) 273.00 +3600000; 6000.00 N
REF:32 !
PARAMETER L(LIQUID,FE,N,V;2) 273.00 +104000; 6000.00 N
REF:32 !
PARAMETER L(LIQUID,FE,NB,N;0) 273.00 -160000; 6000.00 N
REF:16 !
PARAMETER L(LIQUID,FE,NB,NI;0) 273.00 +1e-8; 6000.00 N
REF:54 !
PARAMETER L(LIQUID,FE,NB,P;0) 273.00 +100000; 6000.00 N
REF:232 !
PARAMETER L(LIQUID,FE,NB,P;1) 273.00 +100000; 6000.00 N
REF:232 !
PARAMETER L(LIQUID,FE,NB,P;2) 273.00 +1e-8; 6000.00 N
REF:232 !
PARAMETER L(LIQUID,FE,NB,S;0) 273.00 -150000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,NI,P;0) 273.00 +350000; 6000.00 N
REF:pov12 !
PARAMETER L(LIQUID,FE,NI,S;0) 273.00 +102295+16.742*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,NI,S;1) 273.00 +139946+6.226*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,NI,S;2) 273.00 +103422+115.12*T; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,NI,SI;0) 273.00 +100000-10*T; 6000.00 N
REF:293 !
PARAMETER L(LIQUID,FE,NI,SI;1) 273.00 +220000-10*T; 6000.00 N
REF:293 !
PARAMETER L(LIQUID,FE,NI,SI;2) 273.00 -185000-10*T; 6000.00 N
REF:28 !
PARAMETER L(LIQUID,FE,NI,TI;0) 273.00 -20000; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,FE,NI,TI;1) 273.00 -10000; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,FE,NI,TI;2) 273.00 -90000; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,FE,NI,V;0) 273.00 +1E-7; 6000.00 N
REF:23 !
PARAMETER L(LIQUID,FE,NI,W;0) 273.00 +14621; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,FE,NI,W;1) 273.00 +64236; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,FE,NI,W;2) 273.00 -84842; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,FE,S,SI;0) 273.00 +20000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,S,SI;1) 273.00 +350000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,S,SI;2) 273.00 +350000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,S,TI;0) 273.00 -750000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,S,V;0) 273.00 -120000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,MN,NI,SI;0) 273.00 +1e-8; 6000.00 N
REF:254 !
PARAMETER L(LIQUID,MN,NI,SI;1) 273.00 -120000; 6000.00 N
REF:254 !
PARAMETER L(LIQUID,MN,NI,SI;2) 273.00 -55000; 6000.00 N
REF:254 !
PARAMETER L(LIQUID,NB,NI,Y;0) 273.00 +33700; 6000.00 N
REF:213 !
PARAMETER L(LIQUID,NB,NI,Y;1) 273.00 -22800; 6000.00 N
REF:213 !
PARAMETER L(LIQUID,NB,NI,Y;2) 273.00 +184350; 6000.00 N
REF:213 !
PARAMETER L(LIQUID,NI,SI,TI;0) 273.00 +70000; 6000.00 N
REF:191 !
PARAMETER L(LIQUID,NI,SI,TI;1) 273.00 -60000; 6000.00 N
REF:191 !
PARAMETER L(LIQUID,NI,SI,TI;2) 273.00 +70000; 6000.00 N
REF:191 !
$-------------------------------------------------------------------
$ liquid quaternary liquid
$-------------------------------------------------------------------
PARAMETER L(LIQUID,AL,C,FE,S;0) 273.00 +600000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,CO,NI,W;0) 273.00 -785000; 6000.00 N
REF:79 !
PARAMETER L(LIQUID,C,CR,FE,MN;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,CR,FE,MO;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,CR,FE,NI;0) 273.00 +300000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,CR,FE,V;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,C,FE,NI,W;0) 273.00 -400825; 6000.00 N
REF:20 !
PARAMETER L(LIQUID,CR,FE,MN,N;0) 273.00 -169200; 6000.00 N
REF:22 !
PARAMETER L(LIQUID,CR,FE,MO,N;0) 273.00 +300000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,CR,FE,N,NI;0) 273.00 -261500; 6000.00 N
REF:36 !
PARAMETER L(LIQUID,CR,FE,N,SI;0) 273.00 -500000; 6000.00 N
REF:pov13 !
PARAMETER L(LIQUID,C,FE,S,SI;0) 273.00 +200000; 6000.00 N
REF:12 !
PARAMETER L(LIQUID,FE,MN,S,SI;0) 273.00 +300000; 6000.00 N
REF:12 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: FCC_A1
$###########################################################################
$
TYPE_DEFINITION ' GES A_P_D FCC_A1 MAGNETIC -3.0 0.28 !
PHASE FCC_A1 %' 2 1 1 >
Face-centered cubic Austenite phase with Va on interstitial sublattice;
V- and/or W-rich MC carbo-nitride phase is denoted "fcc_A1#01"
in the MatCalc databases, with C and N on substitutional sublattice.
MC carbo-nitride composition sets can be defined by the user
(syntax see top of database). Typically MC is precipitating
on dislocations and/or lath boundaries.
MC is an important hardening phase in many types of steel.
>> 6 !
CONSTITUENT FCC_A1 : AL,CO,CR,CU,FE%,HF,LA,MN,MO,NB,NI,P,PD,S,SI,TI,V,
W,Y : B,C,H,N,O,VA% : !
$-------------------------------------------------------------------
$ FCC_A1 endmember compounds with VA
$-------------------------------------------------------------------
PARAMETER G(FCC_A1,AL:VA;0) 273.00 +GHSERAL#; 2900.00 N
REF:0 !
PARAMETER G(FCC_A1,CO:VA;0) 273.00 +GCOFCC#; 6000.00 N
REF:73 !
PARAMETER G(FCC_A1,CR:VA;0) 273.00 +7284+0.163*T+GHSERCR#; 6000.00 N
REF:0 !
PARAMETER G(FCC_A1,CU:VA;0) 273.00 +GHSERCU#; 3200.00 N
REF:0 !
PARAMETER G(FCC_A1,FE:VA;0) 273.00 -1462.4+8.282*T-1.15*T*LN(T)
+0.00064*T**2+GHSERFE#; 1811.00 Y
-1713.815+0.94001*T+0.4925095E+31*T**(-9)+GHSERFE#; 6000.00 N
REF:0 !
PARAMETER G(FCC_A1,FE:H;0) 273.00 +25746.7209+48.1250165*T+GFEFCC#
+0.5*GHSERHH#; 6000.00 N
REF:223 !
PARAMETER G(FCC_A1,HF:VA;0) 273.00 +GHFFCC#; 6000.00 N
REF:0 !
PARAMETER G(FCC_A1,LA:VA;0) 273.00 +GLAFCC#; 6000.00 N
REF:0 !
PARAMETER G(FCC_A1,MN:VA;0) 273.00 -3439.3+131.884*T-24.5177*T*LN(T)
-0.006*T**2+69600*T**(-1); 1519.00 Y
-26070.1+309.6664*T-48*T*LN(T)+3.86196E+30*T**(-9); 6000.00 N
REF:66 !
PARAMETER G(FCC_A1,MO:VA;0) 273.00 +15200+0.63*T+GHSERMO#; 5000.00 N
REF:0 !
PARAMETER G(FCC_A1,NB:VA;0) 273.00 +13500+1.7*T+GHEXTNB#; 5000.00 N
REF:0 !
PARAMETER G(FCC_A1,NI:VA;0) 273.00 +GHSERNI#; 3000.00 N
REF:0 !
PARAMETER G(FCC_A1,P:VA;0) 273.00 +GPFCC#; 3000.00 N
REF:0 !
PARAMETER G(FCC_A1,PD:VA;0) 273.00 +GHSERPD#; 3000.00 N
REF:0 !
PARAMETER G(FCC_A1,S:VA;0) 273.00 +105000+GHSERSS#; 6000.00 N
REF:82 !
PARAMETER G(FCC_A1,SI:VA;0) 273.00 +51000-21.8*T+GHSERSI#; 3600.00 N
REF:0 !
PARAMETER G(FCC_A1,TI:VA;0) 273.00 +6000-0.1*T+GHSERTI#; 3000.00 N
REF:0 !
PARAMETER G(FCC_A1,V:VA;0) 273.00 +7500+1.7*T+GHSERVV#; 4000.00 N
REF:0 !
PARAMETER G(FCC_A1,W:VA;0) 273.00 +19300+0.63*T+GHSERWW#; 6000.00 N
REF:0 !
PARAMETER G(FCC_A1,Y:VA;0) 273.00 +GHSERYY#+10000; 6000.00 N
REF:pov12 !
$-------------------------------------------------------------------
$ FCC_A1 endmember compounds with B
$-------------------------------------------------------------------
$ B-solubility in Fe only roughly known, big experimental spread
PARAMETER G(FCC_A1,CR:B;0) 273.00 +GHSERCR#+GHSERBB#+UNDEF#; 6000.00 N
REF:114 !
PARAMETER G(FCC_A1,CU:B;0) 273.00 +GHSERCU#+GHSERBB#+62000; 6000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,FE:B;0) 273.00 +GHSERFE#+GHSERBB#+2800+21.7*T; 6000.00 N
REF:115 !
PARAMETER G(FCC_A1,HF:B;0) 273.00 +GHFFCC#+GHSERBB#-61674.9; 6000.00 N
REF:92 !
PARAMETER G(FCC_A1,MN:B;0) 273.00 +GMNFCC#+GHSERBB#; 6000.00 N
REF:245 !
PARAMETER G(FCC_A1,MO:B;0) 273.00 +GMOFCC#+GHSERBB#-50000; 6000.00 N
REF:pov15 !
PARAMETER G(FCC_A1,NB:B;0) 273.00 +GHSERNB#+GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(FCC_A1,NI:B;0) 273.00 +GHSERNI#+GHSERBB#
+43514-12.217*T; 6000.00 N
REF:161 !
PARAMETER G(FCC_A1,TI:B;0) 273.00 +GTIFCC#+GHSERBB#-150000; 6000.00 N
REF:pov15 !
PARAMETER G(FCC_A1,V:B;0) 273.00 +GHSERVV#+GHSERBB#; 6000.00 N
REF:235 !
$-------------------------------------------------------------------
$ FCC_A1 endmember compounds with C
$-------------------------------------------------------------------
PARAMETER G(FCC_A1,AL:C;0) 273.00 +GHSERAL#+GHSERCC#
+81000; 6000.00 N
REF:155 !
PARAMETER G(FCC_A1,CO:C;0) 273.00 +GHSERCO#+GHSERCC#+50463.8
-6.849*T; 6000.00 N
REF:73 !
PARAMETER G(FCC_A1,CR:C;0) 273.00 +GHSERCR#+GHSERCC#+1200
-1.94*T; 6000.00 N
REF:11 !
PARAMETER G(FCC_A1,FE:C;0) 273.00 +72729-14.95*T+GFEFCC#
+GHSERCC#; 6000.00 N
REF:289 !
PARAMETER G(FCC_A1,HF:C;0) 273.00 +GHFC#; 5000.00 N
REF:194 !
PARAMETER G(FCC_A1,MO:C;0) 273.00 -7500-8.3*T-750000*T**(-1)
+GHSERMO#+GHSERCC#; 6000.00 N
REF:17 !
PARAMETER G(FCC_A1,MN:C;0) 273.00 13.659*T+GHSERMN#
+GHSERCC#; 6000.00 N
REF:265 !
$PARAMETER G(FCC_A1,NB:C;0) 273.00 -162000+283.912*T-46.34274*T*LN(T)
$ -0.0029287*T**2-1.02788144E+9*T**(-3)+563374*T**(-1); 6000.00 N
$REF:pov09 !
PARAMETER G(FCC_A1,NB:C;0) 273.00 -155500+283.5*T
-46.3*T*LN(T)-0.003*T**2+563375*T**(-1)
-1.02788E+09*T**(-3); 6000.00 N
REF:pov23 !
PARAMETER G(FCC_A1,NI:C;0) 273.00 +GHSERNI#+GHSERCC#+62000
-7.6*T; 6000.00 N
REF:11 !
PARAMETER G(FCC_A1,P:C;0) 273.00 +GPRED#+GHSERCC#+92299.72; 6000.00 N
REF:229 !
PARAMETER G(FCC_A1,PD:C;0) 273.00 +GHSERPD#+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FCC_A1,S:C;0) 273.00 +GHSERSS#+GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(FCC_A1,SI:C;0) 273.00 +GHSERSI#+GHSERCC#-20510
+38.7*T; 6000.00 N
REF:24 !
PARAMETER G(FCC_A1,TI:C;0) 273.00 +GTIC#; 6000.00 N
REF:88 !
PARAMETER G(FCC_A1,V:C;0) 273.00 -117302+262.57*T-41.756*T*LN(T)
-0.00557101*T**2+590546*T**(-1); 6000.00 N
REF:15 !
PARAMETER G(FCC_A1,W:C;0) 273.00 -17864+1.875*T+GHSERWW#
+GHSERCC#; 6000.00 N
REF:19 !
$-------------------------------------------------------------------
$ FCC_A1 endmember compounds with N
$-------------------------------------------------------------------
PARAMETER G(FCC_A1,AL:N;0) 273.00 +80*T+GHSERAL#+GHSERNN#; 6000.00 N
REF:92 !
PARAMETER G(FCC_A1,CO:N;0) 273.00 +21028+284.763*T
-50.261*T*LN(T)+198552*T**(-1); 6000.00 N
REF:135 !
PARAMETER G(FCC_A1,CR:N;0) 273.00 -124460+142.16*T-8.75*T*LN(T)
+GHSERCR#+GHSERNN#; 6000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,FE:N;0) 273.00 -37460+375.42*T-37.6*T*LN(T)
+GHSERFE#+GHSERNN#; 6000.00 N
REF:47 !
PARAMETER G(FCC_A1,MN:N;0) 273.00 -75940+292.226*T-50.294*T*LN(T)
+265051*T**(-1); 2500.00 N
REF:22 !
PARAMETER G(FCC_A1,MO:N;0) 273.00 +GHSERMO#+GHSERNN#-65344
+149.7*T-9.78*T*LN(T); 6000.00 N
REF:47 !
$PARAMETER G(FCC_A1,NB:N;0) 273.00 -227779+120.567*T-4*T*LN(T)
$ +GHSERNB#+GHSERNN#; 6000.00 N
$REF:16 !
PARAMETER G(FCC_A1,NB:N;0) 273.00 -223779+117.4*T-3.8*T*LN(T)
+GHSERNB#+GHSERNN#; 6000.00 N
REF:jac18 !
PARAMETER G(FCC_A1,NI:N;0) 273.00 +38680+143.09*T-10.9*T*LN(T)
+.00438*T**2+GHSERNI#+GHSERNN#; 6000.00 N
REF:67 !
PARAMETER G(FCC_A1,S:N;0) 273.00 +GHSERSS#+GHSERNN#+100000; 6000.00 N
REF:pov14 !
PARAMETER G(FCC_A1,SI:N;0) 273.00 +GHSERSI#+GHSERNN#+100000; 6000.00 N
REF:pov14 !
PARAMETER G(FCC_A1,TI:N;0) 273.00 +GTIN#; 6000.00 N
REF:16 !
PARAMETER G(FCC_A1,V:N;0) 273.00 -215000+101*T-2.22*T*LN(T)
+0.00073*T**2+GHSERVV#+GHSERNN#; 6000.00 N
REF:48 !
PARAMETER G(FCC_A1,W:N;0) 273.00 -40752.746+259.88468*T
-45.443666*T*LN(T)+237083*T**(-1)-0.0046519123*T**2; 6000.00 N
REF:140 !
$-------------------------------------------------------------------
$ FCC_A1 endmember compounds with O
$-------------------------------------------------------------------
PARAMETER G(FCC_A1,AL:O;0) 273.00 +GHSERAL#+GHSEROO#; 2900.00 N
REF:pov12 !
PARAMETER G(FCC_A1,CO:O;0) 273.00 +GCOFCC#+GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,CR:O;0) 273.00 +65*T
+GCRFCC#+GHSEROO#; 6000.00 N
REF:199 !
PARAMETER G(FCC_A1,CU:O;0) 273.00 +GHSERCU#+GHSEROO#; 3200.00 N
REF:pov12 !
PARAMETER G(FCC_A1,FE:O;0) 273.00 -175707+88.23*T
+GFEFCC#+GHSEROO#; 6000.00 N
REF:197 !
PARAMETER G(FCC_A1,HF:O;0) 273.00 +GHFFCC#+GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,LA:O;0) 273.00 -570000+91.4*T
+GLAFCC#+GHSEROO#; 6000.00 N
REF:197 !
PARAMETER G(FCC_A1,MN:O;0) 273.00 +GMNFCC#+GHSEROO#; 5000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,MO:O;0) 273.00 +GMOFCC#+GHSEROO#; 5000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,NB:O;0) 273.00 +13500+1.7*T+GHEXTNB#
+GHSEROO#; 5000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,NI:O;0) 273.00 +65*T
+GHSERNI#+GHSEROO#; 6000.00 N
REF:199 !
PARAMETER G(FCC_A1,S:O;0) 273.00 +105000+GHSERSS#+GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,SI:O;0) 273.00 +51000-21.8*T+GHSERSI#
+GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,TI:O;0) 273.00 +6000-0.1*T+GHSERTI#+GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,V:O;0) 273.00 +7500+1.7*T+GHSERVV#+GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,W:O;0) 273.00 +19300+0.63*T+GHSERWW#
+GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(FCC_A1,Y:O;0) 273.00 +GHSERYY#+10000+GHSEROO#; 6000.00 N
REF:pov12 !
$
$******************** binary interactions ***************************
$-------------------------------------------------------------------
$ FCC_A1 binary interactions with VA
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,AL,CR:VA;0) 273.00 -45900+6*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,AL,CU:VA;0) 273.00 -53520+2*T; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,AL,CU:VA;1) 273.00 +38590-2*T; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,AL,CU:VA;2) 273.00 +1170; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,AL,FE:VA;0) 273.00 -97000+26*T; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,AL,FE:VA;1) 273.00 +22600; 6000.00 N
REF:155 !
PARAMETER L(FCC_A1,AL,FE:VA;2) 273.00 +29100-13*T; 6000.00 N
REF:155 !
PARAMETER L(FCC_A1,AL,HF:VA;0) 273.00 -111979; 6000.00 N
REF:214 !
PARAMETER L(FCC_A1,AL,MN:VA;0) 273.00 -69300+25*T; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,AL,MN:VA;1) 273.00 +8800; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,AL,MO:VA;0) 273.00 -92220+20*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,AL,NB:VA;0) 273.00 -113500+21.1*T; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,AL,NB:VA;1) 273.00 +5000; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,AL,NB:VA;2) 273.00 +10000; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,AL,NI:VA;0) 273.00 -162407.750+16.212965*T; 6000.00 N
REF:89 !
PARAMETER L(FCC_A1,AL,NI:VA;1) 273.00 +73417.798-34.914*T; 6000.00 N
REF:89 !
PARAMETER L(FCC_A1,AL,NI:VA;2) 273.00 +33471.014-9.837*T; 6000.00 N
REF:89 !
PARAMETER L(FCC_A1,AL,NI:VA;3) 273.00 -30758.010+10.253*T; 6000.00 N
REF:89 !
PARAMETER L(FCC_A1,AL,SI:VA;0) 273.00 -3423.91-0.09584*T; 6000.00 N
REF:101 !
PARAMETER L(FCC_A1,AL,TI:VA;0) 273.00 -119185+40.723*T; 6000.00 N
REF:159 !
PARAMETER L(FCC_A1,AL,V:VA;0) 273.00 -61980+12.3*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,AL,V:VA;1) 273.00 -8000; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,AL,W:VA;0) 273.00 -19250+20.2*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,AL,W:VA;1) 273.00 -10000; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,CO,CR:VA;0) 273.00 +1500-9.592*T; 6000.00 N
REF:73 !
PARAMETER L(FCC_A1,CO,CU:VA;0) 273.00 +40900-5.5*T; 6000.00 N
REF:85 !
PARAMETER L(FCC_A1,CO,CU:VA;1) 273.00 -1600; 6000.00 N
REF:85 !
PARAMETER L(FCC_A1,CO,CU:VA;2) 273.00 -6900; 6000.00 N
REF:85 !
PARAMETER L(FCC_A1,CO,FE:VA;0) 273.00 -8968.75; 6000.00 N
REF:152 !
PARAMETER L(FCC_A1,CO,FE:VA;2) 273.00 +3528.8; 6000.00 N
REF:152 !
PARAMETER L(FCC_A1,CO,HF:VA;0) 273.00 -83611; 6000.00 N
REF:195 !
PARAMETER L(FCC_A1,CO,MN:VA;0) 273.00 -23756; 6000.00 N
REF:86 !
PARAMETER L(FCC_A1,CO,MN:VA;1) 273.00 -2343; 6000.00 N
REF:86 !
PARAMETER L(FCC_A1,CO,MO:VA;0) 273.00 -29557.1+10.953*T; 6000.00 N
REF:78 !
PARAMETER L(FCC_A1,CO,MO:VA;1) 273.00 -1382.2+15.371*T; 6000.00 N
REF:78 !
PARAMETER L(FCC_A1,CO,MO:VA;2) 273.00 -18135.4; 6000.00 N
REF:78 !
PARAMETER L(FCC_A1,CO,NB:VA;0) 273.00 -41634; 6000.00 N
REF:136 !
PARAMETER L(FCC_A1,CO,NB:VA;1) 273.00 -10241; 6000.00 N
REF:136 !
PARAMETER L(FCC_A1,CO,NI:VA;0) 273.00 -800+1.2629*T; 6000.00 N
REF:79 !
PARAMETER L(FCC_A1,CO,V:VA;0) 273.00 -57151.224+21.699*T; 6000.00 N
REF:134 !
PARAMETER L(FCC_A1,CO,V:VA;1) 273.00 -4581.3012; 6000.00 N
REF:134 !
PARAMETER L(FCC_A1,CO,W:VA;0) 273.00 -19900+12.8*T; 6000.00 N
REF:243 !
PARAMETER L(FCC_A1,CO,W:VA;1) 273.00 +17970-19.3*T; 6000.00 N
REF:243 !
PARAMETER L(FCC_A1,CR,CU:VA;0) 273.00 +45000; 6000.00 N
REF:pov16 !
PARAMETER G(FCC_A1,CR,FE:VA;0) 273.00 +28767-21*T; 6000 N
REF:287 !
PARAMETER G(FCC_A1,CR,FE:VA;1) 273.00 +33057-20.7*T; 6000 N
REF:287 !
PARAMETER L(FCC_A1,CR,LA:VA;0) 273.00 +20000; 6000.00 N
REF:205 !
PARAMETER L(FCC_A1,CR,LA:VA;2) 273.00 +25000; 6000.00 N
REF:205 !
PARAMETER L(FCC_A1,CR,MN:VA;0) 273.00 -19088+17.5423*T; 6000.00 N
REF:22 !
PARAMETER L(FCC_A1,CR,MO:VA;0) 273.00 +28890-7.962*T; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,CR,MO:VA;1) 273.00 +5974-2.428*T; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,CR,NB:VA;0) 273.00 +40000; 6000.00 N
REF:130 !
PARAMETER L(FCC_A1,CR,NI:VA;0) 273.00 +8030-12.8801*T; 6000.00 N
REF:11 !
PARAMETER L(FCC_A1,CR,NI:VA;1) 273.00 +33080-16.0362*T; 6000.00 N
REF:11 !
PARAMETER L(FCC_A1,CR,P:VA;0) 273.00 -70000; 6000.00 N
REF:230 !
PARAMETER L(FCC_A1,CR,SI:VA;0) 273.00 -120000+10.69527*T; 6000.00 N
REF:46 !
PARAMETER L(FCC_A1,CR,SI:VA;1) 273.00 -47614.7+12.17363*T; 6000.00 N
REF:46 !
PARAMETER L(FCC_A1,CR,TI:VA;0) 273.00 +66300.0-27.70*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,CR,V:VA;0) 273.00 -9874-2.6964*T; 6000.00 N
REF:68 !
PARAMETER L(FCC_A1,CR,V:VA;1) 273.00 -1720-2.5237*T; 6000.00 N
REF:68 !
PARAMETER L(FCC_A1,CR,W:VA;0) 273.00 +31520; 6000.00 N
REF:138 !
PARAMETER L(FCC_A1,CR,W:VA;1) 273.00 -1320; 6000.00 N
REF:138 !
PARAMETER L(FCC_A1,CR,Y:VA;0) 273.00 +63000; 6000.00 N
REF:pov12 !
PARAMETER L(FCC_A1,CU,FE:VA;0) 273.00 +48500-8*T; 6000.00 N
REF:pov15 !
PARAMETER L(FCC_A1,CU,FE:VA;1) 273.00 -2500+2*T; 6000.00 N
REF:pov15 !
PARAMETER L(FCC_A1,CU,FE:VA;2) 273.00 +2500-2*T; 6000.00 N
REF:pov15 !
PARAMETER L(FCC_A1,CU,MN:VA;0) 273.00 +20235.508-13.2437*T; 6000.00 N
REF:84 !
PARAMETER L(FCC_A1,CU,MN:VA;1) 273.00 -12154.853+2.9399*T; 6000.00 N
REF:84 !
PARAMETER L(FCC_A1,CU,MN:VA;2) 273.00 +1037.56; 6000.00 N
REF:84 !
PARAMETER L(FCC_A1,CU,NB:VA;0) 273.00 +45699.84-5.22785*T; 6000.00 N
REF:44 !
PARAMETER L(FCC_A1,CU,NI:VA;0) 273.00 +8366+2.8*T; 6000.00 N
REF:224 !
PARAMETER L(FCC_A1,CU,NI:VA;1) 273.00 -4360+1.812*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,CU,S:VA;0) 273.00 -102200-26.5*T; 6000.00 N
REF:82 !
PARAMETER L(FCC_A1,CU,SI:VA;0) 273.00 -34105.96-1.908*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,CU,V:VA;0) 273.00 +53650; 6000.00 N
REF:131 !
PARAMETER L(FCC_A1,FE,HF:VA;0) 273.00 -17000-3.5*T; 6000.00 N
REF:pov11 !
PARAMETER G(FCC_A1,FE,LA:VA;0) 273.00 +35052+22.45*T; 6000.00 N
REF:197 !
PARAMETER G(FCC_A1,FE,MN:VA;0) 273.00 -8602+3*T; 6000 N
REF:293 !
PARAMETER G(FCC_A1,FE,MN:VA;1) 273.00 +1059-1.1*T; 6000 N
REF:293 !
PARAMETER L(FCC_A1,FE,MO:VA;0) 273.00 +28347-17.691*T; 6000.00 N
REF:27 !
$PARAMETER L(FCC_A1,FE,NB:VA;0) 273.00 -2000; 6000.00 N
$REF:pov09 !
PARAMETER L(FCC_A1,FE,NB:VA;0) 298.15 -9000+2.25*T; 6000.00 N
REF:pov23 !
PARAMETER L(FCC_A1,FE,NB:VA;1) 298.15 1e-8; 6000.00 N
REF:pov23 !
PARAMETER L(FCC_A1,FE,NB:VA;2) 298.15 +1e-8; 6000.00 N
REF:pov23 !
PARAMETER L(FCC_A1,FE,NB:VA;3) 298.15 -2000; 6000.00 N
REF:pov23 !
PARAMETER G(FCC_A1,FE,NI:VA;0) 273.00 -15308+1.4*T; 6000 N
REF:293 !
PARAMETER G(FCC_A1,FE,NI:VA;1) 273.00 +14000-4*T; 6000 N
REF:293 !
PARAMETER G(FCC_A1,FE,NI:VA;2) 273.00 -3057; 6000 N
REF:293 !
PARAMETER L(FCC_A1,FE,P:VA;0) 273.00 -144097+19.2414*T; 6000.00 N
REF:230 !
PARAMETER G(FCC_A1,FE,PD:VA;0) 273.00 -36989.6640-10.8485*T; 6000.00 N
REF:242 !
PARAMETER G(FCC_A1,FE,PD:VA;1) 273.00 +63662.7285-19.5828*T; 6000.00 N
REF:242 !
PARAMETER L(FCC_A1,FE,S:VA;0) 273.00 -108733-18*T; 6000.00 N
REF:82 !
PARAMETER G(FCC_A1,FE,SI:VA;0) 2.98150E+02 -115254.045552-2.19316276032*T;
6.00000E+03 N
REF:Cui(2017) !
PARAMETER G(FCC_A1,FE,SI:VA;1) 2.98150E+02 -84776.910912+44.33086072*T;
6.00000E+03 N
REF:Cui(2017) !
PARAMETER G(FCC_A1,FE,SI:VA;2) 2.98150E+02 +20007.028188;
6.00000E+03 N
REF:CUi(2017) !
PARAMETER L(FCC_A1,FE,TI:VA;0) 273.00 -51136+10.4*T; 6000.00 N
REF:88 !
PARAMETER L(FCC_A1,FE,TI:VA;1) 273.00 -1950-6*T; 6000.00 N
REF:16 !
PARAMETER L(FCC_A1,FE,TI:VA;2) 273.00 +14875; 6000.00 N
REF:16 !
PARAMETER L(FCC_A1,FE,V:VA;0) 273.00 -15291-4.138*T; 6000.00 N
REF:15 !
PARAMETER L(FCC_A1,FE,W:VA;0) 273.00 +25977-3.36*T; 6000.00 N
REF:20 !
PARAMETER L(FCC_A1,FE,W:VA;1) 273.00 -7258.6; 6000.00 N
REF:20 !
PARAMETER L(FCC_A1,FE,Y:VA;1) 273.00 -25000; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,HF,NB:VA;0) 273.00 +3887.36+0.02358*T; 6000.00 N
REF:216 !
PARAMETER L(FCC_A1,HF,NI:VA;0) 273.00 -118000; 6000.00 N
REF:pov12 !
PARAMETER L(FCC_A1,HF,NI:VA;1) 273.00 +1e-8; 6000.00 N
REF:pov12 !
PARAMETER L(FCC_A1,HF,TI:VA;0) 273.00 +1e-4; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,HF,W:VA;0) 273.00 +1e-8; 6000.00 N
REF:215 !
PARAMETER L(FCC_A1,LA,NI:VA;0) 273.00 +100000; 6000.00 N
REF:222 !
PARAMETER L(FCC_A1,MN,MO:VA;0) 273.00 -6000; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,MN,NI:VA;0) 273.00 +LF0#; 6000.00 N
REF:244 !
PARAMETER L(FCC_A1,MN,NI:VA;1) 273.00 +LF1#; 6000.00 N
REF:244 !
PARAMETER L(FCC_A1,MN,PD:VA;0) 273.00 -85000+15*T; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,MN,PD:VA;1) 273.00 +47500-30*T; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,MN,PD:VA;2) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,MN,SI:VA;0) 273.00 -95600+2.94097*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,MN,SI:VA;1) 273.00 -7500; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,MN,TI:VA;0) 273.00 -26200+20*T; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,MN,V:VA;0) 273.00 -11820; 6000.00 N
REF:15 !
PARAMETER L(FCC_A1,MO,NB:VA;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,MO,NI:VA;0) 273.00 +4803.7-5.96*T; 6000.00 N
REF:39 !
PARAMETER L(FCC_A1,MO,NI:VA;1) 273.00 +10880; 6000.00 N
REF:39 !
PARAMETER L(FCC_A1,MO,SI:VA;0) 273.00 -60000+5*T; 6000.00 N
REF:pov09 !
PARAMETER L(FCC_A1,MO,TI:VA;0) 273.00 -23224.5; 6000.00 N
REF:125 !
PARAMETER L(FCC_A1,MO,W:VA;0) 273.00 +2000; 6000.00 N
REF:55 !
PARAMETER L(FCC_A1,NB,NI:VA;0) 273.00 -66000-14*T; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,NB,NI:VA;1) 273.00 +96115-23.07497*T; 6000.00 N
REF:54 !
PARAMETER L(FCC_A1,NB,SI:VA;0) 273.00 -154000+17*T; 6000.00 N
REF:pov09 !
PARAMETER L(FCC_A1,NB,SI:VA;1) 273.00 -17000; 6000.00 N
REF:pov09 !
PARAMETER L(FCC_A1,NB,SI:VA;2) 273.00 +35000; 6000.00 N
REF:pov09 !
PARAMETER L(FCC_A1,NB,TI:VA;0) 273.00 +13600; 6000.00 N
REF:16 !
PARAMETER L(FCC_A1,NB,V:VA;0) 273.00 +1e-8; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,NB,Y:VA;0) 273.00 +100000; 6000.00 N
REF:213 !
PARAMETER L(FCC_A1,NI,P:VA;0) 273.00 -176522.3-8.6002*T; 6000.00 N
REF:231 !
PARAMETER L(FCC_A1,NI,SI:VA;0) 273.00 -208234.46+44.14177*T; 6000.00 N
REF:193 !
PARAMETER L(FCC_A1,NI,SI:VA;1) 273.00 -108533.44; 6000.00 N
REF:193 !
PARAMETER L(FCC_A1,NI,SI:VA;2) 273.00 +1e-8; 6000.00 N
REF:pov12 !
PARAMETER L(FCC_A1,NI,TI:VA;0) 273.00 -121925+16.994*T; 6000.00 N
REF:253 !
PARAMETER L(FCC_A1,NI,TI:VA;1) 273.00 -32260; 6000.00 N
REF:253 !
PARAMETER L(FCC_A1,NI,V:VA;0) 273.00 -36365.6+3.75677*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,NI,V:VA;1) 273.00 +11860.7-9.03020*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,NI,V:VA;2) 273.00 -10647.5+7.00954*T; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,NI,W:VA;0) 273.00 +2556+11.6*T; 6000.00 N
REF:20 !
PARAMETER L(FCC_A1,NI,W:VA;1) 273.00 -52900; 6000.00 N
REF:20 !
PARAMETER L(FCC_A1,NI,Y:VA;0) 273.00 -2000; 6000.00 N
REF:213 !
PARAMETER L(FCC_A1,SI,TI:VA;0) 273.00 -275629+42.509*T; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,SI,TI:VA;1) 273.00 +25025-2.002*T; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,SI,TI:VA;2) 273.00 +83941-6.715*T; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,SI,V:VA;0) 273.00 -205373.1+61.02211*T; 6000.00 N
REF:129 !
PARAMETER L(FCC_A1,TI,S:VA;0) 273.00 +UNDEF#; 6000.00 N !
PARAMETER L(FCC_A1,TI,V:VA;0) 273.00 +23400; 6000.00 N
REF:92 !
PARAMETER L(FCC_A1,TI,W:VA;0) 273.00 +33825; 6000.00 N
REF:139 !
$-------------------------------------------------------------------
$ FCC_A1 binary interactions with C
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,AL,CO:C;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,AL,CR:C;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,AL,FE:C;0) 273.00 -104000+80*T; 6000.00 N
REF:155 !
PARAMETER L(FCC_A1,AL,FE:C;1) 273.00 +81000; 6000.00 N
REF:155 !
PARAMETER L(FCC_A1,AL,FE:C;2) 273.00 +1e-8; 6000.00 N
REF:155 !
PARAMETER L(FCC_A1,AL,FE:C,VA;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,AL,FE:C,VA;1) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,AL,NI:C;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,CO,CR:C;0) 273.00 -1500-9.592*T; 6000.00 N
REF:73 !
PARAMETER L(FCC_A1,CO,FE:C;0) 273.00 +313; 6000.00 N
REF:75 !
PARAMETER L(FCC_A1,CO,FE:C;1) 273.00 -1063; 6000.00 N
REF:75 !
PARAMETER L(FCC_A1,CO,MO:C;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,CO,NI:C;0) 273.00 +18289; 6000.00 N
REF:76 !
PARAMETER L(FCC_A1,CO,NI:C;1) 273.00 -9924; 6000.00 N
REF:76 !
PARAMETER L(FCC_A1,CO,V:C;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,CO,W:C;0) 273.00 +87040; 6000.00 N
REF:243 !
PARAMETER L(FCC_A1,CR,FE:C;0) 273.00 -100000+5.5*T; 6000.00 N
REF:293 !
PARAMETER L(FCC_A1,CR,MN:C;0) 273.00 -19088+17.5423*T; 6000.00 N
REF:58 !
PARAMETER L(FCC_A1,CR,MO:C;0) 273.00 +20000-70*T; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,CR,NB:C;0) 273.00 -30000; 6000.00 N
REF:pov12 !
PARAMETER L(FCC_A1,CR,NI:C;0) 273.00 -125935+95*T; 6000.00 N
REF:11 !
PARAMETER L(FCC_A1,CR,TI:C;0) 273.00 -5000-7.5*T; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,CR,V:C;0) 273.00 +35698-50.0981*T; 6000.00 N
REF:68 !
PARAMETER L(FCC_A1,CR,V:C;1) 273.00 -47500; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,CR,V:C;2) 273.00 -30000; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,CU,FE:C;0) 273.00 -75000; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,FE,MN:C;0) 273.00 +20082-11.6312*T; 6000.00 N
REF:255 !
PARAMETER L(FCC_A1,FE,MO:C;0) 273.00 +6000; 6000.00 N
REF:27 !
PARAMETER L(FCC_A1,FE,NB:C;0) 273.00 -35000; 6000.00 N
REF:pov23 !
PARAMETER L(FCC_A1,FE,NB:C;1) 273.00 -35000; 6000.00 N
REF:pov23 !
PARAMETER L(FCC_A1,FE,NI:C;0) 273.00 +50035.5-15.89*T; 6000.00 N
REF:293 !
PARAMETER L(FCC_A1,FE,NI:C;1) 273.00 -32969.9; 6000.00 N
REF:293 !
PARAMETER L(FCC_A1,FE,SI:C;0) 273.00 +96100-5*T; 6000.00 N
REF:293 !
PARAMETER L(FCC_A1,FE,SI:C;1) 273.00 -82400; 6000.00 N
REF:293 !
PARAMETER L(FCC_A1,FE,V:C;0) 273.00 -7645.5-2.069*T; 6000.00 N
REF:15 !
PARAMETER L(FCC_A1,FE,V:C;1) 273.00 -7645.5-2.069*T; 6000.00 N
REF:15 !
PARAMETER L(FCC_A1,FE,W:C;0) 273.00 -116756+100*T; 6000.00 N
REF:20 !
PARAMETER L(FCC_A1,HF,MO:C;0) 273.00 -20000; 6000.00 N
REF:pov10 !
PARAMETER L(FCC_A1,HF,MO:C;1) 273.00 +20000; 6000.00 N
REF:pov10 !
PARAMETER L(FCC_A1,HF,MO:C;2) 273.00 +10000; 6000.00 N
REF:pov10 !
PARAMETER L(FCC_A1,HF,W:C;0) 273.00 +4000; 6000.00 N
REF:195 !
PARAMETER L(FCC_A1,MO,NI:C;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,MO,TI:C;0) 273.00 +35000-25*T; 6000.00 N
REF:pov15 !
PARAMETER L(FCC_A1,MO,V:C;0) 273.00 -64000+40*T; 6000.00 N
REF:pov10 !
PARAMETER L(FCC_A1,MO,V:C;1) 273.00 -20000+10*T; 6000.00 N
REF:pov10 !
PARAMETER L(FCC_A1,NB,TI:C;0) 273.00 -33979; 6000.00 N
REF:16 !
PARAMETER L(FCC_A1,NB,V:C;0) 273.00 +29000; 6000.00 N
REF:88 !
PARAMETER L(FCC_A1,NB,V:C;1) 273.00 -5000; 6000.00 N
REF:88 !
PARAMETER L(FCC_A1,NB,W:C;0) 273.00 +33160-14.154*T; 6000.00 N
REF:19 !
PARAMETER L(FCC_A1,NB,W:C;1) 273.00 -7996; 6000.00 N
REF:19 !
PARAMETER L(FCC_A1,NI,V:C;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,NI,W:C;0) 273.00 -24000+50*T; 6000.00 N
REF:20 !
PARAMETER L(FCC_A1,TI,S:C;0) 273.00 +UNDEF#; 6000.00 N !
PARAMETER L(FCC_A1,TI,V:C;0) 273.00 +12800; 6000.00 N
REF:110 !
PARAMETER L(FCC_A1,TI,V:C;1) 273.00 -2133; 6000.00 N
REF:110 !
PARAMETER L(FCC_A1,TI,W:C;0) 273.00 -27178; 6000.00 N
REF:139 !
PARAMETER L(FCC_A1,TI,W:C;1) 273.00 -5524; 6000.00 N
REF:139 !
$-------------------------------------------------------------------
$ FCC_A1 binary interactions with N
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,CO,FE:N;0) 273.00 -16043; 6000.00 N
REF:142 !
PARAMETER L(FCC_A1,CR,FE:N;0) 273.00 -128930+86.49*T; 6000.00 N
REF:22 !
PARAMETER L(FCC_A1,CR,FE:N;1) 273.00 +24330; 6000.00 N
REF:22 !
PARAMETER L(FCC_A1,CR,MN:N;0) 273.00 -21237; 6000.00 N
REF:22 !
PARAMETER L(FCC_A1,CR,MO:N;0) 273.00 -40000; 6000.00 N
REF:64 !
PARAMETER L(FCC_A1,FE,MN:N;0) 273.00 +53968-38.102*T; 6000.00 N
REF:22 !
PARAMETER L(FCC_A1,FE,MN:N;1) 273.00 -28787; 6000.00 N
REF:22 !
PARAMETER L(FCC_A1,FE,NI:N;0) 273.00 -22710+5.19*T; 6000.00 N
REF:30 !
PARAMETER L(FCC_A1,FE,NI:N;1) 273.00 +3334; 6000.00 N
REF:30 !
$PARAMETER L(FCC_A1,FE,V:N;0) 273.00 -60000; 6000.00 N
$REF:32 !
PARAMETER L(FCC_A1,FE,V:N;0) 273.00 +6000; 6000.00 N
REF:jac18 !
PARAMETER L(FCC_A1,NB,TI:N;0) 273.00 +10000; 6000.00 N
REF:88 !
PARAMETER L(FCC_A1,NB,V:N;0) 273.00 +15000; 6000.00 N
REF:jac18 !
PARAMETER L(FCC_A1,TI,V:N;0) 273.00 +20000; 6000.00 N
REF:88 !
$-------------------------------------------------------------------
$ FCC_A1 binary interactions with B,VA
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,CR:B,VA;0) 273.00 -5000; 6000.00 N
REF:114 !
$-------------------------------------------------------------------
$ FCC_A1 binary interactions with C,VA
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,AL:C,VA;0) 273.00 -80000+8*T; 6000.00 N
REF:155 !
PARAMETER L(FCC_A1,CR:C,VA;0) 273.00 -11977+6.8194*T; 6000.00 N
REF:11 !
$Check the parameters and its influence of the Bs calculation
PARAMETER L(FCC_A1,FE:C,VA;0) 273.00 -30532; 6000.00 N
REF:289 !
PARAMETER L(FCC_A1,MN:C,VA;0) 273.00 -41333; 6000.00 N
REF:265 !
PARAMETER L(FCC_A1,MO:C,VA;0) 273.00 -41300; 6000.00 N
REF:17 !
$PARAMETER L(FCC_A1,NB:C,VA;0) 273.00 -83000+20*T; 6000.00 N
$REF:pov09 !
$PARAMETER L(FCC_A1,NB:C,VA;2) 273.00 -61342+25.207*T; 6000.00 N
$REF:19 !
PARAMETER L(FCC_A1,NB:C,VA;0) 273.00 -50000+10*T; 6000.00 N
REF:pov23 !
PARAMETER L(FCC_A1,NB:C,VA;1) 273.00 +10000-2*T; 6000.00 N
REF:pov23 !
PARAMETER L(FCC_A1,NB:C,VA;2) 273.00 -65000+17.4391*T; 6000.00 N
REF:01Lee !
PARAMETER L(FCC_A1,NI:C,VA;0) 273.00 -14902+7.5*T; 6000.00 N
REF:11 !
$PARAMETER L(FCC_A1,TI:C,VA;0) 273.00 -50000-10*T; 6000.00 N
$REF:pov15 !
$PARAMETER L(FCC_A1,TI:C,VA;1) 273.00 -117500+25*T; 6000.00 N
$REF:pov15 !
PARAMETER L(FCC_A1,TI:C,VA;0) 273.00 -40219.8-18.250*T; 6000.00 N
REF:frisk03 !
PARAMETER L(FCC_A1,TI:C,VA;1) 273.00 -108521+12.735*T; 6000.00 N
REF:frisk03 !
PARAMETER L(FCC_A1,V:C,VA;0) 273.00 -74811+10.201*T; 6000.00 N
REF:15 !
PARAMETER L(FCC_A1,V:C,VA;1) 273.00 -30394; 6000.00 N
REF:15 !
PARAMETER L(FCC_A1,W:C,VA;0) 273.00 -17.98*T; 6000.00 N
REF:19 !
$
PARAMETER L(FCC_A1,AL,MN:C,VA;0) 273.00 -50000; 6000.00 N
REF:155 !
$PARAMETER L(FCC_A1,FE,NB:C,VA;0) 273.00 -40000; 6000.00 N
$REF:113 !
PARAMETER L(FCC_A1,FE,NB:C,VA;0) 273.00 -53000; 6000.00 N
REF:jac24 !
PARAMETER L(FCC_A1,FE,NB:C,VA;1) 273.00 +83000; 6000.00 N
REF:pov23 !
PARAMETER L(FCC_A1,FE,NB:C,VA;2) 273.00 -53000; 6000.00 N
REF:pov23 !
$PARAMETER L(FCC_A1,FE,TI:C,VA;0) 273.00 -180000; 6000.00 N
$REF:16 !
$PARAMETER L(FCC_A1,FE,TI:C,VA;1) 273.00 +318559+39.74*T; 6000.00 N
$REF:88 !
$PARAMETER L(FCC_A1,FE,TI:C,VA;2) 273.00 -318559-39.74*T; 6000.00 N
$REF:88 !
PARAMETER L(FCC_A1,FE,TI:C,VA;1) 273.00 +381879; 6000.00 N
REF:jac23 !
PARAMETER L(FCC_A1,FE,TI:C,VA;2) 273.00 -381879; 6000.00 N
REF:jac23 !
$PARAMETER L(FCC_A1,FE,TI:C,VA;1) 273.00 +318559+39.74*T; 6000.00 N
$REF:88 !
$PARAMETER L(FCC_A1,FE,TI:C,VA;2) 273.00 -318559-39.74*T; 6000.00 N
$REF:88 !
PARAMETER L(FCC_A1,FE,V:C,VA;0) 273.00 -40000; 6000.00 N
REF:15 !
PARAMETER L(FCC_A1,NB,TI:C,VA;0) 273.00 +97661; 6000.00 N
REF:16 !
PARAMETER L(FCC_A1,TI,W:C,VA;0) 273.00 +29729-34.3*T; 6000.00 N
REF:139 !
PARAMETER L(FCC_A1,HF:C,VA;0) 273.00 -102413+27.9760*T; 6000.00 N
REF:194 !
PARAMETER L(FCC_A1,HF:C,VA;1) 273.00 -151822+38.2048*T; 6000.00 N
REF:194 !
$
PARAMETER L(FCC_A1,HF:B,C;0) 273.00 -113610-10.6795*T; 6000.00 N
REF:92 !
$
$-------------------------------------------------------------------
$ FCC_A1 binary interactions with N,VA
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,AL:N,VA;0) 273.00 +1E-8; 6000.00 N
REF:pov09 !
PARAMETER L(FCC_A1,CO:N,VA;0) 273.00 -6500; 6000.00 N
REF:135 !
PARAMETER L(FCC_A1,CR:N,VA;0) 273.00 +20000; 6000.00 N
REF:22 !
PARAMETER L(FCC_A1,FE:N,VA;0) 273.00 -26150; 6000.00 N
REF:22 !
PARAMETER L(FCC_A1,MN:N,VA;0) 273.00 -69698+11.5845*T; 6000.00 N
REF:22 !
PARAMETER L(FCC_A1,MO:N,VA;0) 273.00 -52565; 6000.00 N
REF:64 !
PARAMETER L(FCC_A1,NB:N,VA;0) 273.00 -65218; 6000.00 N
REF:16 !
PARAMETER L(FCC_A1,TI:N,VA;0) 273.00 -42704; 6000.00 N
REF:16 !
PARAMETER L(FCC_A1,TI:N,VA;1) 273.00 -13989; 6000.00 N
REF:16 !
PARAMETER L(FCC_A1,V:N,VA;0) 273.00 -131000+47.1*T; 6000.00 N
REF:48 !
PARAMETER L(FCC_A1,W:N,VA;0) 273.00 -61824; 6000.00 N
REF:140 !
$
PARAMETER L(FCC_A1,CR,FE:N,VA;0) 273.00 -162516; 6000.00 N
REF:22 !
PARAMETER L(FCC_A1,CR,NI:N,VA;0) 273.00 -661270+305*T; 6000.00 N
REF:36 !
PARAMETER L(FCC_A1,FE,V:N,VA;0) 273.00 -120000; 6000.00 N
REF:32 !
PARAMETER L(FCC_A1,NB,TI:N,VA;0) 273.00 -50000; 6000.00 N
REF:16 !
$-------------------------------------------------------------------
$ FCC_A1 binary interactions with O,VA
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,CR:O,VA;0) 273.00 -170000+20*T; 6000.00 N
REF:199 !
PARAMETER L(FCC_A1,NI:O,VA;0) 273.00 -165608+32.24*T; 6000.00 N
REF:199 !
$-------------------------------------------------------------------
$ FCC_A1 binary interactions with C,N
$-------------------------------------------------------------------
$PARAMETER L(FCC_A1,NB:C,N;0) 273.00 +12.5922*T; 6000.00 N
$REF:16 !
PARAMETER L(FCC_A1,NB:C,N;0) 273.00 -5*T; 6000.00 N
REF:jac24 !
$PARAMETER L(FCC_A1,TI:C,N;0) 273.00 -54176; 6000.00 N
$REF:16 !
PARAMETER L(FCC_A1,TI:C,N;0) 273.00 -72712+30.95*T; 6000.00 N
REF:103 !
$PARAMETER L(FCC_A1,V:C,N;0) 273.00 -20000; 6000.00 N
$REF:88 !
PARAMETER L(FCC_A1,V:C,N;0) 273.00 -20000; 6000.00 N
REF:jac23 !
$
PARAMETER L(FCC_A1,CR,TI:C,N;0) 273.00 +150000; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,FE,TI:C,N;0) 273.00 +150000; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,MN,TI:C,N;0) 273.00 +150000; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,MO,TI:C,N;0) 273.00 +150000; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,NI,TI:C,N;0) 273.00 +150000; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,NB,TI:C,N;0) 273.00 +150000; 6000.00 N
REF:88 !
PARAMETER L(FCC_A1,NB,V:C,N;0) 273.00 -114935+95*T; 6000.00 N
REF:88 !
PARAMETER L(FCC_A1,TI,V:C,N;0) 273.00 +40000; 6000.00 N
REF:88 !
$******************** ternary interactions ***************************
$-------------------------------------------------------------------
$ FCC_A1 ternary interactions with VA
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,AL,CR,NI:VA;0) 273.00 +30300; 6000.00 N
REF:91 !
PARAMETER L(FCC_A1,AL,CU,SI:VA;0) 273.00 +1e-8; 6000.00 N
REF:147 !
PARAMETER L(FCC_A1,AL,CU,SI:VA;1) 273.00 +158203.819; 6000.00 N
REF:147 !
PARAMETER L(FCC_A1,AL,CU,SI:VA;2) 273.00 +1e-8; 6000.00 N
REF:147 !
PARAMETER L(FCC_A1,AL,FE,MN:VA;0) 273.00 -125000+45*T; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,AL,FE,MN:VA;1) 273.00 +1e-8; 6000.00 N
REF:155 !
PARAMETER L(FCC_A1,AL,FE,MN:VA;2) 273.00 +1e-8; 6000.00 N
REF:155 !
PARAMETER L(FCC_A1,AL,FE,NI:VA;0) 273.00 +1e-8; 6000.00 N
REF:Zhang2009 !
PARAMETER L(FCC_A1,AL,FE,NI:VA;1) 273.00 -178140.69+96.0612*T; 6000.00 N
REF:Zhang2009 !
PARAMETER L(FCC_A1,AL,FE,NI:VA;2) 273.00 -207403.88+117.740*T; 6000.00 N
REF:Zhang2009 !
PARAMETER L(FCC_A1,CO,CR,CU:VA;0) 273.00 -10000; 6000.00 N
REF:130 !
PARAMETER L(FCC_A1,CO,CR,CU:VA;1) 273.00 +60000; 6000.00 N
REF:130 !
PARAMETER L(FCC_A1,CO,CR,CU:VA;2) 273.00 -10000; 6000.00 N
REF:130 !
PARAMETER L(FCC_A1,CO,CU,FE:VA;0) 273.00 -35327.7+8*T; 6000.00 N
REF:228 !
PARAMETER L(FCC_A1,CO,CU,FE:VA;1) 273.00 -87000+58*T; 6000.00 N
REF:228 !
PARAMETER L(FCC_A1,CO,CU,FE:VA;2) 273.00 -93000+50*T; 6000.00 N
REF:228 !
PARAMETER L(FCC_A1,CO,CU,MN:VA;0) 273.00 -86000+40*T; 6000.00 N
REF:87 !
PARAMETER L(FCC_A1,CO,CU,MN:VA;1) 273.00 -157000+100*T; 6000.00 N
REF:87 !
PARAMETER L(FCC_A1,CO,CU,MN:VA;2) 273.00 -224500+150*T; 6000.00 N
REF:87 !
PARAMETER L(FCC_A1,CO,FE,MO:VA;0) 273.00 +60000-50*T; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,CO,NI,W:VA;0) 273.00 -106943; 6000.00 N
REF:79 !
PARAMETER L(FCC_A1,CO,NI,W:VA;1) 273.00 -46010; 6000.00 N
REF:79 !
PARAMETER L(FCC_A1,CO,NI,W:VA;2) 273.00 +1E-7; 6000.00 N
REF:79 !
PARAMETER L(FCC_A1,CR,CU,FE:VA;0) 273.00 -10000; 6000.00 N
REF:pov16 !
PARAMETER L(FCC_A1,CR,CU,FE:VA;1) 273.00 +1E-8; 6000.00 N
REF:225 !
PARAMETER L(FCC_A1,CR,CU,FE:VA;2) 273.00 -25000+30*T; 6000.00 N
REF:pov16 !
PARAMETER L(FCC_A1,CR,CU,NB:VA;0) 273.00 +85000; 6000.00 N
REF:130 !
PARAMETER L(FCC_A1,CR,CU,NI:VA;0) 273.00 +348250-250*T; 6000.00 N
REF:226 !
PARAMETER L(FCC_A1,CR,CU,NI:VA;1) 273.00 -220950+150*T; 6000.00 N
REF:226 !
PARAMETER L(FCC_A1,CR,CU,NI:VA;2) 273.00 -220950+150*T; 6000.00 N
REF:226 !
PARAMETER L(FCC_A1,CR,FE,MN:VA;0) 273.00 +1815-10.393*T; 6000.00 N
REF:293 !
PARAMETER L(FCC_A1,CR,FE,MO:VA;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,CR,FE,NB:VA;0) 273.00 +1E-7; 6000.00 N
REF:23 !
PARAMETER L(FCC_A1,CR,FE,NI:VA;0) 273.00 -50000+25*T; 6000 N
REF:288 !
PARAMETER L(FCC_A1,CR,FE,NI:VA;1) 273.00 -52750+15*T; 6000 N
REF:288 !
PARAMETER L(FCC_A1,CR,FE,NI:VA;2) 273.00 +9275-2.5*T; 6000 N
REF:288 !
PARAMETER L(FCC_A1,CR,FE,P:VA;0) 273.00 -115000; 6000.00 N
REF:pov12 !
PARAMETER L(FCC_A1,CR,FE,S:VA;0) 273.00 -215000; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,CR,FE,SI:VA;0) 273.00 +50000-80*T; 6000.00 N
REF:pov17 !
PARAMETER L(FCC_A1,CR,FE,TI:VA;0) 273.00 +1E-7; 6000.00 N
REF:23 !
PARAMETER L(FCC_A1,CR,FE,V:VA;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,CR,MO,NI:VA;0) 273.00 +1E-7; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,CR,NB,NI:VA;0) 273.00 -21111; 6000.00 N
REF:237 !
PARAMETER L(FCC_A1,CR,NI,W:VA;0) 273.00 +23006; 6000.00 N
REF:138 !
PARAMETER L(FCC_A1,CU,FE,MN:VA;0) 273.00 -60000+105*T; 6000.00 N
REF:87 !
PARAMETER L(FCC_A1,CU,FE,MN:VA;1) 273.00 -121140+89*T; 6000.00 N
REF:87 !
PARAMETER L(FCC_A1,CU,FE,MN:VA;2) 273.00 -160467+112*T; 6000.00 N
REF:87 !
PARAMETER L(FCC_A1,CU,FE,NI:VA;0) 273.00 -75000+30*T; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,CU,FE,SI:VA;0) 273.00 -231494.5+130*T; 6000.00 N
REF:228 !
PARAMETER L(FCC_A1,CU,FE,SI:VA;1) 273.00 -231494.5+130*T; 6000.00 N
REF:228 !
PARAMETER L(FCC_A1,CU,FE,SI:VA;2) 273.00 -231494.5+130*T; 6000.00 N
REF:228 !
PARAMETER L(FCC_A1,CU,FE,V:VA;0) 273.00 -30000; 6000.00 N
REF:228 !
PARAMETER L(FCC_A1,CU,FE,V:VA;1) 273.00 -30000; 6000.00 N
REF:228 !
PARAMETER L(FCC_A1,CU,FE,V:VA;2) 273.00 -30000; 6000.00 N
REF:228 !
PARAMETER L(FCC_A1,CU,MN,NI:VA;0) 273.00 -67000; 6000.00 N
REF:244 !
PARAMETER L(FCC_A1,CU,MN,NI:VA;1) 273.00 -49000; 6000.00 N
REF:244 !
PARAMETER L(FCC_A1,CU,MN,NI:VA;2) 273.00 -49000; 6000.00 N
REF:244 !
PARAMETER L(FCC_A1,FE,MN,MO:VA;0) 273.00 +30000; 6000.00 N
REF:23 !
PARAMETER L(FCC_A1,FE,MN,MO:VA;1) 273.00 +30000; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,FE,MN,MO:VA;2) 273.00 +30000; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,FE,MN,NI:VA;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,FE,MN,PD:VA;0) 273.00 +1E-8; 6000.00 N
REF:pov14 !
PARAMETER L(FCC_A1,FE,MN,SI:VA;0) 273.00 -63655-37.8*T; 6000.00 N
REF:293 !
PARAMETER L(FCC_A1,FE,MO,NI:VA;0) 273.00 -204791+163.93*T; 6000.00 N
REF:41 !
PARAMETER L(FCC_A1,FE,MO,NI:VA;1) 273.00 +11555-55.81*T; 6000.00 N
REF:41 !
PARAMETER L(FCC_A1,FE,MO,NI:VA;2) 273.00 +77975; 6000.00 N
REF:41 !
PARAMETER L(FCC_A1,FE,MO,SI:VA;0) 273.00 +50000-80*T; 6000.00 N
REF:pov17 !
PARAMETER L(FCC_A1,FE,NB,NI:VA;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,FE,NI,SI:VA;0) 273.00 -20000; 6000.00 N
REF:293 !
PARAMETER L(FCC_A1,FE,NI,SI:VA;1) 273.00 -100000; 6000.00 N
REF:293 !
PARAMETER L(FCC_A1,FE,NI,SI:VA;2) 273.00 -20000; 6000.00 N
REF:28 !
PARAMETER L(FCC_A1,FE,NI,TI:VA;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,FE,NI,V:VA;0) 273.00 -50000; 6000.00 N
REF:pov09 !
PARAMETER L(FCC_A1,FE,NI,W:VA;0) 273.00 -35044; 6000.00 N
REF:20 !
PARAMETER L(FCC_A1,FE,NI,W:VA;1) 273.00 +50436; 6000.00 N
REF:20 !
PARAMETER L(FCC_A1,FE,NI,W:VA;2) 273.00 +1E-7; 6000.00 N
REF:20 !
PARAMETER L(FCC_A1,FE,S,SI:VA;0) 273.00 -60000; 6000.00 N
REF:12 !
PARAMETER L(FCC_A1,MN,NI,SI:VA;0) 273.00 -279173.878; 6000.00 N
REF:251 !
PARAMETER L(FCC_A1,MN,NI,SI:VA;1) 273.00 +5888.419; 6000.00 N
REF:251 !
PARAMETER L(FCC_A1,MN,NI,SI:VA;2) 273.00 +1e-8; 6000.00 N
REF:251 !
$-------------------------------------------------------------------
$ FCC_A1 ternary interactions with C
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,AL,FE,MN:C;0) 273.00 -700000+455*T; 6000.00 N
REF:pov13 !
PARAMETER L(FCC_A1,CO,FE,NI:C;0) 273.00 -61862; 6000.00 N
REF:76 !
PARAMETER L(FCC_A1,CR,MO,V:C;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,CR,MO,V:C;1) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,CR,MO,V:C;2) 273.00 +300000; 6000.00 N
REF:pov11 !
PARAMETER L(FCC_A1,FE,MN,PD:C;0) 273.00 +100000; 6000.00 N
REF:pov13 !
$-------------------------------------------------------------------
$ FCC_A1 ternary interactions with N
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,CR,FE,MN:N;0) 273.00 -137300; 6000.00 N
REF:22 !
$-------------------------------------------------------------------
$ FCC_A1 ternary interactions with C,N,VA
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,NB:C,N,VA;0) 273.00 +1E-7; 6000.00 N
REF:16 !
PARAMETER L(FCC_A1,NB:C,N,VA;1) 273.00 +1E-7; 6000.00 N
REF:16 !
PARAMETER L(FCC_A1,NB:C,N,VA;2) 273.00 -312985; 6000.00 N
REF:16 !
$PARAMETER L(FCC_A1,TI:C,N,VA;0) 273.00 -160000; 6000.00 N
$REF:16 !
PARAMETER L(FCC_A1,TI:C,N,VA;0) 273.00 -170000; 6000.00 N
REF:103 !
$-------------------------------------------------------------------
$ FCC_A1 quaternary interactions with VA
$-------------------------------------------------------------------
PARAMETER L(FCC_A1,CR,FE,MO,NI:VA;0) 273.00 -150000; 6000.00 N
REF:23 !
$-------------------------------------------------------------------
$ FCC_A1 magnetic contribution
$-------------------------------------------------------------------
PARAMETER TC(FCC_A1,AL,NI:VA;0) 273.00 -1112; 6000.00 N
REF:89 !
PARAMETER TC(FCC_A1,AL,NI:VA;1) 273.00 +1745; 6000.00 N
REF:89 !
PARAMETER TC(FCC_A1,CO:VA;0) 273.00 +1396; 6000.00 N
REF:73 !
PARAMETER BMAGN(FCC_A1,CO:VA;0) 273.00 +1.35; 6000.00 N
REF:73 !
PARAMETER TC(FCC_A1,CO,CR:VA;0) 273.00 -1795; 6000.00 N
REF:73 !
PARAMETER TC(FCC_A1,CO,FE:VA;0) 273.00 +283; 6000.00 N
REF:74 !
PARAMETER TC(FCC_A1,CO,FE:VA;1) 273.00 +879; 6000.00 N
REF:74 !
PARAMETER BMAGN(FCC_A1,CO,FE:VA;0) 273.00 +8.407; 6000.00 N
REF:152 !
PARAMETER BMAGN(FCC_A1,CO,FE:VA;1) 273.00 -3.644; 6000.00 N
REF:152 !
PARAMETER TC(FCC_A1,CO,MN:VA;0) 273.00 -2685; 6000.00 N
REF:86 !
PARAMETER TC(FCC_A1,CO,MN:VA;1) 273.00 +3657; 6000.00 N
REF:86 !
PARAMETER BMAGN(FCC_A1,CO,MN:VA;0) 273.00 -1.07; 6000.00 N
REF:86 !
PARAMETER TC(FCC_A1,CO,MO:VA;0) 273.00 -3700; 6000.00 N
REF:78 !
PARAMETER BMAGN(FCC_A1,CO,MO:VA;0) 273.00 -3.578; 6000.00 N
REF:77 !
PARAMETER TC(FCC_A1,CO,NI:VA;0) 273.00 +411; 6000.00 N
REF:79 !
PARAMETER TC(FCC_A1,CO,NI:VA;1) 273.00 -99; 6000.00 N
REF:79 !
PARAMETER BMAGN(FCC_A1,CO,NI:VA;0) 273.00 +1.046; 6000.00 N
REF:79 !
PARAMETER BMAGN(FCC_A1,CO,NI:VA;1) 273.00 +0.165; 6000.00 N
REF:79 !
PARAMETER TC(FCC_A1,CO,W:VA;0) 273.00 -3379; 6000.00 N
REF:79 !
PARAMETER BMAGN(FCC_A1,CO,W:VA;0) 273.00 -3.268; 6000.00 N
REF:79 !
PARAMETER TC(FCC_A1,CR:VA;0) 273.00 -1109; 6000.00 N
REF:11 !
PARAMETER BMAGN(FCC_A1,CR:VA;0) 273.00 -2.46; 6000.00 N
REF:11 !
PARAMETER TC(FCC_A1,CR,NI:VA;0) 273.00 -3605; 6000.00 N
REF:11 !
PARAMETER BMAGN(FCC_A1,CR,NI:VA;0) 273.00 -1.91; 6000.00 N
REF:11 !
PARAMETER TC(FCC_A1,CR,NI:C;0) 273.00 -3605; 3000.00 N
REF:11 !
PARAMETER BMAGN(FCC_A1,CR,NI:C;0) 273.00 -1.91; 3000.00 N
REF:11 !
PARAMETER BMAGN(FCC_A1,CU,FE:VA;0) 273.00 +1e-9; 3000.00 N
REF:pov09 !
PARAMETER BMAGN(FCC_A1,CU,NI:VA;0) 273.00 -0.7316; 3000.00 N
REF:226 !
PARAMETER BMAGN(FCC_A1,CU,NI:VA;1) 273.00 -0.3174; 3000.00 N
REF:226 !
PARAMETER TC(FCC_A1,MN,PD:VA;0) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER TC(FCC_A1,CU,NI:VA;0) 273.00 -935.5; 3000.00 N
REF:226 !
PARAMETER TC(FCC_A1,CU,NI:VA;1) 273.00 -594.9; 3000.00 N
REF:226 !
PARAMETER TC(FCC_A1,FE:VA;0) 273.00 -201; 6000.00 N
REF:20 !
PARAMETER BMAGN(FCC_A1,FE:VA;0) 273.00 -2.1; 6000.00 N
REF:20 !
PARAMETER TC(FCC_A1,FE:B;0) 273.00 -201; 6000.00 N
REF:115 !
PARAMETER BMAGN(FCC_A1,FE:B;0) 273.00 -2.1; 6000.00 N
REF:115 !
PARAMETER TC(FCC_A1,FE,MN:VA;0) 273.00 -2380; 6000 N
REF:293 !
PARAMETER TC(FCC_A1,FE,MN:VA;1) 273.00 -2068; 6000 N
REF:293 !
PARAMETER TC(FCC_A1,FE,MN:VA;2) 273.00 +2800; 6000 N
REF:293 !
PARAMETER BMAGN(FCC_A1,FE,MN:VA;0) 273.00 +1.8; 6000.00 N
REF:293 !
PARAMETER TC(FCC_A1,FE,NI:VA;0) 273.00 +2100; 6000 N
REF:293 !
PARAMETER TC(FCC_A1,FE,NI:VA;1) 273.00 -1000; 6000 N
REF:293 !
PARAMETER TC(FCC_A1,FE,NI:VA;2) 273.00 -1000; 6000 N
REF:293 !
PARAMETER TC(FCC_A1,FE,NI:VA;3) 273.00 -1000; 6000 N
REF:293 !
PARAMETER BMAGN(FCC_A1,FE,NI:VA;0) 273.00 +9.5; 6000 N
REF:293 !
PARAMETER BMAGN(FCC_A1,FE,NI:VA;1) 273.00 +5.5; 6000 N
REF:293 !
PARAMETER BMAGN(FCC_A1,FE,NI:VA;2) 273.00 +1.5; 6000 N
REF:293 !
PARAMETER TC(FCC_A1,FE,NI:C;0) 273.00 +6000; 6000 N
REF:293 !
PARAMETER TC(FCC_A1,FE,NI:C;1) 273.00 +1000; 6000 N
REF:293 !
PARAMETER BMAGN(FCC_A1,FE,NI:C;0) 273.00 +9; 6000 N
REF:293 !
PARAMETER BMAGN(FCC_A1,FE,NI:C;1) 273.00 +20; 6000 N
REF:293 !
PARAMETER TC(FCC_A1,FE,PD:VA;0) 273.00 +3400; 6000.00 N
REF:pov14 !
PARAMETER TC(FCC_A1,FE,PD:VA;1) 273.00 +1500; 6000.00 N
REF:pov14 !
PARAMETER BMAGN(FCC_A1,FE,PD:VA;0) 273.00 +7; 6000.00 N
REF:pov14 !
PARAMETER BMAGN(FCC_A1,FE,PD:VA;1) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER TC(FCC_A1,FE,MN,SI:VA;0) 273.00 +13854; 6000.00 N
REF:53 !
PARAMETER TC(FCC_A1,FE:C;0) 273.00 -201; 6000.00 N
REF:11 !
PARAMETER BMAGN(FCC_A1,FE:C;0) 273.00 -2.1; 6000.00 N
REF:11 !
PARAMETER TC(FCC_A1,MN:VA;0) 273.00 -1620; 6000.00 N
REF:0 !
PARAMETER BMAGN(FCC_A1,MN:VA;0) 273.00 -1.86; 6000.00 N
REF:0 !
PARAMETER TC(FCC_A1,NI:VA;0) 273.00 +633; 6000 N
REF0 !
PARAMETER BMAGN(FCC_A1,NI:VA;0) 273.00 +.52; 6000 N
REF0 !
PARAMETER TC(FCC_A1,NI:C;0) 273.00 +633; 6000.00 N
REF:11 !
PARAMETER BMAGN(FCC_A1,NI:C;0) 273.00 +0.52; 6000.00 N
REF:11 !
PARAMETER BMAGN(FCC_A1,MN,NI:VA;0) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER BMAGN(FCC_A1,MN,NI:VA;1) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER TC(FCC_A1,MN,NI:VA;0) 273.00 -3171.2; 6000.00 N
REF:244 !
PARAMETER TC(FCC_A1,MN,NI:VA;1) 273.00 -4317.7323; 6000.00 N
REF:244 !
PARAMETER TC(FCC_A1,NI,TI:VA;0) 273.00 -2500; 6000.00 N
REF:160 !
PARAMETER TC(FCC_A1,NI,TI:VA;1) 273.00 -3000; 6000.00 N
REF:160 !
PARAMETER TC(FCC_A1,NI,TI:VA;2) 273.00 +1300; 6000.00 N
REF:160 !
$
PARAMETER BMAGN(FCC_A1,CU,FE,NI:VA;0) 273.00 +20; 6000.00 N
REF:224 !
PARAMETER TC(FCC_A1,CU,FE,NI:VA;0) 273.00 +7000; 6000.00 N
REF:224 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: BCC_A2
$###########################################################################
$
TYPE_DEFINITION & GES A_P_D BCC_A2 MAGNETIC -1.0 0.4 !
PHASE BCC_A2 %& 2 1 3 >
Body-centered cubic Ferrite phase.
>> 6 !
CONSTITUENT BCC_A2 : AL,CO,CR,CU,FE%,HF,LA,MN,MO,NB,NI,P,PD,S,SI,TI,
V,W,Y : B,C,H,N,O,VA% : !
$-------------------------------------------------------------------
$ BCC_A2 endmember compounds with VA
$-------------------------------------------------------------------
$PARAMETER G(BCC_A2,VA:VA;0) 273.00 +0; 6000 N
$REF:0 !
PARAMETER G(BCC_A2,AL:VA;0) 273.00 +10083-4.813*T+GHSERAL#; 2900.00 N
REF:0 !
PARAMETER G(BCC_A2,CO:VA;0) 273.00 +GCOBCC#; 6000.00 N
REF:73 !
PARAMETER G(BCC_A2,CR:VA;0) 273.00 +GHSERCR#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,CU:VA;0) 273.00 +4017-1.255*T+GHSERCU#; 3200.00 N
REF:0 !
PARAMETER G(BCC_A2,FE:VA;0) 273.00 +GHSERFE#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,FE:H;0) 273.00 +GHSERFE#+1.5*GHSERHH#
+258000-3170*T+498*T*LN(T)-0.275*T**2; 1811.00 Y
+232264+82*T+1*GHSERFE#+1.5*GHSERHH#; 6000.00 N
REF:pov14 !
PARAMETER G(BCC_A2,HF:VA;0) 273.00 +GHFBCC#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,LA:VA;0) 273.00 +GLABCC#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,MN:VA;0) 273.00 +GMNBCC#; 6000.00 N
REF:66 !
PARAMETER G(BCC_A2,MO:VA;0) 273.00 +GHSERMO#; 5000.00 N
REF:0 !
PARAMETER G(BCC_A2,NB:VA;0) 273.00 +GHSERNB#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,NI:VA;0) 273.00 +8715.084-3.556*T+GHSERNI#; 3000.00 N
REF:0 !
PARAMETER G(BCC_A2,P:VA;0) 273.00 +GPBCC#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,PD:VA;0) 273.00 +GPDBCC#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,S:VA;0) 273.00 +105000+GHSERSS#; 6000.00 N
REF:82 !
PARAMETER G(BCC_A2,SI:VA;0) 273.00 +47000-22.5*T+GHSERSI#; 3600.00 N
REF:0 !
PARAMETER G(BCC_A2,TI:VA;0) 273.00 +GTIBCC#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,V:VA;0) 273.00 +GHSERVV#; 4000.00 N
REF:0 !
PARAMETER G(BCC_A2,W:VA;0) 273.00 +GHSERWW#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,Y:VA;0) 273.00 +GYYBCC#; 6000.00 N
REF:0 !
$-------------------------------------------------------------------
$ BCC_A2 endmember compounds with B
$-------------------------------------------------------------------
$ B-solubility in Fe only roughly known, big experimental spread
PARAMETER G(BCC_A2,CR:B;0) 273.00 +GHSERCR#+3*GHSERBB#
-2657+4.24*T; 6000.00 N
REF:114 !
PARAMETER G(BCC_A2,FE:B;0) 273.00 +GHSERFE#+3*GHSERBB#+6000+50*T; 6000.00 N
REF:pov10 !
PARAMETER G(BCC_A2,MN:B;0) 273.00 +GMNBCC#+3*GHSERBB#; 6000.00 N
REF:245 !
PARAMETER G(BCC_A2,MO:B;0) 273.00 +GHSERMO#+3*GHSERBB#-60000; 6000.00 N
REF:pov15 !
PARAMETER G(BCC_A2,NB:B;0) 273.00 +GHSERNB#+3*GHSERBB#
-321703+125.621*T; 6000.00 N
REF:117 !
PARAMETER G(BCC_A2,TI:B;0) 273.00 +GTIBCC#+3*GHSERBB#
-239999; 6000.00 N
REF:117 !
PARAMETER G(BCC_A2,V:B;0) 273.00 +GHSERVV#+3*GHSERBB#
-170000+67*T; 6000.00 N
REF:235 !
$-------------------------------------------------------------------
$ BCC_A2 endmember compounds with C
$-------------------------------------------------------------------
PARAMETER G(BCC_A2,AL:C;0) 273.00 +GHSERAL#+3*GHSERCC#
+100000+80*T; 6000.0 N
REF:155 !
PARAMETER G(BCC_A2,CO:C;0) 273.00 +GHSERCO#+3*GHSERCC#
+248204-31.271*T; 6000.00 N
REF:73 !
PARAMETER G(BCC_A2,CR:C;0) 273.00 +GHSERCR#+3*GHSERCC#
+416000; 6000.00 N
REF:11 !
PARAMETER G(BCC_A2,FE:C;0) 273.00 +171505+179.7*T+GHSERFE#
+3*GHSERCC#; 6000.00 N
REF:293 !
PARAMETER G(BCC_A2,MN:C;0) 273.00 +10000+30*T+GHSERMN#
+3*GHSERCC#; 6000.00 N
REF:15 !
PARAMETER G(BCC_A2,MO:C;0) 273.00 +331000-75*T+GHSERMO#
+3*GHSERCC#; 6000.00 N
REF:17 !
PARAMETER G(BCC_A2,NB:C;0) 273.00 +520879-70.807*T+GHSERNB#
+3*GHSERCC#; 6000.00 N
REF:19 !
PARAMETER G(BCC_A2,NI:C;0) 273.00 +400000-100*T+GHSERNI#
+3*GHSERCC#; 6000.00 N
REF:11 !
PARAMETER G(BCC_A2,P:C;0) 273.00 +GPRED#+3*GHSERCC#+1308832.45; 6000.00 N
REF:229 !
PARAMETER G(BCC_A2,PD:C;0) 273.00 +GPDBCC#+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(BCC_A2,S:C;0) 273.00 +GHSERSS#+3*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(BCC_A2,SI:C;0) 273.00 +369050-98.167*T+GHSERSI#
+3*GHSERCC#; 6000.00 N
REF:24 !
$PARAMETER G(BCC_A2,TI:C;0) 273.00 +2*GHSERCC#+GTIC#+600000; 4000.00 N
$REF:16 !
PARAMETER G(BCC_A2,TI:C;0) 273.00 +2*GHSERCC#+GTIC#+200000; 4000.00 N
REF:Frisk03 !
PARAMETER G(BCC_A2,V:C;0) 273.00 +108449+GHSERVV#+3*GHSERCC#; 6000.00 N
REF:15 !
PARAMETER G(BCC_A2,W:C;0) 273.00 +375100-35.87*T+GHSERWW#
+3*GHSERCC#; 6000.00 N
REF:19 !
$-------------------------------------------------------------------
$ BCC_A2 endmember compounds with N
$-------------------------------------------------------------------
PARAMETER G(BCC_A2,AL:N;0) 273.00 +23000+10*T+GHSERAL#
+3*GHSERNN#; 6000.00 N
REF:92 !
PARAMETER G(BCC_A2,CR:N;0) 273.00 +GHSERCR#+3*GHSERNN#+311870
+29.12*T; 6000.00 N
REF:22 !
PARAMETER G(BCC_A2,FE:N;0) 273.00 +93562+165.07*T+GHSERFE#
+3*GHSERNN#; 6000.00 N
REF:22 !
PARAMETER G(BCC_A2,MN:N;0) 273.00 -55600+606.648*T
-100.41*T*LN(T)+844897*T**(-1); 2500.00 N
REF:22 !
PARAMETER G(BCC_A2,MO:N;0) 273.00 +299700+79.73*T+GHSERMO#
+3*GHSERNN#; 6000.00 N
REF:64 !
$PARAMETER G(BCC_A2,NB:N;0) 273.00 -207283+110.085*T+GHSERNB#
$ +3*GHSERNN#; 6000.00 N
$REF:16 !
PARAMETER G(BCC_A2,NB:N;0) 273.00 +4273902-324.302*T+GHSERNB
+3*GHSERNN; 6000 N
REF:262 !
PARAMETER G(BCC_A2,NI:N;0) 273.00 +200000+200*T+GHSERNI#
+3*GHSERNN#; 6000.00 N
REF:30 !
PARAMETER G(BCC_A2,S:N;0) 273.00 +GHSERSS#+3*GHSERNN#; 6000.00 N
REF:pov13 !
PARAMETER G(BCC_A2,TI:N;0) 273.00 +2604202+118.04*T+GTIN#
+2*GHSERNN#; 6000.00 N
REF:16 !
PARAMETER G(BCC_A2,V:N;0) 273.00 +843000+GHSERVV#
+3*GHSERNN#; 6000.00 N
REF:48 !
PARAMETER G(BCC_A2,W:N;0) 273.00 +268828.908+444.620024*T
-72.7446506*T*LN(T)+1079965*T**(-1)-0.0251743468*T**2; 6000.00 N
REF:140 !
$-------------------------------------------------------------------
$ BCC_A2 endmember compounds with O
$-------------------------------------------------------------------
PARAMETER G(BCC_A2,AL:O;0) 273.00 +10083-4.813*T+GHSERAL#
+3*GHSEROO#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,CO:O;0) 273.00 +GCOBCC#+3*GHSEROO#; 6000.00 N
REF:73 !
PARAMETER G(BCC_A2,CR:O;0) 273.00 +GHSERCR#+3*GHSEROO#
+243*T; 6000.00 N
REF:198 !
PARAMETER G(BCC_A2,CU:O;0) 273.00 +4017-1.255*T+GHSERCU#
+3*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(BCC_A2,FE:O;0) 273.00 +GHSERFE#+3*GHSEROO#
+271.74*T; 6000.00 N
REF:194 !
PARAMETER G(BCC_A2,HF:O;0) 273.00 +GHSERHF#+3*GHSEROO#
-737857+268.540*T; 6000.00 N
REF:219 !
PARAMETER G(BCC_A2,LA:O;0) 273.00 +GHSERLA#+3*GHSEROO#
+35*T; 6000.00 N
REF:197 !
PARAMETER G(BCC_A2,MN:O;0) 273.00 +GMNBCC#+3*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(BCC_A2,MO:O;0) 273.00 +GHSERMO#
+3*GHSEROO#; 6000.00 N
REF:POV12 !
PARAMETER G(BCC_A2,NB:O;0) 273.00 +GHSERNB#+3*GHSEROO#; 6000.00 N
REF:0 !
PARAMETER G(BCC_A2,NI:O;0) 273.00 +GNIBCC#
+3*GHSEROO#+195*T; 6000.00 N
REF:199 !
PARAMETER G(BCC_A2,S:O;0) 273.00 +105000+GHSERSS#+3*GHSEROO#; 6000.00 N
REF:82 !
PARAMETER G(BCC_A2,SI:O;0) 273.00 +47000-22.5*T+GHSERSI#
+3*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(BCC_A2,TI:O;0) 273.00 +GTIBCC#+3*GHSEROO#-400000; 6000.00 N
REF:240 !
PARAMETER G(BCC_A2,V:O;0) 273.00 +GHSERVV#+3*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(BCC_A2,W:O;0) 273.00 +GHSERWW#+3*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(BCC_A2,Y:O;0) 273.00 +GYYBCC#+3*GHSEROO#-158000
+114.1952*T; 6000.00 N
REF:238 !
$******************** binary interactions ***************************
$-------------------------------------------------------------------
$ BCC_A2 binary interactions with VA
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,AL,CR:VA;0) 273.00 -54900+10*T; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,AL,CU:VA;0) 273.00 -73554+4*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,AL,CU:VA;1) 273.00 +51500-11.84*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,AL,FE:VA;0) 273.00 -122960+31.9888*T; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,AL,FE:VA;1) 273.00 +3089.2; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,AL,HF:VA;0) 273.00 -144994; 6000.00 N
REF:214 !
PARAMETER L(BCC_A2,AL,HF:VA;1) 273.00 -50257+21.950*T; 6000.00 N
REF:214 !
PARAMETER L(BCC_A2,AL,HF:VA;2) 273.00 -2946+19.983*T; 6000.00 N
REF:214 !
PARAMETER L(BCC_A2,AL,MN:VA;0) 273.00 -120077+52.851*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,AL,MN:VA;1) 273.00 -40652+29.276*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,AL,MO:VA;0) 273.00 -75000+25*T; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,AL,NB:VA;0) 273.00 -104050+30*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,AL,NB:VA;1) 273.00 +9140-4*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,AL,NB:VA;2) 273.00 +12000; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,AL,NI:VA;0) 273.00 +B2ALNI#+LB2ALNI#; 6000.00 N
REF:89 !
PARAMETER L(BCC_A2,AL,SI:VA;0) 273.00 -3432+0.204*T; 6000.00 N
REF:pov09 !
PARAMETER L(BCC_A2,AL,TI:VA;0) 273.00 -132903+39.961*T; 6000.00 N
REF:159 !
PARAMETER L(BCC_A2,AL,TI:VA;1) 273.00 +4890; 6000.00 N
REF:159 !
PARAMETER L(BCC_A2,AL,TI:VA;2) 273.00 +400; 6000.00 N
REF:159 !
PARAMETER L(BCC_A2,AL,V:VA;0) 273.00 -95000+20*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,AL,V:VA;1) 273.00 -6000; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,CO,CR:VA;0) 273.00 +17208-13.519*T; 6000.00 N
REF:73 !
PARAMETER L(BCC_A2,CO,CR:VA;1) 273.00 -5470; 6000.00 N
REF:73 !
PARAMETER L(BCC_A2,CO,CU:VA;0) 273.00 +35000; 6000.00 N
REF:87 !
PARAMETER L(BCC_A2,CO,FE:VA;0) 273.00 -26222.7+125*T-15.5020*T*LN(T)
-632250*T**(-1); 6000.00 N
REF:152 !
PARAMETER L(BCC_A2,CO,FE:VA;2) 273.00 +2686.79+632250*T**(-1); 6000.00 N
REF:152 !
PARAMETER L(BCC_A2,CO,MN:VA;0) 273.00 -23945; 6000.00 N
REF:87 !
PARAMETER L(BCC_A2,CO,MO:VA;0) 273.00 +5000+7.597*T; 6000.00 N
REF:77 !
PARAMETER L(BCC_A2,CO,MO:VA;1) 273.00 -19208.67; 6000.00 N
REF:77 !
PARAMETER L(BCC_A2,CO,NB:VA;0) 273.00 +6627; 6000.00 N
REF:136 !
PARAMETER L(BCC_A2,CO,NI:VA;0) 273.00 +2000; 6000.00 N
REF:79 !
PARAMETER L(BCC_A2,CO,V:VA;0) 273.00 -35366.216+17.435*T; 6000.00 N
REF:134 !
PARAMETER L(BCC_A2,CO,W:VA;0) 273.00 +56517; 6000.00 N
REF:79 !
PARAMETER L(BCC_A2,CR,CU:VA;0) 273.00 +80000; 6000.00 N
REF:pov16 !
PARAMETER G(BCC_A2,CR,FE:VA;0) 273.00 +24600-14.98*T; 6000 N
REF:287 !
PARAMETER G(BCC_A2,CR,FE:VA;1) 273.00 +500-1.5*T; 6000 N
REF:287 !
PARAMETER G(BCC_A2,CR,FE:VA;2) 273.00 -14000+9.15*T; 6000 N
REF:287 !
PARAMETER L(BCC_A2,CR,LA:VA;0) 273.00 +40000; 6000.00 N
REF:205 !
PARAMETER L(BCC_A2,CR,LA:VA;2) 273.00 +25000; 6000.00 N
REF:205 !
PARAMETER L(BCC_A2,CR,MN:VA;0) 273.00 -20328+18.7339*T; 6000.00 N
REF:22 !
PARAMETER L(BCC_A2,CR,MN:VA;1) 273.00 -9162+4.4183*T; 6000.00 N
REF:22 !
PARAMETER L(BCC_A2,CR,MO:VA;0) 273.00 +28890-7.962*T; 6000.00 N
REF:39 !
PARAMETER L(BCC_A2,CR,MO:VA;1) 273.00 +5974-2.428*T; 6000.00 N
REF:39 !
PARAMETER L(BCC_A2,CR,NB:VA;0) 273.00 +43426.41-13.01153*T; 6000.00 N
REF:45 !
PARAMETER L(BCC_A2,CR,NB:VA;1) 273.00 +13201.20-6.666*T; 6000.00 N
REF:45 !
PARAMETER L(BCC_A2,CR,NI:VA;0) 273.00 +17170-11.8199*T; 6000.00 N
REF:11 !
PARAMETER L(BCC_A2,CR,NI:VA;1) 273.00 +34418-11.8577*T; 6000.00 N
REF:11 !
PARAMETER L(BCC_A2,CR,NI:VA;2) 273.00 +1e-8; 6000.00 N
REF:11 !
PARAMETER L(BCC_A2,CR,P:VA;0) 273.00 -70000; 6000.00 N
REF:230 !
PARAMETER L(BCC_A2,CR,SI:VA;0) 273.00 -104537.94+10.69527*T; 6000.00 N
REF:46 !
PARAMETER L(BCC_A2,CR,SI:VA;1) 273.00 -47614.70+12.17363*T; 6000.00 N
REF:46 !
PARAMETER L(BCC_A2,CR,TI:VA;0) 273.00 +19100; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,CR,TI:VA;1) 273.00 +5500; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,CR,TI:VA;2) 273.00 +1750; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,CR,V:VA;0) 273.00 -9875-2.6964*T; 6000.00 N
REF:68 !
PARAMETER L(BCC_A2,CR,V:VA;1) 273.00 -1720-2.5237*T; 6000.00 N
REF:68 !
PARAMETER L(BCC_A2,CR,W:VA;0) 273.00 +31520; 6000.00 N
REF:138 !
PARAMETER L(BCC_A2,CR,W:VA;1) 273.00 -1320; 6000.00 N
REF:138 !
PARAMETER L(BCC_A2,CR,Y:VA;0) 273.00 +69000; 6000.00 N
REF:205 !
PARAMETER L(BCC_A2,CR,Y:VA;1) 273.00 -14000; 6000.00 N
REF:205 !
PARAMETER L(BCC_A2,CU,FE:VA;0) 273.00 +56000-13.9*T; 6000.00 N
REF:pov15 !
PARAMETER L(BCC_A2,CU,MN:VA;0) 273.00 +18366.034-16.2210*T; 6000.00 N
REF:84 !
PARAMETER L(BCC_A2,CU,MN:VA;1) 273.00 -12667.53; 6000.00 N
REF:84 !
PARAMETER L(BCC_A2,CU,NB:VA;0) 273.00 +49480.18; 6000.00 N
REF:44 !
PARAMETER L(BCC_A2,CU,NI:VA;0) 273.00 +8366+2.802*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,CU,SI:VA;0) 273.00 -21740+3.9*T; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,CU,SI:VA;1) 273.00 -40000-4.39*T; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,CU,SI:VA;2) 273.00 -100; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,CU,V:VA;0) 273.00 +42377.8; 6000.00 N
REF:131 !
PARAMETER L(BCC_A2,FE,HF:VA;0) 273.00 -61204.7427+32.8179*T; 6000.00 N
REF:218 !
PARAMETER L(BCC_A2,FE,HF:VA;1) 273.00 28434.7786-15.0043*T; 6000.00 N
REF:218 !
PARAMETER L(BCC_A2,FE,LA:VA;0) 273.00 +30358+23.67*T; 6000.00 N
REF:197 !
PARAMETER L(BCC_A2,FE,MN:VA;0) 273.00 +4300-4.55*T; 6000.00 N
REF:293 !
PARAMETER L(BCC_A2,FE,MN:VA;1) 273.00 +1000-0.35*T; 6000 N
REF:293 !
PARAMETER L(BCC_A2,FE,MO:VA;0) 273.00 +36818-9.141*T; 6000.00 N
REF:51 !
PARAMETER L(BCC_A2,FE,MO:VA;1) 273.00 -362-5.724*T; 6000.00 N
REF:51 !
$PARAMETER L(BCC_A2,FE,NB:VA;0) 273.00 -4400+6.333*T; 6000.00 N
$REF:113 !
PARAMETER L(BCC_A2,FE,NB:VA;0) 273.00 -10983+10.288*T; 6000 N
REF:pov23 !
PARAMETER L(BCC_A2,FE,NB:VA;1) 273.00 +4674-5.776*T; 6000.00 N
REF:pov23 !
PARAMETER L(BCC_A2,FE,NB:VA;2) 273.00 +1500; 6000.00 N
REF:pov23 !
PARAMETER G(BCC_A2,FE,NI:VA;0) 273.00 -8000; 6000.00 N
REF:293 !
PARAMETER G(BCC_A2,FE,NI:VA;1) 273.00 +8000-5*T; 6000 N
REF:293 !
PARAMETER L(BCC_A2,FE,P:VA;0) 273.00 -161978+19.807*T; 6000.00 N
REF:230 !
PARAMETER G(BCC_A2,FE,PD:VA;0) 273.00 -38705.8678-12.9870*T; 6000.00 N
REF:242 !
PARAMETER G(BCC_A2,FE,PD:VA;1) 273.00 +54410.3132-15.1683*T; 6000.00 N
REF:242 !
PARAMETER L(BCC_A2,FE,S:VA;0) 273.00 -119675-18.7201*T; 6000.00 N
REF:82 !
PARAMETER G(BCC_A2,FE,SI:VA;0) 273.00 -154013.56+32.29*T;
6.00000E+03 N
REF:291 !
PARAMETER G(BCC_A2,FE,SI:VA;1) 273.00 -63511.47+13.25*T;
6.00000E+03 N
REF:291 !
PARAMETER G(BCC_A2,FE,SI:VA;2) 273.00 35727.58; 6000 N
REF:291 !
PARAMETER L(BCC_A2,FE,TI:VA;0) 273.00 -59098+11.5*T; 6000.00 N
REF:16 !
PARAMETER L(BCC_A2,FE,TI:VA;1) 273.00 -1796+1*T; 6000.00 N
REF:16 !
PARAMETER L(BCC_A2,FE,TI:VA;2) 273.00 +5602+3.5*T; 6000.00 N
REF:16 !
PARAMETER L(BCC_A2,FE,V:VA;0) 273.00 -23674+0.465*T; 6000.00 N
REF:15 !
PARAMETER L(BCC_A2,FE,V:VA;1) 273.00 +8283; 6000.00 N
REF:15 !
PARAMETER L(BCC_A2,FE,W:VA;0) 273.00 +41544; 6000.00 N
REF:20 !
PARAMETER L(BCC_A2,FE,W:VA;1) 273.00 -12621; 6000.00 N
REF:20 !
PARAMETER L(BCC_A2,FE,Y:VA;1) 273.00 -15000; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,LA,NI:VA;0) 273.00 +100000; 6000.00 N
REF:222 !
PARAMETER L(BCC_A2,MN,MO:VA;0) 273.00 +10000; 6000.00 N
REF:pov13 !
PARAMETER L(BCC_A2,MN,NI:VA;0) 273.00 -3508.428-23.78856*T; 6000.00 N
REF:244 !
PARAMETER L(BCC_A2,MN,PD:VA;0) 273.00 -25000-25*T; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,MN,PD:VA;1) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,MN,S:VA;0) 273.00 -249000+13*T; 6000.00 N
REF:81 !
PARAMETER L(BCC_A2,MN,SI:VA;0) 273.00 -89620.7+2.94097*T; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,MN,SI:VA;1) 273.00 -7500; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,MN,TI:VA;0) 273.00 -23200+20*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,MN,TI:VA;1) 273.00 -1000; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,MN,V:VA;0) 273.00 -10000; 6000.00 N
REF:15 !
PARAMETER L(BCC_A2,MO,NB:VA;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,MO,NI:VA;0) 273.00 +46422; 6000.00 N
REF:39 !
PARAMETER L(BCC_A2,MO,SI:VA;0) 273.00 -60000+5*T; 6000.00 N
REF:132 !
PARAMETER L(BCC_A2,MO,TI:VA;0) 273.00 +3383.4-10.0774*T; 6000.00 N
REF:125 !
PARAMETER L(BCC_A2,MO,TI:VA;1) 273.00 -56704.6+32.12*T; 6000.00 N
REF:125 !
PARAMETER L(BCC_A2,MO,TI:VA;2) 273.00 -15172.4; 6000.00 N
REF:125 !
PARAMETER L(BCC_A2,MO,V:VA;0) 273.00 +19245; 6000.00 N
REF:38 !
PARAMETER L(BCC_A2,MO,W:VA;0) 273.00 +2000; 6000.00 N
REF:55 !
PARAMETER L(BCC_A2,NB,NI:VA;0) 273.00 -18724.3+5.02405*T; 6000.00 N
REF:54 !
PARAMETER L(BCC_A2,NB,P:VA;0) 273.00 -328900+12.49*T; 6000.00 N
REF:232 !
PARAMETER L(BCC_A2,NB,P:VA;1) 273.00 +128100-16.36*T; 6000.00 N
REF:232 !
PARAMETER L(BCC_A2,NB,SI:VA;0) 273.00 -154000+17*T; 6000.00 N
REF:128 !
PARAMETER L(BCC_A2,NB,SI:VA;1) 273.00 -17000; 6000.00 N
REF:128 !
PARAMETER L(BCC_A2,NB,SI:VA;2) 273.00 +35000; 6000.00 N
REF:128 !
PARAMETER L(BCC_A2,NB,TI:VA;0) 273.00 +14000; 6000.00 N
REF:16 !
PARAMETER L(BCC_A2,NB,V:VA;0) 273.00 +1e-8; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,NB,W:VA;0) 273.00 -34343+6.074*T; 6000.00 N
REF:19 !
PARAMETER L(BCC_A2,NB,Y:VA;0) 273.00 +150000; 6000.00 N
REF:213 !
PARAMETER L(BCC_A2,NI,P:VA;0) 273.00 -176522.3-8.6002*T; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,NI,TI:VA;0) 273.00 -97427+12.112*T; 6000.00 N
REF:160 !
PARAMETER L(BCC_A2,NI,TI:VA;1) 273.00 -32315; 6000.00 N
REF:160 !
PARAMETER L(BCC_A2,NI,V:VA;0) 273.00 -30513.8+12.6138*T; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,NI,W:VA;0) 273.00 +82000; 6000.00 N
REF:20 !
PARAMETER L(BCC_A2,NI,Y:VA;0) 273.00 -2000; 6000.00 N
REF:213 !
PARAMETER L(BCC_A2,P,TI:VA;0) 273.00 -170000; 6000.00 N
REF:233 !
PARAMETER L(BCC_A2,SI,TI:VA;0) 273.00 -275629+42.509*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,SI,TI:VA;1) 273.00 +25025-2.002*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,SI,TI:VA;2) 273.00 +83941-6.715*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,SI,V:VA;0) 273.00 -205373.1+61.02211*T; 6000.00 N
REF:129 !
PARAMETER L(BCC_A2,TI,V:VA;0) 273.00 +10500-1.5*T; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,TI,V:VA;1) 273.00 +2000; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,TI,V:VA;2) 273.00 +1000; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,TI,W:VA;0) 273.00 +4313+12.761*T; 6000.00 N
REF:139 !
PARAMETER L(BCC_A2,TI,W:VA;1) 273.00 +9768-3.785*T; 6000.00 N
REF:139 !
$-------------------------------------------------------------------
$ BCC_A2 binary interactions with B
$-------------------------------------------------------------------
$
$-------------------------------------------------------------------
$ BCC_A2 binary interactions with C
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,AL,FE:C;0) 273.00 +1e-8; 6000.00 N
REF:155 !
PARAMETER L(BCC_A2,AL,FE:C;1) 273.00 +1e-8; 6000.00 N
REF:155 !
PARAMETER L(BCC_A2,CO,CR:C;0) 273.00 +17208-13.519*T; 6000.00 N
REF:73 !
PARAMETER L(BCC_A2,CO,CR:C;1) 273.00 -5470; 6000.00 N
REF:73 !
PARAMETER L(BCC_A2,CO,NI:C;0) 273.00 +6000; 6000.00 N
REF:76 !
PARAMETER L(BCC_A2,CO,W:C;0) 273.00 -100000; 6000.00 N
REF:79 !
$Careful - preliminary parameter
PARAMETER L(BCC_A2,CR,FE:C;0) 273.00 -1320000+667.7*T; 6000.00 N
REF:khvan14 !
PARAMETER L(BCC_A2,CR,MN:C;0) 273.00 -20328+18.7339*T; 6000.00 N
REF:58 !
PARAMETER L(BCC_A2,CR,MN:C;1) 273.00 -9162+4.4183*T; 6000.00 N
REF:58 !
PARAMETER L(BCC_A2,FE,MN:C;0) 273.00 +0; 6000.00 N
REF:255!
PARAMETER L(BCC_A2,FE,MO:C;0) 273.00 -1750000+940*T; 6000.00 N
REF:27 !
PARAMETER L(BCC_A2,FE,NI:C;0) 273.00 -956.63-1.28726*T; 6000.00 N
REF:20 !
PARAMETER L(BCC_A2,FE,NI:C;1) 273.00 +1789.03-1.92912*T; 6000.00 N
REF:20 !
PARAMETER L(BCC_A2,FE,SI:C;0) 273.00 +1000000-100*T; 6000.00 N
REF:25 !
PARAMETER L(BCC_A2,FE,SI:C;1) 273.00 -900000; 6000.00 N
REF:25 !
PARAMETER L(BCC_A2,FE,V:C;0) 273.00 -23674+0.465*T; 6000.00 N
REF:15 !
PARAMETER L(BCC_A2,FE,V:C;1) 273.00 +8283; 6000.00 N
REF:15 !
PARAMETER L(BCC_A2,FE,W:C;0) 273.00 -140000; 6000.00 N
REF:20 !
PARAMETER L(BCC_A2,MN,V:C;0) 273.00 -10000; 6000.00 N
REF:15 !
PARAMETER L(BCC_A2,MO,TI:C;0) 273.00 -175027.2; 6000.00 N
REF:125 !
PARAMETER L(BCC_A2,MO,V:C;0) 273.00 +330000; 6000.00 N
REF:38 !
PARAMETER L(BCC_A2,MO,W:C;0) 273.00 +2000; 6000.00 N
REF:18 !
PARAMETER L(BCC_A2,NI,W:C;0) 273.00 +1E-8; 6000.00 N
REF:20 !
$-------------------------------------------------------------------
$ BCC_A2 binary interactions with N
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,CR,FE:N;0) 273.00 -799379+293*T; 6000.00 N
REF:22 !
PARAMETER L(BCC_A2,FE,MO:N;0) 273.00 -151200; 6000.00 N
REF:40 !
$-------------------------------------------------------------------
$ BCC_A2 binary interactions with B,VA
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,CR:B,VA;0) 273.00 -28702-13.9*T; 6000.00 N
REF:114 !
PARAMETER L(BCC_A2,NB:B,VA;0) 273.00 -167421; 6000.00 N
REF:117 !
PARAMETER L(BCC_A2,TI:B,VA;0) 273.00 -14723; 6000.00 N
REF:117 !
$-------------------------------------------------------------------
$ BCC_A2 binary interactions with C,VA
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,AL:C,VA;0) 273.00 +130000+14*T; 6000.00 N
REF:155 !
PARAMETER L(BCC_A2,CR:C,VA;0) 273.00 -190*T; 6000.00 N
REF:11 !
PARAMETER L(BCC_A2,FE:C,VA;0) 273.00 +138000-283*T; 6000.00 N
REF:293 !
PARAMETER L(BCC_A2,NB:C,VA;0) 273.00 -588143; 6000.00 N
REF:19 !
PARAMETER L(BCC_A2,MO:C,VA;0) 273.00 -50000; 6000.00 N
REF:17 !
$PARAMETER L(BCC_A2,TI:C,VA;0) 273.00 -881180+45.5*T; 6000.00 N
$REF:16 !
PARAMETER L(BCC_A2,TI:C,VA;0) 273.00 -555895+65.883*T; 6000.00 N
REF:Frisk03 !
PARAMETER L(BCC_A2,V:C,VA;0) 273.00 -297868; 6000.00 N
REF:15 !
$-------------------------------------------------------------------
$ BCC_A2 binary interactions with N,VA
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,CR:N,VA;0) 273.00 -250000; 6000.00 N
REF:pov12 !
PARAMETER L(BCC_A2,MN:N,VA;0) 273.00 -185000; 6000.00 N
REF:22 !
$PARAMETER L(BCC_A2,NB:N,VA;0) 273.00 -357277+129.474*T; 6000.00 N
$REF:16 !
$PARAMETER L(BCC_A2,NB:N,VA;1) 273.00 +1e-8; 6000.00 N
$REF:16 !
PARAMETER L(BCC_A2,NB:N,VA;0) 273.00 -6778349+577.778*T; 6000 N
REF:262 !
PARAMETER L(BCC_A2,NB:N,VA;1) 273.00 -1917408; 6000 N
REF:262 !
PARAMETER L(BCC_A2,TI:N,VA;0) 273.00 -3215338; 6000.00 N
REF:16 !
PARAMETER L(BCC_A2,V:N,VA;0) 273.00 -1680000+325*T; 6000.00 N
REF:48 !
PARAMETER L(BCC_A2,W:N,VA;0) 273.00 +83285-69.977*T; 6000.00 N
REF:140 !
$-------------------------------------------------------------------
$ BCC_A2 binary interactions with O,VA
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,CR:O,VA;0) 273.00 -709542; 6000.00 N
REF:198 !
PARAMETER L(BCC_A2,FE:O,VA;0) 273.00 -526267.6; 6000.00 N
REF:197 !
PARAMETER L(BCC_A2,HF:O,VA;0) 273.00 -981440+20.349*T; 6000.00 N
REF:194 !
PARAMETER L(BCC_A2,LA:O,VA;0) 273.00 -1400000; 6000.00 N
REF:197 !
PARAMETER L(BCC_A2,MO:O,VA;0) 273.00 -725000+400*T; 6000.00 N
REF:POV12 !
PARAMETER L(BCC_A2,NI:O,VA;0) 273.00 -400000+50*T; 6000.00 N
REF:199 !
PARAMETER L(BCC_A2,TI:O,VA;0) 273.00 -1207294+274.32*T; 6000.00 N
REF:240 !
PARAMETER L(BCC_A2,Y:O,VA;0) 273.00 -2500000+195*T; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,Y:O,VA;1) 273.00 -764174; 6000.00 N
REF:238 !
$-------------------------------------------------------------------
$ BCC_A2 binary interactions with C,N
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,TI:C,N;0) 273.00 -11540+20*T; 6000.00 N
REF:103 !
$******************** ternary interactions ***************************
$-------------------------------------------------------------------
$ BCC_A2 ternary interactions with VA
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,AL,CR,NI:VA;0) 273.00 +42500; 6000.00 N
REF:91 !
PARAMETER L(BCC_A2,AL,FE,MN:VA;0) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,AL,FE,MN:VA;1) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,AL,FE,MN:VA;2) 273.00 -2000+13*T; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,AL,FE,NI:VA;0) 273.00 -85763.63; 6000.00 N
REF:292 !
PARAMETER L(BCC_A2,AL,FE,NI:VA;1) 273.00 -23327.05; 6000.00 N
REF:292 !
PARAMETER L(BCC_A2,AL,FE,NI:VA;2) 273.00 -63420.34; 6000.00 N
REF:292 !
PARAMETER L(BCC_A2,AL,TI,V:VA;0) 273.00 +32045.963; 6000.00 N
REF:92 !
PARAMETER L(BCC_A2,CO,CR,CU:VA;0) 273.00 +1e-8; 6000.00 N
REF:130 !
PARAMETER L(BCC_A2,CO,CR,CU:VA;1) 273.00 -220000; 6000.00 N
REF:130 !
PARAMETER L(BCC_A2,CO,CR,CU:VA;2) 273.00 +1e-8; 6000.00 N
REF:130 !
PARAMETER L(BCC_A2,CO,CU,FE:VA;0) 273.00 -155000+75*T; 6000.00 N
REF:228 !
PARAMETER L(BCC_A2,CO,CU,FE:VA;1) 273.00 -155000+75*T; 6000.00 N
REF:228 !
PARAMETER L(BCC_A2,CO,CU,FE:VA;2) 273.00 -155000+75*T; 6000.00 N
REF:228 !
PARAMETER L(BCC_A2,CO,CU,MN:VA;0) 273.00 +5000; 6000.00 N
REF:87 !
PARAMETER L(BCC_A2,CO,CU,MN:VA;1) 273.00 +5000; 6000.00 N
REF:87 !
PARAMETER L(BCC_A2,CO,CU,MN:VA;2) 273.00 +5000; 6000.00 N
REF:87 !
PARAMETER L(BCC_A2,CO,FE,MO:VA;0) 273.00 +30000-51*T; 6000.00 N
REF:pov13 !
PARAMETER L(BCC_A2,CO,FE,MO:VA;1) 273.00 +30000-51*T; 6000.00 N
REF:pov13 !
PARAMETER L(BCC_A2,CO,FE,MO:VA;2) 273.00 +30000-51*T; 6000.00 N
REF:pov13 !
PARAMETER L(BCC_A2,CR,CU,FE:VA;0) 273.00 +15000-38*T; 6000.00 N
REF:pov16 !
PARAMETER L(BCC_A2,CR,CU,FE:VA;1) 273.00 +1e-8; 6000.00 N
REF:225 !
PARAMETER L(BCC_A2,CR,CU,FE:VA;2) 273.00 +15000-38*T; 6000.00 N
REF:pov16 !
PARAMETER L(BCC_A2,CR,CU,NB:VA;0) 273.00 +20000; 6000.00 N
REF:130 !
PARAMETER L(BCC_A2,CR,CU,NI:VA;0) 273.00 +1e-8; 6000.00 N
REF:226 !
PARAMETER L(BCC_A2,CR,FE,MN:VA;0) 273.00 -25000+12*T; 6000.00 N
REF:pov17 !
PARAMETER L(BCC_A2,CR,FE,MO:VA;0) 273.00 1e-7; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,CR,FE,NB:VA;0) 273.00 -35000; 6000.00 N
REF:pov13 !
PARAMETER G(BCC_A2,CR,FE,NI:VA;0) 273.00 -16037+10*T; 6000 N
REF:293 !
PARAMETER G(BCC_A2,CR,FE,NI:VA;1) 273.00 -16375-9.5*T; 6000 N
REF:293 !
PARAMETER G(BCC_A2,CR,FE,NI:VA;2) 273.00 -13000+10*T; 6000 N
REF:293 !
PARAMETER L(BCC_A2,CR,FE,P:VA;0) 273.00 -50000; 6000.00 N
REF:pov12 !
PARAMETER L(BCC_A2,CR,FE,S:VA;0) 273.00 -420000; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,CR,FE,S:VA;1) 273.00 -120000; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,CR,FE,S:VA;2) 273.00 -420000; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,CR,FE,SI:VA;0) 273.00 -54000; 6000.00 N
REF:43 !
PARAMETER L(BCC_A2,CR,FE,TI:VA;0) 273.00 +1E-7; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,CR,FE,V:VA;0) 273.00 +14881; 6000.00 N
REF:52 !
PARAMETER L(BCC_A2,CR,FE,V:VA;1) 273.00 +17968; 6000.00 N
REF:52 !
PARAMETER L(BCC_A2,CR,FE,V:VA;2) 273.00 -7692; 6000.00 N
REF:52 !
PARAMETER L(BCC_A2,CR,MO,NI:VA;0) 273.00 -75000; 6000.00 N
REF:pov17 !
PARAMETER L(BCC_A2,CR,MO,NI:VA;1) 273.00 +1E-7; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,CR,MO,NI:VA;2) 273.00 +1E-7; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,CR,NI,W:VA;0) 273.00 +4102; 6000.00 N
REF:138 !
PARAMETER L(BCC_A2,CR,NI,W:VA;1) 273.00 -122160; 6000.00 N
REF:138 !
PARAMETER L(BCC_A2,CR,NI,W:VA;2) 273.00 +4102; 6000.00 N
REF:138 !
PARAMETER L(BCC_A2,CU,FE,MN:VA;0) 273.00 +20000+1.15*T; 6000.00 N
REF:87 !
PARAMETER L(BCC_A2,CU,FE,MN:VA;1) 273.00 +20000+1.15*T; 6000.00 N
REF:87 !
PARAMETER L(BCC_A2,CU,FE,MN:VA;2) 273.00 +20000+1.15*T; 6000.00 N
REF:87 !
PARAMETER L(BCC_A2,CU,FE,NI:VA;0) 273.00 -75000+150*T; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,CU,FE,SI:VA;0) 273.00 -158642.5+50*T; 6000.00 N
REF:228 !
PARAMETER L(BCC_A2,CU,FE,SI:VA;1) 273.00 -182105.5+70*T; 6000.00 N
REF:228 !
PARAMETER L(BCC_A2,CU,FE,SI:VA;2) 273.00 -158642.5+50*T; 6000.00 N
REF:228 !
PARAMETER L(BCC_A2,CU,FE,V:VA;0) 273.00 +30000-25*T; 6000.00 N
REF:228 !
PARAMETER L(BCC_A2,CU,FE,V:VA;1) 273.00 +30000-25*T; 6000.00 N
REF:228 !
PARAMETER L(BCC_A2,CU,FE,V:VA;2) 273.00 +30000-25*T; 6000.00 N
REF:228 !
PARAMETER L(BCC_A2,FE,MN,MO:VA;0) 273.00 +25000-50*T; 6000.00 N
REF:pov17 !
PARAMETER L(BCC_A2,FE,MN,NI:VA;0) 273.00 -75000+50*T; 6000.00 N
REF:pov17 !
PARAMETER L(BCC_A2,FE,MN,PD:VA;0) 273.00 -40000; 6000.00 N
REF:pov14 !
PARAMETER L(BCC_A2,FE,MN,SI:VA;0) 273.00 -108474-3*T; 6000.00 N
REF:293 !
PARAMETER L(BCC_A2,FE,MO,NI:VA;0) 273.00 -35743; 6000.00 N
REF:41 !
PARAMETER L(BCC_A2,FE,MO,SI:VA;0) 273.00 +1E-8; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,FE,MO,W:VA;0) 273.00 +3000; 6000.00 N
REF:55 !
PARAMETER L(BCC_A2,FE,NB,NI:VA;0) 273.00 +1E-8; 6000.00 N
REF:23 !
PARAMETER L(BCC_A2,FE,NI,S:VA;0) 273.00 -130000; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,FE,NI,S:VA;1) 273.00 -330000; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,FE,NI,S:VA;2) 273.00 +1e-8; 6000.00 N
REF:12 !
PARAMETER L(BCC_A2,FE,NI,SI:VA;0) 273.00 -297000; 6000.00 N
REF:28 !
PARAMETER L(BCC_A2,FE,NI,SI:VA;1) 273.00 -350000; 6000.00 N
REF:28 !
PARAMETER L(BCC_A2,FE,NI,SI:VA;2) 273.00 +1e-8; 6000.00 N
REF:28 !
PARAMETER L(BCC_A2,FE,NI,TI:VA;0) 273.00 -70000; 6000.00 N
REF:23 !
PARAMETER L(BCC_A2,FE,NI,V:VA;0) 273.00 -40000; 6000.00 N
REF:293 !
PARAMETER L(BCC_A2,MN,NI,SI:VA;0) 273.00 -360523.246; 6000.00 N
REF:251 !
PARAMETER L(BCC_A2,MN,NI,SI:VA;1) 273.00 -417536.599; 6000.00 N
REF:251 !
PARAMETER L(BCC_A2,MN,NI,SI:VA;2) 273.00 0; 6000.00 N
REF:251 !
$-------------------------------------------------------------------
$ BCC_A2 ternary interactions with C
$-------------------------------------------------------------------
$
$-------------------------------------------------------------------
$ BCC_A2 ternary interactions with N
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,CR,FE,MN:N;0) 273.00 +1E-8; 6000.00 N
REF:22 !
$-------------------------------------------------------------------
$ BCC_A2 ternary interactions with C,N,VA
$-------------------------------------------------------------------
$
$-------------------------------------------------------------------
$ BCC_A2 quaternary interactions with VA
$-------------------------------------------------------------------
PARAMETER L(BCC_A2,CR,FE,NB,NI:VA;0) 273.00 -500000; 6000.00 N
REF:23 !
$-------------------------------------------------------------------
$ BCC_A2 magnetic contribution
$-------------------------------------------------------------------
PARAMETER TC(BCC_A2,CO:VA;0) 273.00 +1450; 6000.00 N
REF:73 !
PARAMETER BMAGN(BCC_A2,CO:VA;0) 273.00 +1.35; 6000.00 N
REF:73 !
PARAMETER TC(BCC_A2,CR:VA;0) 273.00 -311.5; 6000.00 N
REF:22 !
PARAMETER BMAGN(BCC_A2,CR:VA;0) 273.00 -0.008; 6000.00 N
REF:0 !
PARAMETER TC(BCC_A2,FE:VA;0) 273.00 +1043; 6000.00 N
REF:0 !
PARAMETER BMAGN(BCC_A2,FE:VA;0) 273.00 +2.22; 6000.00 N
REF:0 !
PARAMETER TC(BCC_A2,FE:B;0) 273.00 +1043; 6000.00 N
REF:115 !
PARAMETER BMAGN(BCC_A2,FE:B;0) 273.00 +2.22; 6000.00 N
REF:115 !
PARAMETER TC(BCC_A2,MN:VA;0) 273.00 -580; 6000.00 N
REF:0 !
PARAMETER BMAGN(BCC_A2,MN:VA;0) 273.00 -0.27; 6000.00 N
REF:0 !
PARAMETER TC(BCC_A2,NI:VA;0) 298.15 +575; 6000 N
REF0 !
PARAMETER BMAGN(BCC_A2,NI:VA;0) 298.15 +.85; 6000 N
REF0 !
PARAMETER TC(BCC_A2,AL,FE:VA;1) 273.00 +504; 6000.00 N
REF:92 !
PARAMETER TC(BCC_A2,CO,FE:VA;0) 273.00 +590; 6000.00 N
REF:74 !
PARAMETER BMAGN(BCC_A2,CO,FE:VA;0) 273.00 +1.406; 6000.00 N
REF:152 !
PARAMETER BMAGN(BCC_A2,CO,FE:VA;1) 273.00 -0.6617; 6000.00 N
REF:152 !
PARAMETER TC(BCC_A2,CO,NI:VA;0) 273.00 +556; 6000.00 N
REF:79 !
PARAMETER TC(BCC_A2,CO,NI:VA;1) 273.00 -288; 6000.00 N
REF:79 !
PARAMETER BMAGN(BCC_A2,CO,NI:VA;0) 273.00 +0.474; 6000.00 N
REF:79 !
PARAMETER TC(BCC_A2,CO,W:VA;0) 273.00 -3379; 6000.00 N
REF:79 !
PARAMETER BMAGN(BCC_A2,CO,W:VA;0) 273.00 -3.146; 6000.00 N
REF:79 !
PARAMETER TC(BCC_A2,CO,MO:VA;0) 273.00 -3700; 6000.00 N
REF:77 !
PARAMETER BMAGN(BCC_A2,CO,MO:VA;0) 273.00 -3.445; 6000.00 N
REF:77 !
PARAMETER TC(BCC_A2,CO,FE,MO:VA;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER BMAGN(BCC_A2,CO,FE,MO:VA;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER TC(BCC_A2,CR,FE:VA;0) 273.00 +932.5; 6000 N
REF:287 !
PARAMETER TC(BCC_A2,CR,FE:VA;1) 273.00 -548.2; 6000 N
REF:287 !
PARAMETER BMAGN(BCC_A2,CR,FE:VA;0) 273.00 +2.15; 6000 N
REF:287 !
PARAMETER TC(BCC_A2,CR,NI:VA;0) 273.00 +2373; 6000.00 N
REF:11 !
PARAMETER TC(BCC_A2,CR,NI:VA;1) 273.00 +617; 6000.00 N
REF:11 !
PARAMETER BMAGN(BCC_A2,CR,NI:VA;0) 273.00 +4; 6000.00 N
REF:11 !
PARAMETER TC(BCC_A2,CU,FE:VA;0) 273.00 +800; 6000.00 N
REF:gst15 !
PARAMETER BMAGN(BCC_A2,CU,FE:VA;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER TC(BCC_A2,FE,MO:VA;0) 273.00 +335; 6000.00 N
REF:27 !
PARAMETER TC(BCC_A2,FE,MO:VA;1) 273.00 +526; 6000.00 N
REF:27 !
PARAMETER TC(BCC_A2,FE,NI:VA;0) 273.00 +120; 6000 N
REF:293 !
PARAMETER TC(BCC_A2,FE,NI:VA;1) 273.00 +150; 6000 N
REF:293 !
PARAMETER BMAGN(BCC_A2,FE,NI:VA;0) 273.00 +0.3; 6000 N
REF:293 !
PARAMETER BMAGN(BCC_A2,FE,NI:VA;1) 273.00 +1.6; 6000 N
REF:293 !
PARAMETER BMAGN(BCC_A2,FE,NI:VA;2) 273.00 +0.5; 6000 N
REF:293 !
PARAMETER BMAGN(BCC_A2,FE,NI:VA;3) 273.00 +0.3; 6000 N
REF:293 !
PARAMETER TC(BCC_A2,FE,PD:VA;0) 273.00 +250; 6000.00 N
REF:27 !
PARAMETER TC(BCC_A2,FE,SI:VA;1) 273.00 +8*ETCFESI#; 6000.00 N
REF:24 !
PARAMETER BMAGN(BCC_A2,FE,SI:VA;1) 273.00 +1.07; 6000.00 N
REF:291 !
PARAMETER BMAGN(BCC_A2,FE,V:VA;0) 273.00 -2.26; 6000.00 N
REF:15 !
PARAMETER TC(BCC_A2,FE,V:VA;0) 273.00 -110; 6000.00 N
REF:15 !
PARAMETER TC(BCC_A2,FE,V:VA;1) 273.00 +3075; 6000.00 N
REF:15 !
PARAMETER TC(BCC_A2,FE,V:VA;2) 273.00 +808; 6000.00 N
REF:15 !
PARAMETER TC(BCC_A2,FE,V:VA;3) 273.00 -2169; 6000.00 N
REF:15 !
PARAMETER TC(BCC_A2,MN,PD:VA;0) 273.00 +12000; 6000.00 N
REF:pov14 !
PARAMETER TC(BCC_A2,MN,PD:VA;1) 273.00 -12000; 6000.00 N
REF:pov14 !
PARAMETER BMAGN(BCC_A2,MN,PD:VA;0) 273.00 +1e-8; 6000.00 N
REF:242 !
PARAMETER BMAGN(BCC_A2,MN,PD:VA;1) 273.00 -1e-8; 6000.00 N
REF:242 !
PARAMETER TC(BCC_A2,CR:C;0) 273.00 -311.5; 6000.00 N
REF:11 !
PARAMETER BMAGN(BCC_A2,CR:C;0) 273.00 -0.008; 6000.00 N
REF:11 !
PARAMETER TC(BCC_A2,FE:C;0) 273.00 +1043; 6000.00 N
REF:11 !
PARAMETER BMAGN(BCC_A2,FE:C;0) 273.00 +2.22; 6000.00 N
REF:11 !
PARAMETER TC(BCC_A2,NI:C;0) 273.00 +575; 6000.00 N
REF:11 !
PARAMETER BMAGN(BCC_A2,NI:C;0) 273.00 +0.85; 6000.00 N
REF:11 !
PARAMETER TC(BCC_A2,CR,FE:C;0) 273.00 +1650; 6000.00 N
REF:11 !
PARAMETER TC(BCC_A2,CR,FE:C;1) 273.00 +550; 6000.00 N
REF:11 !
PARAMETER BMAGN(BCC_A2,CR,FE:C;0) 273.00 -0.85; 6000.00 N
REF:11 !
PARAMETER TC(BCC_A2,FE,MN:VA;0) 273.00 +603; 6000 N
REF:293 !
PARAMETER BMAGN(BCC_A2,FE,MN:VA;0) 273.00 +0.5; 6000 N
REF:293 !
PARAMETER TC(BCC_A2,FE,MO:C;0) 273.00 +335; 6000.00 N
REF:27 !
PARAMETER TC(BCC_A2,FE,MO:C;1) 273.00 +526; 6000.00 N
REF:27 !
PARAMETER TC(BCC_A2,CR:N;0) 273.00 -311.5; 6000.00 N
REF:pov09 !
PARAMETER BMAGN(BCC_A2,CR:N;0) 273.00 -0.008; 6000.00 N
REF:22 !
PARAMETER TC(BCC_A2,FE:N;0) 273.00 +1043; 6000.00 N
REF:22 !
PARAMETER BMAGN(BCC_A2,FE:N;0) 273.00 +2.22; 6000.00 N
REF:22 !
PARAMETER TC(BCC_A2,NI:N;0) 273.00 +575; 6000.00 N
REF:30 !
PARAMETER BMAGN(BCC_A2,NI:N;0) 273.00 +0.85; 6000.00 N
REF:30 !
PARAMETER TC(BCC_A2,NI,TI:VA;0) 273.00 -575; 6000.00 N
REF:160 !
PARAMETER BMAGN(BCC_A2,NI,TI:VA;0) 273.00 -0.85; 6000.00 N
REF:160 !
PARAMETER TC(BCC_A2,CR,FE:N;0) 273.00 +1650; 6000.00 N
REF:22 !
PARAMETER TC(BCC_A2,CR,FE:N;1) 273.00 +550; 6000.00 N
REF:22 !
PARAMETER BMAGN(BCC_A2,CR,FE:N;0) 273.00 -0.85; 6000.00 N
REF:22 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: H_BCC
$###########################################################################
$
TYPE_DEFINITION S GES A_P_D H_BCC MAGNETIC -1.0 0.4 !
PHASE H_BCC %S 2 1 1 >
bcc_a2 Fe with H-solubility using alternative sublattice description
with less interstitial sites, e.g. Ref 223
>> 1 !
CONSTITUENT H_BCC : FE% : H,VA% : !
$-------------------------------------------------------------------
$ BCC_A2 endmember compounds with VA
$-------------------------------------------------------------------
PARAMETER G(H_BCC,FE:VA;0) 273.00 +GHSERFE#; 6000.00 N
REF:0 !
PARAMETER G(H_BCC,FE:H;0) 273.00 +71098.3995-986.034062*T+155.942278*T*LN(T)
-0.0894166963*T**2+GHSERFE#+0.5*GHSERHH#; 1811.00 Y
+80393.95+16.72144*T+GHSERFE#+0.5*GHSERHH#; 6000.00 N
REF:223 !
PARAMETER TC(H_BCC,FE:VA;0) 273.00 +1043; 6000.00 N
REF:0 !
PARAMETER BMAGN(H_BCC,FE:VA;0) 273.00 +2.22; 6000.00 N
REF:0 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: HCP_A3
$###########################################################################
$
TYPE_DEFINITION ) GES A_P_D HCP_A3 MAGNETIC -3.0 0.28 !
PHASE HCP_A3 %) 2 1 0.5 >
Hexagonal close-packed. M2C, denoted "hcp#01" in the MatCalc databases,
with C on interstitial sites and Mo as mayor constituent.
Cr and V can dissolve with significant quantities in M2C. M2C carbide
and M2N nitride composition sets can be
defined by the user (syntax see top of database).
M2C is an important precipitate phase, e.g. in complex tool steels, etc.
M2C is commonly precipitating on dislocations
and/or martensite lath boundaries.
>> 3 !
CONSTITUENT HCP_A3 : AL,CO%,CR,CU,FE,HF,MN,MO,NB,NI,PD,SI,TI%,V,W,Y :
B,C,N,O,VA% : !
$-------------------------------------------------------------------
$ HCP_A3 endmember compounds with VA
$-------------------------------------------------------------------
PARAMETER G(HCP_A3,AL:VA;0) 273.00 +5481-1.8*T+GHSERAL#; 2900.00 N
REF:0 !
PARAMETER G(HCP_A3,CO:VA;0) 273.00 +GHSERCO#; 6000.00 N
REF:73 !
PARAMETER G(HCP_A3,CR:VA;0) 273.00 +4438+GHSERCR#; 6000.00 N
REF:0 !
PARAMETER G(HCP_A3,CU:VA;0) 273.00 +600+0.2*T+GHSERCU#; 3200.00 N
REF:0 !
PARAMETER G(HCP_A3,FE:VA;0) 273.00 -3705.78+12.591*T-1.15*T*LN(T)
+0.00064*T**2+GHSERFE#; 1811.00 Y
-3957.199+5.24951*T+0.49251E+31*T**(-9)+GHSERFE#; 6000.00 N
REF:0 !
PARAMETER G(HCP_A3,HF:VA;0) 273.00 GHSERHF#; 6000.00 N
REF:0 !
PARAMETER G(HCP_A3,MN:VA;0) 273.00 -4439.3+133.007*T-24.5177*T*LN(T)
-0.006*T**2+69600*T**(-1); 1519.00 Y
-27070.1+310.7894*T-48*T*LN(T)+3.86196E+30*T**(-9); 6000.00 N
REF:66 !
PARAMETER G(HCP_A3,MO:VA;0) 273.00 +11550+GHSERMO#; 5000.00 N
REF:0 !
PARAMETER G(HCP_A3,NB:VA;0) 273.00 +10000+2.4*T+GHEXTNB#; 6000.00 N
REF:0 !
PARAMETER G(HCP_A3,NI:VA;0) 273.00 +1046+1.255*T+GHSERNI#; 3000.00 N
REF:0 !
PARAMETER G(HCP_A3,PD:VA;0) 273.00 +2000+0.1*T+GHSERPD#; 3000.00 N
REF:0 !
PARAMETER G(HCP_A3,SI:VA;0) 273.00 +49200-20.8*T+GHSERSI#; 3600.00 N
REF:0 !
PARAMETER G(HCP_A3,TI:VA;0) 273.00 +GHSERTI#; 4000.00 N
REF:0 !
PARAMETER G(HCP_A3,V:VA;0) 273.00 +4000+2.4*T+GHSERVV#; 4000.00 N
REF:0 !
PARAMETER G(HCP_A3,W:VA;0) 273.00 +14750+GHSERWW#; 6000.00 N
REF:0 !
PARAMETER G(HCP_A3,Y:VA;0) 273.00 +GHSERYY#; 6000.00 N
REF:0 !
$-------------------------------------------------------------------
$ HCP_A3 endmember compounds with B
$-------------------------------------------------------------------
PARAMETER G(HCP_A3,TI:B;0) 273.00 +GHSERTI#+0.5*GHSERBB#
-56229; 6000.00 N
REF:117 !
$-------------------------------------------------------------------
$ HCP_A3 endmember compounds with C
$-------------------------------------------------------------------
PARAMETER G(HCP_A3,CO:C;0) 273.00 +GHSERCO#+0.5*GHSERCC#
+22916.5-2.855*T; 6000.00 N
REF:73 !
PARAMETER G(HCP_A3,CR:C;0) 273.00 +GHSERCR#+0.5*GHSERCC#
-18504+9.4173*T
-2.4997*T*LN(T)+1.386E-3*T**2; 6000.00 N
REF:11 !
PARAMETER G(HCP_A3,FE:C;0) 273.00 +GFEFCC#+0.5*GHSERCC#
+52905-11.9075*T; 6000.00 N
REF:11 !
PARAMETER G(HCP_A3,MN:C;0) 273.00 +GHSERMN#+0.5*GHSERCC#
-9000-1.0651*T; 6000.00 N
REF:265 !
PARAMETER G(HCP_A3,MO:C;0) 273.00 +1*GHSERMO#+0.5*GHSERCC#
-24150-3.625*T-163000*T**(-1); 6000.00 N
REF:17 !
$PARAMETER G(HCP_A3,NB:C;0) 273.00 -105000+205*T-34.986618*T*LN(T)
$ -0.002897*T**2-58298590*T**(-3)+252376*T**(-1); 6000.00 N
$REF:pov09 !
PARAMETER G(HCP_A3,NB:C;0) 273.00 -104500+206*T
-35*T*LN(T)-0.0029*T**2+252350*T**(-1)
-58298590*T**(-3); 6000.00 N
REF:pov23 !
PARAMETER G(HCP_A3,NI:C;0) 273.00 +GHSERNI#+0.5*GHSERCC#
+34796+2.665*T; 6000.00 N
REF:11 !
$PARAMETER G(HCP_A3,TI:C;0) 273.00 +GHSERTI#+0.5*GHSERCC#
$ -67577-8.6*T; 6000.00 N
$REF:16 !
PARAMETER G(HCP_A3,TI:C;0) 273.00
-105319+179.144*T-30.231*T*LN(T)-0.0033778*T**2; 6000.00 N
REF:Frisk03 !
PARAMETER G(HCP_A3,V:C;0) 273.00 -85473+182.441*T-30.551*T*LN(T)
-0.00538998*T**2+229029*T**(-1); 6000.00 N
REF:15 !
PARAMETER G(HCP_A3,W:C;0) 273.00 +GHSERWW#+0.5*GHSERCC#
-6715-6.65*T; 6000.00 N
REF:19 !
$-------------------------------------------------------------------
$ HCP_A3 endmember compounds with N
$-------------------------------------------------------------------
PARAMETER G(HCP_A3,AL:N;0) 273.00 +80000+GHSERAL#+0.5*GHSERNN#; 6000.00 N
REF:92 !
PARAMETER G(HCP_A3,CO:N;0) 273.00 -13140+198.577*T-36.621*T*LN(T)
+96383*T**(-1)-8.42E-04*T**2; 6000.00 N
REF:135 !
PARAMETER G(HCP_A3,CR:N;0) 273.00 -59000+58.5*T-4*T*LN(T)
+GHSERCR#+0.5*GHSERNN#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,FE:N;0) 273.00 -12015+37.98*T+GHSERFE#
+0.5*GHSERNN#; 6000.00 N
REF:22 !
PARAMETER G(HCP_A3,MN:N;0) 273.00 -56000+211.1804*T-38*T*LN(T)
+129442*T**(-1); 2500.00 N
REF:22 !
PARAMETER G(HCP_A3,MO:N;0) 273.00 -29450+28.7*T+GHSERMO#
+0.5*GHSERNN#; 6000.00 N
REF:64 !
PARAMETER G(HCP_A3,NB:N;0) 273.00 +GHSERNB#+0.5*GHSERNN#-135568
+59.295*T-2*T*LN(T); 6000.00 N
REF:16 !
PARAMETER G(HCP_A3,NI:N;0) 273.00 -4409.6+72.93*T-7.36*T*LN(T)
+0.00614*T**2+GHSERNI#+0.5*GHSERNN#; 6000.00 N
REF:67 !
PARAMETER G(HCP_A3,TI:N;0) 273.00 +0.5*GHSERTI#+0.5*GTIN#-6046.53
-2.653*T; 6000.00 N
REF:16 !
PARAMETER G(HCP_A3,V:N;0) 273.00 -139000+50.4*T+GHSERVV#
+0.5*GHSERNN#; 6000.00 N
REF:48 !
PARAMETER G(HCP_A3,W:N;0) 273.00 -12811.336+186.68879*T-34.217887*T*LN(T)
+105601*T**(-1)-0.004509875*T**2; 6000.00 N
REF:140 !
$-------------------------------------------------------------------
$ HCP_A3 endmember compounds with O
$-------------------------------------------------------------------
PARAMETER G(HCP_A3,AL:O;0) 273.00 +5481-1.8*T+GHSERAL#
+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,CO:O;0) 273.00 +GHSERCO#+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,CR:O;0) 273.00 +4438+GHSERCR#
+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,CU:O;0) 273.00 +600+0.2*T+GHSERCU#
+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,FE:O;0) 273.00 -3705.78+12.591*T-1.15*T*LN(T)
+0.00064*T**2+GHSERFE#+0.5*GHSEROO#; 1811.00 Y
-3957.199+5.24951*T+0.49251E+31*T**(-9)+GHSERFE#
+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,HF:O;0) 273.00 +GHSERHF#+0.5*GHSEROO#
-271214+41.560*T; 6000.00 N
REF:220 !
PARAMETER G(HCP_A3,MN:O;0) 273.00 -4439.3+133.007*T-24.5177*T*LN(T)
-0.006*T**2+69600*T**(-1)+0.5*GHSEROO#; 1519.00 Y
-27070.1+310.7894*T-48*T*LN(T)+3.86196E+30*T**(-9)
+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,MO:O;0) 273.00 +GHSERMO#+0.5*GHSEROO#; 5000.00 N
REF:POV12 !
PARAMETER G(HCP_A3,NB:O;0) 273.00 +10000+2.4*T+GHEXTNB#
+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,NI:O;0) 273.00 +1046+1.255*T+GHSERNI#
+0.5*GHSEROO#; 3000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,SI:O;0) 273.00 +49200-20.8*T+GHSERSI#
+0.5*GHSEROO#; 3600.00 N
REF:pov12 !
PARAMETER G(HCP_A3,TI:O;0) 273.00 +GHSERTI#+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,V:O;0) 273.00 +4000+2.4*T+GHSERVV#
+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,W:O;0) 273.00 +14750+GHSERWW#+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(HCP_A3,Y:O;0) 273.00 +GHSERYY#+0.5*GHSEROO#; 6000.00 N
REF:pov12 !
$******************** binary interactions ***************************
$-------------------------------------------------------------------
$ HCP_A3 binary interactions with VA
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,AL,CR:VA;0) 273.00 -35000+6*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,CU:VA;0) 273.00 +38107; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,HF:VA;0) 273.00 -129770-7.238*T; 6000.00 N
REF:214 !
PARAMETER L(HCP_A3,AL,HF:VA;1) 273.00 -50257+21.950*T; 6000.00 N
REF:214 !
PARAMETER L(HCP_A3,AL,HF:VA;2) 273.00 -2946+19.983*T; 6000.00 N
REF:214 !
PARAMETER L(HCP_A3,AL,MN:VA;0) 273.00 -108066+43.83*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,MN:VA;1) 273.00 -54519.8+40*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,MO:VA;0) 273.00 -85570+25*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,NB:VA;0) 273.00 -113500+21.1*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,NB:VA;1) 273.00 +5000; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,NB:VA;2) 273.00 +10000; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,SI:VA;0) 273.00 -3143.78+0.39297*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,TI:VA;0) 273.00 -134164+37.863*T; 6000.00 N
REF:159 !
PARAMETER L(HCP_A3,AL,TI:VA;1) 273.00 -3475+0.825*T; 6000.00 N
REF:159 !
PARAMETER L(HCP_A3,AL,TI:VA;2) 273.00 -7756; 6000.00 N
REF:159 !
PARAMETER L(HCP_A3,AL,V:VA;0) 273.00 -95000+20*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,V:VA;1) 273.00 -6000; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,W:VA;0) 273.00 -19250+20.2*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,AL,W:VA;1) 273.00 -10000; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,CO,CR:VA;0) 273.00 -6436; 6000.00 N
REF:73 !
PARAMETER L(HCP_A3,CO,CU:VA;0) 273.00 +28000; 6000.00 N
REF:87 !
PARAMETER L(HCP_A3,CO,FE:VA;0) 273.00 +5000; 6000.00 N
REF:152 !
PARAMETER L(HCP_A3,CO,MN:VA;0) 273.00 -21000; 6000.00 N
REF:87 !
PARAMETER L(HCP_A3,CO,MN:VA;1) 273.00 -4000; 6000.00 N
REF:87 !
PARAMETER L(HCP_A3,CO,MO:VA;0) 273.00 -29315.7+23.755*T; 6000.00 N
REF:77 !
PARAMETER L(HCP_A3,CO,MO:VA;1) 273.00 -27975.9-1.936*T; 6000.00 N
REF:77 !
PARAMETER L(HCP_A3,CO,MO:VA;2) 273.00 +24698.3; 6000.00 N
REF:77 !
PARAMETER L(HCP_A3,CO,NB:VA;0) 273.00 -7146; 6000.00 N
REF:136 !
PARAMETER L(HCP_A3,CO,NI:VA;0) 273.00 -1620-0.385*T; 6000.00 N
REF:79 !
PARAMETER L(HCP_A3,CO,W:VA;0) 273.00 +63000; 6000.00 N
REF:79 !
PARAMETER L(HCP_A3,CR,CU:VA;0) 273.00 +81100-25*T; 6000.00 N
REF:130 !
PARAMETER L(HCP_A3,CR,FE:VA;0) 273.00 +10833-7.477*T; 6000.00 N
REF:11 !
PARAMETER L(HCP_A3,CR,MN:VA;0) 273.00 -19088+17.5423*T; 6000.00 N
REF:22 !
PARAMETER L(HCP_A3,CR,MO:VA;0) 273.00 +28890-7.962*T; 6000.00 N
REF:61 !
PARAMETER L(HCP_A3,CR,MO:VA;1) 273.00 +5974-2.428*T; 6000.00 N
REF:61 !
PARAMETER L(HCP_A3,CR,NI:VA;0) 273.00 +20000-15*T; 6000.00 N
REF:pov12 !
PARAMETER L(HCP_A3,CR,TI:VA;0) 273.00 +32500; 6000.00 N
REF:21 !
PARAMETER L(HCP_A3,CR,V:VA;0) 273.00 -9874-2.6964*T; 6000.00 N
REF:68 !
PARAMETER L(HCP_A3,CR,V:VA;1) 273.00 -1720-2.5237*T; 6000.00 N
REF:68 !
PARAMETER L(HCP_A3,CR,W:VA;0) 273.00 +31520; 6000.00 N
REF:138 !
PARAMETER L(HCP_A3,CR,W:VA;1) 273.00 -1320; 6000.00 N
REF:138 !
PARAMETER L(HCP_A3,CR,Y:VA;0) 273.00 +63000; 6000.00 N
REF:205 !
PARAMETER L(HCP_A3,CU,FE:VA;0) 273.00 +48885.74-11.51*T; 6000.00 N
REF:pov09 !
PARAMETER L(HCP_A3,CU,FE:VA;1) 273.00 +12687.16-8.01*T; 6000.00 N
REF:pov09 !
PARAMETER L(HCP_A3,CU,FE:VA;2) 273.00 +4054.11; 6000.00 N
REF:pov09 !
PARAMETER L(HCP_A3,CU,MN:VA;0) 273.00 +13000; 6000.00 N
REF:87 !
PARAMETER L(HCP_A3,CU,NB:VA;0) 273.00 +20000; 6000.00 N
REF:130 !
PARAMETER L(HCP_A3,CU,NI:VA;0) 273.00 +8047.72+3.42217*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,CU,NI:VA;1) 273.00 -2041.3+.99714*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,CU,SI:VA;0) 273.00 -19948-2.356*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,CU,SI:VA;1) 273.00 -23800-1.97*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,CU,SI:VA;2) 273.00 -20; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,FE,HF:VA;0) 273.00 +765833.825; 6000.00 N
REF:218 !
PARAMETER L(HCP_A3,FE,MN:VA;0) 273.00 -5050+3.5*T; 6000.00 N
REF:293 !
PARAMETER L(HCP_A3,FE,MN:VA;1) 273.00 +2121.5; 6000.00 N
REF:293 !
PARAMETER L(HCP_A3,FE,MO:VA;0) 273.00 +28347-17.691*T; 6000.00 N
REF:27 !
PARAMETER L(HCP_A3,FE,NB:VA;0) 273.00 -4784; 6000.00 N
REF:113 !
PARAMETER L(HCP_A3,FE,NI:VA;0) 273.00 -12054.355+3.27413*T; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,FE,NI:VA;1) 273.00 +11082-4.45077*T; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,FE,NI:VA;2) 273.00 -725.8; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,FE,TI:VA;0) 273.00 -28750+11*T; 6000.00 N
REF:16 !
PARAMETER L(HCP_A3,FE,TI:VA;1) 273.00 -1700-6*T; 6000.00 N
REF:16 !
PARAMETER L(HCP_A3,FE,TI:VA;2) 273.00 +15000; 6000.00 N
REF:16 !
PARAMETER L(HCP_A3,FE,V:VA;0) 273.00 -15291-4.138*T; 6000.00 N
REF:15 !
PARAMETER L(HCP_A3,FE,W:VA;0) 273.00 +25977-3.36*T; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,FE,W:VA;1) 273.00 -7258.6; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,FE,Y:VA;0) 273.00 +15000; 6000.00 N
REF:239 !
PARAMETER L(HCP_A3,MN,SI:VA;0) 273.00 -86775+2.94*T; 6000.00 N
REF:251 !
PARAMETER L(HCP_A3,MN,SI:VA;1) 273.00 -7500; 6000.00 N
REF:251 !
PARAMETER L(HCP_A3,MN,TI:VA;0) 273.00 +22100; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,MN,V:VA;0) 273.00 -11820; 6000.00 N
REF:15 !
PARAMETER L(HCP_A3,MO,TI:VA;0) 273.00 +14250.8; 6000.00 N
REF:186 !
PARAMETER L(HCP_A3,MO,V:VA;0) 273.00 -43987.5+37.5*T; 6000.00 N
REF:34 !
PARAMETER L(HCP_A3,MO,W:VA;0) 273.00 +2000; 6000.00 N
REF:18 !
PARAMETER L(HCP_A3,NB,TI:VA;0) 273.00 +13600; 6000.00 N
REF:16 !
PARAMETER L(HCP_A3,NB,V:VA;0) 273.00 +1e-8; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,NB,Y:VA;0) 273.00 +150000; 6000.00 N
REF:213 !
PARAMETER L(HCP_A3,NI,TI:VA;0) 273.00 -22717; 6000.00 N
REF:253 !
PARAMETER L(HCP_A3,NI,W:VA;0) 273.00 +2556+11.6*T; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,NI,W:VA;1) 273.00 -52900; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,NI,Y:VA;0) 273.00 -2000; 6000.00 N
REF:213 !
PARAMETER L(HCP_A3,SI,TI:VA;1) 273.00 -234045.13+51.80942*T; 6000.00 N
REF:94 !
PARAMETER L(HCP_A3,TI,V:VA;0) 273.00 +20000; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,TI,W:VA;0) 273.00 +35774; 6000.00 N
REF:92 !
$-------------------------------------------------------------------
$ HCP_A3 binary interactions with C
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,CO,CR:C;0) 273.00 -6436; 6000.00 N
REF:73 !
PARAMETER L(HCP_A3,CO,FE:C;0) 273.00 +8000; 6000.00 N
REF:79 !
PARAMETER L(HCP_A3,CO,NI:C;0) 273.00 +6000; 6000.00 N
REF:76 !
PARAMETER L(HCP_A3,CO,W:C;0) 273.00 +117000; 6000.00 N
REF:79 !
PARAMETER L(HCP_A3,CR,MN:C;0) 273.00 +60000; 6000.00 N
REF:58 !
PARAMETER L(HCP_A3,CR,MO:C;0) 273.00 -3850+18.5304*T; 6000.00 N
REF:61 !
PARAMETER L(HCP_A3,CR,V:C;0) 273.00 +17165-9.9072*T; 6000.00 N
REF:68 !
PARAMETER L(HCP_A3,CR,V:C;1) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(HCP_A3,CR,V:C;2) 273.00 +1e-8; 6000.00 N
REF:pov11 !
$Data from Djurovic
PARAMETER L(HCP_A3,FE,MN:C;0) 273.00 +21742-50.2703*T; 6000.00 N
REF:265 !
PARAMETER L(HCP_A3,FE,MN:C;1) 273.00 -32608; 6000.00 N
REF:265 !
PARAMETER L(HCP_A3,FE,MO:C;0) 273.00 +13030-25*T; 6000.00 N
REF:293 !
PARAMETER L(HCP_A3,FE,NI:C;0) 273.00 +49074-7.32*T; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,FE,NI:C;1) 273.00 -25800; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,FE,V:C;0) 273.00 -15291-4.138*T; 6000.00 N
REF:15 !
PARAMETER L(HCP_A3,FE,W:C;0) 273.00 -116755+100*T; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,MO,TI:C;0) 273.00 -3387.2; 6000.00 N
REF:125 !
PARAMETER L(HCP_A3,MO,V:C;0) 273.00 -43987.5+37.5*T; 6000.00 N
REF:34 !
PARAMETER L(HCP_A3,NB,TI:C;0) 273.00 -10739+13.0928*T; 6000.00 N
REF:16 !
PARAMETER L(HCP_A3,NB,W:C;0) 273.00 -18676+7.969*T; 6000.00 N
REF:19 !
PARAMETER L(HCP_A3,NB,W:C;1) 273.00 +9876; 6000.00 N
REF:19 !
PARAMETER L(HCP_A3,NI,W:C;0) 273.00 +2556+11.6*T; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,NI,W:C;1) 273.00 -52900; 6000.00 N
REF:20 !
PARAMETER L(HCP_A3,TI,W:C;0) 273.00 -17802; 6000.00 N
REF:139 !
$
$------------------------------------------
$ HCP_A3 binary interactions with N
$------------------------------------------
$
PARAMETER L(HCP_A3,CR,FE:N;0) 273.00 +15000-20*T; 6000.00 N
REF:pov12 !
PARAMETER L(HCP_A3,CR,MN:N;0) 273.00 -43187+32.48*T; 6000.00 N
REF:pov12 !
PARAMETER L(HCP_A3,CR,MO:N;0) 273.00 -40000+30*T; 6000.00 N
REF:pov13 !
PARAMETER L(HCP_A3,CR,NB:N;0) 273.00 +100000; 6000.00 N
REF:pov12 !
PARAMETER L(HCP_A3,CR,NI:N;0) 273.00 +1443; 6000.00 N
REF:36 !
PARAMETER L(HCP_A3,CR,V:N;0) 273.00 -9200; 6000.00 N
REF:koze09 !
PARAMETER L(HCP_A3,FE,MN:N;0) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(HCP_A3,MN,MO:N;0) 273.00 +1e-8; 6000.00 N
REF:pov12 !
PARAMETER L(HCP_A3,NB,TI:N;0) 273.00 -8430+13.0928*T; 6000.00 N
REF:16 !
$-------------------------------------------------------------------
$ HCP_A3 binary interactions with B,VA
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,TI:B,VA;0) 273.00 +9115; 6000.00 N
REF:117 !
$-------------------------------------------------------------------
$ HCP_A3 binary interactions with C,VA
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,CR:C,VA;0) 273.00 +4165; 6000.00 N
REF:11 !
PARAMETER L(HCP_A3,FE:C,VA;0) 273.00 -17335; 6000.00 N
REF:11 !
PARAMETER L(HCP_A3,MN:C,VA;0) 273.00 +8552-9.367*T; 6000.00 N
REF:15 !
PARAMETER L(HCP_A3,MO:C,VA;0) 273.00 +4150; 6000.00 N
REF:27 !
$PARAMETER L(HCP_A3,NB:C,VA;0) 273.00 +13544-4.66*T; 6000.00 N
$REF:19 !
PARAMETER L(HCP_A3,NB:C,VA;0) 273.00 +9000-5.5*T; 6000.00 N
REF:jac24 !
PARAMETER L(HCP_A3,NB:C,VA;1) 273.00 +9000-5.3*T; 6000.00 N
REF:jac24 !
PARAMETER L(HCP_A3,TI:C,VA;0) 273.00 +16854.6-15.411*T; 6000.00 N
REF:Frisk03 !
PARAMETER L(HCP_A3,V:C,VA;0) 273.00 +12430-3.986*T; 6000.00 N
REF:15 !
PARAMETER L(HCP_A3,W:C,VA;0) 273.00 +4165; 6000.00 N
REF:19 !
$
PARAMETER L(HCP_A3,FE,NB:C,VA;0) 273.00 -20000; 6000.00 N
REF:113 !
$-------------------------------------------------------------------
$ HCP_A3 binary interactions with N,VA
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,CO:N,VA;0) 273.00 +5000-5*T; 6000.00 N
REF:135 !
PARAMETER L(HCP_A3,CR:N,VA;0) 273.00 +21120-10.61*T; 6000.00 N
REF:22 !
PARAMETER L(HCP_A3,CR:N,VA;1) 273.00 -6204; 6000.00 N
REF:22 !
PARAMETER L(HCP_A3,FE:N,VA;0) 273.00 +10345-19.71*T; 6000.00 N
REF:22 !
PARAMETER L(HCP_A3,FE:N,VA;1) 273.00 -11130+11.84*T; 6000.00 N
REF:22 !
PARAMETER L(HCP_A3,MN:N,VA;0) 273.00 -7194-5.2075*T; 6000.00 N
REF:22 !
PARAMETER L(HCP_A3,MN:N,VA;1) 273.00 -11810+6.9538*T; 6000.00 N
REF:22 !
PARAMETER L(HCP_A3,TI:N,VA;0) 273.00 -13501; 6000.00 N
REF:16 !
PARAMETER L(HCP_A3,V:N,VA;0) 273.00 -18400+4.84*T; 6000.00 N
REF:48 !
PARAMETER L(HCP_A3,V:N,VA;1) 273.00 -19700+2.13*T; 6000.00 N
REF:48 !
$-------------------------------------------------------------------
$ HCP_A3 binary interactions with O,VA
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,HF:O,VA;0) 273.00 -31345; 6000.00 N
REF:220 !
PARAMETER L(HCP_A3,HF:O,VA;1) 273.00 -6272; 6000.00 N
REF:220 !
$-------------------------------------------------------------------
$ HCP_A3 binary interactions with C,N
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,CR:C,N;0) 273.00 +15000; 6000.00 N
REF:pov13 !
PARAMETER L(HCP_A3,NB:C,N;0) 273.00 -15000; 6000.00 N
REF:16 !
PARAMETER L(HCP_A3,TI:C,N;0) 273.00 -32725; 6000.00 N
REF:16 !
$******************** ternary interactions ***************************
$-------------------------------------------------------------------
$ HCP_A3 ternary interactions with VA
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,AL,NB,TI:VA;0) 273.00 -10*T; 6000.00 N
REF:92 !
PARAMETER L(HCP_A3,CO,CU,MN:VA;0) 273.00 +5000; 6000.00 N
REF:87 !
PARAMETER L(HCP_A3,CO,CU,MN:VA;1) 273.00 +5000; 6000.00 N
REF:87 !
PARAMETER L(HCP_A3,CO,CU,MN:VA;2) 273.00 +5000; 6000.00 N
REF:87 !
$-------------------------------------------------------------------
$ HCP_A3 ternary interactions with C
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,CR,FE,MO:C;0) 273.00 -57062; 6000.00 N
REF:61 !
$-------------------------------------------------------------------
$ HCP_A3 ternary interactions with N
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,CR,FE,MN:N;0) 273.00 -180000; 6000.00 N
REF:pov12 !
$-------------------------------------------------------------------
$ HCP_A3 ternary interactions with C,N,VA
$-------------------------------------------------------------------
PARAMETER L(HCP_A3,NB:C,N,VA;0) 273.00 -30000; 6000.00 N
REF:16 !
PARAMETER L(HCP_A3,TI:C,N,VA;0) 273.00 -15000; 6000.00 N
REF:16 !
$-------------------------------------------------------------------
$ HCP_A3 magnetic contribution
$-------------------------------------------------------------------
PARAMETER TC(HCP_A3,CO:VA;0) 273.00 +1396; 6000.00 N
REF:73 !
PARAMETER BMAGN(HCP_A3,CO:VA;0) 273.00 +1.35; 6000.00 N
REF:73 !
PARAMETER TC(HCP_A3,CO,CR:VA;0) 273.00 -1795; 6000.00 N
REF:73 !
PARAMETER TC(HCP_A3,CO,FE:VA;0) 273.00 -253; 6000.00 N
REF:74 !
PARAMETER TC(HCP_A3,CO,FE:VA;1) 273.00 +1494; 6000.00 N
REF:74 !
PARAMETER BMAGN(HCP_A3,CO,FE:VA;0) 273.00 +5.41; 6000.00 N
REF:74 !
PARAMETER BMAGN(HCP_A3,CO,FE:VA;1) 273.00 -0.24; 6000.00 N
REF:74 !
PARAMETER TC(HCP_A3,CO,MN:VA;0) 273.00 -2685; 6000.00 N
REF:87 !
PARAMETER TC(HCP_A3,CO,MN:VA;1) 273.00 +3657; 6000.00 N
REF:87 !
PARAMETER BMAGN(HCP_A3,CO,MN:VA;0) 273.00 -1.07; 6000.00 N
REF:87 !
PARAMETER TC(HCP_A3,CO,MO:VA;0) 273.00 -1000; 6000.00 N
REF:77 !
PARAMETER BMAGN(HCP_A3,CO,MO:VA;0) 273.00 +1e-8; 6000.00 N
REF:77 !
PARAMETER TC(HCP_A3,CO,NI:VA;0) 273.00 +411; 6000.00 N
REF:79 !
PARAMETER TC(HCP_A3,CO,NI:VA;1) 273.00 -99; 6000.00 N
REF:79 !
PARAMETER BMAGN(HCP_A3,CO,NI:VA;0) 273.00 +1.046; 6000.00 N
REF:79 !
PARAMETER BMAGN(HCP_A3,CO,NI:VA;1) 273.00 +0.165; 6000.00 N
REF:79 !
PARAM G(HCP_A3,CO,TI:VA;0) 273.00 -65952+14.242*T; 6000.00 N
REF:137 !
PARAMETER TC(HCP_A3,CO,W:VA;0) 273.00 -3379; 6000.00 N
REF:79 !
PARAMETER BMAGN(HCP_A3,CO,W:VA;0) 273.00 -3.268; 6000.00 N
REF:79 !
PARAMETER TC(HCP_A3,CR:VA;0) 273.00 -1109; 6000.00 N
REF:11 !
PARAMETER BMAGN(HCP_A3,CR:VA;0) 273.00 -2.46; 6000.00 N
REF:11 !
PARAMETER TC(HCP_A3,MN:VA;0) 273.00 -1620; 6000.00 N
REF:0 !
PARAMETER BMAGN(HCP_A3,MN:VA;0) 273.00 -1.86; 6000.00 N
REF:0 !
PARAMETER TC(HCP_A3,NI:VA;0) 273.00 +633; 6000.00 N
REF:0 !
PARAMETER BMAGN(HCP_A3,NI:VA;0) 273.00 +0.52; 6000.00 N
REF:0 !
PARAMETER TC(HCP_A3,NI:C;0) 273.00 +633; 6000.00 N
REF:11 !
PARAMETER BMAGN(HCP_A3,NI:C;0) 273.00 +0.52; 6000.00 N
REF:11 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: ALPHA_MN
$###########################################################################
$
TYPE_DEFINITION } GES A_P_D ALPHA_MN MAGNETIC -3.0 0.28 !
PHASE ALPHA_MN %} 2 1 1 >
Body-centered cubic Manganese modification, stable below 1000 K.
>> 1 !
CONSTITUENT ALPHA_MN : AL,CO,CR,CU,FE,MN%,MO,NI,PD,SI,V :
C,N,VA% : !
$ Metallic endmember compounds
PARAMETER G(ALPHA_MN,AL:VA;0) 273.00 +10083.00-4.813*T+GHSERAL#; 6000.00 N
REF:92 !
PARAMETER G(ALPHA_MN,CO:VA;0) 273.00 +3000+GHSERCO#; 6000.00 N
REF:pov14 !
PARAMETER G(ALPHA_MN,CR:VA;0) 273.00 +11087.0+2.7196*T+GHSERCR#; 6000.00 N
REF:92 !
PARAMETER G(ALPHA_MN,CU:VA;0) 273.00 +3556+GHSERCU#; 6000.00 N
REF:84 !
PARAMETER G(ALPHA_MN,FE:VA;0) 273.00 +4745+GHSERFE#; 6000.00 N
REF:92 !
PARAMETER G(ALPHA_MN,MN:VA;0) 273.00 +GHSERMN#; 6000.00 N
REF:0 !
PARAMETER G(ALPHA_MN,MO:VA;0) 273.00 +GHSERMO#+10000; 6000.00 N
REF:pov15 !
PARAMETER G(ALPHA_MN,NI:VA;0) 273.00 +GHSERNI#+3556; 6000.00 N
REF:244 !
PARAMETER G(ALPHA_MN,PD:VA;0) 273.00 +GPDBCC#+5000; 6000.00 N
REF:pov14 !
PARAMETER G(ALPHA_MN,SI:VA;0) 273.00 +50208.0-20.377*T+GHSERSI#; 6000.00 N
REF:92 !
PARAMETER G(ALPHA_MN,V:VA;0) 273.00 +9000+GHSERVV#; 6000.00 N
REF:15 !
$ endmember compounds with C
PARAMETER G(ALPHA_MN,CR:C;0) 273.00 +5000+GHSERCR#+GHSERCC#; 6000.00 N
REF:58 !
PARAMETER G(ALPHA_MN,FE:C;0) 273.00 +80000+GHSERFE#+GHSERCC#; 6000.00 N
REF:15 !
PARAMETER G(ALPHA_MN,MN:C;0) 273.00 -10770+30*T+GHSERMN#
+GHSERCC#; 6000.00 N
REF:15 !
PARAMETER G(ALPHA_MN,V:C;0) 273.00 +10000+GHSERVV#+GHSERCC#; 6000.00 N
REF:15 !
$ endmember compounds with N
PARAMETER G(ALPHA_MN,CR:N;0) 273.00 -109574+142.16*T
-8.5*T*LN(T)+GHSERCR#+GHSERNN#; 6000.00 N
REF:22 !
PARAMETER G(ALPHA_MN,FE:N;0) 273.00 -30766+375.42*T
-37.6*T*LN(T)+GHSERFE#+GHSERNN#; 6000.00 N
REF:22 !
PARAMETER G(ALPHA_MN,MN:N;0) 273.00 -53114+299.266*T
-50.216*T*LN(T)+358309*T**(-1); 6000.00 N
REF:22 !
$ Magnetic contribution
$PARAMETER TC(ALPHA_MN,MN:VA;0) 273.00 -285.00; 6000.00 N
$REF:92 !
$PARAMETER BMAGN(ALPHA_MN,MN:VA;0) 273.00 -0.66; 6000.00 N
$REF:92 !
PARAMETER TC(ALPHA_MN,MN:VA;0) 273.00 -95; 6000 N
REF_Bigdeli19 !
PARAMETER BMAGN(ALPHA_MN,MN:VA;0) 273.00 +.22; 6000 N
REF_Bigdeli19 !
$----------------------Interaction parameters----------------------
$PARAMETER L(ALPHA_MN,AL,MN:VA;0) 273.00 -101410+43*T; 6000.00 N
$REF:92 !
PARAMETER L(ALPHA_MN,AL,MN:VA;0) 273.00 -63000+21*T; 6000.00 N
REF:148 !
PARAMETER L(ALPHA_MN,CO,CU:VA;0) 273.00 +5000; 6000.00 N
REF:87 !
PARAMETER L(ALPHA_MN,CO,MN:VA;0) 273.00 -18335; 6000.00 N
REF:29 !
PARAMETER L(ALPHA_MN,CR,MN:VA;0) 273.00 -38349+22.6925*T; 6000.00 N
REF:22 !
PARAMETER L(ALPHA_MN,CU,FE:VA;0) 273.00 +60000; 6000.00 N
REF:87 !
PARAMETER L(ALPHA_MN,CU,MN:VA;0) 273.00 -1000+26*T; 6000.00 N
REF:87 !
PARAMETER G(ALPHA_MN,FE,MN:VA;0) 273.00 -11650; 6000 N
REF:293 !
PARAMETER L(ALPHA_MN,FE,MO:VA;0) 273.00 +100000; 6000.00 N
REF:pov13 !
PARAMETER L(ALPHA_MN,FE,SI:VA;0) 273.00 -153141+46.48*T; 6000.00 N
REF:53 !
PARAMETER L(ALPHA_MN,FE,SI:VA;1) 273.00 -92352; 6000.00 N
REF:53 !
PARAMETER L(ALPHA_MN,FE,SI:VA;2) 273.00 +62240; 6000.00 N
REF:53 !
PARAMETER L(ALPHA_MN,FE,V:VA;0) 273.00 -10000; 6000.00 N
REF:15 !
PARAMETER L(ALPHA_MN,MN,MO:VA;0) 273.00 +3285; 6000.00 N
REF:pov13 !
PARAMETER L(ALPHA_MN,MN,MO:VA;1) 273.00 -6500; 6000.00 N
REF:pov13 !
PARAMETER L(ALPHA_MN,MN,NI:VA;0) 273.00 +40445.791; 6000.00 N
REF:244 !
PARAMETER L(ALPHA_MN,MN,NI:VA;1) 273.00 -49308.67-21.047*T; 6000.00 N
REF:244 !
PARAMETER L(ALPHA_MN,MN,PD:VA;0) 273.00 -29500-33*T; 6000.00 N
REF:pov14 !
PARAMETER L(ALPHA_MN,MN,SI:VA;0) 273.00 -143771.33+22.396*T; 6000.00 N
REF:251 !
PARAMETER L(ALPHA_MN,MN,SI:VA;1) 273.00 +16440.608-3.53*T; 6000.00 N
REF:251 !
PARAMETER L(ALPHA_MN,MN,V:VA;0) 273.00 -22225; 6000.00 N
REF:15 !
$
PARAMETER L(ALPHA_MN,CO,CU,MN:VA;0) 273.00 +1e-8; 6000.00 N
REF:87 !
PARAMETER L(ALPHA_MN,CR,CU,NI:VA;0) 273.00 +50000; 6000.00 N
REF:pov14 !
PARAMETER L(ALPHA_MN,CU,FE,MN:VA;0) 273.00 +1e-8; 6000.00 N
REF:87 !
PARAMETER L(ALPHA_MN,FE,MN,SI:VA;0) 273.00 -80507; 6000.00 N
REF:293 !
$
PARAMETER L(ALPHA_MN,CR,MN:C;0) 273.00 -38349+22.6925*T; 6000.00 N
REF:15 !
PARAMETER L(ALPHA_MN,FE,MN:C;0) 273.00 +34052-23.467*T; 6000.00 N
REF:15 !
PARAMETER L(ALPHA_MN,FE:C,VA;0) 273.00 -34671; 6000.00 N
REF:15 !
PARAMETER L(ALPHA_MN,MN,V:C;0) 273.00 -22225.2; 6000.00 N
REF:15 !
PARAMETER L(ALPHA_MN,MN:C,VA;0) 273.00 -43433; 6000.00 N
REF:15 !
$
PARAMETER L(ALPHA_MN,CR:N,VA;0) 273.00 +20000; 6000.00 N
REF:22 !
PARAMETER L(ALPHA_MN,FE:N,VA;0) 273.00 -26150; 6000.00 N
REF:22 !
PARAMETER L(ALPHA_MN,MN:N,VA;0) 273.00 -58869; 6000.00 N
REF:22 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: BETA_MN
$###########################################################################
$
PHASE BETA_MN % 2 1 1 >
Simple cubic Manganese modification between 1000 K and 1370 K.
>> 1 !
CONSTITUENT BETA_MN : AL,CO,CR,CU,FE,MN%,NI,MO,PD,SI,V : C,N,VA% : !
$ metallic endmember compounds
PARAMETER G(BETA_MN,AL:VA;0) 273.00 +10920.44-4.8116*T+GHSERAL#; 6000.00 N
REF:92 !
PARAMETER G(BETA_MN,CO:VA;0) 273.00 +3000+GHSERCO#; 6000.00 N
REF:pov14 !
PARAMETER G(BETA_MN,CR:VA;0) 273.00 +15899.0+0.6276*T+GHSERCR#; 6000.00 N
REF:92 !
PARAMETER G(BETA_MN,CU:VA;0) 273.00 +4017-1.255*T+GHSERCU#; 6000.00 N
REF:0 !
PARAMETER G(BETA_MN,FE:VA;0) 273.00 +3745+GHSERFE#; 6000.00 N
REF:92 !
PARAMETER G(BETA_MN,MN:VA;0) 273.00 +2314.88+5.936*T-1.4203*T*LN(T)
+1.51409E-03*T**2+442.0*T**(-1)+GHSERMN#; 1519.00 Y
+442.65-0.9715*T+2.3107229E+30*T**(-9)+GHSERMN#; 6000.00 N
REF:0 !
PARAMETER G(BETA_MN,MO:VA;0) 273.00 +GHSERMO#+10000; 6000.00 N
REF:pov15 !
PARAMETER G(BETA_MN,NI:VA;0) 273.00 +GHSERNI#+2092; 6000.00 N
REF:244 !
PARAMETER G(BETA_MN,PD:VA;0) 273.00 +GPDBCC#+5000; 6000.00 N
REF:pov14 !
PARAMETER G(BETA_MN,SI:VA;0) 273.00 +47279.0-20.377*T+GHSERSI#; 6000.00 N
REF:92 !
PARAMETER G(BETA_MN,V:VA;0) 273.00 +10000+GHSERVV#; 6000.00 N
REF:15 !
$ endmember compounds with C
PARAMETER G(BETA_MN,CR:C;0) 273.00 +5000+GHSERCR#+GHSERCC#; 6000.00 N
REF:15 !
PARAMETER G(BETA_MN,FE:C;0) 273.00 +90000+GHSERFE#+GHSERCC#; 6000.00 N
REF:15 !
PARAMETER G(BETA_MN,MN:C;0) 273.00 +5000+30*T+GHSERMN#+GHSERCC#; 6000.00 N
REF:15 !
PARAMETER G(BETA_MN,V:C;0) 273.00 +10000+30*T+GHSERVV#+GHSERCC#; 6000.00 N
REF:15 !
$ endmember compounds with N
PARAMETER G(BETA_MN,CR:N;0) 273.00 -105903+142.16*T-8.5*T*LN(T)
+GHSERCR#+GHSERNN#; 6000.00 N
REF:22 !
PARAMETER G(BETA_MN,FE:N;0) 273.00 -32216+375.42*T-37.6*T*LN(T)
+GHSERFE#+GHSERNN#; 6000.00 N
REF:22 !
PARAMETER G(BETA_MN,MN:N;0) 273.00 -67484+299.266*T-50.216*T*LN(T)
+358309*T**(-1); 6000.00 N
REF:22 !
$----------------------Interaction parameters----------------------
PARAMETER L(BETA_MN,AL,FE:VA;0) 273.00 -114000+21*T; 6000.00 N
REF:pov13 !
PARAMETER L(BETA_MN,AL,MN:VA;0) 273.00 -118512.3+52.73979*T; 6000.00 N
REF:148 !
PARAMETER L(BETA_MN,AL,MN:VA;1) 273.00 -3174.9; 6000.00 N
REF:148 !
PARAMETER L(BETA_MN,CO,CU:VA;0) 273.00 +30000; 6000.00 N
REF:87 !
PARAMETER L(BETA_MN,CO,MN:VA;0) 273.00 -26772-2.39*T; 6000.00 N
REF:29 !
PARAMETER L(BETA_MN,CO,MN:VA;1) 273.00 -3243; 6000.00 N
REF:29 !
PARAMETER L(BETA_MN,CR,CU:VA;0) 273.00 +20000; 6000.00 N
REF:pov12 !
PARAMETER L(BETA_MN,CR,MN:VA;0) 273.00 -31260+16.4919*T; 6000.00 N
REF:92 !
PARAMETER L(BETA_MN,CU,FE:VA;0) 273.00 +80000+20*T; 6000.00 N
REF:87 !
PARAMETER L(BETA_MN,CU,MN:VA;0) 273.00 +53000-10*T; 6000.00 N
REF:87 !
PARAMETER L(BETA_MN,CU,MN:VA;1) 273.00 +13519.89; 6000.00 N
REF:87 !
PARAMETER L(BETA_MN,CU,NI:VA;0) 273.00 +5000; 6000.00 N
REF:pov14 !
$PARAMETER L(BETA_MN,FE,MN:VA;0) 273.00 -11518+2.819*T; 6000.00 N
$REF:15 !
PARAMETER G(BETA_MN,FE,MN:VA;0) 273.00 -11950+1.8*T; 6000 N
REF:293 !
PARAMETER L(BETA_MN,FE,MO:VA;0) 273.00 +100000; 6000.00 N
REF:pov13 !
PARAMETER L(BETA_MN,FE,SI:VA;0) 273.00 -153141+46.48*T; 6000.00 N
REF:53 !
PARAMETER L(BETA_MN,FE,SI:VA;1) 273.00 -92352; 6000.00 N
REF:53 !
PARAMETER L(BETA_MN,FE,SI:VA;2) 273.00 +62240; 6000.00 N
REF:53 !
PARAMETER L(BETA_MN,FE,V:VA;0) 273.00 -10000; 6000.00 N
REF:15 !
PARAMETER L(BETA_MN,MN,MO:VA;0) 273.00 -4000+6.5*T; 6000.00 N
REF:pov13 !
PARAMETER L(BETA_MN,MN,NI:VA;0) 273.00 -6589.18153-20.215*T; 6000.00 N
REF:244 !
PARAMETER L(BETA_MN,MN,NI:VA;1) 273.00 +1e-8; 6000.00 N
REF:244 !
PARAMETER L(BETA_MN,MN,SI:VA;0) 273.00 -142343.62+21.8926*T; 6000.00 N
REF:92 !
PARAMETER L(BETA_MN,MN,SI:VA;1) 273.00 +16440.608-3.53*T; 6000.00 N
REF:92 !
PARAMETER L(BETA_MN,MN,PD:VA;0) 273.00 -66000+5*T; 6000.00 N
REF:pov14 !
PARAMETER L(BETA_MN,MN,V:VA;0) 273.00 -17724; 6000.00 N
REF:15 !
$
PARAMETER L(BETA_MN,CO,CU,MN:VA;0) 273.00 -3000; 6000.00 N
REF:87 !
PARAMETER L(BETA_MN,CO,CU,MN:VA;1) 273.00 -3000; 6000.00 N
REF:87 !
PARAMETER L(BETA_MN,CO,CU,MN:VA;2) 273.00 -5000; 6000.00 N
REF:87 !
PARAMETER L(BETA_MN,CU,FE,MN:VA;0) 273.00 +1e-8; 6000.00 N
REF:87 !
PARAMETER L(BETA_MN,CU,MN,NI:VA;0) 273.00 +1e-8; 6000.00 N
REF:244 !
PARAMETER L(BETA_MN,CU,MN,NI:VA;1) 273.00 -80000; 6000.00 N
REF:244 !
PARAMETER L(BETA_MN,CU,MN,NI:VA;2) 273.00 +1e-8; 6000.00 N
REF:244 !
PARAMETER L(BETA_MN,FE,MN,SI:VA;0) 273.00 -60507; 6000.00 N
REF:293 !
PARAMETER L(BETA_MN,MN,NI,SI:VA;0) 273.00 -1056762+400*T; 6000.00 N
REF:251 !
PARAMETER L(BETA_MN,MN,NI,SI:VA;1) 273.00 +1e-8; 6000.00 N
REF:251 !
PARAMETER L(BETA_MN,MN,NI,SI:VA;2) 273.00 -862679.5+450*T; 6000.00 N
REF:251 !
$
PARAMETER L(BETA_MN,CR,MN:C;0) 273.00 -31260+16.4919*T; 6000.00 N
REF:58 !
PARAMETER L(BETA_MN,FE,MN:C;0) 273.00 +34052-23.467*T; 6000.00 N
REF:15 !
PARAMETER L(BETA_MN,FE:C,VA;0) 273.00 -34671; 6000.00 N
REF:15 !
PARAMETER L(BETA_MN,MN,V:C;0) 273.00 -17724; 6000.00 N
REF:15 !
PARAMETER L(BETA_MN,MN:C,VA;0) 273.00 -43433; 6000.00 N
REF:15 !
$
PARAMETER L(BETA_MN,CR:N,VA;0) 273.00 +20000; 6000.00 N
REF:22 !
PARAMETER L(BETA_MN,FE:N,VA;0) 273.00 -26150; 6000.00 N
REF:22 !
PARAMETER L(BETA_MN,MN:N,VA;0) 273.00 -58869; 6000.00 N
REF:22 !
$
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: BETA_RHOMBO_B
$###########################################################################
$
PHASE BETA_RHOMBO_B % 1 1 >
Rhombohedral Boron.
>> 1 !
CONSTITUENT BETA_RHOMBO_B : B%,CU,MN,NB,TI : !
PARAMETER G(BETA_RHOMBO_B,B;0) 273.00 +GHSERBB#; 6000.00 N
REF:0 !
PARAMETER G(BETA_RHOMBO_B,CU;0) 273.00 +5000+GHSERCU#; 6000.00 N
REF:227 !
PARAMETER G(BETA_RHOMBO_B,MN;0) 273.00 +5000+GHSERMN#; 6000.00 N
REF:pov14 !
PARAMETER G(BETA_RHOMBO_B,NB;0) 273.00 +10000+GHSERNB#; 6000.00 N
REF:117 !
PARAMETER G(BETA_RHOMBO_B,TI;0) 273.00 +GHSERTI#+10000; 6000.00 N
REF:117 !
PARAMETER L(BETA_RHOMBO_B,B,CU;0) 273.00 +34386; 6000.00 N
REF:227 !
PARAMETER L(BETA_RHOMBO_B,B,MN;0) 273.00 -49500-21*T; 6000.00 N
REF:245 !
PARAMETER L(BETA_RHOMBO_B,B,NB;0) 273.00 -150535; 6000.00 N
REF:117 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: DIAMOND_A4
$###########################################################################
$
PHASE DIAMOND_A4 % 1 1 > >> 1 !
CONSTITUENT DIAMOND_A4 : AL,B,C,SI%,TI : !
PARAMETER G(DIAMOND_A4,AL;0) 273.00 +10000+15*T+GHSERAL#; 6000.00 N
REF:pov14 !
PARAMETER G(DIAMOND_A4,B;0) 273.00 +5000+GHSERBB#; 6000.00 N
REF:190 !
PARAMETER G(DIAMOND_A4,C;0) 273.00 -1.63594410E+04+1.7561E+02*T
-2.431E+01*T*LN(T)-4.723E-04*T**2+2.698E+06*T**(-1)
-2.61E+08*T**(-2)+1.1100000E+10*T**(-3); 6000.00 N
REF:92 !
PARAMETER G(DIAMOND_A4,SI;0) 273.00 +GHSERSI#; 6000.00 N
REF:92 !
PARAMETER G(DIAMOND_A4,TI;0) 273.00 +25000+GHSERTI#; 6000.00 N
REF:92 !
$----------------------Interaction parameters----------------------
PARAMETER L(DIAMOND_A4,AL,C;0) 273.00 +80*T; 6000.00 N
REF:92 !
PARAMETER L(DIAMOND_A4,AL,SI;0) 273.00 +113246.16-47.55509*T; 6000.00 N
REF:92 !
PARAMETER L(DIAMOND_A4,B,C;0) 273.00 +50000; 6000.00 N
REF:pov14 !
PARAMETER L(DIAMOND_A4,B,SI;0) 273.00 +57978.16; 6000.00 N
REF:92 !
PARAMETER L(DIAMOND_A4,B,TI;0) 273.00 +50000; 6000.00 N
REF:92 !
PARAMETER L(DIAMOND_A4,C,SI;0) 273.00 +93386.78; 6000.00 N
REF:92 !
PARAMETER L(DIAMOND_A4,SI,TI;0) 273.00 +80*T; 6000.00 N
REF:92 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: GRAPHITE
$###########################################################################
$
PHASE GRAPHITE % 1 1 >
Stable hexagonal Carbon phase.
>> 1 !
CONSTITUENT GRAPHITE : B,C% : !
PARAMETER G(GRAPHITE,C;0) 273.00 +GHSERCC#; 6000.00 N
REF:0 !
PARAMETER G(GRAPHITE,B;0) 273.00 +10000-2*T+GHSERBB#; 6000.00 N
REF:92 !
PARAMETER L(GRAPHITE,B,C;0) 273.00 +34385.95+8.6792*T; 6000.00 N
REF:92 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NISI
$###########################################################################
$Added for thermodynamic modeling of MN-NI-SI
$Thermo-kinetic simulation of RPV steels
PHASE NISI % 2 1 1 !
CONSTITUENT NISI :NI:SI: !
PARAMETER G(NISI,NI:SI;0) 273.00 -76423.4364-1.84187109*T
+GHSERNI+GHSERSI; 6000 N
REF:251!
$###########################################################################
$ THERMODYNAMIC PARAMETERS: CHI_A12
$###########################################################################
$
PHASE CHI_A12 % 4 24 10 24 2 >
Alpha-Mn structure closely related to topologically close-packed
sigma, Mu, and R-Phase.
Unit cell contains 58 atoms plus interstitials (carbon).
>> 3 !
CONSTITUENT CHI_A12 : FE : CR,MO%,W : CR%,FE,MO,NI,SI,W : C,VA% : !
PARAMETER G(CHI_A12,FE:CR:CR:VA;0) 273.00 +24*GFEFCC#+10*GHSERCR#+24*GCRFCC#
+18300-100*T; 6000.00 N
REF:111 !
PARAMETER G(CHI_A12,FE:CR:FE:VA;0) 273.00 +48*GFEFCC#+10*GHSERCR#
+57300-100*T; 6000.00 N
REF:111 !
PARAMETER G(CHI_A12,FE:CR:MO:VA;0) 273.00 +24*GFEFCC#+10*GHSERCR#+24*GMOFCC#
+100000; 6000.00 N
REF:111 !
PARAMETER G(CHI_A12,FE:CR:W:VA;0) 273.00 +24*GFEFCC#+10*GHSERCR#+24*GWFCC#
+10000; 6000.00 N
REF:126 !
PARAMETER G(CHI_A12,FE:MO:CR:VA;0) 273.00 +24*GFEFCC#+10*GHSERMO#+24*GCRFCC#
+5000-365*T; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:MO:FE:VA;0) 273.00 +48*GFEFCC#+10*GHSERMO#
+305210-270*T; 6000.00 N
REF:111 !
PARAMETER G(CHI_A12,FE:MO:MO:VA;0) 273.00 +24*GFEFCC#+10*GHSERMO#+24*GMOFCC#
+97300-100*T; 6000.00 N
REF:111 !
PARAMETER G(CHI_A12,FE:MO:W:VA;0) 273.00 +24*GFEFCC#+10*GHSERMO#+24*GWFCC#
+35300; 6000.00 N
REF:127 !
PARAMETER G(CHI_A12,FE:MO:NI:VA;0) 273.00 +24*GFEFCC#+10*GHSERMO#
+24*GHSERNI#-200000-300*T; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:W:CR:VA;0) 273.00 +24*GFEFCC#+10*GHSERWW#+24*GCRFCC#
-56630-250*T; 6000.00 N
REF:126 !
PARAMETER G(CHI_A12,FE:W:FE:VA;0) 273.00 +24*GFEFCC#+10*GHSERWW#+24*GFEFCC#
-11370+50*T; 6000.00 N
REF:126 !
PARAMETER G(CHI_A12,FE:W:MO:VA;0) 273.00 +24*GFEFCC#+10*GHSERWW#+24*GMOFCC#
+97300-100*T; 6000.00 N
REF:127 !
PARAMETER G(CHI_A12,FE:W:NI:VA;0) 273.00 +24*GFEFCC#+10*GHSERWW#
+24*GHSERNI#; 6000.00 N
REF:pov12 !
PARAMETER G(CHI_A12,FE:W:SI:VA;0) 273.00 +24*GFEFCC#+10*GHSERWW#
+24*GSIFCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:W:W:VA;0) 273.00 +24*GFEFCC#+10*GHSERWW#+24*GWFCC#
+35300; 6000.00 N
REF:126 !
PARAMETER G(CHI_A12,FE:CR:CR:C;0) 273.00 +24*GFEFCC#+10*GHSERCR#+24*GCRFCC#
+2*GHSERCC#-150000; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:CR:FE:C;0) 273.00 +48*GFEFCC#+10*GHSERCR#
+2*GHSERCC#-150000; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:CR:W:C;0) 273.00 +24*GFEFCC#+10*GHSERCR#+24*GWFCC#
+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:MO:FE:C;0) 273.00 +48*GFEFCC#+10*GHSERMO#
+2*GHSERCC#-200000; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:MO:MO:C;0) 273.00 +24*GFEFCC#+10*GHSERMO#+24*GMOFCC#
+2*GHSERCC#-200000; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:CR:MO:C;0) 273.00 +24*GFEFCC#+10*GHSERCR#+24*GMOFCC#
+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:MO:CR:C;0) 273.00 +24*GFEFCC#+10*GHSERMO#+24*GCRFCC#
+2*GHSERCC#-300000; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:CR:NI:C;0) 273.00 +24*GFEFCC#+10*GHSERCR#
+24*GHSERNI#+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:CR:SI:C;0) 273.00 +24*GFEFCC#+10*GHSERCR#
+24*GSIFCC#+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:MO:NI:C;0) 273.00 +24*GFEFCC#+10*GHSERMO#
+24*GHSERNI#+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:MO:SI:C;0) 273.00 +24*GFEFCC#+10*GHSERMO#
+24*GSIFCC#+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:MO:W:C;0) 273.00 +24*GFEFCC#+10*GHSERMO#+24*GWFCC#
+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:W:CR:C;0) 273.00 +24*GFEFCC#+10*GHSERWW#+24*GCRFCC#
+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:W:FE:C;0) 273.00 +24*GFEFCC#+10*GHSERWW#+24*GFEFCC#
+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:W:MO:C;0) 273.00 +24*GFEFCC#+10*GHSERWW#+24*GMOFCC#
+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:W:NI:C;0) 273.00 +24*GFEFCC#+10*GHSERWW#
+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:W:SI:C;0) 273.00 +24*GFEFCC#+10*GHSERWW#
+24*GSIFCC#+2*GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:W:W:C;0) 273.00 +24*GFEFCC#+10*GHSERWW#+24*GWFCC#
+2*GHSERCC#; 6000.00 N
REF:pov13 !
$ Note: the following compound parameters are preliminary!! (pov13)
PARAMETER G(CHI_A12,FE:CR:NI:VA;0) 273.00 +24*GFEFCC#+10*GHSERCR#
+24*GHSERNI#+100000-350*T; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:CR:SI:VA;0) 273.00 +24*GFEFCC#+10*GHSERMO#
+24*GSIFCC#-2600000+250*T; 6000.00 N
REF:pov13 !
PARAMETER G(CHI_A12,FE:MO:SI:VA;0) 273.00 +24*GFEFCC#+10*GHSERMO#
+24*GSIFCC#-2600000+250*T; 6000.00 N
REF:pov13 !
$ Interaction parameters
PARAMETER L(CHI_A12,FE:MO:CR,SI:VA;0) 273.00 -2600000+250*T; 6000.00 N
REF:pov13 !
PARAMETER L(CHI_A12,FE:MO:FE,SI:VA;0) 273.00 -2600000+250*T; 6000.00 N
REF:pov13 !
PARAMETER L(CHI_A12,FE:CR:FE,MO:C;0) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(CHI_A12,FE:CR:CR,FE:C;0) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(CHI_A12,FE:CR:CR,MO:C;0) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(CHI_A12,FE:MO:CR,FE:C;0) 273.00 -300000; 6000.00 N
REF:pov13 !
PARAMETER L(CHI_A12,FE:MO:CR,FE:C;1) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(CHI_A12,FE:MO:CR,FE:C;2) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(CHI_A12,FE:MO:CR,FE:C;3) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(CHI_A12,FE:MO:CR,MO:C;0) 273.00 +1e-8; 6000.00 N
REF:pov13 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: CO3MO
$###########################################################################
$
$ Intermetallic compound (epsilon)
PHASE CO3MO % 2 3 1 > >> 1 !
CONSTITUENT CO3MO : CO : MO,W : !
PARAMETER G(CO3MO,CO:MO;0) 273.00 -47009.6+20.816*T+3*GHSERCO#
+GHSERMO#; 6000.00 N
REF:77 !
PARAMETER G(CO3MO,CO:W;0) 273.00 -17930+2.4*T+3*GHSERCO#
+GHSERWW#; 6000.00 N
REF:243 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: CO3V
$###########################################################################
$
$ Intermetallic compound
PHASE CO3V % 2 3 1 > >> 1 !
CONSTITUENT CO3V : CO : V : !
PARAMETER G(CO3V,CO:V;0) 273.00 -58957.034+14.368*T+3*GHSERCO#
+GHSERVV#; 6000.00 N
REF:134 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: COV3
$###########################################################################
$ Intermetallic compound
PHASE COV3 % 2 1 3 > >> 1 !
CONSTITUENT COV3 : CO : V : !
PARAMETER G(COV3,CO:V;0) 273.00 -33074.458+3*GHSERVV#+GHSERCO#; 6000.00 N
REF:134 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: CR3MN5
$###########################################################################
$
PHASE CR3MN5 % 2 3 5 >
Also called "alpha Phase"
>> 1 !
CONSTITUENT CR3MN5 : CR : MN : !
PARAMETER G(CR3MN5,CR:MN;0) 273.00 +3*GHSERCR#+5*GHSERMN#-72550
+21.1732*T; 6000.00 N
REF:15 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: G_PHASE
$###########################################################################
$
PHASE G_PHASE % 3 16 6 7 >
Silicide precipitate in some Ni, Cu containing stainless steels,
preliminary description. New description (Ni,Fe)16(Cr,Fe,Mn,Ti)6(Si)7
>> 3 !
CONSTITUENT G_PHASE :CO,FE,NI%,CU: CR,FE,MN%,MO,NB,TI,CU : SI% : !
PARAMETER G(G_PHASE,CO:MN:SI;0) 273.00 +16*GHSERCO#+6*GHSERMN#
+7*GHSERSI#; 6000 N
REF:jac17 !
PARAMETER G(G_PHASE,CO:NB:SI;0) 273.00 +16*GHSERCO#+6*GHSERNB#
+7*GHSERSI#-1800000+60*T; 6000.00 N
REF:jac17 !
PARAMETER G(G_PHASE,CO:TI:SI;0) 273.00 +16*GHSERCO#+6*GHSERTI#
+7*GHSERSI#-1900000+50*T; 6000.00 N
REF:jac17 !
PARAMETER G(G_PHASE,FE:CR:SI;0) 273.00 +16*GHSERFE#+6*GHSERCR#
+7*GHSERSI#-651340; 6000 N
REF:287 !
PARAMETER G(G_PHASE,FE:CU:SI;0) 273.00 +16*GHSERFE#+6*GHSERCU#
+7*GHSERSI-435000; 6000 N
REF:287 !
PARAMETER G(G_PHASE,FE:FE:SI;0) 273.00 +16*GHSERFE#+6*GHSERFE#
+7*GHSERSI+500000; 6000 N
REF:287 !
PARAMETER G(G_PHASE,FE:MN:SI;0) 273.00 +16*GHSERFE#+6*GHSERMN#
+7*GHSERSI#-731592; 6000 N
REF:287 !
PARAMETER G(G_PHASE,FE:MO:SI;0) 273.00 +16*GHSERFE#+6*GHSERMO#
+7*GHSERSI# -768701+100*T; 6000 N
REF:287 !
PARAMETER G(G_PHASE,FE:NB:SI;0) 273.00 +16*GHSERFE#+6*GHSERNB#
+7*GHSERSI#; 6000 N
REF:287 !
PARAMETER G(G_PHASE,FE:TI:SI;0) 273.00 +16*GHSERFE#+6*GHSERTI#
+7*GHSERSI#-1354910; 6000 N
REF:jac17 !
PARAMETER G(G_PHASE,NI:CR:SI;0) 273.00 +16*GHSERNI#+6*GHSERCR#
+7*GHSERSI# -1102000+30*T; 6000 N
REF:287 !
PARAMETER G(G_PHASE,NI:CU:SI;0) 273.00 +16*GHSERNI#+6*GHSERCU
+7*GHSERSI -997519.6; 6000 N
REF:287 !
PARAMETER G(G_PHASE,NI:FE:SI;0) 273.00 +16*GHSERNI#+6*GHSERFE#
+7*GHSERSI-1055522; 6000 N
REF:287 !
PARAMETER G(G_PHASE,NI:MN:SI;0) 273.00 +16*GHSERNI#+6*GHSERMN#
+7*GHSERSI# -1280100-110*T; 6000 N
REF:287 !
PARAMETER G(G_PHASE,NI:NB:SI;0) 273.00 +16*GHSERNI#+6*GHSERNB#
+7*GHSERSI# -1900180+120*T; 6000 N
REF:jac17 !
PARAMETER G(G_PHASE,NI:TI:SI;0) 273.00 +16*GHSERNI#+6*GHSERTI#
+7*GHSERSI# -1906260+100*T; 6000 N
REF:jac17 !
PARAMETER G(G_PHASE,NI:MO:SI;0) 273.00 +16*GHSERNI#+6*GHSERMO#
+7*GHSERSI# -1155060-130*T; 6000 N
REF:287 !
PARAMETER G(G_PHASE,FE,NI:MN:SI;0) 273.00 -1150000+250*T; 6000 N
REF:287 !
PARAMETER G(G_PHASE,FE,NI:MO:SI;0) 273.00 -1150000+150*T; 6000 N
REF:287 !
PARAMETER G(G_PHASE,NI:CR,MN:SI;0) 273.00 -500000+100*T; 6000 N
REF:287 !
PARAMETER G(G_PHASE,NI:CR,MO:SI;0) 273.00 -400000+100*T; 6000 N
REF:287 !
PARAMETER G(G_PHASE,FE,NI:CR:SI;0) 273.00 -500000+100*T; 6000 N
REF:287 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: Mn2Ni3SI_PHASE
$###########################################################################
PHASE C15_LAVES % 2 2 1 >
TO2_Phase in Mn-Ni-Si ternary which might compete with G-Phase in duplex steels
$Prototype Cu2Mg - C15 Laves phase - often given as Mn2Ni3Si
$Model as (Mn,Ni,SI)2(Mn,Ni,Si)
>>> 2 !
CONSTITUENT C15_LAVES : FE,NI,MN,SI : FE,MN,NI,SI : !
PARAMETER G(C15_LAVES,FE:FE;0) 273.00 +110290+3*GHSERFE; 6000 N
REF:281 !
PARAMETER G(C15_LAVES,FE:MN;0) 273.00 +46570+2*GHSERFE+GHSERMN; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,MN:FE;0) 273.00 +60510+2*GHSERMN#+GHSERFE#; 6000.00 N
REF:287 !
PARAMETER G(C15_LAVES,FE:NI;0) 273.00 +48300+2*GHSERFE#+GHSERNI#; 6000.00 N
REF:287 !
PARAMETER G(C15_LAVES,NI:FE;0) 273.00 +30637+2*GHSERNI+GHSERFE; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,FE:SI;0) 273.00 +29102+2*GHSERFE+GHSERSI; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,SI:FE;0) 273.00 +146919+2*GHSERSI+GHSERFE; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,MN:MN;0) 273.00 +48176+3*GHSERMN; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,MN:NI;0) 273.00 +65183+2*GHSERMN+GHSERNI; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,NI:MN;0) 273.00 -1566-3*T+GHSERMN+2*GHSERNI#; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,NI:NI;0) 273.00 +65183+3*GHSERNI; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,SI:MN;0) 273.00 +97951+GHSERMN+2*GHSERSI#; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,MN:SI;0) 273.00 +40200+2*GHSERMN+GHSERSI; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,SI:SI;0) 273.00 +33000+3*GHSERSI; 6000 N
REF:284 !
PARAMETER G(C15_LAVES,NI:SI;0) 273.00 +9421+2*GHSERNI+GHSERSI; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,SI:NI;0) 273.00 +127459+2*GHSERSI+GHSERNI; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,NI,SI:MN;0) 273.00 -558422; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,NI,SI:MN;1) 273.00 -336334; 6000 N
REF:287 !
PARAMETER G(C15_LAVES,FE,NI:MN,SI;0) 273.00 -9e6; 6000 N
REF:287 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: T2_MN3Ni10Si7
$###########################################################################
$Phase in equilibrium with G_PHASE
PHASE T2_MNNISI % 3 0.15 0.5 0.3 !
CONSTITUENT T2_MNNISI :MN:NI:SI: !
PARAMETER G(T2_MNNISI,MN:NI:SI;0) 273.00 -38731.05-9.3*T
+0.15*GHSERMN+0.5*GHSERNI+0.3*GHSERSI; 6000 N
REF:Jac18 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: T4_MNNISI
$###########################################################################
$Phase in equilibrium with G_PHASE
PHASE T4 % 3 1 1 1 !
CONSTITUENT T4 :MN:NI:SI: !
PARAMETER G(T4,MN:NI:SI;0) 273.00 -108144.3392-38.8*T
+GHSERMN+GHSERNI+GHSERSI; 6000 N
REF:287 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: Mn3Ni2SI - T7
$###########################################################################
$Phase in equilibrium with Mn2Ni3Si(laves phase)
PHASE T7 % 3 3 2 1 !
CONSTITUENT T7 :MN:NI:SI: !
PARAMETER G(T7,MN:NI:SI;0) 273.00 -185140-56.4*T
+3*GHSERMN+2*GHSERNI+GHSERSI; 6000 N
REF:287 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NI2SIH
$###########################################################################
PHASE NI2SIH % 3 1 1 1 !
CONSTITUENT NI2SIH :NI:NI%,VA:SI: !
PARAMETER G(NI2SIH,NI:NI:SI;0) 273.00 -124473.59-7.83186503*T
+2*GHSERNI+GHSERSI; 6000 N
REF:251 !
PARAMETER G(NI2SIH,NI:VA:SI;0) 273.00 -77347.0925+1.49818935*T
+GHSERNI+GHSERSI; 6000 N
REF:251 !
PARAMETER G(NI2SIH,NI:NI,VA:SI;0) 273.00 17973.4201; 6000 N
REF:251 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NI2SIL
$###########################################################################
PHASE NI2SIL % 2 2 1 !
CONSTITUENT NI2SIL :NI:SI: !
PARAMETER G(NI2SIL,NI:SI;0) 273.00 -128241.081-5.5065848*T
+2*GHSERNI+GHSERSI; 6000 N
REF:251 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NI3Si2
$###########################################################################
PHASE NI3SI2 % 2 3 2 !
CONSTITUENT NI3SI2 :NI:SI: !
PARAMETER G(NI3SI2,NI:SI;0) 273.00 -217858.736+3.90115228*T
+3*GHSERNI+2*GHSERSI; 6000 N
REF:251 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NI3Si2
$###########################################################################
PHASE NI3SIH % 2 3 1 !
CONSTITUENT NI3SIH :NI:SI: !
PARAMETER G(NI3SIH,NI:SI;0) 298.15 -143815.797-10.1234508*T
+3*GHSERNI+GHSERSI; 6000 N
REF:251 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NI3SiL
$###########################################################################
PHASE NI3SIL % 2 3 1 !
CONSTITUENT NI3SIL :NI:SI: !
PARAMETER G(NI3SIL,NI:SI;0) 298.15 -144506.11-9.63042514*T
+3*GHSERNI+GHSERSI; 6000 N
REF:251 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NI5Si2
$###########################################################################
PHASE NI5SI2 % 2 5 2 !
CONSTITUENT NI5SI2 :NI:SI: !
PARAMETER G(NI5SI2,NI:SI;0) 298.15 -303488.914+2.32416866*T
+5*GHSERNI+2*GHSERSI; 6000 N
REF:251 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: GAMMA_PRIME
$###########################################################################
$
$ TYPE_DEFINITION + GES AMEND_PHASE_DESCRIPTION GAMMA_PRIME DIS_PART FCC_A1,,,!
PHASE GAMMA_PRIME % 2 0.25 0.75 >
Cubic Ni3Al-type, L12-structure; simplified description
as solid solution phase consisting of two substitutional sublattices;
Importance as precipitate in high-alloyed Fe-Ni-Cr-base.
>> 3 !
CONST GAMMA_PRIME : AL%,CR,FE,MN,NI,SI,TI% : AL,CR,FE,MN,NI%,SI,TI : !
PARAMETER G(GAMMA_PRIME,AL:AL;0) 273.00 +GHSERAL#+5000; 6000.00 N
REF:89 !
PARAMETER G(GAMMA_PRIME,AL:FE;0) 273.00 +0.25*GHSERAL#
+0.75*GHSERFE#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,AL:NI;0) 273.00 -43000+5.5*T+0.75*GHSERNI#
+0.25*GHSERAL#; 6000.00 N
REF:pov13 !
PARAMETER G(GAMMA_PRIME,AL:TI;0) 273.00 +0.75*GHSERTI#+0.25*GALHCP#
-28419+5.21*T; 6000.00 N
REF:247 !
PARAMETER G(GAMMA_PRIME,CR:AL;0) 273.00 +0.75*GHSERAL#
+0.25*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,CR:CR;0) 273.00 +35000+GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,CR:FE;0) 273.00 +20000+0.75*GHSERFE#
+0.25*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,CR:NI;0) 273.00 +1000-4.5*T+0.75*GHSERNI#
+0.25*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,CR:TI;0) 273.00 15000+0.75*GHSERTI#
+0.25*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,AL:CR;0) 273.00 -12000+0.25*GHSERAL#
+0.75*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,FE:CR;0) 273.00 +0.25*GHSERFE#
+0.75*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,NI:CR;0) 273.00 +0.25*GHSERNI#
+0.75*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,TI:CR;0) 273.00 15000+0.25*GHSERTI#
+0.75*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,FE:AL;0) 273.00 +0.75*GHSERAL#
+0.25*GHSERFE#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,FE:FE;0) 273.00 +GHSERFE#+7000; 6000.00 N
REF:54 !
PARAMETER G(GAMMA_PRIME,FE:NI;0) 273.00 +0.75*GDHCNI#+0.25*GDHCFE#
-12500+6.45*T; 6000.00 N
REF:293 !
PARAMETER G(GAMMA_PRIME,FE:TI;0) 273.00 +0.75*GDHCTI#+0.25*GDHCFE#
+7500; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,MN:NI;0) 273.00 +0.25*GMNFCC+0.75*GHSERNI
-8703.625-1.36245*T; 6000 N
REF:256 !
PARAMETER G(GAMMA_PRIME,MN:MN;0) 273.00 +GMNFCC#; 6000.00 N
REF:256 !
PARAMETER G(GAMMA_PRIME,NI:AL;0) 273.00 +0.75*GHSERAL#
+0.25*GHSERNI#; 6000.00 N
REF:pov15 !
PARAMETER G(GAMMA_PRIME,NI:FE;0) 273.00 +0.75*GDHCFE#+0.25*GDHCNI#
+8000; 6000.00 N
REF_293 !
PARAMETER G(GAMMA_PRIME,NI:MN;0) 273.00 +0.25*GHSERNI+0.75*GMNFCC#
+8703.625+1.36245*T; 6000.00 N
REF:256 !
PARAMETER G(GAMMA_PRIME,NI:NI;0) 273.00 +3900+GHSERNI#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,NI:TI;0) 273.00 +39000-8.5*T+0.25*GDHCNI#
+0.75*GDHCTI#; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,SI:NI;0) 273.00 -47886+5.53*T
+0.75*GHSERNI#+0.25*GHSERSI#; 6000.00 N
REF:287 !
PARAMETER G(GAMMA_PRIME,NI:SI;0) 273.00 +20600+0.75*GHSERSI#
+0.25*GHSERNI#; 6000.00 N
REF:191 !
PARAMETER G(GAMMA_PRIME,SI:SI;0) 273.00 +GSIFCC#; 6000.00 N
REF:191 !
PARAMETER G(GAMMA_PRIME,TI:SI;0) 273.00 -4507.36
+0.75*GHSERSI#+0.25*GHSERTI#; 6000.00 N
REF:191 !
PARAMETER G(GAMMA_PRIME,SI:TI;0) 273.00 -41574.11
+0.25*GHSERSI#+0.75*GHSERTI#; 6000.00 N
REF:191 !
PARAMETER G(GAMMA_PRIME,TI:AL;0) 273.00 +0.75*GALHCP#+0.25*GHSERTI#
-4110.75+1.35*T; 6000.00 N
REF:247 !
PARAMETER G(GAMMA_PRIME,TI:FE;0) 273.00 +0.75*GHSERFE#+0.25*GHSERTI#
-8250+0.5*T; 6000.00 N
REF:pov10 !
PARAMETER G(GAMMA_PRIME,TI:NI;0) 273.00 -39000+8.5*T+0.75*GDHCNI#
+0.25*GDHCTI#; 6000.00 N
REF:pov15 !
PARAMETER G(GAMMA_PRIME,TI:TI;0) 273.00 +5005+GHSERTI#; 6000.00 N
REF:pov10 !
$----------------------Interaction parameters----------------------
PARAMETER L(GAMMA_PRIME,AL:AL,NI;0) 273.00 -100000+15*T; 6000.00 N
REF:pov15 !
PARAMETER L(GAMMA_PRIME,AL,CR:NI;0) 273.00 -5000+5*T; 6000.00 N
REF:pov15 !
PARAMETER L(GAMMA_PRIME,Al,NI:NI;0) 273.00 +2000-2*T; 6000.00 N
REF:pov15 !
PARAMETER L(GAMMA_PRIME,NI,TI:NI;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(GAMMA_PRIME,NI,TI:NI;1) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(GAMMA_PRIME,NI,TI:TI;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(GAMMA_PRIME,TI:NI,TI;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(GAMMA_PRIME,AL:AL,TI;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(GAMMA_PRIME,AL,TI:TI;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(GAMMA_PRIME,AL,TI:NI;0) 273.00 -11800; 6000.00 N
REF:pov15 !
PARAMETER L(GAMMA_PRIME,CR,TI:NI;0) 273.00 -15000+15*T; 6000.00 N
REF:pov13 !
PARAMETER L(GAMMA_PRIME,*:CR,NI;0) 273.00 5000-3*T; 6000.00 N
REF:pov11 !
$ Interactions with Fe
PARAMETER L(GAMMA_PRIME,AL,FE:NI;0) 273.00 -19000; 6000.00 N
REF:pov15 !
PARAMETER L(GAMMA_PRIME,CR,FE:NI;0) 273.00 -1000; 6000.00 N
REF:293 !
PARAMETER L(GAMMA_PRIME,FE,TI:NI;0) 273.00 -19000; 6000.00 N
REF:pov15 !
PARAMETER L(GAMMA_PRIME,MN,NI:MN;0) 273.00 22395.575-2.02*T; 6000.00 N
REF:287 !
PARAMETER L(GAMMA_PRIME,MN,NI:NI;0) 273.00 22395.575-2.02*T; 6000.00 N
REF:287 !
PARAMETER L(GAMMA_PRIME,MN,NI:MN;1) 273.00 -25405.3+9.357*T; 6000.00 N
REF:256 !
PARAMETER L(GAMMA_PRIME,MN,NI:NI;1) 273.00 -25405.3+9.357*T; 6000.00 N
REF:256 !
PARAMETER L(GAMMA_PRIME,MN:MN,NI;0) 273.00 -2943.36-6.06*T; 6000.00 N
REF:256 !
PARAMETER L(GAMMA_PRIME,NI:MN,NI;0) 273.00 -2943.36-6.06*T; 6000.00 N
REF:256 !
PARAMETER L(GAMMA_PRIME,MN:MN,NI;1) 273.00 -195.1725+0.21*T; 6000.00 N
REF:256 !
PARAMETER L(GAMMA_PRIME,NI:MN,NI;1) 273.00 -195.1725+0.21*T; 6000.00 N
REF:256 !
$ Interactions with Si
PARAMETER L(GAMMA_PRIME,NI:NI,SI;0) 273.00 +50000; 6000.00 N
REF:191 !
PARAMETER L(GAMMA_PRIME,NI,SI:NI;0) 273.00 -1000-7*T; 6000.00 N
REF:pov15 !
PARAMETER L(GAMMA_PRIME,NI,SI:SI;0) 273.00 -1000-7*T; 6000.00 N
REF:pov15 !
PARAMETER L(GAMMA_PRIME,SI:NI,SI;0) 273.00 +50000; 6000.00 N
REF:191 !
PARAMETER L(GAMMA_PRIME,SI,TI:NI;0) 273.00 -10500; 6000.00 N
REF:191 !
PARAMETER L(GAMMA_PRIME,TI:FE,NI;0) 273.00 -22500+8.75*T; 6000.00 N
REF:pov17 !
PARAMETER L(GAMMA_PRIME,FE:FE,NI;0) 273.00 -14000; 6000 N
REF:293 !
PARAMETER G(GAMMA_PRIME,FE,NI:NI;0) 273.00 -5000; 6000.00 N
REF:293 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: LAVES_PHASE
$###########################################################################
$
PHASE LAVES_PHASE % 2 2 1 >
MgZn2-type intermetallic phase, topologically close-packed (TCP).
Low ductility and brittle fracture characteristics at low temperatures.
Simplified description without distinguishing cubic C15, hexagonal C14
and dihexagonal C36 types.
Optimized for use in thermokinetic precipitation simulations
in austenitic stainless steel (pov12,pov13).
>> 4 !
CONSTITUENT LAVES_PHASE : CO,CR,FE%,MN,MO,NB,NI,SI,TI,V,W :
CO,CR,FE,MN,MO%,NB,NI,SI,TI,V,W : !
PARAMETER G(LAVES_PHASE,CO:CO;0) 273.00 +3*GHSERCO#+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CO:CR;0) 273.00 +2*GHSERCO#+GHSERCR#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CO:FE;0) 273.00 +2*GHSERCO#+GHSERFE#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CO:MN;0) 273.00 +2*GHSERCO#+GHSERMN#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CO:MO;0) 273.00 +2*GHSERCO#+GHSERMO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CO:NB;0) 273.00 +2*GHSERCO#+GHSERNB#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CO:NI;0) 273.00 +2*GHSERCO#+GHSERNI#
+15000; 6000.00 N
REF:pov12 !
PARAMETER G(LAVES_PHASE,CO:SI;0) 273.00 +2*GHSERCO#+GHSERSI#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CO:TI;0) 273.00 +2*GHSERCO#+GHSERTI#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CO:V;0) 273.00 +2*GHSERCO#+GHSERVV#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,CO:W;0) 273.00 +2*GHSERCO#+GHSERWW#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CR:CO;0) 273.00 +2*GHSERCR#+GHSERCO#
+15000; 6000.00 N
REF:21 !
PARAMETER G(LAVES_PHASE,CR:CR;0) 273.00 +3*GHSERCR#+86000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,CR:FE;0) 273.00 +2*GHSERCR#+GHSERFE#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CR:MN;0) 273.00 +2*GHSERCR#+GHSERFE#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CR:MO;0) 273.00 +2*GCRFCC#+GHSERMO#
+5000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,CR:NB;0) 273.00 +2*GHSERCR#+GHSERNB#-12667.55
+31.01111*T-5*T*LN(T); 6000.00 N
REF:153 !
PARAMETER G(LAVES_PHASE,CR:NI;0) 273.00 +2*GHSERCR#+GHSERNI#
+50000; 6000.00 N
REF:pov12 !
PARAMETER G(LAVES_PHASE,CR:SI;0) 273.00 +2*GHSERCR#+GHSERSI#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,CR:TI;0) 273.00 +2*GHSERCR#+GHSERTI#
-1780-6.3*T; 6000.00 N
REF:21 !
PARAMETER G(LAVES_PHASE,CR:V;0) 273.00 +2*GHSERCR#+GHSERVV#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,CR:W;0) 273.00 +2*GCRFCC#+GHSERWW#
-359-7.2*T; 6000.00 N
REF:59 !
PARAMETER G(LAVES_PHASE,FE:CO;0) 273.00 +2*GHSERFE#+GHSERCO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,FE:CR;0) 273.00 +2*GHSERFE#+GHSERCR#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,FE:FE;0) 273.00 +3*GHSERFE#
+44130; 6000.00 N
REF:271 !
PARAMETER G(LAVES_PHASE,FE:MN;0) 273.00 +2*GHSERFE#+GHSERMN#
+36700; 6000.00 N
REF:271 !
PARAMETER G(LAVES_PHASE,FE:MO;0) 273.00 -11940+2*GFEFCC#
+GHSERMO#; 6000.00 N
REF:pov13 !
$PARAMETER G(LAVES_PHASE,FE:NB;0) 273.00 -70290+13.8*T+2*GFEFCC#
$ +GHSERNB#; 6000.00 N
$REF:pov10 !
PARAMETER G(LAVES_PHASE,FE:NB;0) 273.00 +2*GHSERFE#+GHSERNB#
-67223+13.971*T; 6000.00 N
REF:262 !
PARAMETER G(LAVES_PHASE,FE:NI;0) 273.00 +2*GHSERFE#+GHSERNI#; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,FE:SI;0) 273.00 +2*GHSERFE#+GHSERSI#
+100000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,FE:TI;0) 273.00 -91500+409*T-73.55318*T*LN(T)
-0.01017*T**2+124200*T**(-1); 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,FE:V;0) 273.00 +2*GHSERFE#+GHSERVV#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,FE:W;0) 273.00 -13500+5*T+2*GFEFCC#
+GHSERWW#; 6000.00 N
REF:59 !
PARAMETER G(LAVES_PHASE,MN:CO;0) 273.00 +2*GHSERMN#+GHSERCO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MN:CR;0) 273.00 +2*GHSERMN#+GHSERCR#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MN:FE;0) 273.00 +2*GHSERMN#+GHSERFE#
+29270; 6000.00 N
REF:271 !
PARAMETER G(LAVES_PHASE,MN:MN;0) 273.00 +3*GHSERMN#+20700; 6000.00 N
REF:271 !
PARAMETER G(LAVES_PHASE,MN:MO;0) 273.00 +2*GHSERMN#+GHSERMO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MN:NB;0) 273.00 +2*GHSERMN#+GHSERNB#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MN:NI;0) 273.00 +2*GHSERMN#+GHSERNI#
+53607; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,MN:SI;0) 273.00 +2*GHSERMN#+GHSERSI#
+24471; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,MN:TI;0) 273.00 +2*GHSERMN#+GHSERTI#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MN:V;0) 273.00 +2*GHSERMN#+GHSERVV#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,MN:W;0) 273.00 +2*GHSERMN#+GHSERWW#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MO:CO;0) 273.00 +2*GHSERMO#+GHSERCO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MO:CR;0) 273.00 +2*GHSERMO#+GHSERCR#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MO:FE;0) 273.00 +2*GHSERMO#+GHSERFE#
+50443-7.289*T; 6000.00 N
REF:286 !
PARAMETER G(LAVES_PHASE,MO:MN;0) 273.00 +2*GHSERMO#+GHSERMN#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MO:MO;0) 273.00 +3*GHSERMO#+132120; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,MO:NB;0) 273.00 +2*GHSERMO#+GHSERNB#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MO:NI;0) 273.00 +2*GHSERMO#+GHSERNI#
+45000; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,MO:SI;0) 273.00 +2*GHSERMO#+GHSERSI#
+45000; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,MO:TI;0) 273.00 +2*GHSERMO#+GHSERTI#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,MO:V;0) 273.00 +2*GHSERMO#+GHSERVV#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,MO:W;0) 273.00 +2*GHSERMO#+GHSERWW#
+50000; 6000.00 N
PARAMETER G(LAVES_PHASE,NB:CO;0) 273.00 +2*GHSERNB#+GHSERCO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,NB:CR;0) 273.00 +2*GHSERNB#+GHSERCR#+42667.55
-31.01111*T+5*T*LN(T); 6000.00 N
REF:153 !
$PARAMETER G(LAVES_PHASE,NB:FE;0) 273.00 +2*GHSERNB#+GHSERFE#
$ +15000; 6000.00 N
$REF:16 !
PARAMETER G(LAVES_PHASE,NB:FE;0) 273.00 +2*GHSERNB#+GHSERFE#
+180030; 6000.00 N
REF:262 !
PARAMETER G(LAVES_PHASE,NB:MN;0) 273.00 +2*GHSERNB#+GHSERMN#
+15000; 6000.00 N
REF:16 !
PARAMETER G(LAVES_PHASE,NB:MO;0) 273.00 +2*GHSERNB#+GHSERMO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,NB:NB;0) 273.00 +3*GHSERNB#+15000; 6000.00 N
REF:16 !
PARAMETER G(LAVES_PHASE,NB:NI;0) 273.00 +2*GHSERNB#+GHSERNI#
-40000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,NB:SI;0) 273.00 +2*GHSERNB#+GHSERSI#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,NB:TI;0) 273.00 +2*GHSERNB#+GHSERTI#
+15000; 6000.00 N
REF:16 !
PARAMETER G(LAVES_PHASE,NB:V;0) 273.00 +2*GHSERNB#+GHSERVV#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,NB:W;0) 273.00 +2*GHSERNB#+GHSERWW#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,NI:CO;0) 273.00 +2*GHSERNI#+GHSERCO#
+15000; 6000.00 N
REF:pov12 !
PARAMETER G(LAVES_PHASE,NI:CR;0) 273.00 +2*GHSERNI#+GHSERCR#
+15000; 6000.00 N
REF:pov12 !
PARAMETER G(LAVES_PHASE,NI:FE;0) 273.00 +52818+2*GHSERNI#+GHSERFE#;
6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,NI:MN;0) 273.00 +2*GHSERNI#+GHSERMN#
-2953-5*T; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,NI:MO;0) 273.00 +2*GHSERNI#+GHSERMO#
-4631+5*T; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,NI:NB;0) 273.00 +2*GHSERNI#+GHSERNI#
-40000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,NI:NI;0) 273.00 +2*GHSERNI#+GHSERNI#
+113404; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,NI:SI;0) 273.00 +2*GHSERNI#+GHSERSI#
+30055; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,NI:TI;0) 273.00 +2*GHSERNI#+GHSERTI#
+15000; 6000.00 N
REF:pov12 !
PARAMETER G(LAVES_PHASE,NI:V;0) 273.00 +2*GHSERNI#+GHSERVV#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,NI:W;0) 273.00 +2*GHSERNI#+GHSERWW#
+15000; 6000.00 N
REF:pov12 !
PARAMETER G(LAVES_PHASE,SI:CO;0) 273.00 +2*GHSERSI#+GHSERCO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,SI:CR;0) 273.00 +2*GHSERSI#+GHSERCR#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,SI:FE;0) 273.00 +2*GHSERSI#+GHSERFE#
+262123; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,SI:MN;0) 273.00 +2*GHSERSI#+GHSERMN#
+108316; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,SI:MO;0) 273.00 +2*GHSERSI#+GHSERMO#
+45000; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,SI:NB;0) 273.00 +2*GHSERSI#+GHSERNB#
-46455; 6000.00 N
REF:153 !
PARAMETER G(LAVES_PHASE,SI:NI;0) 273.00 +2*GHSERSI#+GHSERNI#
+188664; 6000.00 N
REF:287 !
PARAMETER G(LAVES_PHASE,SI:SI;0) 273.00 +3*GHSERSI#+142380; 6000.00 N
REF:284 !
PARAMETER G(LAVES_PHASE,SI:TI;0) 273.00 +2*GHSERSI#+GHSERTI#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,SI:V;0) 273.00 +2*GHSERSI#+GHSERVV#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,SI:W;0) 273.00 +2*GHSERSI#+GHSERWW#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,TI:CO;0) 273.00 +2*GHSERTI#+GHSERCO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,TI:CR;0) 273.00 +2*GHSERTI#+GHSERCR#
+31780+6.3*T; 6000.00 N
REF:21 !
PARAMETER G(LAVES_PHASE,TI:FE;0) 273.00 +2*GHSERTI#+GHSERFE#
+15000; 6000.00 N
REF:16 !
PARAMETER G(LAVES_PHASE,TI:MN;0) 273.00 +2*GHSERTI#+GHSERFE#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,TI:MO;0) 273.00 +2*GHSERTI#+GHSERMO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,TI:NB;0) 273.00 +2*GHSERTI#+GHSERNB#
+15000; 6000.00 N
REF:16 !
PARAMETER G(LAVES_PHASE,TI:NI;0) 273.00 +2*GHSERTI#+GHSERNI#
+15000; 6000.00 N
REF:pov12 !
PARAMETER G(LAVES_PHASE,TI:SI;0) 273.00 +2*GHSERTI#+GHSERSI#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,TI:TI;0) 273.00 +3*GHSERTI#+15000; 6000.00 N
REF:16 !
PARAMETER G(LAVES_PHASE,TI:V;0) 273.00 +2*GHSERTI#+GHSERVV#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,TI:W;0) 273.00 +2*GHSERTI#+GHSERWW#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,V:CO;0) 273.00 +2*GHSERVV#+GHSERCO#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,V:CR;0) 273.00 +2*GHSERVV#+GHSERCR#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,V:FE;0) 273.00 +2*GHSERVV#+GHSERFE#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,V:MN;0) 273.00 +2*GHSERVV#+GHSERMN#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,V:MO;0) 273.00 +15000+2*GHSERVV#
+GHSERMO#; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,V:NI;0) 273.00 +2*GHSERVV#+GHSERNI#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,V:NB;0) 273.00 +2*GHSERVV#+GHSERNB#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,V:SI;0) 273.00 +2*GHSERVV#+GHSERSI#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,V:TI;0) 273.00 +2*GHSERVV#+GHSERTI#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,V:V;0) 273.00 +3*GHSERVV#+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,V:W;0) 273.00 +2*GHSERVV#+GHSERWW#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,W:CO;0) 273.00 +2*GHSERWW#+GHSERCO#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,W:CR;0) 273.00 +2*GHSERWW#+GHSERCR#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,W:FE;0) 273.00 +2*GHSERWW#+GHSERFE#
+239000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,W:MN;0) 273.00 +2*GHSERWW#+GHSERMN#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,W:MO;0) 273.00 +2*GHSERWW#+GHSERMO#
+40000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,W:NI;0) 273.00 +2*GHSERWW#+GHSERNI#
+15000; 6000.00 N
REF:pov12 !
PARAMETER G(LAVES_PHASE,W:NB;0) 273.00 +2*GHSERWW#+GHSERNB#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,W:SI;0) 273.00 +2*GHSERWW#+GHSERSI#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,W:TI;0) 273.00 +2*GHSERWW#+GHSERTI#
+15000; 6000.00 N
REF:pov10 !
PARAMETER G(LAVES_PHASE,W:V;0) 273.00 +2*GHSERWW#+GHSERVV#
+15000; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,W:W;0) 273.00 +3*GHSERWW#+133000; 6000.00 N
REF:pov13 !
$----------------------Interaction parameters----------------------
PARAMETER L(LAVES_PHASE,CO,CR:*;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,*:CO,CR;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CO,FE:*;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,*:CO,FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CO,MO:*;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CO,W:*;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,*:CO,MO;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,*:CO,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR:CR,FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,FE:CR;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE:CR,FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,FE:FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR:CR,NB;0) 273.00 +18511.36; 6000.00 N
REF:153 !
PARAMETER L(LAVES_PHASE,NB:CR,NB;0) 273.00 +18511.36; 6000.00 N
REF:153 !
PARAMETER L(LAVES_PHASE,CR,NB:CR;0) 273.00 +90673.45; 6000.00 N
REF:153 !
PARAMETER L(LAVES_PHASE,CR,NB:NB;0) 273.00 +90673.45; 6000.00 N
REF:153 !
PARAMETER L(LAVES_PHASE,CR,SI:NB;0) 273.00 -516132; 6000.00 N
REF:153 !
PARAMETER L(LAVES_PHASE,CR,W:CR;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,W:FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,W:W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR:CR,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,W:CR,FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR:FE,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE,W:CR;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE,W:FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE,W:W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE:CR,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
$
PARAMETER L(LAVES_PHASE,NB:CR,FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,FE:NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE:CR,NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,NB:FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,NB,W:NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,NB:NB,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CO,NB:NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,NB:CO,NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,W:NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,NB:CR,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,W:FE,NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE,NB:W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE,W:NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,NB:FE,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
$
PARAMETER L(LAVES_PHASE,CR,FE:MO;0) 273.00 -15000+7.5*T; 6000.00 N
REF:287!
PARAMETER L(LAVES_PHASE,CR,FE:W;0) 273.00 -12500; 6000.00 N
REF:59 !
PARAMETER L(LAVES_PHASE,CR,SI:MO;0) 273.00 -740000+300*T; 6000.00 N
REF:pov13 !
PARAMETER L(LAVES_PHASE,CR,SI:W;0) 273.00 -250000; 6000.00 N
REF:pov13 !
PARAMETER L(LAVES_PHASE,CR,TI:CR;0) 273.00 +10800+27*T; 6000.00 N
REF:21 !
PARAMETER L(LAVES_PHASE,CR,TI:TI;0) 273.00 +10800+27*T; 6000.00 N
REF:21 !
PARAMETER L(LAVES_PHASE,FE,NB:FE;0) 273.00 +30000; 6000.00 N
REF:16 !
PARAMETER L(LAVES_PHASE,FE,NB:NB;0) 273.00 +30000; 6000.00 N
REF:16 !
PARAMETER L(LAVES_PHASE,FE,NB:TI;0) 273.00 +30000; 6000.00 N
REF:16 !
PARAMETER L(LAVES_PHASE,FE,TI:FE;0) 273.00 -38000; 6000.00 N
REF:16 !
PARAMETER L(LAVES_PHASE,FE,TI:NB;0) 273.00 -38000; 6000.00 N
REF:16 !
PARAMETER L(LAVES_PHASE,FE,TI:TI;0) 273.00 -38000; 6000.00 N
REF:16 !
PARAMETER L(LAVES_PHASE,FE,SI:MO;0) 273.00 -720000+300*T; 6000.00 N
REF:287 !
PARAMETER L(LAVES_PHASE,FE,SI:W;0)
273.00 -250000; 6000.00 N
REF:pov13 !
PARAMETER L(LAVES_PHASE,CR:CR,TI;0) 273.00 +50000; 6000.00 N
REF:21 !
PARAMETER L(LAVES_PHASE,TI:CR,TI;0) 273.00 +50000; 6000.00 N
REF:21 !
PARAMETER L(LAVES_PHASE,FE:MO,W;0) 273.00 -7500; 6000.00 N
REF:55 !
$PARAMETER L(LAVES_PHASE,FE:FE,NB;0) 273.00 +30000; 6000.00 N
$REF:16 !
$PARAMETER L(LAVES_PHASE,NB:FE,NB;0) 273.00 +30000; 6000.00 N
$REF:16 !
PARAMETER L(LAVES_PHASE,FE:FE,NB;0) 273.00 -49713.1163; 6000 N
REF:262 !
PARAMETER L(LAVES_PHASE,NB:FE,NB;0) 273.00 -49713.1163; 6000 N
REF:262 !
PARAMETER L(LAVES_PHASE,TI:FE,NB;0) 273.00 +30000; 6000.00 N
REF:16 !
PARAMETER L(LAVES_PHASE,FE:FE,TI;0) 273.00 +16000; 6000.00 N
REF:16 !
PARAMETER L(LAVES_PHASE,NB:FE,TI;0) 273.00 +16000; 6000.00 N
REF:16 !
PARAMETER L(LAVES_PHASE,TI:FE,TI;0) 273.00 +16000; 6000.00 N
REF:16 !
$
PARAMETER L(LAVES_PHASE,CR:CR,MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,MN:CR;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN:CR,MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,MN:MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,W:MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,W:CR,MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR:MN,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,W:CR;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,W:MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,W:W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN:CR,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,NB:CR,MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,MN:NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN:CR,NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,NB:MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,W:MN,NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,NB:W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,W:NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,NB:MN,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,MN:MO;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,CR,MN:W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,NB:MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,NB:NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,NB:TI;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,TI:MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,TI:NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,TI:TI;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN:MO,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN:MN,NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,NB:MN,NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,TI:MN,NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN:MN,TI;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,NB:MN,TI;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,TI:MN,TI;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN:MN,FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE,MN:MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE:FE,MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE,MN:FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,W:FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,W:FE,MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN:FE,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE,W:MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE:MN,W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,NB:FE,MN;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE,MN:NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE:MN,NB;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,MN,NB:FE;0) 273.00 +70000; 6000.00 N
REF:pov10 !
PARAMETER L(LAVES_PHASE,FE,MN:MO;0) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(LAVES_PHASE,FE,MN:W;0) 273.00 +70000; 6000.00 N
REF:pov10 !
$
PARAMETER L(LAVES_PHASE,CR:CR,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:CR,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,CR,NI:CR;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,CR,NI:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,CR,SI:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
$
PARAMETER L(LAVES_PHASE,FE:CR,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,CR,NI:FE;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI,W:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:NI,W;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,CO,NI:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:CO,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,CR,W:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:CR,W;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,W:FE,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,FE,NI:W;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,FE,W:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:FE,W;0) 273.00 +70000; 6000.00 N
REF:pov12 !
$
PARAMETER L(LAVES_PHASE,FE,NI:FE;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,FE,NI:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,FE,NI:TI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,FE,TI:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,FE:FE,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:FE,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,TI:FE,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:FE,TI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:CR,MN;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,CR,MN:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,MN:CR,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,CR,NI:MN;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,W:MN,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,MN,NI:W;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,MN,W:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:MN,W;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,MN,NI:MN;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,MN,NI:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,MN,NI:TI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,TI:MN,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:MN,TI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,NI:FE,MN;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,FE,MN:NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,FE:MN,NI;0) 273.00 +70000; 6000.00 N
REF:pov12 !
PARAMETER L(LAVES_PHASE,MN,NI:FE;0) 273.00 +70000; 6000.00 N
REF:pov12 !
$
$ Note: the following two interaction parameters are preliminary!! (pov14)
PARAMETER L(LAVES_PHASE,CR,NI:MO;0) 273.00 -30000+20*T; 6000 N
REF:287 !
PARAMETER L(LAVES_PHASE,FE,NI:MO;0) 273.00 -70000+50*T; 6000.00 N
REF:287 !
PARAMETER L(LAVES_PHASE,FE,NI:MN;0) 273.00 -100000; 6000.00 N
REF:287 !
PARAMETER L(LAVES_PHASE,SI,V:MO;0) 273.00 +100000; 6000.00 N
REF:pov13 !
PARAMETER L(LAVES_PHASE,FE,V:MO;0) 273.00 -190000; 6000.00 N
REF:pov13 !
PARAMETER L(LAVES_PHASE,CR,V:MO;0) 273.00 -190000; 6000.00 N
REF:pov13 !
PARAMETER L(LAVES_PHASE,SI,V:W;0) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(LAVES_PHASE,FE,V:W;0) 273.00 -80000; 6000.00 N
REF:pov13 !
PARAMETER L(LAVES_PHASE,CR,V:W;0) 273.00 -80000; 6000.00 N
REF:pov13 !
PARAMETER L(LAVES_PHASE,CR:MO,W;0) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER G(LAVES_PHASE,NI,SI:MN;0) 273.00 -684422-15*T; 6000 N
REF:287 !
PARAMETER G(LAVES_PHASE,NI,SI:MN;1) 273.00 -96334; 6000 N
REF:287 !
PARAMETER G(LAVES_PHASE,NI,SI:MO;0) 273.00 -300000; 6000 N
REF:287 !
PARAMETER G(LAVES_PHASE,FE,NI,SI:MO;0) 273.00 -500000; 6000 N
REF:287 !
PARAMETER L(LAVES_PHASE,FE,NI,SI:MN;0) 273.00 -500000; 6000.00 N
REF:287 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MNNI
$###########################################################################
$
PHASE MNNI % 2 0.5 0.5 > cubic >> 1 !
CONSTITUENT MNNI : CU,MN%,NI : CU,MN,NI% : !
PARAMETER G(MNNI,CU:CU;0) 273.00 +GHSERCU#+10; 6000.00 N
REF:244 !
PARAMETER G(MNNI,MN:MN;0) 273.00 +GMNFCC#+10; 6000.00 N
REF:244 !
PARAMETER G(MNNI,NI:NI;0) 273.00 +GHSERNI#+10; 6000.00 N
REF:244 !
PARAMETER G(MNNI,CU:MN;0) 273.00 +0.5*GHSERCU#
+0.5*GMNFCC#+7400; 6000.00 N
REF:244 !
PARAMETER G(MNNI,MN:CU;0) 273.00 +0.5*GHSERCU#
+0.5*GMNFCC#+7400; 6000.00 N
REF:244 !
PARAMETER G(MNNI,CU:NI;0) 273.00 +0.5*GHSERCU#
+0.5*GHSERNI#+7100; 6000.00 N
REF:244 !
PARAMETER G(MNNI,NI:CU;0) 273.00 +0.5*GHSERCU#
+0.5*GHSERNI#+7100; 6000.00 N
REF:244 !
PARAMETER G(MNNI,NI:MN;0) 273.00 +0.5*GMNFCC#+0.5*GHSERNI#-10
-0.25*GMNNI3#+0.625*GMN2NI2#-0.25*GMN3NI#-0.375*LRMNNI#
+0.25*LF0#; 6000.00 N
REF:244 !
PARAMETER G(MNNI,MN:NI;0) 273.00 +0.5*GMNFCC#+0.5*GHSERNI#-10
-0.25*GMNNI3#+0.625*GMN2NI2#-0.25*GMN3NI#-0.375*LRMNNI#
+0.25*LF0#; 6000.00 N
REF:244 !
$----------------------Interaction parameters----------------------
PARAMETER L(MNNI,MN,NI:MN;0) 273.00 +0.3125*GMNNI3#
-1.09375*GMN2NI2#+0.8125*GMN3NI#+0.15625*LRMNNI#+0.25*LF0#
+0.375*LF1#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,MN:MN,NI;0) 273.00 +0.3125*GMNNI3#
-1.09375*GMN2NI2#+0.8125*GMN3NI#+0.15625*LRMNNI#+0.25*LF0#
+0.375*LF1#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,MN,NI:NI;0) 273.00 +0.8125*GMNNI3#
-1.09375*GMN2NI2#+0.3125*GMN3NI#+0.15625*LRMNNI#+0.25*LF0#
-0.375*LF1#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,NI:MN,NI;0) 273.00 +0.8125*GMNNI3#
-1.09375*GMN2NI2#+0.3125*GMN3NI#+0.15625*LRMNNI#+0.25*LF0#
-0.375*LF1#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,MN,NI:MN;1) 273.00 +0.375*GMN2NI2#
-0.5*GMN3NI#+0.375*LRMNNI#+0.125*LF1#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,MN:MN,NI;1) 273.00 +0.375*GMN2NI2#
-0.5*GMN3NI#+0.375*LRMNNI#+0.125*LF1#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,MN,NI:NI;1) 273.00 +0.5*GMNNI3#
-0.375*GMN2NI2#-0.375*LRMNNI#+0.125*LF1#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,NI:MN,NI;1) 273.00 +0.5*GMNNI3#
-0.375*GMN2NI2#-0.375*LRMNNI#+0.125*LF1#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,MN,NI:MN;2) 273.00 -0.0625*GMNNI3#
+0.09375*GMN2NI2#-0.0625*GMN3NI#-0.15625*LRMNNI#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,MN:MN,NI;2) 273.00 -0.0625*GMNNI3#
+0.09375*GMN2NI2#-0.0625*GMN3NI#-0.15625*LRMNNI#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,MN,NI:NI;2) 273.00 -0.0625*GMNNI3#
+0.09375*GMN2NI2#-0.0625*GMN3NI#-0.15625*LRMNNI#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,NI:MN,NI;2) 273.00 -0.0625*GMNNI3#
+0.09375*GMN2NI2#-0.0625*GMN3NI#-0.15625*LRMNNI#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,MN,NI:MN,NI;1) 273.00 -2.5*GMNNI3#
+3.75*GMN2NI2#-2.5*GMN3NI#+1.75*LRMNNI#; 6000.00 N
REF:244 !
PARAMETER L(MNNI,CU,MN:NI;0) 273.00 -46650+50*T; 6000.00 N
REF:244 !
PARAMETER L(MNNI,NI:CU,MN;0) 273.00 -46650+50*T; 6000.00 N
REF:244 !
PARAMETER L(MNNI,CU,NI:MN;0) 273.00 -20630+10*T; 6000.00 N
REF:244 !
PARAMETER L(MNNI,MN:CU,NI;0) 273.00 -20630+10*T; 6000.00 N
REF:244 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MNNI2
$###########################################################################
$
PHASE MNNI2 % 2 1 2 > >> 1 !
CONSTITUENT MNNI2 : MN%,NI : NI : !
PARAMETER G(MNNI2,MN:NI;0) 298.15 +GHSERMN+2*GHSERNI-27084.651
-5.98849279*T; 6000 N
REF:244 !
PARAMETER G(MNNI2,NI:NI;0) 298.15 +3*GHSERNI+15000; 6000 N
REF:244 !
PARAMETER G(MNNI2,MN,NI:NI;0) 298.15 -19871.3586; 6000 N
REF:244 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MNNI_T3
$###########################################################################
$ PHASE G_PHASE in Hu et al.
$ PHASE MNNI_T3 % 3 0.2069 0.5517 0.2414 > >> 2 !
$ CONSTITUENT MNNI_T3 : MN : NI : SI : !
$PARAMETER G(MNNI_T3,MN:NI:SI;0) 273.00 -48186.5
$ +0.2069*GHSERMN#+0.5517*GHSERNI#+0.2414*GHSERSI; 6000.00 N
$REF:pov14 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MU_PHASE
$###########################################################################
$
PHASE MU_PHASE % 3 7 2 4 >
Hard, brittle intermettalic compound. W6Fe7-type.
Important hardening phase in Fe-Co-Mo alloys. Simplified description,
model IV from ref 77 used. Use for multi-component systems.
>> 4 !
CONSTITUENT MU_PHASE : CO,CR,FE%,MN,MO,NB,NI,SI : MO,NB,W :
CO%,CR,FE,MO,NB,NI,SI,W : !
$[Model IV, REF:77) used for Mo-Co subsystem
PARAMETER G(MU_PHASE,CO:MO:CO;0) 273.00 -64478.6+49.936*T+7*GCOFCC#
+2*GHSERMO#+4*GCOBCC#; 6000.00 N
REF:77 !
PARAMETER G(MU_PHASE,CO:MO:FE;0) 273.00 +300000+7*GCOFCC#
+2*GHSERMO#+4*GHSERFE#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE,CO:MO:MO;0) 273.00 -105406.7+19.784*T
+7*GCOFCC#+6*GHSERMO#; 6000.00 N
REF:77 !
PARAMETER G(MU_PHASE,CO:MO:SI;0) 273.00 +7*GCOFCC#
+2*GHSERMO#+4*GHSERSI#+150000-50*T; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE,CO:NB:NB;0) 273.00 +7*GCOFCC#+6*GHSERNB#
-335543+57.096*T; 6000.00 N
REF:136 !
PARAMETER G(MU_PHASE,CO:W:CO;0) 273.00 +59040+7*GCOFCC#
+4*GCOBCC#+2*GHSERWW#; 6000.00 N
REF:243 !
PARAMETER G(MU_PHASE,CO:W:FE;0) 273.00 +7*GCOFCC#+2*GHSERWW#
+4*GHSERFE#; 6000.00 N
REF:79 !
PARAMETER G(MU_PHASE,CO:W:NI;0) 273.00 +7*GCOFCC#+2*GHSERWW#
+4*GNIBCC#; 6000.00 N
REF:79 !
PARAMETER G(MU_PHASE,CO:W:W;0) 273.00 -32650-14.4*T+7*GCOFCC#
+6*GHSERWW#; 6000.00 N
REF:243 !
PARAMETER G(MU_PHASE,CR:MO:CR;0) 273.00 +7*GCRFCC#+2*GHSERMO#+4*GHSERCR#
+130000-100*T; 6000.00 N
REF:111 !
PARAMETER G(MU_PHASE,CR:MO:FE;0) 273.00 +7*GCRFCC#+2*GHSERMO#+4*GHSERFE#
+130000-100*T; 6000.00 N
REF:111 !
PARAMETER G(MU_PHASE,CR:MO:MO;0) 273.00 +7*GCRFCC#+6*GHSERMO#
+130000-100*T; 6000.00 N
REF:111 !
PARAMETER G(MU_PHASE,FE:MO:CO;0) 273.00 +150000+7*GFEFCC#
+2*GHSERMO#+4*GCOBCC#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE,FE:MO:CR;0) 273.00 +7*GFEFCC#+2*GHSERMO#+4*GHSERCR#
+130000-100*T; 6000.00 N
REF:111 !
PARAMETER G(MU_PHASE,FE:MO:FE;0) 273.00 +7*GFEFCC#+2*GHSERMO#+4*GHSERFE#
+39475-6.032*T; 6000.00 N
REF:111 !
PARAMETER G(MU_PHASE,FE:MO:MO;0) 273.00 +7*GFEFCC#+6*GHSERMO#
-46663-5.891*T; 6000.00 N
REF:111 !
PARAMETER G(MU_PHASE,FE:MO:NI;0) 273.00 +7*GFEFCC#+2*GHSERMO#+4*GNIBCC#
+354030-229.4*T; 6000.00 N
REF:41 !
PARAMETER G(MU_PHASE,FE:MO:SI;0) 273.00 +7*GFEFCC#
+2*GHSERMO#+4*GHSERSI#+150000-50*T; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE,FE:MO:W;0) 273.00 +7*GFEFCC#+2*GHSERMO#+4*GHSERWW#
-72000; 6000.00 N
REF:55 !
PARAMETER G(MU_PHASE,FE:NB:FE;0) 273.00 +7*GFEFCC#+2*GHSERNB#+4*GHSERFE#
+103747; 6000.00 N
REF:16 !
PARAMETER G(MU_PHASE,FE:NB:NB;0) 273.00 +7*GFEFCC#+6*GHSERNB#
-239093+20*T; 6000.00 N
REF:113 !
PARAMETER G(MU_PHASE,FE:W:CO;0) 273.00 +7*GFEFCC#+2*GHSERWW#
+4*GCOBCC#; 6000.00 N
REF:79 !
PARAMETER G(MU_PHASE,FE:W:FE;0) 273.00 +7*GFEFCC#+2*GHSERWW#
+4*GHSERFE#; 6000.00 N
REF:79 !
PARAMETER G(MU_PHASE,FE:W:MO;0) 273.00 +7*GFEFCC#+2*GHSERWW#
+4*GHSERMO#+10000; 6000.00 N
REF:55 !
PARAMETER G(MU_PHASE,FE:W:NI;0) 273.00 +7*GFEFCC#+2*GHSERWW#
+4*GNIBCC#; 6000.00 N
REF:79 !
PARAMETER G(MU_PHASE,FE:W:W;0) 273.00 -53450+19*T+7*GFEFCC#
+6*GHSERWW#; 6000.00 N
REF:79 !
PARAMETER G(MU_PHASE,MN:MO:FE;0) 273.00 +7*GMNFCC#+2*GHSERMO#
+4*GHSERFE#; 6000.00 N
REF:pov13 !
PARAMETER G(MU_PHASE,MN:MO:MO;0) 273.00 -125000+8.5*T+7*GMNFCC#
+6*GHSERMO#; 6000.00 N
REF:pov13 !
PARAMETER G(MU_PHASE,MO:MO:CO;0) 273.00 +105928.1+30.152*T+7*GMOFCC#
+2*GHSERMO#+4*GCOBCC#; 6000.00 N
REF:77 !
PARAMETER G(MU_PHASE,MO:MO:FE;0) 273.00 +105928.1+30.152*T+7*GMOFCC#
+2*GHSERMO#+4*GHSERFE#; 6000.00 N
REF:pov09 !
$ next leads to wrong pd-reproduction of Fe-Mo, too stable mu-phase
$PARAMETER G(MU_PHASE,MO:MO:MO;0) 273.00 +65000+7*GMOFCC#
$+6*GHSERMO#; 6000.00 N
$REF:77 !
$ destabilized
PARAMETER G(MU_PHASE,MO:MO:MO;0) 273.00 +260000+7*GMOFCC#
+6*GHSERMO#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE,MO:MO:SI;0) 273.00 +7*GMOFCC#
+2*GHSERMO#+4*GHSERSI#+150000-50*T; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE,NB:NB:NB;0) 273.00 +65000+13*GHSERNB#; 6000.00 N
REF:54 !
PARAMETER G(MU_PHASE,NB:NB:NI;0) 273.00 +4*GHSERNI#+9*GHSERNB#; 6000.00 N
REF:pov13 !
PARAMETER G(MU_PHASE,NI:MO:FE;0) 273.00 +7*GHSERNI#+2*GHSERMO#+4*GHSERFE#
+784294-249.607*T; 6000.00 N
REF:41 !
PARAMETER G(MU_PHASE,NI:MO:MO;0) 273.00 +7*GHSERNI#+6*GHSERMO#
+28506-47.3*T; 6000.00 N
REF:41 !
PARAMETER G(MU_PHASE,NI:MO:NI;0) 273.00 +7*GHSERNI#+2*GHSERMO#+4*GNIBCC#
+398566-200*T; 6000.00 N
REF:41 !
PARAMETER G(MU_PHASE,NI:NB:NB;0) 273.00 -312097.5+7.3203*T+7*GHSERNI#
+6*GHSERNB#; 6000.00 N
REF:54 !
PARAMETER G(MU_PHASE,NI:W:CO;0) 273.00 +7*GHSERNI#+2*GHSERWW#
+4*GCOBCC#; 6000.00 N
REF:79 !
PARAMETER G(MU_PHASE,NI:W:FE;0) 273.00 +7*GHSERNI#+2*GHSERWW#
+4*GHSERFE#; 6000.00 N
REF:79 !
PARAMETER G(MU_PHASE,NI:W:NI;0) 273.00 +150000-50*T+7*GHSERNI#
+2*GHSERWW#+4*GNIBCC#; 6000.00 N
REF:79 !
PARAMETER G(MU_PHASE,NI:W:W;0) 273.00 +43035+7*GHSERNI#
+6*GHSERWW#; 6000.00 N
REF:79 !
PARAMETER G(MU_PHASE,SI:MO:CO;0) 273.00 +7*GHSERSI#
+2*GHSERMO#+4*GCOBCC#+300000-50*T; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE,SI:MO:FE;0) 273.00 +7*GHSERSI#
+2*GHSERMO#+4*GHSERFE#+300000-50*T; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE,SI:MO:MO;0) 273.00 +7*GHSERSI#
+2*GHSERMO#+4*GHSERMO#+300000-50*T; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE,SI:MO:SI;0) 273.00 +7*GHSERSI#
+2*GHSERMO#+4*GHSERSI#+450000-100*T; 6000.00 N
REF:pov09 !
$----------------------Interaction parameters----------------------
PARAMETER L(MU_PHASE,CR,FE:MO:MO;0) 273.00 -45000; 6000.00 N
REF:111 !
PARAMETER L(MU_PHASE,CO,FE:MO:MO;0) 273.00 -50000-50*T; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE,CO,FE:MO:FE;0) 273.00 -250000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE,CO,FE:MO:CO;0) 273.00 -250000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE,FE,MN:MO:MO;0) 273.00 +350000; 6000.00 N
REF:pov13 !
PARAMETER L(MU_PHASE,FE:MO:CO,FE;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(MU_PHASE,MN,MO:MO:MO;0) 273.00 -100000; 6000.00 N
REF:pov13 !
PARAMETER L(MU_PHASE,MO:MO:CO,FE;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(MU_PHASE,CO:MO:CO,FE;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(MU_PHASE,FE,MO:MO:CO;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(MU_PHASE,CO,MO:MO:FE;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(MU_PHASE,CO:MO:FE,MO;0) 273.00 -250000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE,FE:MO:CO,MO;0) 273.00 -250000; 6000.00 N
REF:pov11 !
$
PARAMETER L(MU_PHASE,CO,FE:MO:SI;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,CO,MO:MO:MO;0) 273.00 -59132.6+161*T; 6000.00 N
REF:77 !
PARAMETER L(MU_PHASE,CO,MO:MO:CO;0) 273.00 -59132.6+161*T; 6000.00 N
REF:77 !
PARAMETER L(MU_PHASE,CO:MO:CO,MO;0) 273.00 -117092.4+115*T; 6000.00 N
REF:77 !
PARAMETER L(MU_PHASE,CO,MO:MO:SI;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,CO:MO:MO,SI;0) 273.00 -1000000; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,CO,NI:W:W;0) 273.00 -100000+50*T; 6000.00 N
REF:pov14 !
PARAMETER L(MU_PHASE,CO,SI:MO:CO;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,CO,SI:MO:FE;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,CO,SI:MO:MO;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,CO,SI:MO:SI;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,FE,MO:MO:FE;0) 273.00 +300000; 6000.00 N
REF:pov13 !
PARAMETER L(MU_PHASE,FE,MO:MO:MO;0) 273.00 +300000; 6000.00 N
REF:pov13 !
PARAMETER L(MU_PHASE,FE,MO:MO:SI;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,FE:MO:MO,SI;0) 273.00 -600000; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,FE,SI:MO:CO;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,FE,SI:MO:FE;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,FE,SI:MO:MO;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,FE,SI:MO:SI;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,FE,NI:MO:FE;0) 273.00 -325000; 6000.00 N
REF:pov13 !
PARAMETER L(MU_PHASE,FE,NI:MO:MO;0) 273.00 -325000; 6000.00 N
REF:pov13 !
PARAMETER L(MU_PHASE,MO:MO:CO,MO;0) 273.00 -117092.4+115*T; 6000.00 N
REF:77 !
PARAMETER L(MU_PHASE,SI:MO:CO,FE;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,SI:MO:CO,MO;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,SI:MO:CO,SI;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,SI:MO:FE,MO;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,SI:MO:FE,SI;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,SI:MO:MO,SI;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
$
PARAMETER L(MU_PHASE,CO,FE:MO:MO,SI;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MU_PHASE,FE,MO:MO:MO,SI;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
$
PARAMETER L(MU_PHASE,NB,NI:NB:NB;0) 273.00 +273734.5; 6000.00 N
REF:54 !
PARAMETER L(MU_PHASE,NB,NI:NB:NB;1) 273.00 +451218.3; 6000.00 N
REF:54 !
$
$#####################################################################
$ THERMODYNAMIC PARAMETERS: MU_PHASE_I
$#####################################################################
$
PHASE MU_PHASE_I % 4 6 1 2 4 >
Hard, brittle intermetallic compound. W6Fe7-type.
Important hardening phase in Fe-Co-Mo alloys. Advanced description,
based on model V from ref 77. Use for Fe-Co-Mo-Si tool steel applications.
>> 4 !
CONSTITUENT MU_PHASE_I : CO,FE%,MO,NB : CO%,FE,MO,NB,SI : CO,FE,MO%,NB,SI :
CO,FE,MO%,NB% : !
PARAMETER G(MU_PHASE_I,CO:CO:CO:MO;0) 273.00 -130245.8+57.602*T+7*GCOFCC#
+2*GCOBCC#+4*GHSERMO#; 6000.00 N
REF:77 !
PARAMETER G(MU_PHASE_I,CO:CO:MO:MO;0) 273.00 -105406.7+19.784*T
+7*GCOFCC#+6*GHSERMO#; 6000.00 N
REF:77 !
PARAMETER G(MU_PHASE_I,CO:MO:CO:MO;0) 273.00 -111839.1+52.818*T
+6*GCOFCC#+4*GHSERMO#+2*GCOBCC#+GMOFCC#; 6000.00 N
REF:77 !
PARAMETER G(MU_PHASE_I,CO:MO:MO:MO;0) 273.00 -87000+15*T
+6*GCOFCC#+6*GHSERMO#+GMOFCC#; 6000.00 N
REF:77 !
PARAMETER G(MU_PHASE_I,CO:MO:MO:CO;0) 273.00 +6*GCOFCC#+GMOFCC#+4*GCOBCC#
+2*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:FE:FE:FE;0) 273.00 +7*GFEFCC#
+2*GHSERFE#+4*GHSERFE#
+100000; 6000.00 N
REF:pov13 !
PARAMETER G(MU_PHASE_I,MO:CO:CO:MO;0) 273.00 +6*GMOFCC#+GCOFCC#+2*GCOBCC#
+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:CO:MO:CO;0) 273.00 +6*GMOFCC#+GCOFCC#+2*GHSERMO#
+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:MO:CO:CO;0) 273.00 +6*GMOFCC#+GMOFCC#+2*GCOBCC#
+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:CO:MO:MO;0) 273.00 +6*GMOFCC#+GCOFCC#+2*GHSERMO#
+4*GHSERMO#+500000; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:MO:CO:MO;0) 273.00 +6*GMOFCC#+GMOFCC#+2*GCOBCC#
+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:MO:MO:CO;0) 273.00 +6*GMOFCC#+GMOFCC#+2*GHSERMO#
+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:FE:MO:FE;0) 273.00 +7*GFEFCC#
+2*GHSERMO#+4*GHSERFE#; 6000.00 N
REF:pov13 !
PARAMETER G(MU_PHASE_I,FE:FE:MO:MO;0) 273.00 +7*GFEFCC#+6*GHSERMO#
-46663-5.891*T; 6000.00 N
REF:111 !
PARAMETER G(MU_PHASE_I,FE:FE:FE:MO;0) 273.00 +7*GFEFCC#+2*GHSERFE#
+4*GHSERMO#-25000; 6000.00 N
REF:pov13 !
PARAMETER G(MU_PHASE_I,MO:FE:FE:FE;0) 273.00 +6*GMOFCC#+GFEFCC#
+2*GHSERFE#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:MO:FE:FE;0) 273.00 +6*GFEFCC#+4*GHSERFE#
+2*GHSERFE#+GMOFCC#; 6000.00 N
REF:pov13 !
PARAMETER G(MU_PHASE_I,FE:MO:FE:MO;0) 273.00 +6*GFEFCC#+4*GHSERMO#
+2*GHSERFE#+GMOFCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:MO:MO:MO;0) 273.00 +6*GFEFCC#+6*GHSERMO#
+GMOFCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:MO:MO:FE;0) 273.00 +6*GFEFCC#
+GMOFCC#+4*GHSERFE#
+2*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:FE:FE:MO;0) 273.00 +6*GMOFCC#+GFEFCC#+2*GHSERFE#
+4*GHSERMO#+200000; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:FE:MO:FE;0) 273.00 +6*GMOFCC#+GFEFCC#+2*GHSERMO#
+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:MO:FE:FE;0) 273.00 +6*GMOFCC#+GMOFCC#+2*GHSERFE#
+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:FE:MO:MO;0) 273.00 +6*GMOFCC#+GFEFCC#+2*GHSERMO#
+4*GHSERMO#+200000; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:MO:FE:MO;0) 273.00 +6*GMOFCC#+GMOFCC#+2*GHSERFE#
+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:MO:MO:FE;0) 273.00 +6*GMOFCC#+GMOFCC#+2*GHSERMO#
+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:MO:MO:MO;0) 273.00 +65000+7*GMOFCC#
+6*GHSERMO#; 6000.00 N
REF:77 !
PARAMETER G(MU_PHASE_I,CO:CO:CO:FE;0) 273.00 +7*GCOFCC#
+2*GCOBCC#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:CO:FE:FE;0) 273.00 +7*GCOFCC#
+6*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:FE:CO:FE;0) 273.00 +6*GCOFCC#+4*GHSERMO#
+2*GCOBCC#+GMOFCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:FE:FE:FE;0) 273.00 +6*GCOFCC#+6*GHSERMO#
+GMOFCC#; 6000.00 N
REF:pov11 !
$
PARAMETER G(MU_PHASE_I,CO:FE:FE:CO;0) 273.00 +6*GCOFCC#+GFEFCC#
+4*GCOBCC#
+2*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:CO:CO:FE;0) 273.00 +6*GFEFCC#+GCOFCC#
+2*GCOBCC#
+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:CO:FE:CO;0) 273.00 +6*GFEFCC#+GCOFCC#
+2*GHSERFE#
+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:FE:CO:CO;0) 273.00 +6*GFEFCC#+GFEFCC#
+2*GCOBCC#
+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:CO:FE:FE;0) 273.00 +6*GFEFCC#+GCOFCC#
+2*GHSERFE#
+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:FE:CO:FE;0) 273.00 +6*GFEFCC#+GFEFCC#
+2*GCOBCC#
+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:FE:FE:CO;0) 273.00 +6*GFEFCC#+GFEFCC#
+2*GHSERFE#
+4*GCOBCC#; 6000.00 N
REF:pov11 !
$
PARAMETER G(MU_PHASE_I,CO:CO:MO:FE;0) 273.00 +7*GCOFCC#
+2*GHSERMO#+4*GHSERFE#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,CO:CO:FE:MO;0) 273.00 -100000+7*GCOFCC#
+4*GHSERMO#+2*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:MO:CO:FE;0) 273.00 +6*GCOFCC#
+GMOFCC#+2*GCOBCC#+4*GHSERFE#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,CO:FE:CO:MO;0) 273.00 +6*GCOFCC#
+GFEFCC#+2*GCOBCC#+4*GHSERMO#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,CO:MO:FE:CO;0) 273.00 +6*GCOFCC#
+GMOFCC#+2*GHSERFE#+4*GCOBCC#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,CO:FE:MO:CO;0) 273.00 +6*GCOFCC#
+GFEFCC#+2*GHSERMO#+4*GCOBCC#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,MO:CO:CO:FE;0) 273.00 +6*GMOFCC#
+GCOFCC#+2*GCOBCC#+4*GHSERFE#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,FE:CO:CO:MO;0) 273.00 +6*GFEFCC#
+GCOFCC#+2*GCOBCC#+4*GHSERMO#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,FE:MO:CO:CO;0) 273.00 +6*GFEFCC#
+GMOFCC#+2*GCOBCC#+4*GCOBCC#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,MO:FE:CO:CO;0) 273.00 +6*GMOFCC#
+GFEFCC#+2*GCOBCC#+4*GCOBCC#; 6000.00 N
REF:pov09 !
$
PARAMETER G(MU_PHASE_I,MO:MO:CO:FE;0) 273.00 +7*GMOFCC#
+2*GCOBCC#+4*GHSERFE#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,MO:MO:FE:CO;0) 273.00 +7*GMOFCC#
+2*GHSERFE#+4*GCOBCC#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,MO:CO:MO:FE;0) 273.00 +6*GMOFCC#
+GCOFCC#+2*GHSERMO#+4*GHSERFE#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,MO:FE:MO:CO;0) 273.00 +6*GMOFCC#
+GFEFCC#+2*GHSERMO#+4*GCOBCC#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,MO:CO:FE:MO;0) 273.00 +6*GMOFCC#
+GCOFCC#+2*GHSERFE#+4*GHSERMO#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,MO:FE:CO:MO;0) 273.00 +6*GMOFCC#
+GFEFCC#+2*GCOBCC#+4*GHSERMO#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,CO:MO:MO:FE;0) 273.00 +6*GCOFCC#
+GMOFCC#+2*GHSERMO#+4*GHSERFE#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,FE:MO:MO:CO;0) 273.00 +6*GFEFCC#
+GMOFCC#+2*GHSERMO#+4*GCOBCC#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,FE:CO:MO:MO;0) 273.00 -95000+6*GFEFCC#
+GCOFCC#+2*GHSERMO#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:FE:MO:MO;0) 273.00 +6*GCOFCC#
+GFEFCC#+2*GHSERMO#+4*GHSERMO#; 6000.00 N
REF:pov09 !
$
PARAMETER G(MU_PHASE_I,FE:FE:CO:MO;0) 273.00 +7*GFEFCC#
+2*GCOBCC#+4*GHSERMO#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,FE:FE:MO:CO;0) 273.00 +7*GFEFCC#
+2*GHSERMO#+4*GCOBCC#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,FE:MO:FE:CO;0) 273.00 +6*GFEFCC#
+GMOFCC#+2*GHSERFE#+4*GCOBCC#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,FE:CO:FE:MO;0) 273.00 +6*GFEFCC#
+GCOFCC#+2*GHSERFE#+4*GHSERMO#-10000; 6000.00 N
REF:pov13 !
PARAMETER G(MU_PHASE_I,FE:CO:MO:FE;0) 273.00 +6*GFEFCC#
+GCOFCC#+2*GHSERMO#+4*GHSERFE#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,FE:MO:CO:FE;0) 273.00 +6*GFEFCC#
+GMOFCC#+2*GCOBCC#+4*GHSERFE#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,CO:FE:FE:MO;0) 273.00 +6*GCOFCC#
+GFEFCC#+2*GHSERFE#+4*GHSERMO#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,MO:FE:FE:CO;0) 273.00 +6*GMOFCC#
+GFEFCC#+2*GHSERFE#+4*GCOBCC#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,MO:CO:FE:FE;0) 273.00 +6*GMOFCC#
+GCOFCC#+2*GHSERFE#+4*GHSERFE#; 6000.00 N
REF:pov09 !
PARAMETER G(MU_PHASE_I,CO:MO:FE:FE;0) 273.00 +6*GCOFCC#
+GMOFCC#+2*GHSERFE#+4*GHSERFE#; 6000.00 N
REF:pov09 !
$
$Added parameter for the Fe-Nb system
PARAMETER G(MU_PHASE_I,FE:FE:FE:NB;0) 273.00 +9*GHSERFE#+4*GHSERNB#
-100230; 6000.00 N
REF:261 !
PARAMETER G(MU_PHASE_I,FE:FE:NB:NB;0) 273.00 +7*GHSERFE#+6*GHSERNB#
-266116+56*T; 6000.00 N
REF:281 !
PARAMETER G(MU_PHASE_I,FE:NB:FE:NB;0) 273.00 +8*GHSERFE#+5*GHSERNB#
-27430; 6000.00 N
REF:281 !
PARAMETER G(MU_PHASE_I,FE:NB:NB:NB;0) 273.00 +6*GHSERFE#+7*GHSERNB#
-131400; 6000.00 N
REF:262 !
PARAMETER G(MU_PHASE_I,NB:FE:FE:NB;0) 273.00 +3*GHSERFE#+10*GHSERNB#
+426530; 6000.00 N
REF:261 !
PARAMETER G(MU_PHASE_I,NB:FE:NB:NB;0) 273.00 +GHSERFE#+12*GHSERNB#
+176020; 6000.00 N
REF:261 !
PARAMETER G(MU_PHASE_I,NB:NB:FE:NB;0) 273.00 +2*GHSERFE#+11*GHSERNB#
+499200; 6000.00 N
REF:281 !
PARAMETER G(MU_PHASE_I,NB:NB:NB:NB;0) 273.00 +13*GHSERNB#
+227500; 6000.00 N
REF:261 !
$
$----------------------Interaction parameters----------------------
$
PARAMETER L(MU_PHASE_I,CO,FE:CO:MO:MO;0) 273.00 -60000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,CO,FE:CO:MO:MO;1) 273.00 -60000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,CO,FE:FE:MO:MO;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,CO,FE:CO:MO:FE;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,CO,FE:CO:MO:CO;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,CO,FE:CO:MO:FE,MO;0) 273.00 0; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,FE:CO:MO:FE,MO;0) 273.00 +200000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,CO:FE:MO:FE,MO;0) 273.00 +200000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,CO:CO:MO:FE,MO;0) 273.00 +200000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,FE:FE:MO:FE,MO;0) 273.00 +200000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,FE:CO:FE,MO:MO;0) 273.00 -175000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,CO:FE:FE,MO:MO;0) 273.00 -175000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,FE:CO:CO,MO:MO;0) 273.00 -175000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,CO:FE:CO,MO:MO;0) 273.00 -175000; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,CO:CO,MO:CO:MO;0) 273.00 -4263+10*T; 6000.00 N
REF:77 !
PARAMETER L(MU_PHASE_I,CO:CO,MO:MO:MO;0) 273.00 -4263+10*T; 6000.00 N
REF:77 !
PARAMETER L(MU_PHASE_I,CO:CO:CO,MO:MO;0) 273.00 -8141+20*T; 6000.00 N
REF:77 !
PARAMETER L(MU_PHASE_I,CO:MO:CO,MO:MO;0) 273.00 -8141+20*T; 6000.00 N
REF:77 !
$
$ PARAMETER WITH SILICON
$
PARAMETER G(MU_PHASE_I,MO:SI:SI:MO;0) 273.00 +6*GMOFCC#+GSIFCC#+2*GSIBCC#
+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:SI:MO:MO;0) 273.00 +6*GMOFCC#+GSIFCC#+2*GHSERMO#
+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:MO:SI:MO;0) 273.00 +6*GMOFCC#+GMOFCC#+2*GSIBCC#
+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:SI:SI:FE;0) 273.00 +6*GFEFCC#+GSIFCC#
+2*GSIBCC#
+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:SI:FE:FE;0) 273.00 +6*GFEFCC#+GSIFCC#
+2*GHSERFE#
+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:FE:SI:FE;0) 273.00 +6*GFEFCC#+GFEFCC#
+2*GSIBCC#
+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:SI:SI:FE;0) 273.00 +6*GMOFCC#
+GSIFCC#+2*GSIBCC#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:SI:SI:MO;0) 273.00 +6*GFEFCC#
+GSIFCC#+2*GSIBCC#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:MO:SI:FE;0) 273.00 +7*GMOFCC#
+2*GSIBCC#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:SI:MO:FE;0) 273.00 +6*GMOFCC#
+GSIFCC#+2*GHSERMO#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:SI:FE:MO;0) 273.00 +6*GMOFCC#
+GSIFCC#+2*GHSERFE#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:FE:SI:MO;0) 273.00 +6*GMOFCC#
+GFEFCC#+2*GSIBCC#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:SI:MO:MO;0) 273.00 +6*GFEFCC#
+GSIFCC#+2*GHSERMO#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:FE:SI:MO;0) 273.00 +7*GFEFCC#
+2*GSIBCC#+4*GHSERMO#-400000+32*T; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:SI:FE:MO;0) 273.00 +6*GFEFCC#
+GSIFCC#+2*GHSERFE#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:SI:MO:FE;0) 273.00 +6*GFEFCC#
+GSIFCC#+2*GHSERMO#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:MO:SI:FE;0) 273.00 +6*GFEFCC#
+GMOFCC#+2*GSIBCC#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:SI:FE:FE;0) 273.00 +6*GMOFCC#
+GSIFCC#+2*GHSERFE#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:SI:SI:CO;0) 273.00 +6*GCOFCC#
+GSIFCC#+2*GSIBCC#
+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:SI:CO:CO;0) 273.00 +6*GCOFCC#
+GSIFCC#+2*GCOBCC#
+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:CO:SI:CO;0) 273.00 +6*GCOFCC#
+GCOFCC#+2*GSIBCC#
+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:SI:SI:FE;0) 273.00 +6*GCOFCC#
+GSIFCC#+2*GSIBCC#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:SI:SI:CO;0) 273.00 +6*GFEFCC#
+GSIFCC#+2*GSIBCC#+4*GCOBCC#; 6000.00 N
REF:pov11 !
$
PARAMETER G(MU_PHASE_I,CO:CO:SI:FE;0) 273.00 +7*GCOFCC#
+2*GSIBCC#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:SI:CO:FE;0) 273.00 +6*GCOFCC#
+GSIFCC#+2*GCOBCC#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:SI:FE:CO;0) 273.00 +6*GCOFCC#
+GSIFCC#+2*GHSERFE#+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:FE:SI:CO;0) 273.00 +6*GCOFCC#
+GFEFCC#+2*GSIBCC#+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:SI:CO:CO;0) 273.00 +6*GFEFCC#
+GSIFCC#+2*GCOBCC#+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:FE:SI:CO;0) 273.00 +7*GFEFCC#
+2*GSIBCC#+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:SI:FE:CO;0) 273.00 +6*GFEFCC#
+GSIFCC#+2*GHSERFE#+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:SI:CO:FE;0) 273.00 +6*GFEFCC#
+GSIFCC#+2*GCOBCC#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,FE:CO:SI:FE;0) 273.00 +6*GFEFCC#
+GCOFCC#+2*GSIBCC#+4*GHSERFE#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:SI:FE:FE;0) 273.00 +6*GCOFCC#
+GSIFCC#+2*GHSERFE#+4*GHSERFE#; 6000.00 N
REF:pov11 !
$
PARAMETER G(MU_PHASE_I,MO:SI:SI:CO;0) 273.00 +6*GMOFCC#
+GSIFCC#+2*GSIBCC#+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:SI:SI:MO;0) 273.00 +6*GCOFCC#
+GSIFCC#+2*GSIBCC#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:MO:SI:CO;0) 273.00 +7*GMOFCC#
+2*GSIBCC#+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:SI:MO:CO;0) 273.00 +6*GMOFCC#
+GSIFCC#+2*GHSERMO#+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:SI:CO:MO;0) 273.00 +6*GMOFCC#
+GSIFCC#+2*GCOBCC#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:CO:SI:MO;0) 273.00 +6*GMOFCC#
+GCOFCC#+2*GSIBCC#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:SI:MO:MO;0) 273.00 +6*GCOFCC#
+GSIFCC#+2*GHSERMO#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:CO:SI:MO;0) 273.00 -400000+32*T+7*GCOFCC#
+2*GSIBCC#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:SI:CO:MO;0) 273.00 +6*GCOFCC#
+GSIFCC#+2*GCOBCC#+4*GHSERMO#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:SI:MO:CO;0) 273.00 +6*GCOFCC#
+GSIFCC#+2*GHSERMO#+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:MO:SI:CO;0) 273.00 +6*GCOFCC#
+GMOFCC#+2*GSIBCC#+4*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,MO:SI:CO:CO;0) 273.00 +6*GMOFCC#
+GSIFCC#+2*GCOBCC#+4*GCOBCC#; 6000.00 N
REF:pov11 !
$
PARAMETER G(MU_PHASE_I,FE:CO:SI:MO;0) 273.00 +6*GFEFCC#
+GCOFCC#+2*GSIBCC#+4*GHSERMO#-400000+32*T; 6000.00 N
REF:pov11 !
PARAMETER G(MU_PHASE_I,CO:FE:SI:MO;0) 273.00 +1*GFEFCC#
+6*GCOFCC#+2*GSIBCC#+4*GHSERMO#-400000+32*T; 6000.00 N
REF:pov11 !
$
PARAMETER L(MU_PHASE_I,CO:CO,SI:MO:MO;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(MU_PHASE_I,FE:CO,SI:MO:MO;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: ETA
$###########################################################################
$
PHASE ETA % 2 3 1 > Hexagonal Ni3Ti-type, D024 structure,
precipitate e.g. in some maraging steels >> 3 !
CONSTITUENT ETA : AL,FE,NI%,TI : AL,FE,NI,TI% : !
PARAMETER G(ETA,AL:AL;0) 273.00 +4*GHSERAL#+1000; 6000.00 N
REF:pov15 !
PARAMETER G(ETA,AL:FE;0) 273.00 +3*GHSERAL#+GHSERFE#; 6000.00 N
REF:pov10 !
PARAMETER G(ETA,AL:NI;0) 273.00 +3*GHSERAL#+GHSERNI#; 6000.00 N
REF:pov10 !
PARAMETER G(ETA,FE:AL;0) 273.00 +3*GHSERFE#+GHSERAL#; 6000.00 N
REF:pov10 !
PARAMETER G(ETA,FE:FE;0) 273.00 +4*GHSERFE#+1000; 6000.00 N
REF:pov15 !
PARAMETER G(ETA,FE:NI;0) 273.00 +3*GDHCFE#+GDHCNI#; 6000.00 N
REF:160 !
PARAMETER G(ETA,FE:TI;0) 273.00 +3*GHSERFE#+GHSERTI#-33000+2*T; 6000.00 N
REF:160 !
PARAMETER G(ETA,NI:AL;0) 273.00 +3*GHSERNI#+GHSERAL#-120000-7*T; 6000.00 N
REF:pov14 !
PARAMETER G(ETA,NI:FE;0) 273.00 +3*GDHCNI#+GDHCFE#; 6000.00 N
REF:160 !
PARAMETER G(ETA,NI:NI;0) 273.00 +4*GDHCNI#+5000; 6000.00 N
REF:pov15 !
PARAMETER G(ETA,NI:TI;0) 273.00 -165000+29*T
+3*GDHCNI#+GDHCTI#; 6000.00 N
REF:pov15 !
PARAMETER G(ETA,TI:AL;0) 273.00 +3*GHSERTI#+GHSERAL#; 6000.00 N
REF:pov10 !
PARAMETER G(ETA,TI:FE;0) 273.00 +3*GDHCTI#+GDHCFE#+30000; 6000.00 N
REF:160 !
PARAMETER G(ETA,TI:NI;0) 273.00 165000-29*T
+GDHCNI#+3*GDHCTI#; 6000.00 N
REF:pov15 !
PARAMETER G(ETA,TI:TI;0) 273.00 +4*GDHCTI#+5000; 6000.00 N
REF:pov15 !
$
PARAMETER L(ETA,NI:NI,TI;0) 273.00 +100000-75*T; 6000.00 N
REF:pov15 !
PARAMETER L(ETA,NI:NI,TI;1) 273.00 +110000-66*T; 6000.00 N
REF:pov15 !
PARAMETER L(ETA,TI:NI,TI;0) 273.00 +20000; 6000.00 N
REF:160 !
PARAMETER L(ETA,NI,TI:TI;0) 273.00 +60000; 6000.00 N
REF:160 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NITI2
$###########################################################################
$
PHASE NITI2 % 2 2 1 > Cubic, precipitate in high Ni-Ti alloys >> 1 !
CONSTITUENT NITI2 : NI,TI% : NI%,TI : !
PARAMETER G(NITI2,TI:NI;0) 273.00 +3*GTI2NI#; 6000.00 N
REF:160 !
PARAMETER G(NITI2,NI:TI;0) 273.00 +2*GLAVNI#+GLAVTI#
+30000-3*GTI2NI#; 6000.00 N
REF:160 !
$
PARAMETER L(NITI2,NI,TI:NI;0) 273.00 60000; 6000.00 N
REF:160 !
PARAMETER L(NITI2,NI:NI,TI;0) 273.00 60000; 6000.00 N
REF:160 !
PARAMETER L(NITI2,TI:NI,TI;0) 273.00 60000; 6000.00 N
REF:160 !
PARAMETER L(NITI2,NI,TI:TI;0) 273.00 60000; 6000.00 N
REF:160 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: PI_PHASE
$###########################################################################
$
PHASE PI_PHASE % 3 7 13 4 > >> 2 !
CONSTITUENT PI_PHASE : FE%,NI : CR,MO% : N : !
PARAMETER G(PI_PHASE,FE:CR:N;0) 273.00 +7*GHSERFE#+13*GHSERCR#
+4*GHSERNN#-485000+300*T; 6000.00 N
REF:pov13 !
PARAMETER G(PI_PHASE,FE:MO:N;0) 273.00 +7*GHSERFE#+13*GHSERMO#
+4*GHSERNN#-615000+300*T; 6000.00 N
REF:pov13 !
PARAMETER G(PI_PHASE,NI:CR:N;0) 273.00 +7*GHSERNI#+13*GHSERCR#
+4*GHSERNN#-530000+300*T; 6000.00 N
REF:pov13 !
PARAMETER G(PI_PHASE,NI:MO:N;0) 273.00 +7*GHSERNI#+13*GHSERMO#
+4*GHSERNN#-645000+300*T; 6000.00 N
REF:pov13 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: R_PHASE
$###########################################################################
$
PHASE R_PHASE % 3 27 14 12 >
Topologically close-packed structure, closely related to Sigma and Mu-Phase.
>> 2 !
CONSTITUENT R_PHASE : CR,FE,MN : MN,MO% : CR,FE,MN,MO,NI,SI : !
PARAMETER G(R_PHASE,CR:MN:CR;0) 273.00 +27*GCRFCC#+14*GHSERMN#
+12*GHSERCR#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,CR:MN:FE;0) 273.00 +27*GCRFCC#+14*GHSERMN#
+12*GHSERFE#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,CR:MN:MN;0) 273.00 +27*GCRFCC#+14*GHSERMN#
+12*GHSERMN#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,CR:MN:MO;0) 273.00 +27*GCRFCC#+14*GHSERMN#
+12*GHSERMO#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,CR:MO:CR;0) 273.00 +27*GCRFCC#+14*GHSERMO#
+12*GHSERCR#-20000; 6000.00 N
REF:111 !
PARAMETER G(R_PHASE,CR:MO:FE;0) 273.00 +27*GCRFCC#+14*GHSERMO#
+12*GHSERFE#+645260-620*T; 6000.00 N
REF:111 !
PARAMETER G(R_PHASE,CR:MO:MO;0) 273.00 +27*GCRFCC#+26*GHSERMO#
-20000; 6000.00 N
REF:111 !
PARAMETER G(R_PHASE,FE:MN:FE;0) 273.00 +12*GHSERFE#+14*GMNBCC#
+27*GFEFCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,FE:MN:MN;0) 273.00 +12*GHSERMN#+14*GMNBCC#
+27*GFEFCC#; 6000.00 N
REF:pov15 !
PARAMETER G(R_PHASE,FE:MN:MO;0) 273.00 +12*GHSERMO#+14*GMNBCC#
+27*GFEFCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,FE:MO:CR;0) 273.00 +27*GFEFCC#+14*GHSERMO#
+12*GHSERCR#+645260-620*T; 6000.00 N
REF:111 !
PARAMETER G(R_PHASE,FE:MO:FE;0) 273.00 +27*GFEFCC#+14*GHSERMO#
+12*GHSERFE#-77487-50.486*T; 6000.00 N
REF:111 !
PARAMETER G(R_PHASE,FE:MO:MN;0) 273.00 +12*GHSERMN#+14*GHSERMO#
+27*GFEFCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,FE:MO:MO;0) 273.00 +27*GFEFCC#+26*GHSERMO#
+313474-289.472*T; 6000.00 N
REF:111 !
PARAMETER G(R_PHASE,MN:MN:FE;0) 273.00 +12*GHSERFE#+14*GMNBCC#
+27*GMNFCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,MN:MN:MN;0) 273.00 +26*GMNBCC#
+27*GMNFCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,MN:MO:FE;0) 273.00 +12*GHSERFE#+14*GHSERMO#
+27*GMNFCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,MN:MO:MN;0) 273.00 +12*GMNBCC#+27*GMNFCC#
+14*GHSERMO#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,MN:MO:MO;0) 273.00 +27*GMNFCC#
+26*GHSERMO#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,MN:MN:MO;0) 273.00 +12*GHSERMO#+14*GMNBCC#
+27*GMNFCC#; 6000.00 N
REF:pov13 !
$
PARAMETER G(R_PHASE,CR:MN:NI;0) 273.00 +14*GMNBCC#+27*GCRFCC#
+12*GNIBCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,CR:MO:NI;0) 273.00 +14*GHSERMO#+27*GCRFCC#
+12*GNIBCC#-200000; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,FE:MN:NI;0) 273.00 +14*GMNBCC#+27*GFEFCC#
+12*GNIBCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,FE:MO:NI;0) 273.00 +14*GHSERMO#+27*GFEFCC#
+12*GNIBCC#-200000; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,MN:MN:NI;0) 273.00 +14*GMNBCC#+27*GMNFCC#
+12*GNIBCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,MN:MO:NI;0) 273.00 +14*GHSERMO#+27*GMNFCC#
+12*GNIBCC#; 6000.00 N
REF:pov13 !
$
PARAMETER G(R_PHASE,CR:MN:SI;0) 273.00 +14*GMNBCC#+27*GCRFCC#
+12*GSIBCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,CR:MO:SI;0) 273.00 +14*GHSERMO#+27*GCRFCC#
+12*GSIBCC#-1000000; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,FE:MN:SI;0) 273.00 +14*GMNBCC#+27*GFEFCC#
+12*GSIBCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,FE:MO:SI;0) 273.00 +14*GHSERMO#+27*GFEFCC#
+12*GSIBCC#-1000000; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,MN:MN:SI;0) 273.00 +14*GMNBCC#+27*GMNFCC#
+12*GSIBCC#; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,MN:MO:SI;0) 273.00 +14*GHSERMO#+27*GMNFCC#
+12*GSIBCC#; 6000.00 N
REF:pov13 !
$
PARAMETER G(R_PHASE,FE:MO:FE,NI;0) 273.00 -500000; 6000.00 N
REF:pov13 !
PARAMETER G(R_PHASE,FE:MO:FE,SI;0) 273.00 -2000000; 6000.00 N
REF:pov13 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: SIGMA
$###########################################################################
$
PHASE SIGMA % 3 8 4 18 >
NOTE: In austenitic stainless steels, set Ni% instead of Fe% on sublattice 1.
Intermetallic transition elements compound with broad solid solubility range.
Tetragonal with five non-equivalent sites.
A simplified 3-sublattice description is used.
Hard and brittle topologically close-packed (TCP) precipitates.
Optimized for use in thermokinetic precipitation simulations in
austenitic stainless steel (pov12,pov13). For typical austenitic
stainless steels
(e.g. grade 316) use default mayor constituents :FE%:CR%::
>> 4 !
CONSTITUENT SIGMA : CO,FE%,MN,NI:CR%,MO,V:CO,CR,FE,MN,MO,NI,SI,V :!
PARAMETER G(SIGMA,CO:CR:CO;0) 273.00 +17077-30.518*T+8*GCOFCC#
+4*GHSERCR#+18*GCOBCC#; 6000.00 N
REF:73 !
PARAMETER G(SIGMA,CO:CR:CR;0) 273.00 -7466-104.215*T+8*GCOFCC#
+22*GHSERCR#; 6000.00 N
REF:73 !
PARAMETER G(SIGMA,CO:CR:FE;0) 273.00 +8*GCOFCC#+4*GHSERCR#
+18*GHSERFE#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:CR:MN;0) 273.00 +8*GCOFCC#+4*GHSERCR#
+18*GMNBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:CR:MO;0) 273.00 +8*GCOFCC#+4*GHSERCR#
+18*GHSERMO#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:CR:NI;0) 273.00 +8*GCOFCC#+4*GHSERCR#
+18*GNIBCC#-170000; 6000.00 N
REF:pov15 !
PARAMETER G(SIGMA,CO:CR:SI;0) 273.00 +8*GCOFCC#+4*GHSERCR#
+18*GSIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:CR:V;0) 273.00 +8*GCOFCC#+4*GHSERCR#
+18*GHSERVV#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:MO:CO;0) 273.00 -130932.67+240.554*T+8*GCOFCC#
+4*GHSERMO#+18*GCOBCC#; 6000.00 N
REF:77 !
PARAMETER G(SIGMA,CO:MO:CR;0) 273.00 +8*GCOFCC#+4*GHSERMO#
+18*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:MO:FE;0) 273.00 +8*GCOFCC#+4*GHSERMO#
+18*GHSERFE#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:MO:MN;0) 273.00 +8*GCOFCC#+4*GHSERMO#
+18*GMNBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:MO:MO;0) 273.00 -87868.24+14.662*T+8*GCOFCC#
+22*GHSERMO#; 6000.00 N
REF:77 !
PARAMETER G(SIGMA,CO:MO:NI;0) 273.00 +8*GCOFCC#+4*GHSERMO#
+18*GNIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:MO:SI;0) 273.00 +8*GCOFCC#+4*GHSERMO#
+18*GSIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:MO:V;0) 273.00 +8*GCOFCC#+4*GHSERMO#
+18*GHSERVV#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:V:CO;0) 273.00 -398317.14+169.8*T+8*GCOFCC#
+18*GCOBCC#+4*GHSERVV#; 6000.00 N
REF:134 !
PARAMETER G(SIGMA,CO:V:CR;0) 273.00 +8*GCOFCC#+4*GHSERMO#
+18*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:V:FE;0) 273.00 +8*GCOFCC#+4*GHSERMO#
+18*GHSERFE#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:V:MN;0) 273.00 +8*GCOFCC#+4*GHSERMO#
+18*GMNBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:V:MO;0) 273.00 +8*GCOFCC#+4*GHSERVV#
+18*GHSERMO#; 6000.00 N
REF:77 !
PARAMETER G(SIGMA,CO:V:NI;0) 273.00 +8*GCOFCC#+4*GHSERVV#
+18*GNIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:V:SI;0) 273.00 +8*GCOFCC#+4*GHSERVV#
+18*GSIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,CO:V:V;0) 273.00 -260096.1+14.598*T+8*GCOFCC#
+22*GHSERVV#; 6000.00 N
REF:134 !
PARAMETER G(SIGMA,FE:CR:CO;0) 273.00 +8*GFEFCC#+4*GHSERCR#
+18*GCOBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,FE:CR:CR;0) 273.00 +8*GFEFCC#+22*GHSERCR#
+92300-95.96*T; 6000.00 N
REF:62 !
PARAMETER G(SIGMA,FE:CR:FE;0) 273.00 +117300-95.96*T+8*GFEFCC#
+4*GHSERCR#+18*GHSERFE#; 6000.00.00 N
REF:62 !
PARAMETER G(SIGMA,FE:CR:MN;0) 273.00 -83639.5+18.26*T+8*GFEFCC#
+4*GHSERCR#+18*GMNBCC#; 6000.00.00 N
REF:22 !
PARAMETER G(SIGMA,FE:CR:MO;0) 273.00 +8*GFEFCC#+4*GHSERCR#
+18*GHSERMO#+312580-260*T; 6000.00 N
REF:111 !
PARAMETER G(SIGMA,FE:CR:NI;0) 273.00 -50000+32*T+8*GFEFCC#+4*GHSERCR#
+18*GNIBCC#; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,FE:CR:V;0) 273.00 +8*GFEFCC#+4*GHSERCR#+18*GHSERVV#
-245761-67.3294*T; 6000.00 N
REF:68 !
PARAMETER G(SIGMA,FE:MO:CO;0) 273.00 +8*GFEFCC#+4*GHSERMO#
+18*GCOBCC#; 6000.00 N
REF:pov11 !
PARAMETER G(SIGMA,FE:MO:CR;0) 273.00 +8*GFEFCC#+4*GHSERMO#+18*GHSERCR#
+488480-300*T; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,FE:MO:FE;0) 273.00 -1813-27.272*T+8*GFEFCC#
+4*GHSERMO#+18*GHSERFE#; 6000.00 N
REF:27 !
PARAMETER G(SIGMA,FE:MO:MN;0) 273.00 +50000+8*GFEFCC#+4*GHSERMO#
+18*GMNBCC#; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,FE:MO:MO;0) 273.00 +83326-69.618*T+8*GFEFCC#
+22*GHSERMO#; 6000.00 N
REF:27 !
PARAMETER G(SIGMA,FE:MO:NI;0) 273.00 +8*GFEFCC#+18*GNIBCC#+4*GHSERMO#
+408600-200*T; 6000.00 N
REF:41 !
PARAMETER G(SIGMA,FE:MO:V;0) 273.00 +8*GFEFCC#+4*GHSERMO#
+18*GHSERVV#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,FE:V:CO;0) 273.00 +8*GFEFCC#+4*GHSERVV#
+18*GCOBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,FE:V:CR;0) 273.00 +8*GFEFCC#+4*GHSERVV#
+18*GHSERCR#; 6000.00 N
REF:68 !
PARAMETER G(SIGMA,FE:V:FE;0) 273.00 +8*GFEFCC#+4*GHSERVV#+18*GHSERFE#
-157961+60.729*T; 6000.00 N
REF:68 !
PARAMETER G(SIGMA,FE:V:MN;0) 273.00 +8*GFEFCC#+4*GHSERVV#
+18*GMNBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,FE:V:MO;0) 273.00 +8*GFEFCC#+4*GHSERVV#
+18*GHSERMO#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,FE:V:NI;0) 273.00 +8*GFEFCC#+4*GHSERVV#
+18*GNIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,FE:V:SI;0) 273.00 +8*GFEFCC#+4*GHSERVV#
+18*GSIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,FE:V:V;0) 273.00 +8*GFEFCC#+22*GHSERVV#
-205321-60.967*T; 6000.00 N
REF:68 !
PARAMETER G(SIGMA,MN:CR:CO;0) 273.00 +8*GMNFCC#+4*GHSERCR#
+18*GCOBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:CR:CR;0) 273.00 +65859.5+8*GMNFCC#
+22*GHSERCR#; 6000.00 N
REF:62 !
PARAMETER G(SIGMA,MN:CR:FE;0) 273.00 +8*GMNFCC#+4*GHSERCR#+18*GHSERFE#
-95576-45.1955*T; 6000.00 N
REF:62 !
PARAMETER G(SIGMA,MN:CR:MN;0) 273.00 -172946+69.0245*T+8*GMNFCC#
+4*GHSERCR#+18*GMNBCC#; 6000.00 N
REF:62 !
PARAMETER G(SIGMA,MN:CR:MO;0) 273.00 +8*GMNFCC#+4*GHSERCR#
+18*GHSERMO#+312580-260*T; 6000.00 N
REF:111 !
PARAMETER G(SIGMA,MN:CR:NI;0) 273.00 +8*GMNFCC#+4*GHSERCR#
+18*GNIBCC#; 6000.00 N
REF:13 !
PARAMETER G(SIGMA,MN:CR:V;0) 273.00 +8*GMNFCC#+4*GHSERCR#
+18*GHSERVV#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:MO:CO;0) 273.00 +8*GMNFCC#+4*GHSERMO#
+18*GCOBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:MO:CR;0) 273.00 +8*GMNFCC#+4*GHSERMO#
+18*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:MO:FE;0) 273.00 +50000+8*GMNFCC#+4*GHSERMO#
+18*GHSERFE#; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,MN:MO:MN;0) 273.00 +8*GMNFCC#+4*GHSERMO#+18*GMNBCC#
+50000-32*T; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,MN:MO:MO;0) 273.00 +8*GMNFCC#+22*GHSERMO#
-144000+142*T; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,MN:MO:NI;0) 273.00 +8*GMNFCC#+18*GNIBCC#
+4*GHSERMO#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:MO:V;0) 273.00 +8*GMNFCC#+4*GHSERMO#
+18*GHSERVV#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:V:CO;0) 273.00 +8*GMNFCC#+4*GHSERVV#
+18*GCOBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:V:CR;0) 273.00 +8*GMNFCC#+4*GHSERVV#
+18*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:V:FE;0) 273.00 +8*GMNFCC#+4*GHSERVV#
+18*GHSERFE#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:V:MN;0) 273.00 +8*GMNFCC#+4*GHSERVV#
+18*GMNBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:V:MO;0) 273.00 +8*GMNFCC#+4*GHSERVV#
+18*GHSERMO#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:V:NI;0) 273.00 +8*GMNFCC#+4*GHSERVV#
+18*GNIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:V:SI;0) 273.00 +8*GMNFCC#+4*GHSERVV#
+18*GSIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,MN:V:V;0) 273.00 +8*GMNFCC#+22*GHSERVV#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:CR:CO;0) 273.00 +8*GHSERNI#+4*GHSERCR#
+18*GCOBCC#-170000; 6000.00 N
REF:pov15 !
PARAMETER G(SIGMA,NI:CR:CR;0) 273.00 +8*GHSERNI#+22*GHSERCR#
+180000-170*T; 6000.00 N
REF:13 !
PARAMETER G(SIGMA,NI:CR:FE;0) 273.00 +8*GHSERNI#+4*GHSERCR#
+18*GHSERFE#-50000+32*T; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,NI:CR:MN;0) 273.00 +8*GHSERNI#+4*GHSERCR#
+18*GMNBCC#; 6000.00 N
REF:13 !
PARAMETER G(SIGMA,NI:CR:MO;0) 273.00 +8*GHSERNI#+4*GHSERCR#
+18*GHSERMO#
+38189-120*T; 6000.00 N
REF:39 !
PARAMETER G(SIGMA,NI:CR:NI;0) 273.00 +8*GHSERNI#+4*GHSERCR#
+18*GNIBCC#+175400; 6000.00 N
REF:13 !
PARAMETER G(SIGMA,NI:CR:V;0) 273.00 +8*GHSERNI#+4*GHSERCR#
+18*GHSERVV#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:MO:CO;0) 273.00 +8*GHSERNI#+4*GHSERMO#
+18*GCOBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:MO:CR;0) 273.00 +8*GHSERNI#+4*GHSERMO#
+18*GHSERCR#+386423; 6000.00 N
REF:39 !
PARAMETER G(SIGMA,NI:MO:FE;0) 273.00 +8*GHSERNI#+18*GHSERFE#+4*GHSERMO#
+658600-200*T; 6000.00 N
REF:41 !
PARAMETER G(SIGMA,NI:MO:MN;0) 273.00 +8*GHSERNI#+4*GHSERMO#
+18*GMNBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:MO:MO;0) 273.00 +8*GHSERNI#+22*GHSERMO#
+85662; 6000.00 N
REF:39 !
PARAMETER G(SIGMA,NI:MO:NI;0) 273.00 +8*GHSERNI#+4*GHSERMO#
+18*GNIBCC#-16385; 6000.00 N
REF:39 !
PARAMETER G(SIGMA,NI:MO:V;0) 273.00 +8*GHSERNI#+4*GHSERMO#
+18*GHSERVV#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:V:CO;0) 273.00 +8*GHSERNI#+4*GHSERVV#
+18*GCOBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:V:CR;0) 273.00 +8*GHSERNI#+4*GHSERVV#
+18*GHSERCR#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:V:FE;0) 273.00 +8*GHSERNI#+4*GHSERVV#
+18*GHSERFE#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:V:MN;0) 273.00 +8*GHSERNI#+4*GHSERVV#
+18*GMNBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:V:MO;0) 273.00 +8*GHSERNI#+4*GHSERVV#
+18*GHSERMO#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:V:NI;0) 273.00 +8*GHSERNI#+4*GHSERVV#
+18*GNIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:V:SI;0) 273.00 +8*GHSERNI#+4*GHSERVV#
+18*GSIBCC#; 6000.00 N
REF:pov10 !
PARAMETER G(SIGMA,NI:V:V;0) 273.00 +8*GHSERNI#+4*GHSERVV#
+18*GHSERVV#; 6000.00 N
REF:pov10 !
$ The following endmember parameters are preliminary!!
PARAMETER G(SIGMA,FE:CR:SI;0) 273.00 +8*GFEFCC#+4*GHSERCR#
+18*GSIBCC#-1300000+300*T; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,FE:MO:SI;0) 273.00 +8*GFEFCC#+4*GHSERMO#+18*GSIBCC#
-1300000+300*T; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,MN:CR:SI;0) 273.00 +8*GMNFCC#+4*GHSERCR#+18*GSIBCC#
-1300000+300*T; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,MN:MO:SI;0) 273.00 +8*GMNFCC#+4*GHSERMO#+18*GSIBCC#
-1300000+300*T; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,NI:CR:SI;0) 273.00 -1300000+300*T+8*GHSERNI#+4*GHSERCR#
+18*GSIBCC#; 6000.00 N
REF:pov13 !
PARAMETER G(SIGMA,NI:MO:SI;0) 273.00 +8*GHSERNI#+4*GHSERMO#+18*GSIBCC#
-1300000+300*T; 6000.00 N
REF:pov13 !
$----------------------Interaction parameters----------------------
PARAMETER L(SIGMA,CO:MO:CO,MO;0) 273.00 -157492.37; 6000.00 N
REF:77 !
PARAMETER L(SIGMA,CO:V:CO,V;0) 273.00 -368781.96+246.3798*T; 6000.00 N
REF:134 !
PARAMETER L(SIGMA,FE:CR:CR,MO;0) 273.00 -148000; 6000.00 N
REF:111 !
PARAMETER L(SIGMA,FE:CR:CR,NI;0) 273.00 +1e-8; 6000.00 N
REF:pov12 !
PARAMETER L(SIGMA,FE:CR:FE,NI;0) 273.00 -200000; 6000.00 N
REF:pov13 !
PARAMETER L(SIGMA,FE:CR:CR,SI;0) 273.00 -2115000+155*T; 6000.00 N
REF:43 !
PARAMETER L(SIGMA,FE:CR:FE,SI;0) 273.00 -2015000+155*T; 6000.00 N
REF:43 !
PARAMETER L(SIGMA,FE:CR:CR,MN;0) 273.00 -1095771+862.0312*T; 6000.00 N
REF:111 !
PARAMETER L(SIGMA,FE:CR:FE,MO;0) 273.00 +350000; 6000.00 N
REF:pov12 !
PARAMETER L(SIGMA,FE:CR:FE,V;0) 273.00 -235158; 6000.00 N
REF:68 !
PARAMETER L(SIGMA,FE:MO:CR,FE;0) 273.00 +1e-8; 6000.00 N
REF:pov13 !
PARAMETER L(SIGMA,FE:MO:CR,MO;0) 273.00 +121000; 6000.00 N
REF:111 !
PARAMETER L(SIGMA,FE:MO:FE,MO;0) 273.00 +222909; 6000.00 N
REF:27 !
PARAMETER L(SIGMA,FE,MN:MO:FE;0) 273.00 +150000; 6000.00 N
REF:pov13 !
PARAMETER L(SIGMA,FE,MN:MO:MO;0) 273.00 +150000; 6000.00 N
REF:pov13 !
PARAMETER L(SIGMA,FE,NI:MO:MO;0) 273.00 -164570-10*T; 6000.00 N
REF:41 !
PARAMETER L(SIGMA,FE:V:FE,V;0) 273.00 -305784; 6000.00 N
REF:68 !
PARAMETER L(SIGMA,MN:CR:CR,MN;0) 273.00 -1095771+862.0312*T; 6000.00 N
REF:62 !
PARAMETER L(SIGMA,MN:MO:MN,MO;0) 273.00 -400000; 6000.00 N
REF:pov13 !
$ Note: the following interaction parameters are preliminary!!
PARAMETER L(SIGMA,NI:CR:FE,MO;0) 273.00 -800000+100*T; 6000.00 N
REF:pov15 !
PARAMETER L(SIGMA,NI:CR,MO:FE;0) 273.00 -800000+100*T; 6000.00 N
REF:pov15 !
PARAMETER L(SIGMA,FE,NI:CR:SI;0) 273.00 -1300000+300*T; 6000.00 N
REF:pov13 !
PARAMETER L(SIGMA,FE,NI:CR:SI;1) 273.00 -1300000+300*T; 6000.00 N
REF:pov13 !
PARAMETER L(SIGMA,FE,NI:CR:SI;2) 273.00 -1300000+300*T; 6000.00 N
REF:pov13 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: FE17Y2
$###########################################################################
$
PHASE FE17Y2 % 2 0.895 0.105 > >> 1 !
CONSTITUENT FE17Y2 : FE : Y : !
PARAMETER G(FE17Y2,FE:Y;0) 273.00 +0.895*GHSERFE#+0.105*GHSERYY#
-13698+1.9165*T; 6000.00 N
REF:239 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NI5Y
$###########################################################################
$
PHASE NI5Y % 2 5 1 > >> 1 !
CONSTITUENT NI5Y :NI : Y : !
PARAMETER G(NI5Y,NI:Y;0) 273.00 +5*GHSERNI#+GHSERYY#
-186706+31.187*T; 6000.00 N
REF:213 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: ORDERED PD-FE-MN phases
$###########################################################################
$
TYPE_DEFINITION " GES A_P_D PDFE_L12 MAGNETIC -3.0 0.28 !
PHASE PDFE_L12 %" 2 0.25 0.75 > ferromagnetic fcc-based
L12-ordered Pd3X phase >> 2 !
CONSTITUENT PDFE_L12 : FE%,MN,PD : FE,MN,PD% : !
PARAMETER G(PDFE_L12,FE:FE;0) 273.00 +GFEFCC#+100; 6000.00 N
REF:pov14 !
PARAMETER G(PDFE_L12,FE:MN;0) 273.00 +0.25*GHSERFE#+0.75*GHSERMN; 6000.00 N
REF:pov14 !
PARAMETER G(PDFE_L12,MN:FE;0) 273.00 +0.25*GHSERMN#+0.75*GHSERFE; 6000.00 N
REF:pov14 !
PARAMETER G(PDFE_L12,MN:MN;0) 273.00 +GMNFCC#+100; 6000.00 N
REF:pov14 !
PARAMETER G(PDFE_L12,FE:PD;0) 273.00 +0.25*GHSERFE#+0.75*GHSERPD
-15600-2*T; 6000.00 N
REF:pov14 !
PARAMETER G(PDFE_L12,PD:FE;0) 273.00 +0.75*GHSERFE#+0.25*GHSERPD
+15600+2*T; 6000.00 N
REF:pov14 !
PARAMETER G(PDFE_L12,MN:PD;0) 273.00 +0.25*GHSERMN+0.75*GHSERPD
-35000+16*T; 6000.00 N
REF:pov14 !
PARAMETER G(PDFE_L12,PD:MN;0) 273.00 +0.25*GHSERPD+0.75*GHSERMN
+35000-16*T; 6000.00 N
REF:pov14 !
PARAMETER G(PDFE_L12,PD:PD;0) 273.00 +GHSERPD+100; 6000.00 N
REF:pov14 !
PARAMETER L(PDFE_L12,FE:FE,PD;0) 273.00 +15250; 6000.00 N
REF:pov14 !
PARAMETER L(PDFE_L12,FE:FE,PD;1) 273.00 +40000; 6000.00 N
REF:pov14 !
PARAMETER L(PDFE_L12,FE,PD:PD;0) 273.00 -7500+6*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDFE_L12,MN,PD:PD;0) 273.00 -5000; 6000.00 N
REF:pov14 !
PARAMETER L(PDFE_L12,MN,PD:PD;1) 273.00 -10000; 6000.00 N
REF:pov14 !
PARAMETER L(PDFE_L12,FE:MN,PD;0) 273.00 -20000; 6000.00 N
REF:pov14 !
PARAMETER TC(PDFE_L12,FE:FE;0) 273.00 +67; 6000.00 N
REF:242 !
PARAMETER BMAGN(PDFE_L12,FE:FE;0) 273.00 +0.7; 6000.00 N
REF:242 !
PARAMETER TC(PDFE_L12,FE:PD;0) 273.00 +520; 6000.00 N
REF:pov14 !
PARAMETER TC(PDFE_L12,PD:FE;0) 273.00 +520; 6000.00 N
REF:pov14 !
PARAMETER BMAGN(PDFE_L12,FE:PD;0) 273.00 +0.7; 6000.00 N
REF:pov14 !
PARAMETER BMAGN(PDFE_L12,PD:FE;0) 273.00 +0.7; 6000.00 N
REF:pov14 !
$
PHASE PDMN_AF % 2 0.5 0.5 > antiferromagnetic fcc-based
L10-ordered PdX phase >> 2 !
CONSTITUENT PDMN_AF : MN%,PD : MN,PD% : !
PARAMETER G(PDMN_AF,MN:PD;0) 273.00 +0.5*GHSERMN+0.5*GHSERPD
-44000+25*T; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_AF,MN:MN;0) 273.00 +0.5*GHSERMN+0.5*GHSERMN
+20000; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_AF,PD:MN;0) 273.00 +0.5*GHSERMN+0.5*GHSERPD
-44000+25*T; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_AF,PD:PD;0) 273.00 +2000+GHSERPD; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_AF,MN,PD:PD;0) 273.00 -40000+25*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_AF,MN,PD:PD;1) 273.00 -30000-50*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_AF,PD:MN,PD;0) 273.00 +65000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_AF,PD:MN,PD;1) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_AF,MN:MN,PD;0) 273.00 -30000-20*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_AF,MN:MN,PD;2) 273.00 +23000-100*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_AF,MN,PD:MN;0) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_AF,MN,PD:MN;2) 273.00 +1e-8; 6000.00 N
REF:pov14 !
$
TYPE_DEFINITION B GES A_P_D PDMN_P MAGNETIC -3.0 0.28 !
PHASE PDMN_P %B 2 0.5 0.5 > paramagnetic fcc-based
L10-ordered PdX phase >> 2 !
CONSTITUENT PDMN_P : FE,MN%,PD : FE,MN,PD% : !
PARAMETER G(PDMN_P,MN:PD;0) 273.00 +0.5*GHSERMN+0.5*GHSERPD
-40000+20*T; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_P,MN:MN;0) 273.00 +0.5*GHSERMN+0.5*GHSERMN
+20000; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_P,PD:MN;0) 273.00 +0.5*GHSERMN+0.5*GHSERPD
-40000+20*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,MN,PD:PD;0) 273.00 -40000+25*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,MN,PD:PD;1) 273.00 -30000-50*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,PD:MN,PD;0) 273.00 +65000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,PD:MN,PD;1) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,MN:MN,PD;0) 273.00 -30000-20*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,MN,PD:MN;0) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,MN:MN,PD;2) 273.00 +23000-100*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,MN,PD:MN;2) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_P,FE:FE;0) 273.00 +10000+GHSERFE; 6000.00 N
REF:242 !
PARAMETER G(PDMN_P,FE:PD;0) 273.00 +0.5*GHSERFE+0.5*GHSERPD
-14000+3*T; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_P,PD:FE;0) 273.00 +0.5*GHSERFE+0.5*GHSERPD
-14000+3*T; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_P,PD:PD;0) 273.00 +2000+GHSERPD; 6000.00 N
REF:242 !
PARAMETER L(PDMN_P,FE:FE,PD;0) 273.00 +3000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,FE,PD:FE;0) 273.00 +3000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,FE:FE,PD;1) 273.00 +15000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,FE,PD:FE;1) 273.00 +15000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,PD:FE,PD;0) 273.00 -31500; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,FE,PD:PD;0) 273.00 -31500; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,PD:FE,PD;1) 273.00 -30000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,FE,PD:PD;1) 273.00 -30000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,PD:FE,PD;2) 273.00 -17500; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,FE,PD:PD;2) 273.00 -17500; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,FE,PD:MN;0) 273.00 -105000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,FE,PD:MN;1) 273.00 +250000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,FE,PD:MN;2) 273.00 -200000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,MN:FE,PD;0) 273.00 -105000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,MN:FE,PD;1) 273.00 +260000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_P,MN:FE,PD;2) 273.00 -200000; 6000.00 N
REF:pov14 !
PARAMETER TC(PDMN_P,FE:FE;0) 273.00 +67; 6000.00 N
REF:242 !
PARAMETER BMAGN(PDMN_P,FE:FE;0) 273.00 +0.7; 6000.00 N
REF:242 !
PARAMETER TC(PDMN_P,FE:PD;0) 273.00 +1760; 6000.00 N
REF:pov14 !
PARAMETER TC(PDMN_P,PD:FE;0) 273.00 +1760; 6000.00 N
REF:pov14 !
PARAMETER TC(PDMN_P,PD:FE,PD;0) 273.00 -2900; 6000.00 N
REF:pov14 !
PARAMETER TC(PDMN_P,FE,PD:PD;0) 273.00 -2900; 6000.00 N
REF:pov14 !
PARAMETER TC(PDMN_P,PD:FE,PD;1) 273.00 -2900; 6000.00 N
REF:pov14 !
PARAMETER TC(PDMN_P,FE,PD:PD;1) 273.00 -2900; 6000.00 N
REF:pov14 !
PARAMETER BMAGN(PDMN_P,FE:PD;0) 273.00 +0.25; 6000.00 N
REF:pov14 !
PARAMETER BMAGN(PDMN_P,PD:FE;0) 273.00 +0.25; 6000.00 N
REF:pov14 !
$
PHASE PDMN_B2 % 2 0.5 0.5 > paramagnetic bcc-based
B2-ordered PdX phase >> 2 !
CONSTITUENT PDMN_B2 : FE,MN,PD% : FE,MN%,PD : !
PARAMETER G(PDMN_B2,MN:MN;0) 273.00 +0.5*GHSERMN+0.5*GHSERMN
+20000; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_B2,PD:PD;0) 273.00 +0.5*GHSERPD+0.5*GHSERPD
+20000; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_B2,MN:PD;0) 273.00 273 +46000-23*T
+0.05*T**(+2)-1e-05*T**(+3)+1000000*T**(-1)+0.5*GHSERMN#
-5*T*LN(T)+0.5*GHSERPD#; 6000 N ; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_B2,PD:MN;0) 273.00 273 +46000-23*T
+0.05*T**(+2)-1e-05*T**(+3)+1000000*T**(-1)
-5*T*LN(T)+0.5*GHSERMN#+0.5*GHSERPD#; 6000 N ; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_B2,FE:FE;0) 273.00 +20000+GHSERFE; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_B2,FE:PD;0) 273.00 +0.5*GHSERFE+0.5*GHSERPD
-10000; 6000.00 N
REF:pov14 !
PARAMETER G(PDMN_B2,PD:FE;0) 273.00 +0.5*GHSERFE+0.5*GHSERPD
-10000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,MN,PD:MN;0) 273.00 -86000-9.5*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,MN:MN,PD;0) 273.00 -86000-9.5*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,MN,PD:MN;1) 273.00 -22500+12*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,MN:MN,PD;1) 273.00 -22500+12*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,MN,PD:MN;2) 273.00 +150000-25*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,MN:MN,PD;2) 273.00 +150000-25*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,PD:MN,PD;0) 273.00 -115000+10*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,MN,PD:PD;0) 273.00 -115000+10*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,PD:MN,PD;1) 273.00 -60000+30*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,MN,PD:PD;1) 273.00 -60000+30*T; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,FE,PD:MN;0) 273.00 -140000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,FE,PD:MN;1) 273.00 +140000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,MN:FE,PD;0) 273.00 -140000; 6000.00 N
REF:pov14 !
PARAMETER L(PDMN_B2,MN:FE,PD;1) 273.00 +140000; 6000.00 N
REF:pov14 !
$
PHASE PD2MN % 2 0.3333 0.6667 > orthorhombic >> 1 !
CONSTITUENT PD2MN : MN : PD : !
PARAMETER G(PD2MN,MN:PD;0) 273.00 +0.3333*GHSERMN+0.6667*GHSERPD
-40500+14.5*T; 6000.00 N
REF:pov14 !
$
PHASE PD3MN % 2 0.25 0.75 > D023-ordered fcc-type >> 1 !
CONSTITUENT PD3MN : MN%,PD : MN,PD% : !
PARAMETER G(PD3MN,MN:MN;0) 273.00 +GMNFCC#+3000; 6000.00 N
REF:pov14 !
PARAMETER G(PD3MN,MN:PD;0) 273.00 +0.25*GHSERMN#+0.75*GHSERPD#
-37000+17*T; 6000.00 N
REF:pov14 !
PARAMETER G(PD3MN,PD:MN;0) 273.00 +0.25*GHSERPD#+0.75*GHSERMN#
+37000-17*T; 6000.00 N
REF:pov14 !
PARAMETER G(PD3MN,PD:PD;0) 273.00 +GHSERPD#+3000; 6000.00 N
REF:pov14 !
PARAMETER L(PD3MN,MN:MN,PD;0) 273.00 -25000; 6000.00 N
REF:pov14 !
PARAMETER L(PD3MN,MN:MN,PD;1) 273.00 +50000; 6000.00 N
REF:pov14 !
PARAMETER L(PD3MN,MN,PD:PD;2) 273.00 +1e-8; 6000.00 N
REF:pov14 !
$
PHASE PD5MN3 % 2 0.375 0.625 > orthorhombic >> 1 !
CONSTITUENT PD5MN3 : MN : PD : !
PARAMETER G(PD5MN3,MN:PD;0) 273.00 +0.375*GHSERMN#+0.625*GHSERPD#
-42650+15.35*T; 6000.00 N
REF:pov14 !
$
$ Next phase description is preliminary!!
PHASE PD6FE5MN2 % 3 0.3846 0.46154 0.15385 > observed in high-Pd
Fe-Pd with Mn.
>> 2 !
CONSTITUENT PD6FE5MN2 : FE : PD : MN : !
PARAMETER G(PD6FE5MN2,FE:PD:MN;0) 273.00 -35000+0.3846*GHSERFE#
+0.46154*GHSERPD#+0.15385*GHSERMN#; 6000.00 N
REF:pov14 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: CEMENTITE
$###########################################################################
$
TYPE_DEFINITION M GES A_P_D CEMENTITE MAGNETIC -3.0 0.28 !
PHASE CEMENTITE %M 2 3 1 >
(Fe,M)C3; orthorhombic. Unit cell consists of four formula units.
In particular Cr and Mn can dissolve into cementite
in large quantities. W, V, Mo with limited solubilities.
>> 5 !
CONSTITUENT CEMENTITE : AL,CO,CR,CU,FE%,MN,MO,NB,NI,SI,V,W :
B,C%,N : !
PARAMETER G(CEMENTITE,AL:B;0) 273.00 +3*GHSERAL#+GHSERBB#
+250000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,CO:B;0) 273.00 +10000+3*GHSERCO#
+GHSERBB#; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,CR:B;0) 273.00 +3*GHSERCR#+GHSERBB#
+10000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,CU:B;0) 273.00 +3*GHSERCU#+GHSERBB#
+80000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,FE:B;0) 273.00 -70000+8*T+3*GHSERFE#
+GHSERBB#; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,MN:B;0) 273.00 +10000+3*GHSERMN#
+GHSERBB#; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,MO:B;0) 273.00 +3*GHSERMO#+GHSERBB#
+10000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,NB:B;0) 273.00 +3*GHSERNB#+GHSERBB#
+10000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,NI:B;0) 273.00 +3*GHSERNI#+1*GHSERBB#-95722.9
+21.72115*T; 6000.00 N
REF:161 !
PARAMETER G(CEMENTITE,SI:B;0) 273.00 +3*GHSERSI#+GHSERBB#+250000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,V:B;0) 273.00 +3*GHSERVV#+GHSERBB#+10000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,W:B;0) 273.00 +54150+3*GHSERWW#+GHSERBB#; 6000.00 N
REF:pov14 !
$
PARAMETER G(CEMENTITE,AL:C;0) 273.00 +3*GHSERAL#+GHSERCC#+250000; 6000.00 N
REF:koze !
PARAMETER G(CEMENTITE,CO:C;0) 273.00 -1567+3.963*T+3*GHSERCO#
+GHSERCC#; 6000.00 N
REF:75 !
PARAMETER G(CEMENTITE,CR:C;0) 273.00 +3*GHSERCR#+GHSERCC#
-48000-9.2888*T; 6000.00 N
REF:11 !
PARAMETER G(CEMENTITE,CU:C;0) 273.00 +3*GHSERCU#+GHSERCC#+80000; 6000.00 N
REF:12 !
PARAMETER G(CEMENTITE,FE:C;0) 273.00 +GFECEM#; 6000.00 N
REF:11 !
PARAMETER G(CEMENTITE,MN:C;0) 273.00 -39644+3.04*T+3*GHSERMN#
+GHSERCC#; 6000.00 N
REF:255 !
PARAMETER G(CEMENTITE,MO:C;0) 273.00 +3*GHSERMO#+GHSERCC#
+77000-57.4*T; 6000.00 N
REF:51 !
PARAMETER G(CEMENTITE,NB:C;0) 273.00 +3*GHSERNB#+GHSERCC#-86000; 6000.00 N
REF:19 !
PARAMETER G(CEMENTITE,NI:C;0) 273.00 +3*GHSERNI#+GHSERCC#
+34700-20*T; 6000.00 N
REF:11 !
PARAMETER G(CEMENTITE,SI:C;0) 273.00 +3*GHSERSI#+GHSERCC#+250000; 6000.00 N
REF:35 !
PARAMETER G(CEMENTITE,V:C;0) 273.00 -156971+601.922*T-100.438*T*LN(T)
+765557*T**(-1); 6000.00 N
REF:15 !
PARAMETER G(CEMENTITE,W:C;0) 273.00 +54150+3*GHSERWW#+GHSERCC#; 6000.00 N
REF:20 !
$
PARAMETER G(CEMENTITE,AL:N;0) 273.00 +3*GHSERAL#+GHSERNN#
+250000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,CO:N;0) 273.00 +10000+3*GHSERCO#
+GHSERNN#; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,CR:N;0) 273.00 +3*GHSERCR#+GHSERNN#
+10000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,CU:N;0) 273.00 +3*GHSERCU#+GHSERNN#
+80000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,FE:N;0) 273.00 -9230+99.334*T+3*GHSERFE#
+GHSERNN#; 6000.00 N
REF:26 !
PARAMETER G(CEMENTITE,MN:N;0) 273.00 +10000+3*GHSERMN#
+GHSERNN#; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,MO:N;0) 273.00 +3*GHSERMO#+GHSERNN#
+10000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,NB:N;0) 273.00 +3*GHSERNB#+GHSERNN#
+10000; 6000.00 N
REF:pov14 !
PARAMETER G(CEMENTITE,NI:N;0) 273.00 +3*GHSERNI#+GHSERNN#
+10000; 6000.00 N
REF:pov14 !
$----------------------Interaction parameters----------------------
PARAMETER L(CEMENTITE,CR,FE:C;0) 273.00 +14586-9.18*T; 6000.00 N
REF:khvan14 !
PARAMETER L(CEMENTITE,CR,FE,MO:C;0) 273.00 +1e-8; 6000.00 N
REF:pov11 !
PARAMETER L(CEMENTITE,CR,FE,NI:C;0) 273.00 +60000; 6000.00 N
REF:11 !
PARAMETER L(CEMENTITE,CR,MN:C;0) 273.00 +9000; 6000.00 N
REF:58 !
PARAMETER L(CEMENTITE,CR,MO:C;0) 273.00 +40000; 6000.00 N
REF:51 !
PARAMETER L(CEMENTITE,CR,NI:C;0) 273.00 +27898; 6000.00 N
REF:11 !
PARAMETER L(CEMENTITE,CR,V:C;0) 273.00 -29622-8.0892*T; 6000.00 N
REF:52 !
PARAMETER L(CEMENTITE,CR,V:C;1) 273.00 -5160-7.5711*T; 6000.00 N
REF:52 !
PARAMETER L(CEMENTITE,FE,MN:C;0) 273.00 -7715+1.3687*T; 6000.00 N
REF:255 !
PARAMETER L(CEMENTITE,FE,MO:C;0) 273.00 +1E-8; 6000.00 N
REF:12 !
PARAMETER L(CEMENTITE,FE,NB:C;0) 273.00 +1E-8; 6000.00 N
REF:12 !
PARAMETER L(CEMENTITE,FE,NI:C;0) 273.00 +29400; 6000.00 N
REF:31 !
PARAMETER L(CEMENTITE,FE,NI:B;0) 273.00 -23400; 6000.00 N
REF:192 !
PARAMETER L(CEMENTITE,FE,SI:C;0) 273.00 +1E-8; 6000.00 N
REF:24 !
PARAMETER L(CEMENTITE,FE,V:C;0) 273.00 -45873-12.414*T; 6000.00 N
REF:15 !
$
PARAMETER L(CEMENTITE,FE:B,C;0) 273.00 +10000-20*T; 6000.00 N
REF:pov14 !
$
$******************** magnetic contributions ***************************
$
PARAMETER TC(CEMENTITE,FE:C;0) 273.00 +485; 6000.00 N
REF:156 !
PARAMETER BMAGN(CEMENTITE,FE:C;0) 273.00 +1.008; 6000.00 N
REF:156 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: CR2VC2
$###########################################################################
$
PHASE CR2VC2 % 3 2 1 2 > >> 1 !
CONSTITUENT CR2VC2 : CR : V : C : !
PARAMETER G(CR2VC2,CR:V:C;0) 273.00 +2*GHSERCR#+GHSERVV#+2*GHSERCC#
-105987-38.2069*T; 6000.00 N
REF:68 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: K_CARB
$###########################################################################
$
PHASE K_CARB % 3 3 1 1 >
cubic L12-type kappa-carbide, observed in high-Al steel >> 3 !
CONSTITUENT K_CARB : FE,MN : AL : C,VA : !
PARAMETER G(K_CARB,FE:AL:C;0) 273.00 +3*GFEFCC#+GHSERAL#+GHSERCC#
-115000+25.2*T; 6000.00 N
REF:155 !
PARAMETER G(K_CARB,MN:AL:C;0) 273.00 +3*GMNFCC#+GHSERAL#+GHSERCC#
-135000+30*T; 6000.00 N
REF:pov13 !
PARAMETER G(K_CARB,FE:AL:VA;0) 273.00 +3*GFEFCC#+GHSERAL#
-94000+17.6*T; 6000.00 N
REF:155 !
PARAMETER G(K_CARB,MN:AL:VA;0) 273.00 +3*GFEFCC#+GHSERAL#; 6000.00 N
REF:155 !
PARAMETER G(K_CARB,FE:AL:C,VA;0) 273.00 +13752-24*T; 6000.00 N
REF:155 !
PARAMETER G(K_CARB,FE,MN:AL:C;0) 273.00 +5000; 6000.00 N
REF:pov13 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: KSI_CARBIDE
$###########################################################################
$
PHASE KSI_CARBIDE % 2 3 1 >
Mo-Cr-Fe carbide.
>> 2 !
CONSTITUENT KSI_CARBIDE :AL,CO,CR,CU,FE,MN,MO%,NB,NI,SI,TI,
V,W : C,VA% : !
PARAMETER G(KSI_CARBIDE,CR:C;0) 273.00 +3*GHSERCR#+GHSERCC#
+114060-47.2519*T; 6000.00 N
REF:61 !
PARAMETER G(KSI_CARBIDE,FE:C;0) 273.00 +3*GHSERFE#+GHSERCC#
+14540+20*T; 6000.00 N
REF:63 !
PARAMETER G(KSI_CARBIDE,MO:C;0) 273.00 +3*GHSERMO#+GHSERCC#
+167009-33*T; 6000.00 N
REF:63 !
PARAMETER L(KSI_CARBIDE,CR,FE:C;0) 273.00 -139900; 6000.00 N
REF:61 !
PARAMETER L(KSI_CARBIDE,CR,MO:C;0) 273.00 -348033; 6000.00 N
REF:61 !
PARAMETER L(KSI_CARBIDE,FE,MO:C;0) 273.00 -380000; 6000.00 N
REF:63 !
$
PARAMETER G(KSI_CARBIDE,AL:C;0) 273.00 +3*GHSERAL#+GHSERCC#
+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,CO:C;0) 273.00 +3*GHSERCO#+GHSERCC#
+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,CU:C;0) 273.00 +3*GHSERCU#+GHSERCC#
+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,MN:C;0) 273.00 +3*GHSERMN#+GHSERCC#
+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,NB:C;0) 273.00 +3*GHSERNB#+GHSERCC#
+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,NI:C;0) 273.00 +3*GHSERNI#+GHSERCC#
+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,SI:C;0) 273.00 +3*GHSERSI#+GHSERCC#
+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,TI:C;0) 273.00 +3*GHSERTI#+GHSERCC#
+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,V:C;0) 273.00 +3*GHSERVV#+GHSERCC#
+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,W:C;0) 273.00 +3*GHSERWW#+GHSERCC#
+300000; 6000.00 N
REF:pov14 !
$
PARAMETER G(KSI_CARBIDE,AL:VA;0) 273.00 +3*GHSERAL#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,CO:VA;0) 273.00 +3*GHSERCO#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,CR:VA;0) 273.00 +3*GHSERCR#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,CU:VA;0) 273.00 +3*GHSERCU#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,FE:VA;0) 273.00 +3*GHSERFE#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,MN:VA;0) 273.00 +3*GHSERMN#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,MO:VA;0) 273.00 +3*GHSERMO#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,NB:VA;0) 273.00 +3*GHSERNB#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,NI:VA;0) 273.00 +3*GHSERNI#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,SI:VA;0) 273.00 +3*GHSERSI#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,TI:VA;0) 273.00 +3*GHSERTI#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,V:VA;0) 273.00 +3*GHSERVV#+300000; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_CARBIDE,W:VA;0) 273.00 +3*GHSERWW#+300000; 6000.00 N
REF:pov14 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: M3C2
$###########################################################################
$
PHASE M3C2 % 2 3 2 >
Cr-rich carbide.
>> 1 !
CONSTITUENT M3C2 : CR,MO,V : C : !
PARAMETER G(M3C2,CR:C;0) 273.00 +GCRM3C2#; 6000.00 N
REF:68 !
PARAMETER G(M3C2,MO:C;0) 273.00 +3*GHSERMO#+2*GHSERCC#
+27183; 6000.00 N
REF:61 !
PARAMETER G(M3C2,V:C;0) 273.00 -222500+16.6545*T+3*GHSERVV#
+2*GHSERCC#; 6000.00 N
REF:68 !
PARAMETER L(M3C2,CR,MO:C;0) 273.00 +40000; 6000.00 N
REF:61 !
PARAMETER L(M3C2,CR,V:C;0) 273.00 +21072; 6000.00 N
REF:68 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: M6C
$###########################################################################
$
PHASE M6C % 4 3 2 1 1 >
Mo,W-rich carbide, can contain significant amounts
of Cr and V. Equilibrium phase in steels with
relatively low Cr contents. Has a large unit cell.
Precipitation predominantly on grain boundaries,
also on lath boundaries and prior austenite grain boundaries.
M6C#01 is Si-rich nitride Cr3Ni2SiN. Precipitates in some
Si- and N-containing stainless steels
after long-term aging.
>> 5 !
CONSTITUENT M6C : CO,CR,FE%,MO,V,W : CO,CR,FE,MO,NI,SI,V,W :
CO,FE,MO,NI,SI,V,W : C%,N : !
PARAMETER G(M6C,CR:CR:CO:C;0) 273.00 +5*GHSERCR#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:CO:C;0) 273.00 +3*GHSERCO#
+2*GHSERCR#+GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:CO:C;0) 273.00 +3*GHSERCR#
+2*GHSERCO#+GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:FE:C;0) 273.00 +3*GHSERCO#
+2*GHSERFE#+GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:FE:C;0) 273.00 +4*GHSERFE#
+2*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:CO:C;0) 273.00 +5*GHSERFE#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:FE:C;0) 273.00 +5*GHSERCO#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:CO:C;0) 273.00 +3*GHSERCO#
+2*GHSERFE#+GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:CO:C;0) 273.00 +3*GHSERFE#
+2*GHSERCO#+GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:CO:C;0) 273.00 -30000+3*GHSERMO#
+2*GHSERCO#+GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:CO:C;0) 273.00 -30000+4*GHSERCO#
+2*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:MO:C;0) 273.00 -30000+5*GHSERCO#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:CO:C;0) 273.00 -30000+5*GHSERMO#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:MO:C;0) 273.00 -100000+3*GHSERMO#
+2*GHSERCO#+GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:MO:C;0) 273.00 -30000+3*GHSERCO#
+2*GHSERMO#+GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:CO:C;0) 273.00 +4*GHSERCO#
+2*GHSERNI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:V:CO:C;0) 273.00 +5*GHSERVV#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:CO:C;0) 273.00 +3*GHSERCO#
+2*GHSERVV#+GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:CO:C;0) 273.00 +3*GHSERVV#
+2*GHSERCO#+GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:CO:C;0) 273.00 +6*GHSERCO#
+GHSERCC#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:W:C;0) 273.00 +6*GHSERWW#
+GHSERCC#+7500; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:CO:C;0) 273.00 +35000+3*GHSERWW#+2*GHSERCO#
+GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:CO:C;0) 273.00 +35000+4*GHSERCO#
+2*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:W:C;0) 273.00 +35000+5*GHSERCO#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:CO:C;0) 273.00 +35000+5*GHSERWW#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:W:C;0) 273.00 +35000+3*GHSERWW#
+2*GHSERCO#+GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:W:C;0) 273.00 -73000+3*GHSERCO#
+2*GHSERWW#+GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CR:FE:C;0) 273.00 +5*GHSERCR#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:FE:C;0) 273.00 +3*GHSERFE#
+2*GHSERCR#+GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:FE:FE:C;0) 273.00 +3*GHSERCR#
+2*GHSERFE#+GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CR:MO:C;0) 273.00 +5*GHSERCR#
+1*GHSERMO#+GHSERCC#-40000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CR:MO:C;0) 273.00 +3*GHSERMO#
+2*GHSERCR#+GHSERMO#+GHSERCC#-40000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:MO:C;0) 273.00 +3*GHSERCR#
+2*GHSERMO#+GHSERMO#+GHSERCC#-40000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CR:W:C;0) 273.00 +5*GHSERCR#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:W:C;0) 273.00 +3*GHSERWW#
+2*GHSERCR#+GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:W:C;0) 273.00 +3*GHSERCR#
+2*GHSERWW#+GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:MO:C;0) 273.00 +6*GHSERMO#
+GHSERCC#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:FE:FE:C;0) 273.00 -60000+25*T+3*GHSERMO#
+2*GHSERFE#+GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:FE:C;0) 273.00 -60000+25*T+4*GHSERFE#
+2*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:MO:C;0) 273.00 +90000-75*T+5*GHSERFE#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:FE:C;0) 273.00 -60000+25*T+5*GHSERMO#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:FE:MO:C;0) 273.00 -40000-40*T+3*GHSERMO#
+2*GHSERFE#+GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:MO:C;0) 273.00 -120000+40*T+3*GHSERFE#
+2*GHSERMO#+GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:FE:C;0) 273.00 +4*GHSERFE#
+2*GHSERNI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:V:FE:C;0) 273.00 +5*GHSERVV#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:FE:C;0) 273.00 +3*GHSERFE#
+2*GHSERVV#+GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:FE:FE:C;0) 273.00 +3*GHSERVV#
+2*GHSERFE#+GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:FE:C;0) 273.00 +6*GHSERFE#
+GHSERCC#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:FE:C;0) 273.00 +35000+3*GHSERWW#+2*GHSERFE#+GHSERFE#
+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:FE:C;0) 273.00 +35000+4*GHSERFE#
+2*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:W:C;0) 273.00 +5*GHSERFE#
+1*GHSERWW#+GHSERCC#-35000+15*T; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:FE:C;0) 273.00 +5*GHSERWW#
+1*GHSERFE#+GHSERCC#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:W:C;0) 273.00 +3*GHSERWW#
+2*GHSERFE#+GHSERWW#+GHSERCC#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:W:C;0) 273.00 -80000+20*T+3*GHSERFE#
+2*GHSERWW#+GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:NI:MO:C;0) 273.00 -65000+10*T+3*GHSERMO#
+2*GHSERNI#+GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:V:MO:C;0) 273.00 +5*GHSERVV#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:MO:C;0) 273.00 +3*GHSERMO#
+2*GHSERVV#+GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:MO:C;0) 273.00 +3*GHSERVV#
+2*GHSERMO#+GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:W:C;0) 273.00 +3*GHSERMO#
+2*GHSERWW#+GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:W:C;0) 273.00 +4*GHSERWW#
+2*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:MO:C;0) 273.00 +5*GHSERWW#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:W:C;0) 273.00 +5*GHSERMO#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:MO:C;0) 273.00 +3*GHSERMO#
+2*GHSERWW#+GHSERMO#+GHSERCC#-10000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:MO:C;0) 273.00 +3*GHSERWW#
+2*GHSERMO#+GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:W:C;0) 273.00 +35000+3*GHSERWW#
+2*GHSERNI#+GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:V:W:C;0) 273.00 +5*GHSERVV#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:W:C;0) 273.00 +3*GHSERWW#
+2*GHSERVV#+GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:W:C;0) 273.00 +3*GHSERVV#
+2*GHSERWW#+GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:CO:C;0) 273.00 +3*GHSERFE#+2*GHSERCR#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:FE:C;0) 273.00 +3*GHSERCO#+2*GHSERCR#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:FE:C;0) 273.00 +3*GHSERCR#+2*GHSERCO#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:FE:CO:C;0) 273.00 +3*GHSERCR#+2*GHSERFE#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CR:CO:C;0) 273.00 +3*GHSERMO#+2*GHSERCR#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:MO:C;0) 273.00 +3*GHSERCO#+2*GHSERCR#
+1*GHSERMO#+GHSERCC#-75000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:MO:C;0) 273.00 +3*GHSERCR#+2*GHSERCO#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:CO:C;0) 273.00 +3*GHSERCR#+2*GHSERMO#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:NI:CO:C;0) 273.00 +3*GHSERCR#+2*GHSERNI#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:CO:C;0) 273.00 +3*GHSERVV#+2*GHSERCR#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:CO:C;0) 273.00 +3*GHSERCR#+2*GHSERVV#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:CO:C;0) 273.00 +3*GHSERWW#+2*GHSERCR#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:W:C;0) 273.00 +3*GHSERCO#+2*GHSERCR#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:W:C;0) 273.00 +3*GHSERCR#+2*GHSERCO#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:CO:C;0) 273.00 +3*GHSERCR#+2*GHSERWW#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:MO:C;0) 273.00 +3*GHSERFE#+2*GHSERCO#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:CO:C;0) 273.00 +3*GHSERFE#+2*GHSERMO#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:FE:C;0) 273.00 +3*GHSERCO#+2*GHSERMO#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:MO:C;0) 273.00 +3*GHSERCO#+2*GHSERFE#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:FE:C;0) 273.00 +3*GHSERMO#+2*GHSERCO#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:FE:CO:C;0) 273.00 +3*GHSERMO#+2*GHSERFE#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:CO:C;0) 273.00 +3*GHSERFE#+2*GHSERNI#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:FE:C;0) 273.00 +3*GHSERCO#+2*GHSERNI#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:CO:C;0) 273.00 +3*GHSERFE#+2*GHSERVV#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:FE:C;0) 273.00 +3*GHSERCO#+2*GHSERVV#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:FE:C;0) 273.00 +3*GHSERVV#+2*GHSERCO#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:FE:CO:C;0) 273.00 +3*GHSERVV#+2*GHSERFE#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:W:C;0) 273.00 +3*GHSERFE#+2*GHSERCO#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:CO:C;0) 273.00 +3*GHSERFE#+2*GHSERWW#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:FE:C;0) 273.00 +3*GHSERCO#+2*GHSERWW#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:W:C;0) 273.00 +3*GHSERCO#+2*GHSERFE#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:FE:C;0) 273.00 +3*GHSERWW#+2*GHSERCO#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:CO:C;0) 273.00 +3*GHSERWW#+2*GHSERFE#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:MO:C;0) 273.00 +3*GHSERCO#+2*GHSERNI#
+1*GHSERMO#+GHSERCC#-35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:NI:CO:C;0) 273.00 +3*GHSERMO#+2*GHSERNI#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:MO:C;0) 273.00 +3*GHSERVV#+2*GHSERCO#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:CO:C;0) 273.00 +3*GHSERVV#+2*GHSERMO#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:MO:C;0) 273.00 +3*GHSERCO#+2*GHSERVV#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:CO:C;0) 273.00 +3*GHSERMO#+2*GHSERVV#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:MO:C;0) 273.00 +3*GHSERWW#+2*GHSERCO#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:CO:C;0) 273.00 +3*GHSERWW#+2*GHSERMO#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:W:C;0) 273.00 +3*GHSERCO#+2*GHSERMO#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:MO:C;0) 273.00 +3*GHSERCO#+2*GHSERWW#
+1*GHSERMO#+GHSERCC#-115000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:W:C;0) 273.00 +3*GHSERMO#+2*GHSERCO#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:CO:C;0) 273.00 +3*GHSERMO#+2*GHSERWW#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:CO:C;0) 273.00 +3*GHSERVV#+2*GHSERNI#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:W:C;0) 273.00 +3*GHSERCO#+2*GHSERNI#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:CO:C;0) 273.00 +3*GHSERWW#+2*GHSERNI#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:CO:C;0) 273.00 +3*GHSERWW#+2*GHSERVV#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:W:C;0) 273.00 +3*GHSERCO#+2*GHSERVV#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:W:C;0) 273.00 +3*GHSERVV#+2*GHSERCO#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:CO:C;0) 273.00 +3*GHSERVV#+2*GHSERWW#
+1*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:FE:C;0) 273.00 +3*GHSERCR#+2*GHSERMO#
+1*GHSERFE#+GHSERCC#-100000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:FE:MO:C;0) 273.00 +3*GHSERCR#+2*GHSERFE#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CR:FE:C;0) 273.00 +3*GHSERMO#+2*GHSERCR#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:MO:C;0) 273.00 +3*GHSERFE#+2*GHSERCR#
+1*GHSERMO#+GHSERCC#-30000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:NI:FE:C;0) 273.00 +3*GHSERCR#+2*GHSERNI#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:FE:C;0) 273.00 +3*GHSERCR#+2*GHSERVV#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:FE:C;0) 273.00 +3*GHSERVV#+2*GHSERCR#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:FE:C;0) 273.00 +3*GHSERCR#+2*GHSERWW#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:FE:W:C;0) 273.00 +3*GHSERCR#+2*GHSERFE#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:FE:C;0) 273.00 +3*GHSERWW#+2*GHSERCR#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:W:C;0) 273.00 +3*GHSERFE#+2*GHSERCR#
+1*GHSERWW#+GHSERCC#-65000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:NI:MO:C;0) 273.00 +3*GHSERCR#+2*GHSERNI#
+1*GHSERMO#+GHSERCC#-10000-60*T; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:MO:C;0) 273.00 +3*GHSERCR#+2*GHSERVV#
+1*GHSERMO#+GHSERCC#-140000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:MO:C;0) 273.00 +3*GHSERVV#+2*GHSERCR#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:W:C;0) 273.00 +3*GHSERCR#+2*GHSERMO#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:MO:C;0) 273.00 +3*GHSERCR#+2*GHSERWW#
+1*GHSERMO#+GHSERCC#-100000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CR:W:C;0) 273.00 +3*GHSERMO#+2*GHSERCR#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:MO:C;0) 273.00 +3*GHSERWW#+2*GHSERCR#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:NI:W:C;0) 273.00 +3*GHSERCR#+2*GHSERNI#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:W:C;0) 273.00 +3*GHSERCR#+2*GHSERVV#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:W:C;0) 273.00 +3*GHSERVV#+2*GHSERCR#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:MO:C;0) 273.00 +3*GHSERFE#+2*GHSERNI#
+1*GHSERMO#+GHSERCC#-50000-50*T; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:NI:FE:C;0) 273.00 +3*GHSERMO#+2*GHSERNI#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:MO:C;0) 273.00 +3*GHSERFE#+2*GHSERVV#
+1*GHSERMO#+GHSERCC#-140000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:FE:C;0) 273.00 +3*GHSERMO#+2*GHSERVV#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:FE:C;0) 273.00 +3*GHSERVV#+2*GHSERMO#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:FE:MO:C;0) 273.00 +3*GHSERVV#+2*GHSERFE#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:W:C;0) 273.00 +3*GHSERFE#+2*GHSERMO#
+1*GHSERWW#+GHSERCC#-65000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:MO:C;0) 273.00 +3*GHSERFE#+2*GHSERWW#
+1*GHSERMO#+GHSERCC#-65000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:FE:C;0) 273.00 +3*GHSERMO#+2*GHSERWW#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:FE:W:C;0) 273.00 +3*GHSERMO#+2*GHSERFE#
+1*GHSERWW#+GHSERCC#-65000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:FE:C;0) 273.00 +3*GHSERWW#+2*GHSERMO#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:MO:C;0) 273.00 +3*GHSERWW#+2*GHSERFE#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:FE:C;0) 273.00 +3*GHSERVV#+2*GHSERNI#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:W:C;0) 273.00 +3*GHSERFE#+2*GHSERNI#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:FE:C;0) 273.00 +3*GHSERWW#+2*GHSERNI#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:W:C;0) 273.00 +3*GHSERFE#+2*GHSERVV#
+1*GHSERWW#+GHSERCC#-200000+25*T; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:FE:C;0) 273.00 +3*GHSERWW#+2*GHSERVV#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:FE:C;0) 273.00 +3*GHSERVV#+2*GHSERWW#
+1*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:FE:W:C;0) 273.00 +3*GHSERVV#+2*GHSERFE#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:MO:C;0) 273.00 +3*GHSERVV#+2*GHSERNI#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:NI:W:C;0) 273.00 +3*GHSERMO#+2*GHSERNI#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:MO:C;0) 273.00 +3*GHSERWW#+2*GHSERNI#
+1*GHSERMO#+GHSERCC#-100000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:W:C;0) 273.00 +3*GHSERMO#+2*GHSERVV#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:MO:C;0) 273.00 +3*GHSERWW#+2*GHSERVV#
+1*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:MO:C;0) 273.00 +3*GHSERVV#+2*GHSERWW#
+1*GHSERMO#+GHSERCC#-200000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:W:C;0) 273.00 +3*GHSERVV#+2*GHSERMO#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:W:C;0) 273.00 +3*GHSERVV#+2*GHSERNI#
+1*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
$
$ Si-Parameters
PARAMETER G(M6C,CR:CR:SI:C;0) 273.00 +5*GHSERCR#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:SI:C;0) 273.00 +3*GHSERCO#
+2*GHSERCR#+GHSERSI#+GHSERCC#-150000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:SI:C;0) 273.00 +3*GHSERCR#
+2*GHSERCO#+GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:SI:C;0) 273.00 +5*GHSERFE#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:SI:C;0) 273.00 +3*GHSERCO#
+2*GHSERFE#+GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:SI:C;0) 273.00 +3*GHSERFE#
+2*GHSERCO#+GHSERSI#+GHSERCC#-100000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:SI:C;0) 273.00 +3*GHSERMO#
+2*GHSERCO#+GHSERSI#+GHSERCC#-150000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:SI:C;0) 273.00 +3*GHSERCO#
+2*GHSERMO#+GHSERSI#+GHSERCC#-150000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:SI:C;0) 273.00 +5*GHSERMO#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:SI:C;0) 273.00 -250000+3*GHSERCO#
+2*GHSERNI#+GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:V:SI:C;0) 273.00 +5*GHSERVV#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:SI:C;0) 273.00 +3*GHSERCO#
+2*GHSERVV#+GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:SI:C;0) 273.00 +3*GHSERVV#
+2*GHSERCO#+GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:SI:C;0) 273.00 +5*GHSERCO#
+GHSERSI#+GHSERCC#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:SI:C;0) 273.00 +3*GHSERWW#+2*GHSERCO#+GHSERSI#
+GHSERCC#-50000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:SI:C;0) 273.00 +3*GHSERCO#
+2*GHSERWW#+GHSERSI#+GHSERCC#-25000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:SI:C;0) 273.00 +5*GHSERWW#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:SI:C;0) 273.00 +3*GHSERFE#+2*GHSERCR#
+1*GHSERSI#+GHSERCC#-65000-50*T; 6000.00 N
REF:pov16 !
PARAMETER G(M6C,MO:CR:SI:C;0) 273.00 +3*GHSERMO#+2*GHSERCR#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:SI:C;0) 273.00 +3*GHSERCR#+2*GHSERMO#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:NI:SI:C;0) 273.00 +3*GHSERCR#+2*GHSERNI#
+1*GHSERSI#+GHSERCC#-200000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:SI:C;0) 273.00 +3*GHSERVV#+2*GHSERCR#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:SI:C;0) 273.00 +3*GHSERCR#+2*GHSERVV#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:SI:C;0) 273.00 +3*GHSERWW#+2*GHSERCR#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:SI:C;0) 273.00 +3*GHSERCR#+2*GHSERWW#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:SI:C;0) 273.00 +3*GHSERFE#+2*GHSERMO#
+1*GHSERSI#+GHSERCC#-90000-75*T; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:FE:SI:C;0) 273.00 +3*GHSERMO#+2*GHSERFE#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:SI:C;0) 273.00 +3*GHSERFE#+2*GHSERNI#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:SI:C;0) 273.00 +3*GHSERFE#+2*GHSERVV#
+1*GHSERSI#+GHSERCC#-65000-50*T; 6000.00 N
REF:pov16 !
PARAMETER G(M6C,V:FE:SI:C;0) 273.00 +3*GHSERVV#+2*GHSERFE#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:SI:C;0) 273.00 +3*GHSERFE#+2*GHSERWW#
+1*GHSERSI#+GHSERCC#-200000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:SI:C;0) 273.00 +3*GHSERWW#+2*GHSERFE#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:NI:SI:C;0) 273.00 +3*GHSERMO#+2*GHSERNI#
+1*GHSERSI#+GHSERCC#-250000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:SI:C;0) 273.00 +3*GHSERVV#+2*GHSERMO#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:SI:C;0) 273.00 +3*GHSERMO#+2*GHSERVV#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:SI:C;0) 273.00 +3*GHSERWW#+2*GHSERMO#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:SI:C;0) 273.00 +3*GHSERMO#+2*GHSERWW#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:SI:C;0) 273.00 +3*GHSERVV#+2*GHSERNI#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:SI:C;0) 273.00 +3*GHSERWW#+2*GHSERNI#
+1*GHSERSI#+GHSERCC#-250000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:SI:C;0) 273.00 +3*GHSERWW#+2*GHSERVV#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:SI:C;0) 273.00 +3*GHSERVV#+2*GHSERWW#
+1*GHSERSI#+GHSERCC#; 6000.00 N
REF:pov15 !
$
PARAMETER G(M6C,V:V:V:C;0) 273.00 +6*GHSERVV#
+GHSERCC#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:V:C;0) 273.00 +3*GHSERCO#
+2*GHSERVV#+GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:V:C;0) 273.00 +4*GHSERVV#
+2*GHSERCO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:V:C;0) 273.00 +5*GHSERCO#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CR:V:C;0) 273.00 +5*GHSERCR#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:V:C;0) 273.00 +3*GHSERVV#
+2*GHSERCR#+GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:V:C;0) 273.00 +3*GHSERCR#
+2*GHSERVV#+GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:V:C;0) 273.00 +3*GHSERFE#
+2*GHSERVV#+GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:FE:V:C;0) 273.00 +4*GHSERVV#
+2*GHSERFE#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:V:C;0) 273.00 +5*GHSERFE#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:V:C;0) 273.00 +3*GHSERMO#
+2*GHSERVV#+GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:V:C;0) 273.00 +4*GHSERVV#
+2*GHSERMO#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:V:C;0) 273.00 +5*GHSERMO#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:V:C;0) 273.00 +4*GHSERVV#
+2*GHSERNI#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:V:C;0) 273.00 +3*GHSERWW#
+2*GHSERVV#+GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:V:C;0) 273.00 +4*GHSERVV#
+2*GHSERWW#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:V:C;0) 273.00 +5*GHSERWW#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:V:C;0) 273.00 +3*GHSERCO#+2*GHSERCR#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:V:C;0) 273.00 +3*GHSERCR#+2*GHSERCO#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:V:C;0) 273.00 +3*GHSERFE#+2*GHSERCO#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:V:C;0) 273.00 +3*GHSERCO#+2*GHSERFE#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:V:C;0) 273.00 +3*GHSERCO#+2*GHSERMO#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:V:C;0) 273.00 +3*GHSERMO#+2*GHSERCO#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:V:C;0) 273.00 +3*GHSERCO#+2*GHSERNI#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:V:C;0) 273.00 +3*GHSERWW#+2*GHSERCO#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:V:C;0) 273.00 +3*GHSERCO#+2*GHSERWW#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:FE:V:C;0) 273.00 +3*GHSERCR#+2*GHSERFE#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:V:C;0) 273.00 +3*GHSERFE#+2*GHSERCR#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:V:C;0) 273.00 +3*GHSERCR#+2*GHSERMO#
+1*GHSERVV#+GHSERCC#-140000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CR:V:C;0) 273.00 +3*GHSERMO#+2*GHSERCR#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:NI:V:C;0) 273.00 +3*GHSERCR#+2*GHSERNI#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:V:C;0) 273.00 +3*GHSERCR#+2*GHSERWW#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:V:C;0) 273.00 +3*GHSERWW#+2*GHSERCR#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:V:C;0) 273.00 +3*GHSERFE#+2*GHSERMO#
+1*GHSERVV#+GHSERCC#-140000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:FE:V:C;0) 273.00 +3*GHSERMO#+2*GHSERFE#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:V:C;0) 273.00 +3*GHSERFE#+2*GHSERNI#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:V:C;0) 273.00 +3*GHSERFE#+2*GHSERWW#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:V:C;0) 273.00 +3*GHSERWW#+2*GHSERFE#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:NI:V:C;0) 273.00 +3*GHSERMO#+2*GHSERNI#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:V:C;0) 273.00 +3*GHSERMO#+2*GHSERWW#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:V:C;0) 273.00 +3*GHSERWW#+2*GHSERMO#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:V:C;0) 273.00 +3*GHSERWW#+2*GHSERNI#
+1*GHSERVV#+GHSERCC#; 6000.00 N
REF:pov15 !
$
$ Nitrogen parameters
PARAMETER G(M6C,CR:CR:CO:N;0) 273.00 +5*GHSERCR#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:CO:N;0) 273.00 +3*GHSERCO#
+2*GHSERCR#+GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:CO:N;0) 273.00 +3*GHSERCR#
+2*GHSERCO#+GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:FE:N;0) 273.00 +3*GHSERCO#
+2*GHSERFE#+GHSERFE#
+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:FE:N;0) 273.00 +4*GHSERFE#
+2*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:CO:N;0) 273.00 +5*GHSERFE#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:FE:N;0) 273.00 +5*GHSERCO#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:CO:N;0) 273.00 +3*GHSERCO#
+2*GHSERFE#+GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:CO:N;0) 273.00 +3*GHSERFE#
+2*GHSERCO#+GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:CO:N;0) 273.00 +3*GHSERMO#
+2*GHSERCO#+GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:CO:N;0) 273.00 +4*GHSERCO#
+2*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:MO:N;0) 273.00 +5*GHSERCO#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:CO:N;0) 273.00 +5*GHSERMO#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:MO:N;0) 273.00 +3*GHSERMO#
+2*GHSERCO#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:MO:N;0) 273.00 +3*GHSERCO#
+2*GHSERMO#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:CO:N;0) 273.00 +4*GHSERCO#
+2*GHSERNI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:V:CO:N;0) 273.00 +5*GHSERVV#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:CO:N;0) 273.00 +3*GHSERCO#
+2*GHSERVV#+GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:CO:N;0) 273.00 +3*GHSERVV#
+2*GHSERCO#+GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:CO:N;0) 273.00 +6*GHSERCO#
+GHSERNN#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:W:N;0) 273.00 +6*GHSERWW#
+GHSERNN#+7500; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:CO:N;0) 273.00 +35000+3*GHSERWW#+2*GHSERCO#+GHSERCO#
+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:CO:N;0) 273.00 +35000+4*GHSERCO#
+2*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:W:N;0) 273.00 +35000+5*GHSERCO#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:CO:N;0) 273.00 +35000+5*GHSERWW#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:W:N;0) 273.00 +35000+3*GHSERWW#
+2*GHSERCO#+GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:W:N;0) 273.00 +3*GHSERCO#
+2*GHSERWW#+GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CR:FE:N;0) 273.00 +5*GHSERCR#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:FE:N;0) 273.00 +3*GHSERFE#
+2*GHSERCR#+GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:FE:FE:N;0) 273.00 +3*GHSERCR#
+2*GHSERFE#+GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CR:MO:N;0) 273.00 +5*GHSERCR#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CR:MO:N;0) 273.00 +3*GHSERMO#
+2*GHSERCR#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:MO:N;0) 273.00 +3*GHSERCR#
+2*GHSERMO#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CR:W:N;0) 273.00 +5*GHSERCR#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:W:N;0) 273.00 +3*GHSERWW#
+2*GHSERCR#+GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:W:N;0) 273.00 +3*GHSERCR#
+2*GHSERWW#+GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:MO:N;0) 273.00 +6*GHSERMO#
+GHSERNN#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:FE:FE:N;0) 273.00 +3*GHSERMO#
+2*GHSERFE#+GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:FE:N;0) 273.00 +4*GHSERFE#
+2*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:MO:N;0) 273.00 +5*GHSERFE#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:FE:N;0) 273.00 +5*GHSERMO#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:FE:MO:N;0) 273.00 +3*GHSERMO#
+2*GHSERFE#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:MO:N;0) 273.00 +3*GHSERFE#
+2*GHSERMO#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:FE:N;0) 273.00 +4*GHSERFE#
+2*GHSERNI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:V:FE:N;0) 273.00 +5*GHSERVV#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:FE:N;0) 273.00 +3*GHSERFE#
+2*GHSERVV#+GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:FE:FE:N;0) 273.00 +3*GHSERVV#
+2*GHSERFE#+GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:FE:N;0) 273.00 +6*GHSERFE#
+GHSERNN#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:FE:N;0) 273.00 +35000+3*GHSERWW#+2*GHSERFE#+GHSERFE#
+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:FE:N;0) 273.00 +35000+4*GHSERFE#
+2*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:W:N;0) 273.00 +5*GHSERFE#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:FE:N;0) 273.00 +5*GHSERWW#
+1*GHSERFE#+GHSERNN#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:W:N;0) 273.00 +3*GHSERWW#
+2*GHSERFE#+GHSERWW#+GHSERNN#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:W:N;0) 273.00 +3*GHSERFE#
+2*GHSERWW#+GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:NI:MO:N;0) 273.00 +3*GHSERMO#
+2*GHSERNI#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:V:MO:N;0) 273.00 +5*GHSERVV#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:MO:N;0) 273.00 +3*GHSERMO#
+2*GHSERVV#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:MO:N;0) 273.00 +3*GHSERVV#
+2*GHSERMO#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:W:N;0) 273.00 +3*GHSERMO#
+2*GHSERWW#+GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:W:N;0) 273.00 +4*GHSERWW#
+2*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:MO:N;0) 273.00 +5*GHSERWW#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:W:N;0) 273.00 +5*GHSERMO#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:MO:N;0) 273.00 +3*GHSERMO#
+2*GHSERWW#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:MO:N;0) 273.00 +3*GHSERWW#
+2*GHSERMO#+GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:W:N;0) 273.00 +35000+3*GHSERWW#
+2*GHSERNI#+GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:V:W:N;0) 273.00 +5*GHSERVV#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:W:N;0) 273.00 +3*GHSERWW#
+2*GHSERVV#+GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:W:N;0) 273.00 +3*GHSERVV#
+2*GHSERWW#+GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:CO:N;0) 273.00 +3*GHSERFE#+2*GHSERCR#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:FE:N;0) 273.00 +3*GHSERCO#+2*GHSERCR#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:FE:N;0) 273.00 +3*GHSERCR#+2*GHSERCO#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:FE:CO:N;0) 273.00 +3*GHSERCR#+2*GHSERFE#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CR:CO:N;0) 273.00 +3*GHSERMO#+2*GHSERCR#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:MO:N;0) 273.00 +3*GHSERCO#+2*GHSERCR#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:MO:N;0) 273.00 +3*GHSERCR#+2*GHSERCO#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:CO:N;0) 273.00 +3*GHSERCR#+2*GHSERMO#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:NI:CO:N;0) 273.00 +3*GHSERCR#+2*GHSERNI#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:CO:N;0) 273.00 +3*GHSERVV#+2*GHSERCR#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:CO:N;0) 273.00 +3*GHSERCR#+2*GHSERVV#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:CO:N;0) 273.00 +3*GHSERWW#+2*GHSERCR#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:W:N;0) 273.00 +3*GHSERCO#+2*GHSERCR#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:W:N;0) 273.00 +3*GHSERCR#+2*GHSERCO#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:CO:N;0) 273.00 +3*GHSERCR#+2*GHSERWW#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:MO:N;0) 273.00 +3*GHSERFE#+2*GHSERCO#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:CO:N;0) 273.00 +3*GHSERFE#+2*GHSERMO#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:FE:N;0) 273.00 +3*GHSERCO#+2*GHSERMO#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:MO:N;0) 273.00 +3*GHSERCO#+2*GHSERFE#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:FE:N;0) 273.00 +3*GHSERMO#+2*GHSERCO#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:FE:CO:N;0) 273.00 +3*GHSERMO#+2*GHSERFE#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:CO:N;0) 273.00 +3*GHSERFE#+2*GHSERNI#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:FE:N;0) 273.00 +3*GHSERCO#+2*GHSERNI#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:CO:N;0) 273.00 +3*GHSERFE#+2*GHSERVV#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:FE:N;0) 273.00 +3*GHSERCO#+2*GHSERVV#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:FE:N;0) 273.00 +3*GHSERVV#+2*GHSERCO#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:FE:CO:N;0) 273.00 +3*GHSERVV#+2*GHSERFE#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:W:N;0) 273.00 +3*GHSERFE#+2*GHSERCO#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:CO:N;0) 273.00 +3*GHSERFE#+2*GHSERWW#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:FE:N;0) 273.00 +3*GHSERCO#+2*GHSERWW#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:W:N;0) 273.00 +3*GHSERCO#+2*GHSERFE#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:FE:N;0) 273.00 +3*GHSERWW#+2*GHSERCO#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:CO:N;0) 273.00 +3*GHSERWW#+2*GHSERFE#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:MO:N;0) 273.00 +3*GHSERCO#+2*GHSERNI#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:NI:CO:N;0) 273.00 +3*GHSERMO#+2*GHSERNI#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:MO:N;0) 273.00 +3*GHSERVV#+2*GHSERCO#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:CO:N;0) 273.00 +3*GHSERVV#+2*GHSERMO#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:MO:N;0) 273.00 +3*GHSERCO#+2*GHSERVV#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:CO:N;0) 273.00 +3*GHSERMO#+2*GHSERVV#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:MO:N;0) 273.00 +3*GHSERWW#+2*GHSERCO#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:CO:N;0) 273.00 +3*GHSERWW#+2*GHSERMO#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:W:N;0) 273.00 +3*GHSERCO#+2*GHSERMO#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:MO:N;0) 273.00 +3*GHSERCO#+2*GHSERWW#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:W:N;0) 273.00 +3*GHSERMO#+2*GHSERCO#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:CO:N;0) 273.00 +3*GHSERMO#+2*GHSERWW#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:CO:N;0) 273.00 +3*GHSERVV#+2*GHSERNI#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:W:N;0) 273.00 +3*GHSERCO#+2*GHSERNI#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:CO:N;0) 273.00 +3*GHSERWW#+2*GHSERNI#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:CO:N;0) 273.00 +3*GHSERWW#+2*GHSERVV#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:W:N;0) 273.00 +3*GHSERCO#+2*GHSERVV#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:V:N;0) 273.00 +3*GHSERCO#+2*GHSERWW#
+1*GHSERVV#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:W:N;0) 273.00 +3*GHSERVV#+2*GHSERCO#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:CO:N;0) 273.00 +3*GHSERVV#+2*GHSERWW#
+1*GHSERCO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:FE:N;0) 273.00 +3*GHSERCR#+2*GHSERMO#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:FE:MO:N;0) 273.00 +3*GHSERCR#+2*GHSERFE#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CR:FE:N;0) 273.00 +3*GHSERMO#+2*GHSERCR#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:MO:N;0) 273.00 +3*GHSERFE#+2*GHSERCR#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:NI:FE:N;0) 273.00 +3*GHSERCR#+2*GHSERNI#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:FE:N;0) 273.00 +3*GHSERCR#+2*GHSERVV#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:FE:N;0) 273.00 +3*GHSERVV#+2*GHSERCR#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:FE:N;0) 273.00 +3*GHSERCR#+2*GHSERWW#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:FE:W:N;0) 273.00 +3*GHSERCR#+2*GHSERFE#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:FE:N;0) 273.00 +3*GHSERWW#+2*GHSERCR#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:W:N;0) 273.00 +3*GHSERFE#+2*GHSERCR#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:NI:MO:N;0) 273.00 +3*GHSERCR#+2*GHSERNI#
+1*GHSERMO#+GHSERNN#-10000-63*T; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:MO:N;0) 273.00 +3*GHSERCR#+2*GHSERVV#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:MO:N;0) 273.00 +3*GHSERVV#+2*GHSERCR#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:W:N;0) 273.00 +3*GHSERCR#+2*GHSERMO#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:MO:N;0) 273.00 +3*GHSERCR#+2*GHSERWW#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CR:W:N;0) 273.00 +3*GHSERMO#+2*GHSERCR#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:MO:N;0) 273.00 +3*GHSERWW#+2*GHSERCR#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:NI:W:N;0) 273.00 +3*GHSERCR#+2*GHSERNI#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:W:N;0) 273.00 +3*GHSERCR#+2*GHSERVV#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:W:N;0) 273.00 +3*GHSERVV#+2*GHSERCR#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:MO:N;0) 273.00 +3*GHSERFE#+2*GHSERNI#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:NI:FE:N;0) 273.00 +3*GHSERMO#+2*GHSERNI#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:MO:N;0) 273.00 +3*GHSERFE#+2*GHSERVV#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:FE:N;0) 273.00 +3*GHSERMO#+2*GHSERVV#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:FE:N;0) 273.00 +3*GHSERVV#+2*GHSERMO#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:FE:MO:N;0) 273.00 +3*GHSERVV#+2*GHSERFE#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:W:N;0) 273.00 +3*GHSERFE#+2*GHSERMO#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:MO:N;0) 273.00 +3*GHSERFE#+2*GHSERWW#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:FE:N;0) 273.00 +3*GHSERMO#+2*GHSERWW#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:FE:W:N;0) 273.00 +3*GHSERMO#+2*GHSERFE#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:FE:N;0) 273.00 +3*GHSERWW#+2*GHSERMO#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:MO:N;0) 273.00 +3*GHSERWW#+2*GHSERFE#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:FE:N;0) 273.00 +3*GHSERVV#+2*GHSERNI#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:W:N;0) 273.00 +3*GHSERFE#+2*GHSERNI#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:FE:N;0) 273.00 +3*GHSERWW#+2*GHSERNI#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:W:N;0) 273.00 +3*GHSERFE#+2*GHSERVV#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:FE:N;0) 273.00 +3*GHSERWW#+2*GHSERVV#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:FE:N;0) 273.00 +3*GHSERVV#+2*GHSERWW#
+1*GHSERFE#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:FE:W:N;0) 273.00 +3*GHSERVV#+2*GHSERFE#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:MO:N;0) 273.00 +3*GHSERVV#+2*GHSERNI#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:NI:W:N;0) 273.00 +3*GHSERMO#+2*GHSERNI#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:MO:N;0) 273.00 +3*GHSERWW#+2*GHSERNI#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:W:N;0) 273.00 +3*GHSERMO#+2*GHSERVV#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:MO:N;0) 273.00 +3*GHSERWW#+2*GHSERVV#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:MO:N;0) 273.00 +3*GHSERVV#+2*GHSERWW#
+1*GHSERMO#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:W:N;0) 273.00 +3*GHSERVV#+2*GHSERMO#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:W:N;0) 273.00 +3*GHSERVV#+2*GHSERNI#
+1*GHSERWW#+GHSERNN#; 6000.00 N
REF:pov15 !
$ Si-Parameters
PARAMETER G(M6C,CR:CR:SI:N;0) 273.00 +5*GHSERCR#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CR:SI:N;0) 273.00 +3*GHSERCO#
+2*GHSERCR#+GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:CO:SI:N;0) 273.00 +3*GHSERCR#
+2*GHSERCO#+GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:FE:SI:N;0) 273.00 +5*GHSERFE#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:FE:SI:N;0) 273.00 +3*GHSERCO#
+2*GHSERFE#+GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CO:SI:N;0) 273.00 +3*GHSERFE#
+2*GHSERCO#+GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CO:SI:N;0) 273.00 +3*GHSERMO#
+2*GHSERCO#+GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:MO:SI:N;0) 273.00 +3*GHSERCO#
+2*GHSERMO#+GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:MO:SI:N;0) 273.00 +5*GHSERMO#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:NI:SI:N;0) 273.00 +3*GHSERCO#
+2*GHSERNI#+GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:V:SI:N;0) 273.00 +5*GHSERVV#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:V:SI:N;0) 273.00 +3*GHSERCO#
+2*GHSERVV#+GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CO:SI:N;0) 273.00 +3*GHSERVV#
+2*GHSERCO#+GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:CO:SI:N;0) 273.00 +5*GHSERCO#
+GHSERSI#+GHSERNN#+35000; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CO:SI:N;0) 273.00 +3*GHSERWW#+2*GHSERCO#+GHSERSI#
+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CO:W:SI:N;0) 273.00 +3*GHSERCO#
+2*GHSERWW#+GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:W:SI:N;0) 273.00 +5*GHSERWW#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:CR:SI:N;0) 273.00 +3*GHSERFE#+2*GHSERCR#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:CR:SI:N;0) 273.00 +3*GHSERMO#+2*GHSERCR#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:MO:SI:N;0) 273.00 +3*GHSERCR#+2*GHSERMO#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:CR:SI:N;0) 273.00 +3*GHSERVV#+2*GHSERCR#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:V:SI:N;0) 273.00 +3*GHSERCR#+2*GHSERVV#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:CR:SI:N;0) 273.00 +3*GHSERWW#+2*GHSERCR#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:W:SI:N;0) 273.00 +3*GHSERCR#+2*GHSERWW#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:MO:SI:N;0) 273.00 +3*GHSERFE#+2*GHSERMO#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:NI:SI:N;0) 273.00 +3*GHSERFE#+2*GHSERNI#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:V:SI:N;0) 273.00 +3*GHSERFE#+2*GHSERVV#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:FE:SI:N;0) 273.00 +3*GHSERVV#+2*GHSERFE#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,FE:W:SI:N;0) 273.00 +3*GHSERFE#+2*GHSERWW#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:FE:SI:N;0) 273.00 +3*GHSERWW#+2*GHSERFE#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:MO:SI:N;0) 273.00 +3*GHSERVV#+2*GHSERMO#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:V:SI:N;0) 273.00 +3*GHSERMO#+2*GHSERVV#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:MO:SI:N;0) 273.00 +3*GHSERWW#+2*GHSERMO#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,MO:W:SI:N;0) 273.00 +3*GHSERMO#+2*GHSERWW#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:NI:SI:N;0) 273.00 +3*GHSERVV#+2*GHSERNI#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:NI:SI:N;0) 273.00 +3*GHSERWW#+2*GHSERNI#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,W:V:SI:N;0) 273.00 +3*GHSERWW#+2*GHSERVV#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,V:W:SI:N;0) 273.00 +3*GHSERVV#+2*GHSERWW#
+1*GHSERSI#+GHSERNN#; 6000.00 N
REF:pov15 !
$ Next are former Cr3Ni2SiN parameters
PARAMETER G(M6C,CR:NI:SI:N;0) 273.00 +3*GHSERCR#+2*GHSERNI#+GHSERSI#
+GHSERNN#-275000+20*T; 6000.00 N
REF:pov13 !
PARAMETER G(M6C,CR:SI:NI:N;0) 273.00 +3*GHSERCR#+2*GHSERSI#+GHSERNI#
+GHSERNN#-275500+20*T; 6000.00 N
REF:pov15 !
PARAMETER G(M6C,CR:FE:SI:C;0) 273.00 +3*GHSERCR#+2*GHSERFE#+GHSERSI#
+GHSERCC#; 6000.00 N
REF:pov13 !
PARAMETER G(M6C,CR:FE:SI:N;0) 273.00 +3*GHSERCR#+2*GHSERFE#+GHSERSI#
+GHSERNN#-180000; 6000.00 N
REF:pov13 !
$PARAMETER G(M6C,MO:NI:SI:C;0) 273.00 +3*GHSERMO#+2*GHSERNI#+GHSERSI#
$ +GHSERCC#; 6000.00 N
$REF:pov13 !
PARAMETER G(M6C,MO:NI:SI:N;0) 273.00 +3*GHSERMO#+2*GHSERNI#+GHSERSI#
+GHSERNN#-240000; 6000.00 N
REF:pov13 !
$PARAMETER G(M6C,MO:FE:SI:C;0) 273.00 +3*GHSERMO#+2*GHSERFE#+GHSERSI#
$ +GHSERCC#; 6000.00 N
$REF:pov13 !
PARAMETER G(M6C,MO:FE:SI:N;0) 273.00 +3*GHSERMO#+2*GHSERFE#+GHSERSI#
+GHSERNN#-200000; 6000.00 N
REF:pov13 !
$
$----------------------Interaction parameters----------------------
PARAMETER L(M6C,FE:CR,V:MO:C;0) 273.00 -75000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:CR:MO,SI:C;0) 273.00 -200000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:MO:MO,SI:C;0) 273.00 -50000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:W:MO,SI:C;0) 273.00 +1e-8; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:MO,W:MO:C;0) 273.00 -50000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:MO,W:MO:C;1) 273.00 +1e-8; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:MO,W:MO:C;2) 273.00 +1e-8; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:MO:MO,W:C;0) 273.00 -100000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:MO,W:W:C;0) 273.00 +40000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:MO,W:W:C;1) 273.00 +1e-8; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:MO,W:W:C;2) 273.00 +1e-8; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:CR,MO:SI:C;0) 273.00 -100000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:CR,V:SI:C;0) 273.00 -200000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:CR,W:SI:C;0) 273.00 -25000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:MO,V:SI:C;0) 273.00 -150000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:MO,W:SI:C;0) 273.00 +80000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:V,W:SI:C;0) 273.00 -50000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO:CR:MO,SI:C;0) 273.00 -200000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE,V:W:MO:C;0) 273.00 -50000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CR,FE:V:MO:C;0) 273.00 -100000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CR,FE:W:MO:C;0) 273.00 +20000-75*T; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO,FE:W:MO:C;0) 273.00 -80000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO,FE:MO:MO:C;0) 273.00 -150000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO,FE:CR:MO:C;0) 273.00 -90000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO:CR,FE:MO:C;0) 273.00 -50000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO:W:MO,SI:C;0) 273.00 +100000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO:W:MO,SI:C;1) 273.00 -150000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO:W:MO,SI:C;2) 273.00 +1e-8; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO,FE:CR:SI:C;0) 273.00 +1e-8; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO,FE:CR:W:C;0) 273.00 -150000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO,FE:MO:SI:C;0) 273.00 -150000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO,FE:W:SI:C;0) 273.00 +80000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO,FE:W:W:C;0) 273.00 -75000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CO:V,W:SI:C;0) 273.00 +1e-8; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:V,W:MO:C;0) 273.00 -90000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:V,W:MO:C;1) 273.00 +90000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,FE:V,W:MO:C;2) 273.00 +1e-8; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CR:V,W:MO:C;0) 273.00 +1e-8; 6000.00 N
REF:pov15 !
$
PARAMETER L(M6C,CO,CR:NI:MO:C;0) 273.00 -75000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CR,MO:NI:MO:C;0) 273.00 -100000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CR,MO:NI:SI:C;0) 273.00 -100000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,CR,MO:W:MO:C;0) 273.00 -100000; 6000.00 N
REF:pov15 !
PARAMETER L(M6C,MO:NI,W:MO:C;0) 273.00 -100000; 6000.00 N
REF:pov15 !
$
PARAMETER L(M6C,CR:NI:SI:C,N;0) 273.00 -80000; 6000.00 N
REF:pov15 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: M7C3
$###########################################################################
$
PHASE M7C3 % 2 7 3 >
Trigonal Cr-rich carbide with a large crystallographic unit cell.
In particular Fe- and Mn-solubilities.
>> 5 !
CONSTITUENT M7C3 : CO,CR,FE,MN,MO,NI,SI,V,W : C : !
PARAMETER G(M7C3,CO:C;0) 273.00 +75000+50*T+7*GHSERCO#
+3*GHSERCC#; 6000.00 N
REF:73 !
PARAMETER G(M7C3,CR:C;0) 273.00 +GCRM7C3#; 6000.00 N
REF:11 !
PARAMETER G(M7C3,FE:C;0) 273.00 +7*GHSERFE#+3*GHSERCC#
+75000-48.2168*T; 6000.00 N
REF:11 !
PARAMETER G(M7C3,MN:C;0) 273.00 -106695+9.36*T+7*GHSERMN#
+3*GHSERCC#; 6000.00 N
REF:255 !
PARAMETER G(M7C3,MO:C;0) 273.00 +7*GHSERMO#+3*GHSERCC#
-140415+24.24*T; 6000.00 N
REF:61 !
PARAMETER G(M7C3,NI:C;0) 273.00 +7*GHSERNI#+3*GHSERCC#
+107130-36.605*T; 6000.00 N
REF:11 !
PARAMETER G(M7C3,SI:C;0) 273.00 +7*GHSERSI#+3*GHSERCC#+250000; 6000.00 N
REF:pov11 !
PARAMETER G(M7C3,V:C;0) 273.00 -454245+1518.48*T-250.981*T*LN(T)
+2148691*T**(-1); 6000.00 N
REF:15 !
PARAMETER G(M7C3,W:C;0) 273.00 +7*GHSERWW#+3*GHSERCC#
+138000-50*T; 6000.00 N
REF:57 !
$----------------------Interaction parameters----------------------
PARAMETER L(M7C3,CO,CR:C;0) 273.00 -96092; 6000.00 N
REF:73 !
PARAMETER L(M7C3,CR,FE:C;0) 273.00 -32045-10*T; 6000.00 N
REF:293 !
PARAMETER L(M7C3,CR,MN:C;0) 273.00 +72737-56.4964*T; 6000.00 N
REF:58 !
PARAMETER L(M7C3,CR,MO:C;0) 273.00 +165280; 6000.00 N
REF:61 !
PARAMETER L(M7C3,CR,NI:C;0) 273.00 +100000; 6000.00 N
REF:11 !
PARAMETER L(M7C3,CR,V:C;0) 273.00 -110271; 6000.00 N
REF:68 !
PARAMETER L(M7C3,FE,MN:C;0) 273.00 +20157-24.7104*T; 6000.00 N
REF:255 !
PARAMETER L(M7C3,FE,MO:C;0) 273.00 -60000; 6000.00 N
REF:pov11 !
PARAMETER L(M7C3,FE,NI:C;0) 273.00 +UNDEF#; 6000.00 N !
PARAMETER L(M7C3,MO,V:C;0) 273.00 +1e-8; 6000.00 N
REF:pov10 !
PARAMETER L(M7C3,CR,FE,V:C;0) 273.00 -250158; 6000.00 N
REF:68 !
PARAMETER L(M7C3,CR,FE,MO:C;0) 273.00 -170000; 6000.00 N
REF:pov11 !
PARAMETER L(M7C3,CR,FE,NI:C;0) 273.00 +UNDEF#; 6000.00 N !
PARAMETER L(M7C3,FE,MO,NI:C;0) 273.00 +UNDEF#; 6000.00 N !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: M12C
$###########################################################################
$
$M12C (Co6W6C)
PHASE M12C % 3 6 6 1 >
Co-W-rich carbide.
>> 1 !
CONSTITUENT M12C : CO : W : C : !
PARAMETER G(M12C,CO:W:C;0) 273.00 -88450-19.1*T+6*GHSERCO#
+6*GHSERWW#+GHSERCC#; 6000.00 N
REF:243 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: M23C6
$###########################################################################
$
PHASE M23C6 % 3 20 3 6 >
Face-centered cubic Cr-rich carbide, can contain significant amounts
of W, Mo, V, Ni. Has a large crystallographic unit cell.
Common equilibrium carbide in 9-12 mass.% Cr-steels.
Precipitation predominantly on prior austenite grain boundaries
and lath boundaries.
>> 5 !
CONSTITUENT M23C6 : CO,CR,FE,MN,NI,V : CO,CR,FE,MN,MO,NI,V,W :
B,C% : !
PARAMETER G(M23C6,CO:CO:B;0) 273.00 +23*GHSERCO#+6*GHSERBB#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,CO:CO:C;0) 273.00 +145000+116*T+23*GHSERCO#
+6*GHSERCC#; 6000.00 N
REF:73 !
PARAMETER G(M23C6,CO:CR:B;0) 273.00 +0.8695652*GCOM23C6#
+0.1304348*GCRM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,CO:CR:C;0) 273.00 +0.8695652*GCOM23C6#
+0.1304348*GCRM23C6#; 6000.00 N
REF:73 !
PARAMETER G(M23C6,CO:FE:B;0) 273.00 +0.8695652*GCOM23C6#
+0.1304348*GFEM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:FE:C;0) 273.00 +0.8695652*GCOM23C6#
+0.1304348*GFEM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:MN:B;0) 273.00 +0.8695652*GCOM23C6#
+0.1304348*GMNM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:MN:C;0) 273.00 +0.8695652*GCOM23C6#
+0.1304348*GMNM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:MO:B;0) 273.00 +20*GHSERCO#+3*GHSERMO#
+6*GHSERCC#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:MO:C;0) 273.00 +200000+20*GHSERCO#+3*GHSERMO#
+6*GHSERCC#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:NI:B;0) 273.00 +0.869565*GCOM23C6#
+0.130435*GNIM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:NI:C;0) 273.00 +0.869565*GCOM23C6#
+0.130435*GNIM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:V:B;0) 273.00 +0.869565*GCOM23C6#
+0.130435*GVM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:V:C;0) 273.00 +0.869565*GCOM23C6#
+0.130435*GVM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:W:B;0) 273.00 +0.869565*GCOM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CO:W:C;0) 273.00 +0.869565*GCOM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,CR:CO:B;0) 273.00 +0.8695652*GCRM23C6#+0.1304348*GCOM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,CR:CO:C;0) 273.00 +0.8695652*GCRM23C6#
+0.1304348*GCOM23C6#; 6000.00 N
REF:73 !
PARAMETER G(M23C6,CR:CR:B;0) 273.00 -250000+100*T+GCRM23C6#
-6*GHSERCC#+6*GHSERBB#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,CR:CR:C;0) 273.00 +GCRM23C6#; 6000.00 N
REF:11 !
PARAMETER G(M23C6,CR:FE:B;0) 273.00 -250000+100*T+0.8695652*GCRM23C6#
+0.1304348*GFEM23C6#-6*GHSERCC#+6*GHSERBB#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,CR:FE:C;0) 273.00 +0.8695652*GCRM23C6#
+0.1304348*GFEM23C6#; 6000.00 N
REF:11 !
PARAMETER G(M23C6,CR:MN:B;0) 273.00 +0.869565*GCRM23C6#+0.130435*GMNM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,CR:MN:C;0) 273.00 +0.8695652*GCRM23C6#
+0.1304348*GMNM23C6#; 6000.00 N
REF:58 !
PARAMETER G(M23C6,CR:MO:B;0) 273.00 +20*GHSERCR#+3*GHSERMO#
-50000-350*T+6*GHSERBB#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,CR:MO:C;0) 273.00 +20*GHSERCR#+3*GHSERMO#+6*GHSERCC#
-439117-50.0535*T; 6000.00 N
REF:61 !
PARAMETER G(M23C6,CR:NI:B;0) 273.00 +0.8695652*GCRM23C6#+0.1304348*GNIM23C6#
-6*GHSERCC#+6*GHSERBB#-250000+250*T; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,CR:NI:C;0) 273.00 +0.8695652*GCRM23C6#
+0.1304348*GNIM23C6#; 6000.00 N
REF:11 !
PARAMETER G(M23C6,CR:V:B;0) 273.00 +0.869565217*GCRM23C6#+0.130435*GVM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,CR:V:C;0) 273.00 +0.869565217*GCRM23C6#
+0.130435*GVM23C6#; 6000.00 N
REF:52 !
PARAMETER G(M23C6,CR:W:B;0) 273.00 +0.869565217*GCRM23C6#+3*GHSERWW#
+0.7826087*GHSERCC#+18850-75.4*T-6*GHSERCC#+6*GHSERBB#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,CR:W:C;0) 273.00 +0.869565217*GCRM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#+18850-75.4*T; 6000.00 N
REF:57 !
PARAMETER G(M23C6,FE:CO:B;0) 273.00 +0.1304348*GCOM23C6#
+0.8695652*GFEM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,FE:CO:C;0) 273.00 +0.1304348*GCOM23C6#
+0.8695652*GFEM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,FE:CR:B;0) 273.00 +0.1304348*GCRM23C6#+0.8695652*GFEM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,FE:CR:C;0) 273.00 +0.1304348*GCRM23C6#
+0.8695652*GFEM23C6#; 6000.00 N
REF:11 !
PARAMETER G(M23C6,FE:FE:B;0) 273.00 +23*GHSERFE#+6*GHSERBB#
-391500+17.4*T; 6000.00 N
REF:124 !
PARAMETER G(M23C6,FE:FE:C;0) 273.00 +GFEM23C6#; 6000.00 N
REF:11 !
PARAMETER G(M23C6,FE:MN:B;0) 273.00 +0.869565*GFEM23C6#+0.130435*GMNM23C6#
-6*GHSERCC#+6*GHSERBB#-365000; 6000.00 N
REF:pov14 !
PARAMETER G(M23C6,FE:MN:C;0) 273.00 +0.869565*GFEM23C6#
+0.130435*GMNM23C6#; 6000.00 N
REF:15 !
PARAMETER G(M23C6,FE:MO:B;0) 273.00 +20*GHSERFE#+3*GHSERMO#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,FE:MO:C;0) 273.00 +20*GHSERFE#+3*GHSERMO#
+6*GHSERCC#-76351-5.0949*T; 6000.00 N
REF:61 !
PARAMETER G(M23C6,FE:NI:B;0) 273.00 +0.8695652*GFEM23C6#+0.1304348*GNIM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,FE:NI:C;0) 273.00 +0.8695652*GFEM23C6#
+0.1304348*GNIM23C6#; 6000.00 N
REF:11 !
PARAMETER G(M23C6,FE:V:B;0) 273.00 +0.869565*GFEM23C6#+0.130435*GVM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,FE:V:C;0) 273.00 +0.869565*GFEM23C6#
+0.130435*GVM23C6#; 6000.00 N
REF:15 !
PARAMETER G(M23C6,FE:W:B;0) 273.00 +0.869565217*GFEM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#-103240+38.4*T-6*GHSERCC#
+6*GHSERBB#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,FE:W:C;0) 273.00 +0.869565217*GFEM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#-103240+38.4*T; 6000.00 N
REF:57 !
PARAMETER G(M23C6,MN:CO:B;0) 273.00 +0.8695652*GMNM23C6#
+0.1304348*GCOM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,MN:CO:C;0) 273.00 +0.8695652*GMNM23C6#
+0.1304348*GCOM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,MN:CR:B;0) 273.00 +0.869565*GMNM23C6#+0.130435*GCRM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,MN:CR:C;0) 273.00 +0.8695652*GMNM23C6#
+0.1304348*GCRM23C6#; 6000.00 N
REF:58 !
PARAMETER G(M23C6,MN:FE:B;0) 273.00 +0.869565*GMNM23C6#+0.130435*GFEM23C6#
-6*GHSERCC#+6*GHSERBB#-365000; 6000.00 N
REF:pov14 !
PARAMETER G(M23C6,MN:FE:C;0) 273.00 +0.869565*GMNM23C6#
+0.130435*GFEM23C6#; 6000.00 N
REF:15 !
PARAMETER G(M23C6,MN:MN:B;0) 273.00 +GMNM23C6#-6*GHSERCC#
+6*GHSERBB#-250000-50*T; 6000.00 N
REF:pov14 !
PARAMETER G(M23C6,MN:MN:C;0) 273.00 +GMNM23C6#; 6000.00 N
REF:15 !
PARAMETER G(M23C6,MN:MO:B;0) 273.00 +20*GHSERMN#+3*GHSERMO#
+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,MN:MO:C;0) 273.00 +20*GHSERMN#+3*GHSERMO#
+6*GHSERCC#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,MN:NI:B;0) 273.00 +0.869565*GMNM23C6#
+0.130435*GNIM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,MN:NI:C;0) 273.00 +0.869565*GMNM23C6#
+0.130435*GNIM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,MN:V:B;0) 273.00 +0.869565*GMNM23C6#+0.130435*GVM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,MN:V:C;0) 273.00 +0.869565*GMNM23C6#
+0.130435*GVM23C6#; 6000.00 N
REF:15 !
PARAMETER G(M23C6,MN:W:B;0) 273.00 +0.869565217*GMNM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,MN:W:C;0) 273.00 +0.869565217*GMNM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:CO:B;0) 273.00 +0.8695652*GNIM23C6#
+0.1304348*GCOM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:CO:C;0) 273.00 +0.8695652*GNIM23C6#
+0.1304348*GCOM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:CR:B;0) 273.00 +0.8695652*GNIM23C6#+0.1304348*GCRM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,NI:CR:C;0) 273.00 +0.8695652*GNIM23C6#
+0.1304348*GCRM23C6#; 6000.00 N
REF:11 !
PARAMETER G(M23C6,NI:FE:B;0) 273.00 +0.869565*GNIM23C6#
+0.130435*GFEM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:FE:C;0) 273.00 +0.869565*GNIM23C6#
+0.130435*GFEM23C6#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:MN:B;0) 273.00 +0.869565*GNIM23C6#
+0.130435*GMNM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:MN:C;0) 273.00 +0.869565*GNIM23C6#
+0.130435*GMNM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:MO:B;0) 273.00 +20*GHSERNI#+3*GHSERMO#
+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:MO:C;0) 273.00 +20*GHSERNI#+3*GHSERMO#
+6*GHSERCC#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:NI:B;0) 273.00 +GNIM23C6#-6*GHSERCC#
+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,NI:NI:C;0) 273.00 +GNIM23C6#; 6000.00 N
REF:11 !
PARAMETER G(M23C6,NI:V:B;0) 273.00 +0.869565*GNIM23C6#
+0.130435*GVM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:V:C;0) 273.00 +0.869565*GNIM23C6#
+0.130435*GVM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:W:B;0) 273.00 +0.869565*GNIM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,NI:W:C;0) 273.00 +0.869565*GNIM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,V:CO:B;0) 273.00 +0.869565217*GVM23C6#
+0.130435*GCOM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,V:CO:C;0) 273.00 +0.869565217*GVM23C6#
+0.130435*GCOM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,V:CR:B;0) 273.00 +0.869565217*GVM23C6#+0.130435*GCRM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,V:CR:C;0) 273.00 +0.869565217*GVM23C6#
+0.130435*GCRM23C6#; 6000.00 N
REF:52 !
PARAMETER G(M23C6,V:FE:B;0) 273.00 +0.869565*GVM23C6#+0.130435*GFEM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,V:FE:C;0) 273.00 +0.869565*GVM23C6#
+0.130435*GFEM23C6#; 6000.00 N
REF:15 !
PARAMETER G(M23C6,V:MN:B;0) 273.00 +0.869565*GVM23C6#+0.130435*GMNM23C6#
-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,V:MN:C;0) 273.00 +0.869565*GVM23C6#
+0.130435*GMNM23C6#; 6000.00 N
REF:15 !
PARAMETER G(M23C6,V:MO:B;0) 273.00 +20*GHSERVV#+3*GHSERMO#
+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,V:MO:C;0) 273.00 +20*GHSERVV#+3*GHSERMO#
+6*GHSERCC#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,V:NI:B;0) 273.00 +0.869565*GVM23C6#
+0.130435*GNIM23C6#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,V:NI:C;0) 273.00 +0.869565*GVM23C6#
+0.130435*GNIM23C6#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,V:V:B;0) 273.00 +GVM23C6#-6*GHSERCC#
+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov09 !
PARAMETER G(M23C6,V:V:C;0) 273.00 +GVM23C6#; 6000.00 N
REF:15 !
PARAMETER G(M23C6,V:W:B;0) 273.00 +GVM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#-6*GHSERCC#+6*GHSERBB#+UNDEF#; 6000.00 N
REF:pov10 !
PARAMETER G(M23C6,V:W:C;0) 273.00 +GVM23C6#
+3*GHSERWW#+0.7826087*GHSERCC#+UNDEF#; 6000.00 N
REF:pov10 !
$----------------------Interaction parameters----------------------
PARAMETER L(M23C6,CO:CO,CR:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CO,CR:CO:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CO,CR:CR:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR:CO,CR:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,FE:CR:B;0) 273.00 -205342+141.6667*T; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,FE:FE:B;0) 273.00 -205342+141.6667*T; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,FE:MO:B;0) 273.00 -177850+153.905*T; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,FE:V:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,FE:W:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,NI:CR:B;0) 273.00 +100000; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,NI:NI:B;0) 273.00 +100000; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,V:CR:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,V:FE:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,V:V:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,FE:CR,MO:B;0) 273.00 +1E-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,FE:FE,MO:B;0) 273.00 +1E-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,FE,V:CR:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,FE,V:FE:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,CR,FE,V:V:B;0) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(M23C6,FE,MN:MN:B;0) 273.00 +160000-500*T; 6000.00 N
REF:pov14 !
PARAMETER L(M23C6,FE,MN:MN:B;1) 273.00 -260000+500*T; 6000.00 N
REF:pov14 !
PARAMETER L(M23C6,MN:FE,MN:B;0) 273.00 +160000-500*T; 6000.00 N
REF:pov14 !
PARAMETER L(M23C6,MN:FE,MN:B;1) 273.00 -260000+500*T; 6000.00 N
REF:pov14 !
PARAMETER L(M23C6,FE,MN:FE,MN:B;0) 273.00 -100000; 6000.00 N
REF:pov14 !
$
PARAMETER L(M23C6,CO:CO,CR:C;0) 273.00 -182237; 6000.00 N
REF:73 !
PARAMETER L(M23C6,CO,CR:CO:C;0) 273.00 -182237; 6000.00 N
REF:73 !
PARAMETER L(M23C6,CO,CR:CR:C;0) 273.00 -182237; 6000.00 N
REF:73 !
PARAMETER L(M23C6,CR:CO,CR:C;0) 273.00 -182237; 6000.00 N
REF:73 !
PARAMETER L(M23C6,CR:MO,W:C;0) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(M23C6,CR:MO,W:C;1) 273.00 +175000; 6000.00 N
REF:pov14 !
PARAMETER L(M23C6,CR:MO,W:C;2) 273.00 +1e-8; 6000.00 N
REF:pov14 !
$PARAMETER L(M23C6,CR,FE:CR:C;0) 273.00 -205342+141.6667*T; 6000.00 N
$REF:11 !
$PARAMETER L(M23C6,CR,FE:FE:C;0) 273.00 -205342+141.6667*T; 6000.00 N
$REF:11 !
PARAMETER L(M23C6,CR,FE:CR:C;0) 273.00 +4609; 6000 N
REF:khvan14 !
PARAMETER L(M23C6,CR,FE:CR:C;1) 273.00 -43600; 6000 N
REF:khvan14 !
PARAMETER L(M23C6,CR,FE:FE:C;0) 273.00 +4609; 6000 N
REF:khvan14 !
PARAMETER L(M23C6,CR,FE:FE:C;1) 273.00 -43600; 6000 N
REF:khvan14 !
PARAMETER L(M23C6,CR:CR,FE:C;0) 273.00 +991; 6000 N
REF:khvan14 !
PARAMETER L(M23C6,CR:CR,FE:C;1) 273.00 -6540; 6000 N
REF:khvan14 !
PARAMETER L(M23C6,FE:CR,FE:C;0) 273.00 +991; 6000 N
REF:khvan14 !
PARAMETER L(M23C6,FE:CR,FE:C;1) 273.00 -6540; 6000 N
REF:khvan14 !
PARAMETER L(M23C6,CR,FE:MN:C;0) 273.00 -205342+141.6667*T; 6000.00 N
REF:58 !
PARAMETER L(M23C6,CR,FE:MO:C;0) 273.00 -177850+153.9050*T; 6000.00 N
REF:61 !
PARAMETER L(M23C6,CR,FE:V:C;0) 273.00 -205342+141.6667*T; 6000.00 N
REF:52 !
PARAMETER L(M23C6,CR,FE:W:C;0) 273.00 +18950; 6000.00 N
REF:57 !
PARAMETER L(M23C6,CR,FE:CR,MO:C;0) 273.00 +1E-8; 6000.00 N
REF:61 !
PARAMETER L(M23C6,CR,FE:FE,MO:C;0) 273.00 +1E-8; 6000.00 N
REF:61 !
PARAMETER L(M23C6,CR,MN:CR:C;0) 273.00 -173680+160*T; 6000.00 N
REF:58 !
PARAMETER L(M23C6,CR,MN:CR:C;1) 273.00 -286614; 6000.00 N
REF:58 !
PARAMETER L(M23C6,CR,MN:FE:C;0) 273.00 -173680+160*T; 6000.00 N
REF:58 !
PARAMETER L(M23C6,CR,MN:FE:C;1) 273.00 -286614; 6000.00 N
REF:58 !
PARAMETER L(M23C6,CR,MN:MN:C;0) 273.00 -173680+160*T; 6000.00 N
REF:58 !
PARAMETER L(M23C6,CR,MN:MN:C;1) 273.00 -286614; 6000.00 N
REF:58 !
PARAMETER L(M23C6,CR,NI:CR:C;0) 273.00 +100000; 6000.00 N
REF:11 !
PARAMETER L(M23C6,CR,NI:NI:C;0) 273.00 +100000; 6000.00 N
REF:11 !
PARAMETER L(M23C6,CR,V:CR:C;0) 273.00 -382069; 6000.00 N
REF:52 !
PARAMETER L(M23C6,CR,V:FE:C;0) 273.00 -382069; 6000.00 N
REF:52 !
PARAMETER L(M23C6,CR,V:V:C;0) 273.00 -382069; 6000.00 N
REF:52 !
PARAMETER L(M23C6,CR,FE,V:CR:C;0) 273.00 -1499585; 6000.00 N
REF:52 !
PARAMETER L(M23C6,CR,FE,V:FE:C;0) 273.00 -1499585; 6000.00 N
REF:52 !
PARAMETER L(M23C6,CR,FE,V:V:C;0) 273.00 -1499585; 6000.00 N
REF:52 !
PARAMETER L(M23C6,FE,MN:CR,FE:C;0) 273.00 -100000; 6000.00 N
REF:58 !
PARAMETER L(M23C6,FE,MN:CR,MN:C;0) 273.00 -100000; 6000.00 N
REF:58 !
PARAMETER L(M23C6,FE,MN:FE,MN:C;0) 273.00 -100000; 6000.00 N
REF:15 !
PARAMETER L(M23C6,FE:MO,W:C;0) 273.00 +1e-8; 6000.00 N
REF:pov14 !
PARAMETER L(M23C6,FE:MO,W:C;1) 273.00 +175000; 6000.00 N
REF:pov14 !
PARAMETER L(M23C6,FE:MO,W:C;2) 273.00 +1e-8; 6000.00 N
REF:pov14 !
$
PARAMETER L(M23C6,FE:FE:B,C;0) 273.00 -227000+80*T; 6000.00 N
REF:pov13 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MOC_ETA
$###########################################################################
$
PHASE MOC_ETA % 2 1 1 > hexagonal eta-carbide,
stable at high temperatures >> 2 !
CONSTITUENT MOC_ETA : MO : C%,VA : !
PARAMETER G(MOC_ETA,MO:C;0) 273.00 -9100-5.35*T
-750000*T**(-1)+GHSERMO#+GHSERCC#; 6000.00 N
REF:249 !
PARAMETER G(MOC_ETA,MO:VA;0) 273.00 +15200+0.63*T+GHSERMO#; 6000.00 N
REF:249 !
PARAMETER L(MOC_ETA,MO:C,VA;0) 273.00 -59000; 6000.00 N
REF:249 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: V3C2
$###########################################################################
$
PHASE V3C2 % 2 3 2 > >> 2 !
CONSTITUENT V3C2 : V : C : !
PARAMETER G(V3C2,V:C;0) 273.00 -260341+16.897*T+3*GHSERVV#
+2*GHSERCC#; 6000.00 N
REF:68 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: WC
$###########################################################################
$
PHASE WC % 2 1 1 > simple hexagonal >> 2 !
CONSTITUENT WC : MO,W : C : !
PARAMETER G(WC,MO:C;0) 273.00 -32983+2.5*T+GHSERMO#+GHSERCC#; 6000.00 N
REF:249 !
PARAMETER G(WC,W:C;0) 273.00 -58192+287.16*T-46.48*T*LN(T)-0.0021435*T**2
-9.2217E-8*T**3+590500*T**(-1); 6000.00 N
REF:79 !
PARAMETER L(WC,MO,W:C;0) 273.00 -2200; 6000.00 N
REF:250 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: EPS_CARB
$###########################################################################
$
PHASE EPS_CARB % 2 6 3 > stoichiometric metastable Fe2C epsilon phase,
hexagonal. Preliminary description. >> 3 !
CONSTITUENT EPS_CARB :AL,CO,CR,CU,FE%,MN,MO,NB,NI,SI,TI,V,W : C%,VA : !
PARAMETER G(EPS_CARB,FE:C;0) 273.00 +7500+60*T+2.25*GFECEM#; 6000.00 N
REF:pov13 !
$
PARAMETER G(EPS_CARB,AL:C;0) 273.00 +300000+6*GHSERAL#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,CO:C;0) 273.00 +300000+6*GHSERCO#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,CR:C;0) 273.00 +300000+6*GHSERCR#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,CU:C;0) 273.00 +500000+6*GHSERCU#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,MN:C;0) 273.00 +300000+6*GHSERMN#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,MO:C;0) 273.00 +300000+6*GHSERMO#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,NB:C;0) 273.00 +300000+6*GHSERNB#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,NI:C;0) 273.00 +300000+6*GHSERNI#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,SI:C;0) 273.00 +300000+6*GHSERSI#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,TI:C;0) 273.00 +300000+6*GHSERTI#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,V:C;0) 273.00 +300000+6*GHSERVV#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,W:C;0) 273.00 +300000+6*GHSERWW#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
$
PARAMETER G(EPS_CARB,AL:VA;0) 273.00 +300000+6*GHSERAL#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,CO:VA;0) 273.00 +300000+6*GHSERCO#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,CR:VA;0) 273.00 +300000+6*GHSERCR#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,CU:VA;0) 273.00 +500000+6*GHSERCU#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,FE:VA;0) 273.00 +300000+6*GHSERFE#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,MN:VA;0) 273.00 +300000+6*GHSERMN#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,MO:VA;0) 273.00 +300000+6*GHSERMO#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,NB:VA;0) 273.00 +300000+6*GHSERNB#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,NI:VA;0) 273.00 +300000+6*GHSERNI#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,SI:VA;0) 273.00 +300000+6*GHSERSI#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,TI:VA;0) 273.00 +300000+6*GHSERTI#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,V:VA;0) 273.00 +300000+6*GHSERVV#; 6000.00 N
REF:pov14 !
PARAMETER G(EPS_CARB,W:VA;0) 273.00 +300000+6*GHSERWW#; 6000.00 N
REF:pov14 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: ETA_CARB
$###########################################################################
$
PHASE ETA_CARB % 2 6 3 > orthorhombic metastable Fe2C.
Preliminary description. >> 2 !
CONSTITUENT ETA_CARB : AL,CO,CR,CU,FE%,MN,MO,NB,NI,SI,TI,V,W : C%,VA : !
PARAMETER G(ETA_CARB,FE:C;0) 273.00 -7500+100*T+2.25*GFECEM#; 6000.00 N
REF:pov13 !
$
PARAMETER G(ETA_CARB,AL:C;0) 273.00 +300000+6*GHSERAL#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,CO:C;0) 273.00 +300000+6*GHSERCO#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,CR:C;0) 273.00 +300000+6*GHSERCR#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,CU:C;0) 273.00 +500000+6*GHSERCU#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,MN:C;0) 273.00 +300000+6*GHSERMN#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,MO:C;0) 273.00 +300000+6*GHSERMO#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,NB:C;0) 273.00 +300000+6*GHSERNB#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,NI:C;0) 273.00 +300000+6*GHSERNI#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,SI:C;0) 273.00 +300000+6*GHSERSI#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,TI:C;0) 273.00 +300000+6*GHSERTI#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,V:C;0) 273.00 +300000+6*GHSERVV#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,W:C;0) 273.00 +300000+6*GHSERWW#
+3*GHSERCC#; 6000.00 N
REF:pov14 !
$
PARAMETER G(ETA_CARB,AL:VA;0) 273.00 +300000+6*GHSERAL#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,CO:VA;0) 273.00 +300000+6*GHSERCO#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,CR:VA;0) 273.00 +300000+6*GHSERCR#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,CU:VA;0) 273.00 +500000+6*GHSERCU#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,FE:VA;0) 273.00 +500000+6*GHSERFE#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,MN:VA;0) 273.00 +300000+6*GHSERMN#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,MO:VA;0) 273.00 +300000+6*GHSERMO#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,NI:VA;0) 273.00 +300000+6*GHSERNI#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,NB:VA;0) 273.00 +300000+6*GHSERNB#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,SI:VA;0) 273.00 +300000+6*GHSERSI#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,TI:VA;0) 273.00 +300000+6*GHSERTI#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,V:VA;0) 273.00 +300000+6*GHSERVV#; 6000.00 N
REF:pov14 !
PARAMETER G(ETA_CARB,W:VA;0) 273.00 +300000+6*GHSERWW#; 6000.00 N
REF:pov14 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: FE24C10
$###########################################################################
$
PHASE FE24C10 % 2 24 10 > nonstoichiometric metastable Fe2.4C
epsilon phase, hexagonal. Preliminary description. >> 4 !
CONSTITUENT FE24C10 :AL,CO,CR,CU,FE%,MN,MO,NB,NI,SI,TI,V,W : C%,VA : !
PARAMETER G(FE24C10,FE:C;0) 273.00 8.5*GFECEM#+130*T; 6000.00 N
REF:pov13 !
$
PARAMETER G(FE24C10,AL:C;0) 273.00 +300000+24*GHSERAL#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,CO:C;0) 273.00 +300000+24*GHSERCO#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,CR:C;0) 273.00 +300000+24*GHSERCR#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,CU:C;0) 273.00 +500000+24*GHSERCU#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,MN:C;0) 273.00 +300000+24*GHSERMN#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,MO:C;0) 273.00 +300000+24*GHSERMO#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,NB:C;0) 273.00 +300000+24*GHSERNB#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,NI:C;0) 273.00 +300000+24*GHSERNI#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,SI:C;0) 273.00 +300000+24*GHSERSI#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,TI:C;0) 273.00 +300000+24*GHSERTI#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,V:C;0) 273.00 +300000+24*GHSERVV#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,W:C;0) 273.00 +300000+24*GHSERWW#
+10*GHSERCC#; 6000.00 N
REF:pov14 !
$
PARAMETER G(FE24C10,AL:VA;0) 273.00 +300000+24*GHSERAL#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,CO:VA;0) 273.00 +300000+24*GHSERCO#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,CR:VA;0) 273.00 +300000+24*GHSERCR#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,CU:VA;0) 273.00 +500000+24*GHSERCU#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,FE:VA;0) 273.00 +300000+24*GHSERFE#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,MN:VA;0) 273.00 +300000+24*GHSERMN#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,MO:VA;0) 273.00 +300000+24*GHSERMO#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,NB:VA;0) 273.00 +300000+24*GHSERNB#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,NI:VA;0) 273.00 +300000+24*GHSERNI#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,SI:VA;0) 273.00 +300000+24*GHSERSI#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,TI:VA;0) 273.00 +300000+24*GHSERTI#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,V:VA;0) 273.00 +300000+24*GHSERVV#; 6000.00 N
REF:pov14 !
PARAMETER G(FE24C10,W:VA;0) 273.00 +300000+24*GHSERWW#; 6000.00 N
REF:pov14 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: KSI_FE5C2
$###########################################################################
$
PHASE KSI_FE5C2 % 2 5 2 > Metastable Fe5C2 Haegg phase, monoclinic.
Preliminary description. >> 2 !
CONSTITUENT KSI_FE5C2 :AL,CO,CR,CU,FE%,MN,MO,NB,NI,SI,TI,V,W : C%,VA : !
PARAMETER G(KSI_FE5C2,FE:C;0) 273.00 -5000+40*T+1.75*GFECEM#; 6000.00 N
REF:pov13 !
$
PARAMETER G(KSI_FE5C2,AL:C;0) 273.00 +300000+5*GHSERAL#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,CO:C;0) 273.00 +300000+5*GHSERCO#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,CR:C;0) 273.00 +300000+5*GHSERCR#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,CU:C;0) 273.00 +500000+5*GHSERCU#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,MN:C;0) 273.00 +300000+5*GHSERMN#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,MO:C;0) 273.00 +300000+5*GHSERMO#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,NB:C;0) 273.00 +300000+5*GHSERNB#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,NI:C;0) 273.00 +300000+5*GHSERNI#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,SI:C;0) 273.00 +300000+5*GHSERSI#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,TI:C;0) 273.00 +300000+5*GHSERTI#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,V:C;0) 273.00 +300000+5*GHSERVV#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,W:C;0) 273.00 +300000+5*GHSERWW#
+2*GHSERCC#; 6000.00 N
REF:pov14 !
$
PARAMETER G(KSI_FE5C2,AL:VA;0) 273.00 +300000+5*GHSERAL#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,CO:VA;0) 273.00 +300000+5*GHSERCO#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,CR:VA;0) 273.00 +300000+5*GHSERCR#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,CU:VA;0) 273.00 +500000+5*GHSERCU#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,FE:VA;0) 273.00 +300000+5*GHSERFE#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,MN:VA;0) 273.00 +300000+5*GHSERMN#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,MO:VA;0) 273.00 +300000+5*GHSERMO#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,NB:VA;0) 273.00 +300000+5*GHSERNB#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,NI:VA;0) 273.00 +300000+5*GHSERNI#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,SI:VA;0) 273.00 +300000+5*GHSERSI#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,TI:VA;0) 273.00 +300000+5*GHSERTI#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,V:VA;0) 273.00 +300000+5*GHSERVV#; 6000.00 N
REF:pov14 !
PARAMETER G(KSI_FE5C2,W:VA;0) 273.00 +300000+5*GHSERWW#; 6000.00 N
REF:pov14 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: ALN
$###########################################################################
$
PHASE ALN % 2 1 1 >
AlN phase description based on assessed solubility product,
specifically designed for applications to thermokinetic precipitation
simulations in microalloyed steels.
>> 4 !
CONSTITUENT ALN : AL : N : !
PARAMETER G(ALN,AL:N;0) 273.00 -262982+63*T+GHSERAL#+GHSERNN#; 6000.00 N
REF:236 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: ALN_EQU
$###########################################################################
$
PHASE ALN_EQU % 2 1 1 >
New phase description based on calorimetric data.
>> 4 !
CONSTITUENT ALN_EQU : AL,CR : N : !
PARAMETER G(ALN_EQU,AL:N;0) 273.00 -325000+290*T-46.94867*T*LN(T)
-0.00189068*T**(+2)+874528*T**(-1)+1.1756e-007*T**(+3); 6000.00 N
REF:pov11 !
PARAMETER G(ALN_EQU,CR:N;0) 273.00 -145000+290*T-46.94867*T*LN(T)
-0.00189068*T**(+2)+874528*T**(-1)+1.1756e-007*T**(+3); 6000.00 N
REF:pov12 !
PARAMETER L(ALN_EQU,AL,CR:N;0) 273.00 -50000; 6000.00 N
REF:pov12 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: BN_HP4
$###########################################################################
$
PHASE BN_HP4 % 2 1 1 >
Hexagonal Boron Nitride, graphite-type structure.
>> 4 !
CONSTITUENT BN_HP4 : B : N : !
PARAMETER G(BN_HP4,B:N;0) 273.00 -250600.0+91.281942*T+GHSERBB#
+GHSERNN#; 6000.00 N
REF:92 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: FE4N
$###########################################################################
$
PHASE FE4N % 2 4 1 > >> 1 !
CONSTITUENT FE4N : CR,FE%,MN,NI : N : !
PARAMETER G(FE4N,CR:N;0) 273.00 -135240+717.87*T-127.18*T*LN(T)
-0.002899*T**2+450231*T**(-1)-1.0968E-06*T**3; 6000.00 N
REF:22 !
PARAMETER G(FE4N,FE:N;0) 273.00 -38744+73.52*T+4*GHSERFE#
+GHSERNN#; 6000.00 N
REF:64 !
PARAMETER G(FE4N,MN:N;0) 273.00 -155790+691.0638*T-126.9328*T*LN(T)
+307417*T**(-1); 2500.00 N
REF:66 !
PARAMETER G(FE4N,NI:N;0) 273.00 -5393+142.97*T-15.65*T*LN(T)
+0.0154*T**2+4*GHSERNI#+GHSERNN#; 6000.00 N
REF:67 !
PARAMETER L(FE4N,FE,MN:N;0) 273.00 +36297-28.8876*T; 6000.00 N
REF:22 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MN6N4
$###########################################################################
$
PHASE MN6N4 % 2 6 4 > >> 1 !
CONSTITUENT MN6N4 : MN : N : !
PARAMETER G(MN6N4,MN:N;0) 273.00 -465614+1428.332*T-251.337*T*LN(T)
+1027898*T**(-1); 6000.00 N
REF:66 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MN6N5
$###########################################################################
$
PHASE MN6N5 % 2 6 5 > >> 1 !
CONSTITUENT MN6N5 : MN : N : !
PARAMETER G(MN6N5,MN:N;0) 273.00 -546880+1591.607*T-276.668*T*LN(T)
+1297983*T**(-1); 6000.00 N
REF:66 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MNSIN2
$###########################################################################
$
PHASE MNSIN2 % 3 0.25 0.25 0.5 >
Precipitate in electrical steels
>> 1 !
CONSTITUENT MNSIN2 : MN : SI : N : !
PARAMETER G(MNSIN2,MN:SI:N;0) 273.00 0.25*GHSERMN#+0.25*GHSERSI#
+0.5*GHSERNN#-86500+43*T; 6000.00 N
REF:pov12 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: SI3N4
$###########################################################################
$
PHASE SI3N4 % 2 3 4 >
Important precipitate in electrical steels containing 2.5 to 4 wt.% Si
>> 2 !
CONSTITUENT SI3N4 : SI : N : !
PARAMETER G(SI3N4,SI:N;0) 273.00 -788513.0009+733.225*T-121.79*T*LN(T)
-0.02065*T**2+1666886.4*T**(-1)+6.9938E-7*T**3; 6000.00 N
REF:158 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: ZET
$###########################################################################
$
$------------------------------------------------------------------------
$ newer Z-phase assessment by Hilmar Danielsen from 2006-11-01
$------------------------------------------------------------------------
PHASE ZET % 3 1 1 1 >
Cr-Fe-Nb-V-Mo nitride. Important precipitate in austenitic stainless steels.
Also found in 9-12 mass.% Cr-steels after prolonged exposure to temperatures
close to service temperatures.
>> 3 !
CONSTITUENT ZET : CR%,FE : NB,MO,V : N%,VA : !
PARAMETER G(ZET,CR:MO:N;0) 273.00 +GHSERCR#+GHSERMO#+GHSERNN#; 6000.00 N
REF:71 !
PARAMETER G(ZET,CR:MO:VA;0) 273.00 +GHSERCR#+GHSERMO#+20000; 6000.00 N
REF:pov13 !
PARAMETER G(ZET,CR:NB:N;0) 273.00 -228500+85*T+GHSERCR#
+GHSERNB#+GHSERNN#; 6000.00 N
REF:71 !
PARAMETER G(ZET,CR:NB:VA;0) 273.00 +GHSERCR#+GHSERNB#; 6000.00 N
REF:71 !
PARAMETER G(ZET,CR:V:N;0) 273.00 -239500+100*T+GHSERCR#
+GHSERVV#+GHSERNN#; 6000.00 N
REF:71 !
PARAMETER G(ZET,CR:V:VA;0) 273.00 +GHSERCR#+GHSERVV#; 6000.00 N
REF:71 !
PARAMETER G(ZET,FE:MO:N;0) 273.00 +GHSERFE#+GHSERMO#+GHSERNN#; 6000.00 N
REF:71 !
PARAMETER G(ZET,FE:MO:VA;0) 273.00 +GHSERFE#+GHSERMO#; 6000.00 N
REF:71 !
PARAMETER G(ZET,FE:NB:N;0) 273.00 -88000+60*T+GHSERFE#
+GHSERNB#+GHSERNN#; 6000.00 N
REF:71 !
PARAMETER G(ZET,FE:NB:VA;0) 273.00 +GHSERFE#+GHSERNB#; 6000.00 N
REF:71 !
PARAMETER G(ZET,FE:V:N;0) 273.00 -56000+80*T+GHSERFE#
+GHSERVV#+GHSERNN#; 6000.00 N
REF:71 !
PARAMETER G(ZET,FE:V:VA;0) 273.00 +GHSERFE#+GHSERVV#; 6000.00 N
REF:71 !
$----------------------Interaction parameters----------------------
PARAMETER L(ZET,CR:MO,NB:N;0) 273.00 -168000+100*T; 6000.00 N
REF:71 !
PARAMETER L(ZET,CR:NB:N,VA;0) 273.00 -64000; 6000.00 N
REF:71 !
PARAMETER L(ZET,CR:V:N,VA;0) 273.00 -87000; 6000.00 N
REF:71 !
PARAMETER L(ZET,CR,FE:NB:N;0) 273.00 -270000+100*T; 6000.00 N
REF:71 !
PARAMETER L(ZET,CR,FE:V:N;0) 273.00 -260000+100*T; 6000.00 N
REF:71 !
PARAMETER L(ZET,FE:V:N,VA;0) 273.00 -87000; 6000.00 N
REF:71 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: CRB
$###########################################################################
$
PHASE CRB % 2 0.5 0.5 >
Orthorhombic, space group Cmcm.
>> 2 !
CONSTITUENT CRB : CR%,FE,NI : B% : !
PARAMETER G(CRB,CR:B;0) 273.00 +0.5*GHSERCR#+0.5*GHSERBB#
-55000+9*T+0.1*T*LN(T)+2E-4*T**2; 6000.00 N
REF:pov12 !
PARAMETER G(CRB,FE:B;0) 273.00 +0.5*GHSERFE#+0.5*GHSERBB#
-34200+22*T; 6000.00 N
REF:145 !
PARAMETER G(CRB,NI:B;0) 273.00 +0.5*GHSERNI#+0.5*GHSERBB#
-20865.7+1.67458*T; 6000.00 N
REF:190 !
PARAMETER L(CRB,CR,FE:B;0) 273.00 +12000-39*T; 6000.00 N
REF:145 !
PARAMETER L(CRB,CR,FE:B;1) 273.00 -29000+23*T; 6000.00 N
REF:145 !
PARAMETER L(CRB,CR,FE:B;2) 273.00 +25000-5*T; 6000.00 N
REF:145 !
PARAMETER L(CRB,FE,NI:B;0) 273.00 +7000; 6000.00 N
REF:192 !
PARAMETER L(CRB,CR,NI:B;0) 273.00 +7000; 6000.00 N
REF:POV12 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: CR2B
$###########################################################################
$
PHASE CR2B % 2 0.666667 0.333333 >
Orthorhombic.
>> 1 !
CONSTITUENT CR2B : CR%,FE,MN : B : !
PARAMETER G(CR2B,CR:B;0) 273.00 +0.6666667*GHSERCR#+0.3333333*GHSERBB#
-37550+2.53*T+0.1*T*LN(T)+6E-4*T**2; 6000.00 N
REF:145 !
PARAMETER G(CR2B,FE:B;0) 273.00 +0.6666667*GHSERFE#+0.3333333*GHSERBB#
-20000+3*T; 6000.00 N
REF:POV12 !
PARAMETER G(CR2B,MN:B;0) 273.00 +0.666667*GHSERMN#+0.333333*GHSERBB#
-31651.9-6.17*T; 6000.00 N
REF:pov14 !
PARAMETER L(CR2B,CR,FE:B;0) 273.00 -12000-6.5*T; 6000.00 N
REF:145 !
PARAMETER L(CR2B,CR,FE:B;1) 273.00 -62000+43*T; 6000.00 N
REF:145 !
PARAMETER L(CR2B,CR,FE:B;2) 273.00 +20000-18*T; 6000.00 N
REF:145 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: CR5B3
$###########################################################################
$
PHASE CR5B3 % 2 0.625 0.375 > >> 1 !
CONSTITUENT CR5B3 : CR : B : !
PARAMETER G(CR5B3,CR:B;0) 273.00 +0.625*GHSERCR#+0.375*GHSERBB#
-41950+0.65*T+0.5*T*LN(T)+5E-4*T**2; 6000.00 N
REF:145 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: FEB
$###########################################################################
$
TYPE_DEFINITION ^ GES A_P_D FEB MAGNETIC -3.0 0.28 !
PHASE FEB %^ 2 0.5 0.5 >
Orthorhombic, space group Pnma.
>> 1 !
CONSTITUENT FEB : CR,FE%,MN,NI : B: !
PARAMETER G(FEB,FE:B;0) 273.00 -33000+6.35*T
+0.5*GHSERFE#+0.5*GHSERBB#; 6000.00 N
REF:192 !
PARAMETER G(FEB,CR:B;0) 273.00 +0.5*GHSERFE#+0.5*GHSERBB#
-28000+3*T; 6000.00 N
REF:pov12 !
PARAMETER G(FEB,MN:B;0) 273.00 +0.5*GHSERMN#+0.5*GHSERBB#
-35800-9.9995*T; 6000.00 N
REF:245 !
PARAMETER G(FEB,NI:B;0) 273.00 +0.5*GHSERNI#+0.5*GHSERBB#
-16365.7+1.67458*T; 6000.00 N
REF:192 !
PARAMETER L(FEB,CR,FE:B;0) 273.00 -40000+7*T; 6000.00 N
REF:145 !
PARAMETER L(FEB,CR,FE:B;1) 273.00 +5000-18*T; 6000.00 N
REF:145 !
PARAMETER L(FEB,FE,NI:B;0) 273.00 +6000; 6000.00 N
REF:192 !
$
PARAMETER TC(FEB,FE:B;0) 273.00 +600; 6000.00 N
REF:192 !
PARAMETER BMAGN(FEB,FE:B;0) 273.00 +1.03; 6000.00 N
REF:192 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: FENBB
$###########################################################################
$
PHASE FENBB % 3 1 1 1 > >> 1 !
CONSTITUENT FENBB : FE :NB :B : !
PARAMETER G(FENBB,FE:NB:B;0) 273.00 +GHSERBB#+GHSERFE#+GHSERNB#
-157500-6*T; 6000.00 N
REF:146 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: FE3NB3B4
$###########################################################################
$
PHASE FE3NB3B4 % 3 3 3 4 > >> 1 !
CONSTITUENT FE3NB3B4 : FE :NB :B : !
PARAMETER G(FE3NB3B4,FE:NB:B;0) 273.00 +4*GHSERBB#+3*GHSERFE#+3*GHSERNB#
-580000+10*T; 6000.00 N
REF:146 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: M2B
$###########################################################################
$
TYPE_DEFINITION A GES A_P_D M2B MAGNETIC -3.0 0.28 !
PHASE M2B %A 2 0.666667 0.333333 >
Tetragonal.
>> 2 !
CONSTITUENT M2B : CR,FE,MN,MO,NI : B : !
PARAMETER G(M2B,CR:B;0) 273.00 +0.6666667*GHSERCR#+0.3333333*GHSERBB#
-32000+7.6*T; 6000.00 N
REF:145 !
PARAMETER G(M2B,FE:B;0) 273.00 -24175+3.62*T+0.667*GHSERFE#
+0.333*GHSERBB#; 6000.00 N
REF:192 !
PARAMETER G(M2B,MN:B;0) 273.00 +0.666667*GHSERMN#+0.333333*GHSERBB#
-31700-6.4802*T; 6000.00 N
REF:245 !
PARAMETER G(M2B,MO:B;0) 273.00 +0.33333*GHSERBB#+0.66667*GHSERMO#
-42176+2*T; 6000.00 N
REF:118 !
PARAMETER G(M2B,NI:B;0) 273.00 +0.33333*GHSERBB#+0.66667*GHSERNI#
-24100.7555+4.01743184*T; 6000.00 N
REF:161 !
PARAMETER L(M2B,CR,FE:B;0) 273.00 -42000+12*T; 6000.00 N
REF:145 !
PARAMETER L(M2B,CR,FE:B;1) 273.00 -94000+75*T; 6000.00 N
REF:145 !
PARAMETER L(M2B,CR,FE:B;2) 273.00 -46500+9.15*T; 6000.00 N
REF:145 !
PARAMETER L(M2B,CR,NI:B;0) 273.00 +50000; 6000.00 N
REF:pov12 !
PARAMETER L(M2B,FE,MN:B;0) 273.00 -25000+22*T; 6000.00 N
REF:pov14 !
PARAMETER L(M2B,FE,MO:B;0) 273.00 +50000; 6000.00 N
REF:pov14 !
PARAMETER L(M2B,FE,NI:B;0) 273.00 -36800+19.4*T; 6000.00 N
REF:192 !
$
PARAMETER TC(M2B,FE:B;0) 273.00 +1018; 6000.00 N
REF:192 !
PARAMETER BMAGN(M2B,FE:B;0) 273.00 +1.91; 6000.00 N
REF:192 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MNB2
$###########################################################################
$
PHASE MNB2 % 2 0.333333 0.666667 >
Hexagonal, space group P6/mmm.
>> 1 !
CONSTITUENT MNB2 : MN : B : !
PARAMETER G(MNB2,MN:B;0) 273.00 +0.333333*GHSERMN#
+0.666667*GHSERBB#-21100-12.556*T; 6000.00 N
REF:245 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MNB4
$###########################################################################
$
PHASE MNB4 % 2 0.2 0.8 !
CONSTITUENT MNB4 : MN : B : > >> 1 !
PARAMETER G(MNB4,MN:B;0) 273.00 +0.2*GHSERMN#
+0.8*GHSERBB#-17744.3-4.5934*T; 6000.00 N
REF:245 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: O_MN2B
$###########################################################################
$
PHASE O_MN2B % 2 0.670691 0.329309 >
Orthorhombic.
>> 1 !
CONSTITUENT O_MN2B : MN : B : !
PARAMETER G(O_MN2B,MN:B;0) 273.00 +0.670691*GHSERMN#+0.329309*GHSERBB#
-31651.9-6.17*T; 6000.00 N
REF:245 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MN3B4
$###########################################################################
$
PHASE MN3B4 % 2 0.428571 0.571429 >
Orthorhombic, space group Immm.
>> 1 !
CONSTITUENT MN3B4 : MN : B : !
PARAMETER G(MN3B4,MN:B;0) 273.00 +0.428571*GHSERMN#
+0.571429*GHSERBB#-38786.7-6.9904*T; 6000.00 N
REF:245 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MOB
$###########################################################################
$
PHASE MOB % 2 0.5 0.5 > >> 2 !
CONSTITUENT MOB : MO : B : !
PARAMETER G(MOB,MO:B;0) 273.00 +0.5*GHSERMO#+0.5*GHSERBB#
-52017+0.21*T; 6000.00 N
REF:118 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MOB2
$###########################################################################
$
PHASE MOB2 % 2 1 2 > >> 1 !
CONSTITUENT MOB2 : MO : B%,VA : !
PARAMETER G(MOB2,MO:B;0) 273.00 +2*GHSERBB#+GHSERMO#
-123803-1.25*T; 6000.00 N
REF:118 !
PARAMETER G(MOB2,MO:VA;0) 273.00 +GHSERMO#+13106; 6000.00 N
REF:118 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MO2M1B2
$###########################################################################
$
PHASE MO2M1B2 % 3 2 1 2 > tetragonal, space group P4/mbm >> 2 !
CONSTITUENT MO2M1B2 : MO : CR,FE : B : !
PARAMETER G(MO2M1B2,MO:CR:B;0) 273.00 +2*GHSERBB#+2*GHSERMO#
+GHSERCR#-230000; 6000.00 N
REF:pov14 !
PARAMETER G(MO2M1B2,MO:FE:B;0) 273.00 +2*GHSERBB#+2*GHSERMO#
+GHSERFE#-216000; 6000.00 N
REF:pov14 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NBB
$###########################################################################
$
PHASE NBB % 2 1 1 > >> 1 !
CONSTITUENT NBB : NB : B%,NB : !
PARAMETER G(NBB,NB:B;0) 273.00 +GHSERNB#+GHSERBB#-157380
-21.8*T+3.381*T*LN(T)-1.953E-4*T**2; 6000.00 N
REF:117 !
PARAMETER G(NBB,NB:NB;0) 273.00 +2*GHSERNB#+75000; 6000.00 N
REF:117 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NB3B2
$###########################################################################
$
PHASE NB3B2 % 2 3 2 > >> 1 !
CONSTITUENT NB3B2 : FE,NB% : B : !
PARAMETER G(NB3B2,NB:B;0) 273.00 +3*GHSERNB#+2*GHSERBB#-372301
-53.233*T+11.662*T*LN(T)-2.276E-3*T**2; 6000.00 N
REF:117 !
PARAMETER G(NB3B2,FE:B;0) 273.00 +3*GHSERFE#+2*GHSERBB#
-114000+31.5*T; 6000.00 N
REF:146 !
PARAMETER L(NB3B2,FE,NB:B;0) 273.00 -197500-34*T; 6000.00 N
REF:146 !
PARAMETER L(NB3B2,FE,NB:B;1) 273.00 +85000+151*T; 6000.00 N
REF:146 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: NB5B6
$###########################################################################
$
PHASE M5B6 % 2 5 6 >
Orthorhombic, space group Cmmm.
>> 1 !
CONSTITUENT M5B6 : FE,NB,V : B : !
PARAMETER G(M5B6,FE:B;0) 273.00 +5*GHSERFE#+6*GHSERBB#+55000; 6000.00 N
REF:235 !
PARAMETER G(M5B6,NB:B;0) 273.00 +5*GHSERNB#+6*GHSERBB#-886400
-87.40*T+13.75*T*LN(T)+8.756E-4*T**2; 6000.00 N
REF:117 !
PARAMETER G(M5B6,V:B;0) 273.00 +5*GHSERVV#+6*GHSERBB#
-746554+69.7719*T; 6000.00 N
REF:235 !
PARAMETER L(M5B6,FE,V:B;0) 273.00 -472615+42.35*T; 6000.00 N
REF:235 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: TIB
$###########################################################################
$
PHASE TIB % 2 1 1 >
Orthorhombic, space group Pnma.
>> 1 !
CONSTITUENT TIB : TI : B%,TI : !
PARAMETER G(TIB,TI:B;0) 273.00 +GHSERBB#+GHSERTI#-165000-67.317*T+9.5*T*LN(T)
-5e-4*T**2; 6000.00 N
REF:117 !
PARAMETER G(TIB,TI:TI;0) 273.00 +40000+2*GHSERTI#; 6000.00 N
REF:117 !
PARAMETER L(TIB,TI:B,TI;0) 273.00 -37503+29.790*T; 6000.00 N
REF:117 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: TIB2
$###########################################################################
$
$ hexagonal solution phase
$ note: due to model translation for CrB2 (originally 0.3333:0.66667)
$ slight change of configurational entropy
$ simplified model without Va on sublattice 1
$
PHASE TIB2 % 2 1 2 >
Hexagonal, space group P6/mmm.
>> 1 !
CONSTITUENT TIB2 : B,CR%,FE,TI% : B%,CR,FE,TI,VA : !
$PARAMETER G(TIB2,B:B;0) 273.00 +100000+3*GHSERBB#; 6000.00 N
$REF:144 !
PARAMETER G(TIB2,B:B;0) 273.00 +89628+3*GHSERBB#; 6000.00 N
REF:117 !
PARAMETER G(TIB2,B:CR;0) 273.00 +2*GHSERCR#+GHSERBB#; 6000.00 N
REF:pov09 !
PARAMETER G(TIB2,B:FE;0) 273.00 +2*GHSERFE#+GHSERBB#; 6000.00 N
REF:pov12 !
PARAMETER G(TIB2,B:TI;0) 273.00 +2*GHSERTI#+GHSERBB#; 6000.00 N
REF:117 !
PARAMETER G(TIB2,CR:B;0) 273.00 -109980+0.78*T+0.12*T*LN(T)
+0.0009*T**2; 6000.00 N
REF:145 !
PARAMETER G(TIB2,CR:CR;0) 273.00 +18000+3*GHSERCR#; 6000.00 N
REF:pov09 !
PARAMETER G(TIB2,CR:VA;0) 273.00 +GHSERCR#+150000; 6000.00 N
REF:145 !
PARAMETER G(TIB2,FE:B;0) 273.00 +2*GHSERBB#+GHSERFE#+15000; 6000.00 N
REF:235 !
PARAMETER G(TIB2,FE:FE;0) 273.00 +18000+3*GHSERFE#; 6000.00 N
REF:pov12 !
PARAMETER G(TIB2,FE:VA;0) 273.00 +GHSERFE#+150000; 6000.00 N
REF:pov12 !
PARAMETER G(TIB2,TI:B;0) 273.00 +2*GHSERBB#+GHSERTI#-329000+1.865*T
+1.2547*T*LN(T)+3.131E-3*T**2-4.105E-7*T**3; 6000.00 N
REF:117 !
PARAMETER G(TIB2,TI:TI;0) 273.00 +18000+3*GHSERTI#; 6000.00 N
REF:117 !
PARAMETER G(TIB2,TI:VA;0) 273.00 +GHSERTI#+150000; 6000.00 N
REF:pov09 !
$----------------------Interaction parameters----------------------
PARAMETER L(TIB2,B:B,TI;0) 273.00 -18500+53.211*T; 6000.00 N
REF:117 !
PARAMETER L(TIB2,TI:B,TI;0) 273.00 -18500+53.211*T; 6000.00 N
REF:117 !
PARAMETER L(TIB2,B,TI:B;0) 273.00 +91514+46.777*T; 6000.00 N
REF:117 !
PARAMETER L(TIB2,B,TI:TI;0) 273.00 -91514+46.777*T; 6000.00 N
REF:117 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: TI3B4
$###########################################################################
$
PHASE TI3B4 % 2 3 4 >
Orthorhombic, space group Immm.
>> 1 !
CONSTITUENT TI3B4 : CR,FE,NB,TI% : B : !
PARAMETER G(TI3B4,CR:B;0) 273.00 -357000+18.2*T+3.5*T*LN(T)+0.0021*T**2
+4*GHSERBB#+3*GHSERCR#; 6000.00 N
REF:145 !
PARAMETER G(TI3B4,FE:B;0) 273.00 +35000+4*GHSERBB#+3*GHSERCR#; 6000.00 N
REF:235 !
PARAMETER G(TI3B4,NB:B;0) 273.00 -571700-35.515*T+5.807*T*LN(T)
+1.671E-3*T**2+4*GHSERBB#+3*GHSERNB#; 6000.00 N
REF:117 !
$PARAMETER G(TI3B4,TI:B;0) 273.00 -700300+15.99*T+5.44*T*LN(T)
$ +4*GHSERBB#+3*GHSERTI#; 6000.00 N
$REF:144 !
PARAMETER G(TI3B4,TI:B;0) 273.00 -660000-162.241*T+25*T*LN(T)-2E-3*T**2
+4*GHSERBB#+3*GHSERTI#; 6000.00 N
REF:117 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: A_CHALC
$###########################################################################
$
PHASE A_CHALC % 2 2 1 >
Hexagonal close-packed Cu2S, A-chalcosite.
>> 1 !
CONSTITUENT A_CHALC : CU : S : !
PARAMETER G(A_CHALC,CU:S;0) 273.00 +2*GHSERCU#+GHSERSS#
-78474.5-83.8534*T+7.2618*T*LN(T); 3000.00 N
REF:82 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: ANILITE
$###########################################################################
$
PHASE ANILITE % 2 1.75 1 > >> 1 !
CONSTITUENT ANILITE : CU : S : !
PARAMETER G(ANILITE,CU:S;0) 273.00 +1.75*GHSERCU#+GHSERSS#
-76000.8-22.78185*T; 3000.00 N
REF:82 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: B_CHALC
$###########################################################################
$
PHASE B_CHALC % 2 2 1 >
Cu2S, B-chalcosite.
>> 1 !
CONSTITUENT B_CHALC : CU : S : !
PARAMETER G(B_CHALC,CU:S;0) 273.00 +2*GHSERCU#+GHSERSS#
-79412-56.4306*T+3.0602*T*LN(T); 3000.00 N
REF:82 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: COVELLITE
$###########################################################################
$
PHASE COVELLITE % 2 1 1 > >> 1 !
CONSTITUENT COVELLITE : CU : S : !
PARAMETER G(COVELLITE,CU:S;0) 273.00 +GHSERCU#+GHSERSS#
-52804.7-6.6291*T; 3000.00 N
REF:82 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: CU2S
$###########################################################################
$
PHASE CU2S % 3 2 1 1 >
Use for thermo-kinetic simulations in low-carbon steels.
Fcc-structured, but with coherency in ferritic matrix due to preferred
cube-cube orientation relationship. Strengthening of nano-sized
Cu2S precipitates in strip cast low carbon steel.
>> 2 !
CONSTITUENT CU2S : CU%,FE : S : S,VA% : !
PARAMETER G(CU2S,CU:S:VA;0) 273.00 +GDIG#; 6000.00 N
REF:82 !
PARAMETER G(CU2S,FE:S:VA;0) 273.00 -20000+2*GHSERFE#
+GHSERSS#; 3000.00 N
REF:pov15 !
PARAMETER G(CU2S,CU:S:S;0) 273.00 -82000+GDIG#+GHSERSS#; 6000.00 N
REF:pov15 !
PARAMETER G(CU2S,FE:S:S;0) 273.00 -20000+2*GHSERFE#+2*GHSERSS#; 6000.00 N
REF:pov15 !
PARAMETER L(CU2S,CU,FE:S:VA;0) 273.00 -200000; 6000.00 N
REF:pov15 !
PARAMETER L(CU2S,CU,FE:S:VA;1) 273.00 +150000; 6000.00 N
REF:pov15 !
PARAMETER L(CU2S,CU,FE:S:VA;2) 273.00 -100000; 6000.00 N
REF:pov15 !
PARAMETER L(CU2S,CU,FE:S:S;0) 273.00 -150000; 6000.00 N
REF:pov15 !
PARAMETER L(CU2S,CU,FE:S:S;1) 273.00 -150000; 6000.00 N
REF:pov15 !
PARAMETER L(CU2S,CU,FE:S:S;2) 273.00 -150000; 6000.00 N
REF:pov15 !
PARAMETER L(CU2S,CU:S:S,VA;0) 273.00 -165000; 6000.00 N
REF:pov15 !
PARAMETER L(CU2S,FE:S:S,VA;0) 273.00 -150000; 6000.00 N
REF:pov15 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: DIGENITE
$###########################################################################
$
PHASE DIGENITE % 3 2 1 1 >
Use for equilibrium calculation only.
>> 1 !
CONSTITUENT DIGENITE : CU%,FE,VA : CU,VA% : S : !
PARAMETER G(DIGENITE,CU:CU:S;0) 273.00 +3*GHSERCU#+GHSERSS#
-49.382*T; 6000.00 N
REF:82 !
PARAMETER G(DIGENITE,FE:CU:S;0) 273.00 +2*GHSERFE#+GHSERCU#
+GHSERSS#; 6000.00 N
REF:82 !
PARAMETER G(DIGENITE,VA:CU:S;0) 273.00 +GHSERCU#+GHSERSS#+100000; 6000.00 N
REF:82 !
PARAMETER G(DIGENITE,CU:VA:S;0) 273.00 +GDIG#; 6000.00 N
REF:82 !
PARAMETER G(DIGENITE,FE:VA:S;0) 273.00 +2*GHSERFE#+GHSERSS#; 6000.00 N
REF:82 !
PARAMETER G(DIGENITE,VA:VA:S;0) 273.00 +GHSERSS#+105281; 6000.00 N
REF:82 !
$----------------------Interaction parameters----------------------
PARAMETER L(DIGENITE,CU,VA:VA:S;0) 273.00 -154893+51.3874*T; 6000.00 N
REF:82 !
PARAMETER L(DIGENITE,CU,FE:VA:S;0) 273.00 -81000; 6000.00 N
REF:82 !
PARAMETER L(DIGENITE,CU,FE,VA:VA:S;0) 273.00 -900000; 6000.00 N
REF:82 !
PARAMETER L(DIGENITE,FE,VA:VA:S;0) 273.00 -550000; 6000.00 N
REF:82 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: DISULF
$###########################################################################
$
PHASE DISULF % 2 1 2 >
Pyrite, FeS2.
>> 1 !
CONSTITUENT DISULF : FE : S : !
PARAMETER G(DISULF,FE:S;0) 273.00 +GHSERFE#+2*GHSERSS#
-177763+48.567*T; 6000.00 N
REF:82 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: DJURLEITE
$###########################################################################
$
PHASE DJURLEITE % 2 1.93 1 > >> 1 !
CONSTITUENT DJURLEITE : CU : S : !
PARAMETER G(DJURLEITE,CU:S;0) 273.00 +1.93*GHSERCU#+GHSERSS#
-79718.6-30.97899*T; 3000.00 N
REF:82 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: FC_MONO
$###########################################################################
$
PHASE FC_MONO % 1 1 >
Monoclinic sulfur (high T)
>> 1 !
CONSTITUENT FC_MONO : S : !
PARAMETER G(FC_MONO,S;0) 273.00 +GHSERSS#+188.29+2.8932*T
-0.57614*T*LN(T); 1300.00 N
REF:0 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: FES_P
$###########################################################################
$
PHASE FES_P % 2 1 1 >
Fe-rich Fe,Mn-sulfide.
>> 1 !
CONSTITUENT FES_P : FE%,MN : S : !
PARAMETER G(FES_P,FE:S;0) 273.00 -71292-201.349*T+24.2116*T*LN(T)
-0.003402*T**2+GHSERFE#+GHSERSS#; 6000.00 N
REF:81 !
PARAMETER G(FES_P,MN:S;0) 273.00 -174952-368.385*T+48.2649*T*LN(T)
-0.01153*T**2+GHSERMN#+GHSERSS#; 6000.00 N
REF:81 !
PARAMETER L(FES_P,FE,MN:S;0) 273.00 +8500; 6000.00 N
REF:81 !
PARAMETER L(FES_P,FE,MN:S;1) 273.00 +5500; 6000.00 N
REF:81 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: MNS_Q
$###########################################################################
$
PHASE MNS_Q % 2 1 1 >
Mn-rich relevant Fe,Mn-sulfide precipitates in low Carbon steels.
Interactions between MnS_Q and Cu2S precipitates are important.
>> 2 !
CONSTITUENT MNS_Q : CU,FE,MN% : S : !
PARAMETER G(MNS_Q,CU:S;0) 273.00 +GHSERCU#+GHSERSS#; 6000.00 N
REF:pov09 !
PARAMETER G(MNS_Q,FE:S;0) 273.00 -70100-201.349*T+24.2116*T*LN(T)
-0.003402*T**2+GHSERFE#+GHSERSS#; 6000.00 N
REF:81 !
PARAMETER G(MNS_Q,MN:S;0) 273.00 -182867-368.385*T+48.2648*T*LN(T)
-0.01153*T**2+GHSERMN#+GHSERSS#; 6000.00 N
REF:81 !
PARAMETER L(MNS_Q,CU,FE:S;0) 273.00 -110000; 6000.00 N
REF:pov09 !
PARAMETER L(MNS_Q,CU,FE:S;1) 273.00 +1E-8; 6000.00 N
REF:pov09 !
PARAMETER L(MNS_Q,CU,MN:S;0) 273.00 -110000; 6000.00 N
REF:pov09 !
PARAMETER L(MNS_Q,CU,MN:S;1) 273.00 +1e-8; 6000.00 N
REF:pov09 !
PARAMETER L(MNS_Q,FE,MN:S;0) 273.00 +8500; 6000.00 N
REF:81 !
PARAMETER L(MNS_Q,FE,MN:S;1) 273.00 +5500; 6000.00 N
REF:81 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: PYRR
$###########################################################################
$
PHASE PYRR % 2 1 1 >
(Cu,Fe)S pyrrhotite, hexagonal close-packed,
for thermodynamic equilibrium calculations only.
>> 1 !
CONSTITUENT PYRR : CU,FE,VA : S : !
PARAMETER G(PYRR,CU:S;0) 273.00 +GHSERCU#+GHSERSS#; 1350.00 N
REF:82 !
PARAMETER G(PYRR,FE:S;0) 273.00 +GHSERFE#+GHSERSS#-107518
-18.19*T+1.78*T*LN(T); 1350.00 N
REF:82 !
PARAMETER G(PYRR,VA:S;0) 273.00 +GHSERSS#+258600; 3000.00 N
REF:82 !
$----------------------Interaction parameters----------------------
PARAMETER L(PYRR,CU,FE:S;0) 273.00 -90000; 3000.00 N
REF:82 !
PARAMETER L(PYRR,FE,VA:S;0) 273.00 -407000+10*T; 3000.00 N
REF:82 !
PARAMETER L(PYRR,FE,VA:S;1) 273.00 +60000+20*T; 3000.00 N
REF:82 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: TIS
$###########################################################################
$
PHASE TIS % 2 1 1 >
Minor role as precipitate in ultra-low carbon steel.
>> 1 !
CONSTITUENT TIS : TI : S : !
PARAMETER G(TIS,TI:S;0) 273.00 +GHSERTI#+GHSERSS#
-87724-125.24*T; 3000.00 N
REF:pov09 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: TI4C2S2
$###########################################################################
$
PHASE TI4C2S2 % 3 4 2 2 >
Main Ti-Carbosulfide precipitate in ultra-low carbon steel.
>> 2 !
CONSTITUENT TI4C2S2 : TI : C : S : !
PARAMETER G(TI4C2S2,TI:C:S;0) 273.00 +4*GHSERTI#+2*GHSERCC#+2*GHSERSS#
-449804-348*T; 3000.00 N
REF:pov09 !
$
$###########################################################################
$ THERMODYNAMIC PARAMETERS: OXIDE PHASES
$###########################################################################
$
TYPE_DEFINITION R GES A_P_D CORUND MAGNETIC -3.0 0.28 !
PHASE CORUND %R 2 2 3 > corund-structured (Al,Cr,Fe)2O3 >> 3 !
CONSTITUENT CORUND :AL,CR%,FE%,NI : O : !
PARAMETER G(CORUND,AL:O;0) 273.00 +GAL2O3#; 6000.00 N
REF:200 !
PARAMETER G(CORUND,CR:O;0) 273.00 +GCR2O3#; 6000.00 N
REF:198 !
PARAMETER G(CORUND,FE:O;0) 273.00 +GFE2O3#; 6000.00 N
REF:221 !
PARAMETER G(CORUND,NI:O;0) 273.00 +2*GHSERNI#
+3*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER L(CORUND,CR,FE:O;0) 273.00 -100000+50*T; 6000.00 N
REF:pov12 !
PARAMETER L(CORUND,AL,CR:O;0) 273.00 +120000-50*T; 6000.00 N
REF:pov12 !
PARAMETER L(CORUND,AL,FE:O;0) 273.00 +100000; 6000.00 N
REF:pov12 !
PARAMETER L(CORUND,AL,NI:O;0) 273.00 +200000; 6000.00 N
REF:pov12 !
PARAMETER TC(CORUND,CR:O;0) 273.00 308.6; 6000.00 N
REF:198 !
PARAMETER BMAGN(CORUND,CR:O;0) 273.00 3; 6000.00 N
REF:198 !
PARAMETER TC(CORUND,FE:O;0) 273.00 -2867; 6000.00 N
REF:221 !
PARAMETER BMAGN(CORUND,FE:O;0) 273.00 -25.1; 6000.00 N
REF:221 !
$
PHASE HALITE % 2 1 1 > halite-structured (Cr,Fe,Ni)O >> 3 !
CONSTITUENT HALITE :AL,CR,FE%,NI : O : !
PARAMETER G(HALITE,AL:O;0) 273.00 0.33333*GAL2O3#
+0.33333*GHSERAL#+200000; 6000.00 N
REF:pov12 !
PARAMETER G(HALITE,CR:O;0) 273.00 0.33333*GCR2O3#
+0.33333*GHSERCR#+100000; 6000.00 N
REF:pov12 !
PARAMETER G(HALITE,FE:O;0) 273.00 +GFEO#; 6000.00 N
REF:199 !
PARAMETER G(HALITE,NI:O;0) 273.00 +GNIO#; 6000.00 N
REF:199 !
PARAMETER L(HALITE,AL,CR:O;0) 273.00 +1e-8; 6000.00 N
REF:pov12 !
PARAMETER L(HALITE,AL,NI:O;0) 273.00 +1e-8; 6000.00 N
REF:pov12 !
PARAMETER L(HALITE,AL,FE:O;0) 273.00 +1e-8; 6000.00 N
REF:pov12 !
PARAMETER L(HALITE,CR,FE:O;0) 273.00 -50000; 6000.00 N
REF:pov12 !
PARAMETER L(HALITE,CR,NI:O;0) 273.00 -50000; 6000.00 N
REF:pov12 !
PARAMETER L(HALITE,FE,NI:O;0) 273.00 -21995.73+19.74*T; 6000.00 N
REF:199 !
PARAMETER L(HALITE,FE,NI:O;1) 273.00 -3335.37; 6000.00 N
REF:199 !
$
PHASE HF1O2_M % 2 0.33333 0.66667 > monoclinic,
strengthening dispersoid >> 2 !
CONSTITUENT HF1O2_M :HF : O: !
PARAMETER G(HF1O2_M,HF:O;0) 273.00 +0.333333*GHF1O2_S#; 6000.00 N
REF:220 !
$
PHASE HF1O2_T % 2 0.33333 0.66667 > tetragonal >> 1 !
CONSTITUENT HF1O2_T :HF : O: !
PARAMETER G(HF1O2_T,HF:O;0) 273.00 +0.333333*GHF1O2_S#
+2736-1.333333*T; 6000.00 N
REF:220 !
$
PHASE HF1O2_C % 2 0.33333 0.66667 > cubic >> 1 !
CONSTITUENT HF1O2_C :HF : O: !
PARAMETER G(HF1O2_C,HF:O;0) 273.00 +0.333333*GHF1O2_S#
+6473.3333-2.66667*T; 6000.00 N
REF:220 !
$
PHASE LA2O3_A % 2 2 3 > hexagonal, strengthening dispersoid >> 2 !
CONSTITUENT LA2O3_A :LA : O : !
PARAMETER G(LA2O3_A,LA:O;0) 273.00 +GLA2O3D#; 6000.00 N
REF:204 !
$
PHASE LA2O3_H % 2 2 3 > ordered hexagonal >> 1 !
CONSTITUENT LA2O3_H :LA : O : !
PARAMETER G(LA2O3_H,LA:O;0) 273.00 +GLA2O3H#; 6000.00 N
REF:204 !
$
PHASE LA2O3_C % 2 2 3 > cubic >> 1 !
CONSTITUENT LA2O3_C :LA : O : !
PARAMETER G(LA2O3_C,LA:O;0) 273.00 +GLA2O3X#; 6000.00 N
REF:204 !
$
PHASE SIO2 % 2 1 2 > Low Quartz >> 1 !
CONSTITUENT SIO2 :SI : O : !
PARAMETER G(SIO2,SI:O;0) 273.00 +GSIO2#; 6000.00 N
REF:201 !
$
PHASE SPINEL % 3 1 2 4 > Fe-Cr-Spinel >> 2 !
CONSTITUENT SPINEL :AL,CR,FE%,NI : AL,CR%,FE,NI : O : !
PARAMETER G(SPINEL,CR:FE:O;0) 273.00 +GHSERCR#+2*GHSERFE#+4*GHSEROO#
-1200000+350*T-10*T*LN(T); 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,FE:FE:O;0) 273.00 +3*GHSERFE#+4*GHSEROO#
-1150000+440*T-10*T*LN(T); 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,NI:AL:O;0) 273.00 +2*GHSERAL#+GHSERNI#+4*GHSEROO#
-1900000+320*T+12*T*LN(T)-0.004*T**2; 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,CR:AL:O;0) 273.00 +2*GHSERAL#+GHSERCR#
+4*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,FE:AL:O;0) 273.00 +2*GHSERAL#+GHSERFE#
+4*GHSEROO#-1975000+425*T-10*T*LN(T); 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,FE:NI:O;0) 273.00 +2*GHSERNI#+GHSERFE#
+4*GHSEROO#-500000+325*T-10*T*LN(T); 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,NI:FE:O;0) 273.00 +2*GHSERFE#+GHSERNI#+4*GHSEROO#
-1000000+325*T-10*T*LN(T); 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,NI:CR:O;0) 273.00 +2*GHSERCR#+GHSERNI#+4*GHSEROO#
-1240000+300*T-10*T*LN(T); 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,CR:NI:O;0) 273.00 +2*GHSERNI#+GHSERCR#
+4*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,FE:CR:O;0) 273.00 +2*GHSERCR#+GHSERFE#+4*GHSEROO#
-1420000+425*T-10*T*LN(T); 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,NI:NI:O;0) 273.00 +3*GHSERNI#+4*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,CR:CR:O;0) 273.00 +GCR3O4#; 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,AL:AL:O;0) 273.00 +3*GHSERAL#+4*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,AL:CR:O;0) 273.00 +1*GHSERAL#+2*GHSERCR#
+4*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,AL:FE:O;0) 273.00 +1*GHSERAL#+2*GHSERFE#
+4*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER G(SPINEL,AL:NI:O;0) 273.00 +1*GHSERAL#+2*GHSERNI#
+4*GHSEROO#; 6000.00 N
REF:pov12 !
PARAMETER L(SPINEL,NI:CR,FE:O;0) 273.00 +120000-80*T; 6000.00 N
REF:pov12 !
PARAMETER L(SPINEL,NI:AL,CR:O;0) 273.00 +100000; 6000.00 N
REF:pov12 !
PARAMETER L(SPINEL,NI:AL,FE:O;0) 273.00 +100000; 6000.00 N
REF:pov12 !
PARAMETER L(SPINEL,FE:AL,CR:O;0) 273.00 +1e-8; 6000.00 N
REF:pov12 !
$
PHASE TIO2 % 2 1 2 > Note: fully oxidized compound
without oxygen vacancies >> 2 !
CONSTITUENT TIO2 :TI : O : !
PARAMETER G(TIO2,TI:O;0) 273.00 -976986.6+484.74037*T-77.76175*T*LN(T)
-67156800*T**(-2)+1683920*T**(-1); 6000.00 N
REF:202 !
$
PHASE TI2O3 % 2 2 3 > >> 1 !
CONSTITUENT TI2O3 :TI : O : !
PARAMETER G(TI2O3,TI:O;0) 273.00 +GTI2O3#; 6000.00 N
REF:202 !
$
PHASE TRID % 2 1 2 > Tridymite >> 1 !
CONSTITUENT TRID :SI : O : !
PARAMETER G(TRID,SI:O;0) 273.00 +GTRID#; 6000.00 N
REF:201 !
$
PHASE Y2O3_C % 2 2 3 > cubic Yttrium oxide,
strengthening dispersoid >> 2 !
CONSTITUENT Y2O3_C :Y : O : !
PARAMETER G(Y2O3_C,Y:O;0) 273.00 +GY2O3C#; 6000.00 N
REF:211 !
$
PHASE Y2O3_H % 2 2 3 > hexagonal Yttrium oxide,
strengthening dispersoid >> 2 !
CONSTITUENT Y2O3_H :Y : O : !
PARAMETER G(Y2O3_H,Y:O;0) 273.00 +GY2O3H#; 6000.00 N
REF:211 !
$
PHASE YALO3 % 3 1 1 3 > strengthening dispersoid,
perovskite structure >> 2 !
CONSTITUENT YALO3 :Y : AL : O : !
PARAMETER G(YALO3,Y:AL:O;0) 273.00 -23515.2904-6.51754*T+0.5*GAL2O3#
+0.5*GY2O3C#; 6000.00 N
REF:241 !
$
PHASE Y4AL2O9 % 3 4 2 9 > monoclinic strengthening dispersoid >> 2 !
CONSTITUENT Y4AL2O9 :Y : AL : O : !
PARAMETER G(Y4AL2O9,Y:AL:O;0) 273.00 -5697300+2242.505*T-368.16*T*LN(T)
-0.01836*T**2+4310328.16*T**(-1); 6000.00 N
REF:238 !
$
PHASE Y2TIO5 % 3 2 1 5 > orthorhombic, strengthening dispersoid >> 2 !
CONSTITUENT Y2TIO5 :Y : TI : O : !
PARAMETER G(Y2TIO5,Y:TI:O;0) 273.00 +GY2O3C#+0.5*GTI2O3#+0.5*GHSEROO#
-184500+36.1*T; 6000.00 N
REF:pov14 !
$
PHASE Y2TI2O7 % 3 2 2 7 > pyrochlore structure,
strengthening dispersoid >> 2 !
CONSTITUENT Y2TI2O7 :Y : TI : O : !
PARAMETER G(Y2TI2O7,Y:TI:O;0) 273.00 +GY2O3C#+1*GTI2O3#+GHSEROO#
-365000+70*T; 6000.00 N
REF:pov14 !
$
PHASE O1_GAS % 1 1.0 > for thermodynamic properties calculations only >> 0 !
CONSTITUENT O1_GAS :O : !
PARAMETER G(O1_GAS,O;0)
273.00 GHSEROO#; 6000.00 N
REF:0 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: M2P
$###########################################################################
PHASE M2P % 2 2 1 > >> 1 !
CONSTITUENT M2P : CR,FE,NB,TI : P : !
PARAMETER G(M2P,CR:P;0) 273.00 +2*GHSERCR#+GHSERPP#-159530+5*T
-1.9695*T*LN(T); 6000.00 N
REF:230 !
PARAMETER G(M2P,FE:P;0) 273.00 +2*GHSERCR#+GHSERPP#-169322+53.907*T
-1.9695*T*LN(T); 6000.00 N
REF:230 !
PARAMETER G(M2P,NB:P;0) 273.00 +2*GHSERNB#+GHSERPP#
-230400+60*T; 6000.00 N
REF:232 !
PARAMETER G(M2P,TI:P;0) 273.00 +2*GHSERNB#+GHSERPP#
-363800+78*T; 6000.00 N
REF:233 !
PARAMETER L(M2P,CR,FE:P;0) 273.00 -41500; 6000.00 N
REF:230 !
PARAMETER L(M2P,FE,NB:P;0) 273.00 -180000+20*T; 6000.00 N
REF:232 !
$###########################################################################
$ THERMODYNAMIC PARAMETERS: M3P
$###########################################################################
PHASE M3P % 2 3 1 > >> 1 !
CONSTITUENT M3P : CR,FE,NB,TI : P : !
PARAMETER G(M3P,CR:P;0) 273.00 +3*GHSERCR#+GHSERPP#-176091-49.399*T
+7.9518*T*LN(T); 6000.00 N
REF:230 !
PARAMETER G(M3P,FE:P;0) 273.00 +3*GHSERCR#+GHSERPP#-193222+66.046*T
-1.9695*T*LN(T); 6000.00 N
REF:230 !
PARAMETER G(M3P,NB:P;0) 273.00 +3*GHSERNB#+GHSERPP#
-314800+80*T; 6000.00 N
REF:232 !
PARAMETER G(M3P,TI:P;0) 273.00 +3*GHSERTI#+GHSERPP#
-380000+90*T; 6000.00 N
REF:233 !
PARAMETER L(M3P,CR,FE:P;0) 273.00 -53000+20*T; 6000.00 N
REF:230 !
$
$
$
$
$***************************************************************************
$
$ E) List of references
$
$***************************************************************************
$
A00201-0 unary A.T. Dinsdale,
SGTE Data of pure elements,
CALPHAD, Vol. 15, No. 4, pp 317-425, 1991.
A00042-11 C-Cr-Fe-Ni-V-W B.J. Lee,
On the stability of Cr-Carbides,
CALPHAD, Vol. 16, pp 121-149, 1992.
A00040-12 Al-C-Cr-Cu-Fe-Mn-Ni-Si...
J. Miettinen,
Thermodynamic substitutional solution data for steels,
Report TKK-MK-76, pp 1-24, 1999.
A00003-13 Cr-Fe-Ni J. Miettinen,
Thermodynamic reassessment of the Fe-Cr-Ni system
with emphasis on the iron-rich corner,
CALPHAD, Vol. 23, No. 2, pp 231-248, 1999.
A00029-14 C-Fe P. Gustafson,
A thermodynamic evaluation of the Fe-C system,
Scand. J. Met., Vol. 14, pp 259-267, 1985.
A00022-15 C-Fe-Mn-V W. Huang,
Thermodynamic properties of the Fe-Mn-V-C system,
Met. Trans., Vol. 22A, pp 1911-1920, 1991.
A00093-16 C-Fe-N-Nb-Ti B.J. Lee,
A Thermodynamic assessment of the Fe-Nb-Ti-C-N system,
Metal. Mater. Trans., Vol. 32A, 2423-2439, 2001.
A00092-17 C-Mo-Ti J.H. Shim, C.S. Oh, D.N. Lee,
A thermodynamic evaluation of the Ti-Mo-C system,
Metall. Mater. Trans., Vol. 27B, No. 12, pp 955-966, 1996.
A00102-18 C-Fe-Mo-W P. Gustafson,
A thermodynamic evaluation of the Co-Fe-Mo-W system,
Z. Metallkd., Vol. 79, No. 7, pp 421-425, 1988.
A00094-19 C-Nb-W W. Huang , M. Selleby,
Thermodynamic assessment of the Nb-W-C system,
Z. Metallkd., Vol. 88, No. 1, pp 55-62, 1997.
A00101-20 C-Co-Fe-Ni-W A. F. Guillermet,
The Co-Fe-Ni-W-C phase diagram: a thermodynamic description
and calculated sections for (Co-Fe-Ni) bonded cemented WC tools,
Z. Metallkd., Vol. 80, No. 2, pp 83-94, 1989.
A00036-21 C-Cr-Ti J. C. Schuster, Y. Du,
Thermodynamic description of the system Ti-Cr-C,
CALPHAD, Vol. 23, No. 3-4, pp 393-408, 1999.
A00066-22 Cr-Fe-Mn-N K. Frisk, Caian Qiu,
A thermodynamic evaluation of the solubility of N
in solid and liquid Cr-Fe-Mn alloys,
Z. Metallkd., Vol. 85, pp 60-69, 1994.
A00034-23 Cr-Cu-Fe-Mn-Mo-Ni-Si-V...
J. Miettinen,
Approximate thermodynamic solution phase data for steels,
CALPHAD, Vol. 22, No. 2, pp 275-300, 1998.
A00010-24 C-Fe-Si J. Lacaze, B. Sundman,
An assessment of the Fe-C-Si system,
Metall. Trans., Vol. 22A, pp 2211-2223, 1991.
A00028-25 C-Fe-Si J. Miettinen,
Reassessed thermodynamic solution phase data for ternary Fe-Si-C system,
CALPHAD, Vol. 22, No. 2, pp 231-256, 1998.
A00008-26 C-Fe-N H. Du, M. Hillert,
An assessment of the Fe-C-N system,
Z. Metallkd., Vol. 82, No. 4, pp 310-316, 1991.
A00015-27 C-Fe-Mo J. O. Andersson,
A termodynamic evaluation of the Fe-Mo-C system,
CALPHAD, Vol. 12, No. 1, pp 9-23, 1988.
A00031-28 Cr-Fe-Si,Fe-Ni-Si
J. Miettinen,
Thermodynamic description of solution phases of systems Fe-Cr-Si
and Fe-Ni-Si with low silicon contents and with application to stainless steels,
CALPHAD, Vol. 23, No. 2, pp 249-262, 1999.
A00030-29 Mn-based J. Miettinen,
Thermodynamic solution phase data for binary Mn-based systems,
CALPHAD, Vol. 25, No. 1, pp 43-58, 2001.
A00090-30 Fe-N-Ni K. Frisk,
A Thermodynamic evaluation of the Fe-Ni-N system,
Z. Metallkd., Vol. 82, No. 1, pp 59-66, 1991.
A00046-31 C-Fe-Ni A. Gabriel , P. Gustafson,
A thermodynamic evaluation of the C-Fe-Ni system,
CALPHAD, Vol. 11, pp 203-218, 1987
A00021-32 Fe-N-V H. Ohtani, M. Hillert,
A thermodynamic assessment of the Fe-N-V system,
CALPHAD, Vol. 15, No. 1, pp 25-39, 1991.
A00116-34 C-Cr-Fe-Mo-V A. Kroupa, J. Havrankova, M. Svoboda, J. Vrestal,
Phase diagram in the iron-rich corner of the Fe-Cr-Mo-V-C system below 1000 K,
J. Phase Equilib.,Vol. 22, No. 3, pp 312-323, 2001.
A00114-35 C-Co-Cr-Si G. Ghosh, G.B. Olson,
Precipitation of paraequilibrium cementite:
experiments, and thermodynamic and kinetic modeling,
Acta Mater., Vol. 50, pp 2099-2119, 2002.
A00087-36 Cr-Fe-N-Ni K. Frisk,
A thermodynamic evaluation of the Cr-Fe-Ni-N system,
Z. Metallkd., Vol. 82, No. 2, pp 108-117, 1991.
A00119-38 C-Mo-V, Mo-V K. Frisk,
Thermodynamic analysis of the Mo-V and Mo-V-C systems,
CALPHAD, Vol. 26, No. 3, pp 459-476, 2002.
000000-39 Cr-Mo-Ni K. Frisk,
Trita-Mac-0429, Mat. Res. Centre, Royal Inst. of Tech., Stockholm, 1990.
A00056-40 Fe-Mo-N K. Frisk,
Trita-Mac-0433, Mat. Res. Centre, Royal Inst. of Tech., Stockholm, 1990.
000000-41 Fe-Mo-Ni K. Frisk,
Trita-Mac-0428, Mat. Res. Centre, Royal Inst. of Tech., Stockholm, 1990.
A00041-43 Fe-Cr-Si M. Lindholm,
A thermodynamic description of the Fe-Cr-Si system with emphasis
on the equilibria of the sigma phase,
J. Phase Equilib., Vol. 18, No. 5, pp 432-440, 1997.
A00060-44 Cr-Cu,Cu-Nb, Cu-V
M. Haemaelaeinen, K. Jaeaeskelaeinen, R. Luoma, M. Nuotio, P. Taskinen, O. Teppo,
A thermodynamic analysis of the binary alloy systems Cu-Cr, Cu-Nb and Cu-V,
CALPHAD, Vol. 14, No. 2, pp 125-137, 1990.
A00061-45 Cr-Nb J.G. Costa Neto, S.G. Fries, H.L. Lukas,
Thermodynamic optimisation of the Nb-Cr system,
CALPHAD, Vol. 17, No. 3, pp 219-228, 1993.
A00044-46 Cr-Si C.A. Coughanowr, I. Ansara, H.L. Lukas,
Assessment of the Cr-Si system,
CALPHAD, Vol. 18, No.2, pp 125-140, 1994.
A00067-47 Cr-N, Fe-N, Mo-N K. Frisk,
A thermodynamic evaluation of the Cr-N, Fe-N, Mo-N and Cr-Mo-N systems,
CALPHAD, Vol. 15, No. 1, 79-106, 1991.
A00073-48 V-N H. Ohtani, M. Hillert,
A thermodynamic assessmant of the V-N system,
CALPHAD, Vol. 15, No. 1, pp 11-24, 1991.
A00053-51 C-Cr-Fe-Mo M. Hillert, C. Qiu,
A reassessment of the Fe-Cr-Mo-C system,
J. Phase Equilib., Vol. 13, No. 5, pp 512-521, 1992.
A00081-52 C-Cr-Fe-V B.J. Lee, D.N. Lee,
A thermodynamic evaluation of the Fe-Cr-V-C system,
J. Phase Equilib., Vol. 13, No. 4, pp 349-364, 1992.
A00085-53 Fe-Mn-Si A. Forsberg, J. Agren,
Thermodynamic evaluation of the Fe-Mn-Si system and
the gamma/epsilon martensitic transformation,
J. Phase Equilib., Vol. 14, No. 3, pp 354-363, 1993.
A00230-54 Fe-Nb-Ni M. Mathon, D. Connetable, B. Sundman, J. Lacaze,
Calphad-type assessment of the Fe-Nb-Ni ternary system.
CALPHAD 33 (2009) 136-161.
A00108-55 Fe-Mo-W P. Gustafson,
An experimental study and a thermodynamic evaluation of the Fe-Mo-W system,
Z. Metallkd., Vol. 79, No. 6, pp 388-396, 1988.
A00103-57 C-Cr-Fe-W P. Gustaffson,
A thermodynamic evaluation of the C-Cr-Fe-W system,
Metall. Trans., Vol. 19A, pp 2547-2554, 1988.
A00043-58 C-Cr-Fe-Mn B.J. Lee,
Thermodynamic evaluation of the Fe-Cr-Mn-C system,
Metall. Trans. A, Vol. 24A, pp 1017-1025, 1993.
A00104-59 Cr-Fe-W P. Gustafson,
An experimental study and thermodynamic evaluation of the Cr-Fe-W system,
Metall. Trans., Vol. 19A, pp 2531-2546, 1988.
A00123-61 Cr-Fe-Mo-C C. Qiu,
An analysis of the Cr-Fe-Mo-C system and modification of thermodynamic parameters,
ISIJ Int., Vol. 32, pp 1117-1127, 1992.
A00124-62 Fe-Cr-Mn-C B.J. Lee,
A thermodynamic evaluation of the Fe-Cr-Mn-C system,
Metall. Trans., Vol. 24A, pp 1017-1025, 1993.
A00125-63 Fe-Mo-C J.O. Andersson,
A thermodynamic evaluation of the Fe-Mo-C system,
CALPHAD, Vol. 12, pp 9-23, 1988.
A00126-64 Cr-N,Fe-N,Mo-N and Cr-Mo-N
K. Frisk,
A thermodynamic evaluation of the Cr-N,Fe-N,Mo-N and Cr-Mo-N systems,
CALPHAD, Vol. 15, pp 79-106, 1991.
A00128-66 Mn-N C. Qiu, A.F.Guillermet,
Predicative approach to the entropy of manganese nitrides
and calculation of the Mn-N phase diagram,
Z. Metallkd., Vol. 84, No. 1, pp 11-22, 1993.
A00129-67 Ni-N A.F. Guillermet, K.Frisk,
Thermodynamic properties of Ni nitrides and phase stability in the Ni-N system,
Int. J. Thermophys., Vol. 12, No. 2, pp 417-431, 1991.
A00130-68 Fe-Cr-V-C B.J. Lee, D.N. Lee,
A thermodynamic evaluation of the Fe-Cr-V-C system,
J. Phase Equilib., Vol. 13, pp 349-364, 1992.
A00133-71 Z-phase H.K. Danielsen, J. Hald,
A thermodynamic model of Z-phase Cr(V,Nb)N,
CALPHAD 31(2007)505-514.
A00135-73 Co-Cr, C-Co-Cr A. Kusoffsky, B. Jansson,
A thermodynamic evaluation of the Co-Cr and the C-Co-Cr systems,
CALPHAD, Vol.21, pp 321-333, 1997.
A00136-74 Fe-Co A.F. Guillermet,
Critical evaluation of the thermodynamic propereties of the iron-cobalt system,
High Temp.-High Press., Vol.19, pp 477-499, 1987.
A00137-75 Fe-Co-C A.F. Guillermet,
Thermodynamic properties of the Fe-Co-C system,
Z. Metallkd., Vol. 79, pp 317-329, 1988.
A00138-76 Co-Ni-C,Fe-Co-Ni-C
A.F. Guillermet,
Thermodynamic properties of the Fe-Co-Ni-C system,
Z. Metallkd., Vol. 79, pp 524-536, 1988.
$ next one: original assessment is 1999, A00140 (pov09)
A00139-77 Co-Mo A.V. Davydov, U.R. Kattner,
Revised thermodynamic description for the Co-Mo system (short communications),
J. Phase Equilib., Vol.24, pp 209-211, 2003.
A00140-78 Co-Mo A.V. Davydov, U.R. Kattner,
Thermodynamic assessment of the Co-Mo system,
J. Phase Equilib., Vol. 20, pp 5-16, 1999.
A00141-79(=A00101-20) Co-Fe-Ni-W-C
A.F. Guillermet,
The Co-Fe-Ni-W-C phase diagram: a thermodynamic description and calculated sections
for (Co-Fe-Ni) bonded cemented WC tools,
Z. Metallkd., Vol. 80, pp 83-94, 1989.
A00142-80 Fe-Cu M.A. Turchanin, P.G. Agraval and I.V. Nikolaenko,
Thermodynamics of alloys and phase equilibria in the copper-iron system,
J. Phase Equilib., Vol. 24, No. 4, pp 307-319, 2003.
A00032-81 Fe-FeS-MnS-Mn J. Miettinen, B. Hallstedt,
Thermodynamic assessment of the Fe-FeS-MnS-Mn system,
CALPHAD, Vol. 22, No. 2, pp 257-273, 1998.
A00151-82 Fe-Cu-S B.J. Lee, B. Sundman, S.I. Kim, K.-G. Chin,
Thermodynamic calculations on the stability of Cu2S in low carbon steels,
ISIJ Int., Vol. 47, No. 1, pp 163-171, 2007.
A00153-84 Cu-Mn C. He, Y. Du, H.-L. Chen, S. Liu, H. Xu, Y. Ouyang, Z.-K. Liu,
Thermodynamic modeling of the Cu-Mn system supported by key experiments,
J. Alloys Cmpds., Vol. 457, pp 233-238, 2008.
A00155-85 Co-Cu J. Kubista, J. Vrestal,
Thermodynamics of the liquid Co-Cu system and calculation of phase diagram,
J. Phase Equilib., Vol. 21, pp 125-129, 2000.
000000-86 Co-Mn W. Huang,
An assessment of the Co-Mn system,
CALPHAD, Vol. 13, pp 345-, 1989.
A00157-87 Cu-Mn-(Fe,Co) C.P. Wang, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida,
Thermodynamic assessments of the Cu-Mn-X (X: Fe, Co) systems,
J. Alloys Compds., Vol. 438, pp 129-141, 2007.
A00154-88 Fe-Nb-Ti-V-C-N K. Frisk,
Thermodynamic modelling of multicomponent cubic Nb, Ti and V carbides/carbonitrides,
CALPHAD, Vol. 32, pp 326-337, 2008.
A00158-89 Al-Ni I. Ansara, N. Dupin, H.L. Lukas, B. Sundman,
Thermodynamic assessment of the Al-Ni system,
J. Alloys Cmpds., Vol. 247, pp 20-30, 1997.
A00160-91 Al-Ni-Cr N. Dupin, I. Ansara, B. Sundman,
Thermodynamic re-assessment of the ternary system Al-Cr-Ni,
CALPHAD, Vol. 25, pp 279-298, 2001.
000000-92 bin, tern N. Saunders,
COST 507: Thermochemical database for light metal alloys, Vol. 2, pp 23-27, 1998.
A00162-93 Al-Ni-Si W. Xiong, Y. Du, R.-X. Hu, J. Wang, W.-W. Zhang, P. Nash, X.-G. Lu,
Construction of the Al-Ni-Si phase diagram,
Int. J. Mater. Res., Vol. 99, No. 6, pp 598-612, 2008.
A00163-94 Ni-Si-Ti Y. Du, C. He, J.S. Schuster, S. Liu, H. Xu,
Thermodynamic description of the Ni-Si-Ti ternary system,
Int. J. Mater. Res., Vol. 97, No. 5, pp 543-555, 2006.
A00164-95 Al-Fe-Ni L. Zhang, Y. Du,
Thermodynamic description of the Al-Fe-Ni system,
CALPHAD, Vol. 31, pp 529-540, 2007.
A00168-100 Al-Fe-Si Y. Du, J.C. Schuster, Z.-K. Liu, R. Hu, P. Nash, W. Sun, W. Zhang, J. Wang, L. Zhang,
C. Tang, Z. Zhu, S. Liu, Y. Ouyang, W. Zhang, N. Krendelsberger,
A thermodynamic description of the Al-Fe-Si system
over the whole composition and temperature ranges via a hybrid approach of
CALPHAD and key experiments,
Intermet., Vol. 16, pp 554-570, 2008.
A00169-101 Al-Fe-Si Z.-K. Liu, Y.A. Chang,
Thermodynamic assessment of the Al-Fe-Si system,
Metall. Mater. Trans A, Vol. 30A, pp 1081-1095, 1999.
A00171-103 Ti-C-N K. Frisk, J. Zackrisson, B. Sundman, A. Markstr?
Experimental investigation of the equilibrium composition of titanium carbonitride
and analysis using thermodynamic modelling,
Z. Metallkd., Vol. 95, pp 987-992, 2004.
A00174-107 Al-Cu-Fe J. Miettinen,
Thermodynamic description of the Cu-Al-Fe system at the Cu-Fe side,
CALPHAD, Vol. 27, No. 1, pp 91-102, 2003.
A00186-110 Ti-V-C A. Markstr? D. Andersson, K. Frisk,
Combined ab-initio and experimental assessment of A1-xBxC mixed carbides,
CALPHAD, Vol. 32, pp 615-623, 2008.
A00216-111 Cr-Fe-Mo J-O. Andersson, N. Lange,
An experimental study and a thermodynamic evaluation of the Fe-Cr-Mo system,
Metall. Trans. A, Vol. 19A, No. 6, pp 1385-1394, 1988.
A00189-113 Fe-C-Nb W. Huang,
A thermodynamic evaluation of the Fe-Nb-C system,
Z. Metallkd., Vol. 81, pp 397-404, 1990.
A00190-114 Cr-B C.E. Campbell and U.R. Kattner,
Assessment of the Cr-B system and extrapolation to the Ni-Al-Cr-B quaternary system,
CALPHAD, Vol. 26, No. 3, pp 477-490, 2002.
A00191-115 Fe-B T. Van Rompaey, K.C. H. Kumar, P. Wollants,
Thermodynamic optimization of the B-Fe system,
J. Alloys Cmpd., Vol. 334, pp 173-181, 2002.
A00193-117 Nb-B-Ti V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova,
Re-assessment of the constituent binary systems B-Nb and B-Ti on the basis
of new experimental data,
J. Alloy Cmpd., Vol. 448, pp 185-194, 2008.
A00194-118 B-Mo-Si Y. Yang, Y.A. Chang,
Thermodynamic modeling of the Mo-Si-B system,
Intermetall., Vol. 13, pp 121-128, 2005.
000000-123 Cu-Ni A. Jansson,
TRITA-MAC-0340, Mater. Res. Centre, Royal Inst. Tech., Stockholm, 1987.
A00200-124 Fe-C-B H. Ohtani, M. Hasebe, K. Ishida, T. Nishizawa,
Calculation of Fe-C-B ternary phase diagram,
Transactions ISIJ, Vol. 28, pp 1043-1050, 1988.
A00196-125 Mo-Ti-C-N H.-J. Chung, J.-H. Shim, D.N. Lee,
Thermodynamic evaluation and calculation of phase equilibria of the Ti-Mo-C-N quaternary system,
J. Alloys Cmpds., Vol. 282, pp 142-148, 1999.
000000-126 Cr-Fe-W P. Gustafson,
TRITA-MAC-0342, Mater. Res. Centre, Royal Inst. Tech., Stockholm, 1987.
000000-127 Cr-Fe-Mo-W-C P. Gustafson,
TRITA-MAC-0354, Mater. Res. Centre, Royal Inst. Tech., Stockholm, 1987.
A00217-128 Al-Nb-Si G. Shao,
Thermodynamic assessment of the Nb-Si-Al system,
Intermetal., Vol. 12, pp 655-664, 2004.
A00218-129 Si-V C. Zhang, Y. Du, W. Xiong, H. Xu, P. Nash, J. Ouyang, R. Hu,
Thermodynamic modeling of the V-Si system supported by key experiments,
CALPHAD, Vol. 32, pp 320-325, 2008.
A00219-130 Cr-Cu-Nb-Co X.J. Liu, C.P. Wang, K. Ishida,
Experimental determination and thermodynamic calculation of the phase equilibria
in the Cu-Cr-Nb amd Cu-Cr-Co systems,
J. Alloys Cmpd., Vol. 478, pp 287-296, 2009.
A00220-131 Cu-V J. Zhao, Y. Du, L. Zhang, H. Yu,
Thermodynamic reassessment of the Cu-V system supported by key experiments,
CALPHAD, Vol. 32, pp 252-255, 2008.
A00221-132 Mo-Si-Al Y. Liu, G. Shao, P. Tsakiropoulos,
Thermodynamic reassessment of the Mo-Si and Al-Mo-Si systems,
Intermet., Vol. 8, pp 553-962, 2000.
A00242-134 Co-V,Co-V-C S. Huang, L. Li, O. Van der Briest, J. Vleugels,
Thermodynamic assessment of the Co-V and Co-V-C system,
J. Alloys Cmpd., Vol. 385, pp 114-118, 2004.
000000-135 Co-N F. Guillermet and S. Jonsson,
Predictive approach to thermodynamic properties of Co nitrides
and phase stability in the Co-N system,
Z. f? ?etallkde. 83 (1992) 21-31.
000000-136 Co-Nb K.C. Hari Kumar, I. Ansara, P. Wollants, L. Delaey,
Thermodynamic optimisation of the Co-Nb system,
J. Alloys and Compounds, 267 (1998) 105-112.
000000-137 Co-Ti G. Cacciamani, R. Ferro, I. Ansara, N. Dupin,
Thermodynamic modelling of the Co-Ti system,
Intermetal. 8 (2000) 213-222.
000000-138 Cr-Ni-W P. Gustafson,
A thermodynamic evaluation of the Cr-Ni-W system,
CALPHAD, 11 (1987) 277-292.
000000-139 Ti-W S. Jonsson,
Z. Metallkd. 87 (1996) 788-795.
000000-140 W-N S. Jonsson,
Z. Metallkd. 84 (1993) 106-117.
000000-142 Co-Fe-N A. F. Guillermet and S. Jonsson,
Thermodynamic analysis of the Fe-Co-N system
and predictive approach of the phase diagram,
Z. f? Metallkde. 83 (1992) 165-175.
A00243-144 Ti-B X. Ma, C. Li, Z. Du, W. Zhang,
Thermodynamic assessment of the Ti-B system,
J. Alloys Cmpd., Vol. 370, pp 149-158, 2004.
000000-145 Fe-Cr-B K. Yamada, H. Ohtani, M. Hasebe,
Thermodynamic analysis of the Fe-Cr-B ternary system,
High Temp. Mater. Proc., Vol. 27, No. 4, pp 269-283, 2009.
A00244-146 Fe-Nb-B K. Yoshitomi, Y. Nakama, H. Ohtani, M. Hasebe,
Thermodynamic analysis of the Fe-Nb-B ternary system,
ISIJ Int., Vol. 48, No. 6, pp 835-844, 2008.
A00206-147 Al-Cu-Si C.-Y. He, J. Du, H.-L. Chen, H. Xu,
Experimental investigation and thermodynamic modeling of the Al-Cu-Si system,
CALPHAD, Vol. 33, pp 200-210, 2009.
A00202-148 Al-Fe-Mg-Mn-Si Y. Du, Y.A. Chang, S. Liu, B. Huang, F.-Y- Xie, Y. Yang, S.-L. Chen,
Thermodynamic description of the Al-Fe-Mg-Mn-Si system,
Z. Metallkd., Vol. 96, No. 12, pp 1351-1362, 2005.
A00211-149 Al-Mn-Si Y. Du, J.C. Schuster,F. Weitzer, N. Krendelsberger,
B. Huang, Z. Jin, W. Gong, Z. Yuan, H. Xu,
A thermodynamic description of the Al-Mn-Si system
over the entire composition and temperature range,
Metall. Mater. Trans. A, Vol. 35A, pp 1613-1628, 2004.
A00327-152 Fe-Co I. Ohnuma, H. Enoki, O. Ikeda, R. Kainuma, H. Ohtani, B. Sundman, K. Ishida,
Phase equilibria in the Fe-Co binary system,
Acta Mater., Vol. 50, pp 379-393, 2002.
000000-153 Cr-Nb-Si N. David, Y. Cartigny, T. Belmonte, J.M. Fiorani, M. Vilasi,
Thermodynamic description of the Cr-Nb-Si isothermal section at 1473 K,
Intermetal., Vol. 14, pp 464-473, 2006
A00251-155 Fe-Al-Mn-C K.-G. Chin, H.-J. Lee, J.-H. Kwak, J.-Y. Kan, B.-J. Lee,
Thermodynamic calculation on the stability of (Fe,Mn)3AlC carbide
in high aluminium steels,
J. Alloys Cmpd. 505 (2010) 217-223.
A00252-156 Fe-C B. Hallstedt, D. Djurovic, J. von Appen, R. Dronskowski, A. Dick,
F. K??nn, T. Hickel, J. Neugebauer,
Thermodynamic properties of cementite (Fe3C), CALPHAD 34 (2010) 129-133.
A00261-158 N-Si X. Ma, C. Li, F. Wang, W. Zhang,
Thermodynamic assessment of the Si-N system,
CALPHAD 27 (2003) 383-388.
A00272-159 Al-Ti V.T. Witusiewicz, A.A. Bondar, U. Hecht, S. Rex, T.Ya. Velikanova,
The Al-B-Nb-Ti system, III. Thermodynamic re-evaluation of
the constituent binary system Al-Ti,
J. Alloys Cmpd. 465 (2008) 64-77.
A00229-160 Fe-Ni-Ti J. De Keyzer, G. Cacciamani, N. Dupin, P. Wollants,
Thermodynamic modeling and optimization of the Fe-Ni-Ti system,
CALPHAD, Vol. 33, pp 109-123, 2009.
A00275-190 B-Ni-Si T. Tokunaga, K. Nishio, H. Ohtani, M. Hasebe,
Phase equilbria in the Ni-Si-B system,
Mater. Trans. 9 (2003) 1651-1654.
A00276-191 Ni-Si-Ti T. Tokunaga, K. Hashima, H. Ohtani, M. Hasebe,
Thermodynamic analysis of the Ni-Si-Ti system using thermochemical properties
determined from ab initio calculations,
Mater. Trans. 45 (2004) 1507-1514.
A00303-192 B-Fe-Ni T. Tokunaga, H. Ohtani, M. Hasebe,
Thermodynamic study of phase equilibria in Ni-Fe-B system,
Mater. Trans. 46 (2005) 1193-1198.
A00277-193 Ni-Si T. Tokunaga, K. Nishio, H. Ohtani, M. Hasebe,
Thermodynamic assessment of the Ni-Si system by incorporating
ab initio calculations into the CALPHAD approach,
CALPHAD 27 (2003) 161-168.
A00227-194 C-Hf H. Bittermann and P. Rogl,
Critical assessment and thermodynamic calculation of the
binary system Hafnium-Carbon (Hf-C),
J. Phase Equilib. 18 (1997) 344-356.
A00256-195 C-Co-Hf-W(-Zr) J. Bratberg and B. Jansson,
Thermodynamic evaluation of the C-Co-W-Hf-Zr system
for cemented carbides applications,
J. Phase Equilib. Diff. 27 (2006) 213-219.
A00259-196 Cr-Hf-Y B.B. Hasek,
Thermodynamic modeling and first-principles calculations
of the Cr-Hf-Y ternary system, Thesis, Pennstate University, 2010.
A00274-197 Fe-La-O E. Povoden-Karadeniz, A.N. Grundy, M. Chen, T. Ivas, L.J. Gauckler,
Thermodynamic Assessment of the La-Fe-O system,
J. Phase Equilib. Diff. 30 (2009) 351.
A00275-198 Cr-O E. Povoden, N. Grundy, L.J. Gauckler,
Thermodynamic reassessment of the Cr-O system in the framework of
solid oxide fuel cell (SOFC) research,
J. Phase Equilb. Diffus. 27 (2006) 353.
A00276-199 Cr-Fe-Ni-O L. Kjellqvist, M. Selleby, B. Sundman,
Thermodynamic modelling of the Cr-Fe-Ni-O system,
CALPHAD 32 (2008) 577-592.
A00304-200 Al-Mg-O B. Hallstedt,
Thermodynamic assessment of the system MgO-Al2O3,
J. Am. Ceram. Soc. 75 (1992) 1497.
A00278-201 Si-O B. Hallstedt,
Thermodynamic assessment of the silicon-oxygen system,
CALPHAD 16 (1992) 53.
A00279-202 Ti-O M. Cancarevic, M. Zinkevich, F. Aldinger,
Thermodynamic description of the Ti-O system using the associate model for the liquid phase,
CALPHAD 31 (2007) 330.
000000-203 Ti-O P. Waldner, G. Eriksson,
Thermodynamic modelling of the system titanium-oxygen,
CALPHAD 23 (1999) 189.
000000-204 La-Ga-O M. Zinkevich, S. Geupel, F. Aldinger, A. Durygin, S.K. Saxena, M. Yang, Z.-K. Liu,
Phase diagram and thermodynamics of the La2O3-Ga2O3 system revisited,
J. Phys. Chem. Solids 67 (2006) 1901.
A00280-205 Cr-La W. Chen, M.C. Gao, Oe.N. dogan, P. King, A.D. Rollett,
Thermodynamic assesment of Cr-rare earth systems,
J. Phase Equilib. Diffus. 30 (2009) 578.
A00286-211 Al-Si-Y-Oxide H. Mao, M. Selleby, O. Fabrichnaya,
Thermodynamic reassessment of the Y2O3-Al2O3-SiO2 system and its subsystems,
CALPHAD 32 (2008) 399-412.
A00287-213 Nb-Ni-Y N. Mattern, M. Zinkevich, W. Loeser, G. Behr, J. Acker,
Experimental and thermodynamic assessment of the Nb-Ni-Y system,
J. Phase Equilb. Diff. 29 (2008) 141-155.
A00288-214 Al-Hf T. Wang, Z. Jin, J.-C. Zhao,
Thermodynamic assessment of the Al-Hf binary system,
J. Phase Equilib. 23 (2002) 416-423.
A00228-215 Hf-Mo-W G. Shao,
Thermodynamic assessment of the Hf-Mo and Hf-W systems,
Intermetal. 10 (2002) 429-434.
A00258-216 Hf-Nb G. Ghosh, A. van de Walle, M. Asta, G.B. Olson,
Phase stability of the Hf-Nb system: From first-principles to CALPHAD,
CALPHAD 26 (2002) 491-511.
A00257-217 Al-Hf-Ni C. Zhang, J. Zhu, Y. Yang, H.-B. Cao, F. Zhang, W.-S. Cao, Y.A. Chang,
Thermodynamic modeling and experimental investigation of the Ni-rich corner
of the Ni-Al-Hf system,
Intermetal. 16 (2008) 139-147.
A00289-218 Fe-Hf M. Idbenali, N. Selhauoi, L. Bouirden, C. Servant,
Thermodynamic assessment of the Fe-Hf binary system,
J. Alloys Cmpd. 456 (2008) 151-158.
A00274-219 Hf-O C. Wang, M. Zinkevich, F. Aldinger,
The Zirconia-Hafnia system: DTA measurements and thermodynamic calculations,
J. Am. Ceram. Soc. 89 (2006) 3751-3758.
A00273-220 Hf-O D. Shin, R. Arroyave, Z.-K. Liu,
Thermodynamic modeling of the Hf-Si-O system,
CALPHAD 30 (2006) 375-386.
A00000-221 Fe-O M. Selleby, B. Sundman,
A reassessment of the Ca-fe-O system,
CALPHAD 20 (1996) 381.
A00290-222 La-Ni Z. Du, D. Wang, W. Zhang,
Thermodynamic assessment of the La-Ni system,
J. Alloys Cmpd. 264 (1998) 209-213.
A00291-223 Fe-H M. Zinkevich, N. Mattern, A. Handstein, O. Gutfleisch,
Thermodynamics of Fe-Sm, Fe-H, and H-Sm systems and its application to the
hydrogen-disproportionation-desorption-recombination (HDDR) process
for the system Fe17Sm2-H2,
J. Alloys Cmpd. 339 (2002) 118-139.
A00292-224 Cu-Fe-Ni C. Servant, B. Sundman, O. Lyon,
Thermodynamic assessment of the Cu-Fe-Ni system,
CALPHAD 25 (2001) 79-95.
A00293-225 Cr-Cu-Fe L.A. Dreval, M.A. Turchanin, A.R. Abdulov, A.A. Bondar,
Thermodynamic assessment of the Cu-Fe-Cr phase diagram,
Chem. Met. Alloys 3 (2010) 132-139.
A00294-226 Cr-Cu-Ni T. Ikoma, M. Kajihara,
Thermodynamic evaluation of phase equilibria in the ternary Cu-Cr-Ni system,
Mater. Sci. Eng. A 437 (2006) 293-300.
A00295-227 B-Cu C.P. Wang, S.H. Guo, A.T. Tang, F.S. Pan, X.J. Liu, K. Ishida,
Thermodynamic assessments of the Cu-B and Cu-Tm systems,
J. Alloys Cmpd. 482 (2009) 67-72.
A00296-228 Cu-Fe-X C.P. Wang, X.J. Liu, I. Ohnuma, R. Kainuma, K. Ishida,
Phase equilibria in Fe-Cu-X (X: Co,Cr,Si,V) ternary systems,
J. Phase Equilib. 23 (2002) 236-245.
000000-229 Fe-C-P J.-H. Shim, H.-J. Chung, D.N. Lee,
Thermodynamic assessment of the Fe-C-P system,
Z. Metallkd. 91 (2000) 114-120.
A00297-230 Cr-Fe-P J. Miettinen,
Thermodynamic description of Cr-P and Fe-Cr-P systems at low phosphorus contents,
CALPHAD 23 (1999) 141-154.
000000-231 Ni-P J.-H. Shim, H.-J. Chung, D.N. Lee,
Calculation of phase equilibria and evaluation of glass-forming ability of Ni-P alloys,
J. Alloys Cmpd. 282 (1999) 175-181.
A00298-232 Fe-Nb-P T. Tokunaga, N. Hanaya, H. Ohtani, M. Hasebe,
Thermodynamic analysis of phase equilibria in the Fe-Nb-P ternary system,
ISIJ Int. 49 (2009) 947-956.
A00299-233 Fe-Ti-P H. Ohtani, N. Hanaya, M. Hasebe, S.-I. Teraoka, M. Abe,
Thermodynamic analysis of the Fe-Ti-P ternary system by incorporationg
first-principles calculations into the CALPHAD approach,
CALPHAD 30 (2006) 147-158.
A00300-234 Al-Fe-P C. Wu, W. Huang, X. Su, H. Peng, J. Wang, Y. Liu,
Experimental investigation and thermodynamic calculation of the Al-Fe-P system
at low phosphorus contents,
CALPHAD 38 (2012) 1-6.
A00301-235 B-Fe-V V. Homolova, A. Kroupa, A. Vyrostkova,
Calculation of Fe-B-V ternary phase diagram,
J. Alloys Cmpd. 520 (2012) 30-35.
A00315-236 AlN R. Radis and E. Kozeschnik,
Kinetics of AlN precipitation in mocroalloyed steel,
Model. Sim. Mater. Sci. Eng. 18 (2010) 055003, 16pp.
A00317-237 Cr-Nb-Ni Y. Du, S. Liu, Y.A. Chang, Y. Yang,
A thermodynamic modeling of the Cr-Nb-Ni system,
CALPHAD 29 (2005) 140-148.
A00318-238 Y-Al-Si-O-C Z. Pan, O. Fabrichnaya, H.J. Seifert, R. Neher, K. Brandt, M. Herrmann,
Thermodynamic evaluation of the Si-C-Al-Y-O system for LPS-SiC application,
J. Phase Equilib. Diffusion 31 (2010) 238-249.
A00319-239 Fe-Y S. Kardellass, C. Servant, N. Selhaoui, A. Iddaoudi, M. Ait Amar, L. Bouirden,
A thermodynamic assessment of the iron-yttrium system,
J. Alloys Compd. 583 (2014) 598-606.
A00320-240 Ti-O R. Arrojave,
Thermodynamics and kinetics of ceramic/metal interfacial interactions,
Doctoral Thesis, Massachusetts Institute of Technology, 2004.
A00321-241 Al-Y-O O. Fabrichnaya, F. Aldinger,
Assessment of thermodynamic parmaeters in the system ZrO2-Y2O3-Al2O3,
Int. J. Mater. Res. 95 (2004) 27-39.
A00224-242 Pd-Fe G. Gosh, C. Kantner, G.B. Olson,
Thermodynamic modeling of the Pd-X(X=Ag,Co,Fe,Ni),
J. Phase Equilib. 20 (1999) 295-308.
A00322-243 Co-W-C A. Markstr? B. Sundman, K. Frisk,
A revised thermodynamic description of the Co-W-C system,
J. Phase Equilib. Diff. 26 (2005) 152-160.
A00325-244 Cu-Mn-Ni W. Sun, H. Xu, Y. Du, S. Liu, H. Chen, L. Zhang, B. Huang,
Experimental investigation and thermodynamic modeling of the Cu-Mn-Ni system,
CALPHAD 33 (2009) 642-649.
A00326-245 Mn-B W. Sun, Y. Du, S. Liu, B. Huang, C. Jiang,
Thermodynamic assessment of the Mn-B system,
J. Phase Equilib. Diff. 31 (2010) 357-364.
A00298-249 Mo-C J.-O. Andersson,
Thermodynamic properties of Mo-C,
CALPHAD 2 (1988) 1-8.
000000-250 Mo-W-C P. Gustafson,
Thermodynamic evaluation of the C-Mo-W system,
Z. Metallkd. 79 (1988) 397-402.
A00299-251 Mn-Ni-Si B. Hu, H. Xu, S. Liu, Y. Du, C. He, C. Sha, D. Zhao, Y. Peng,
Experimental investigation and thermodynamic modeling of the Mn-Ni-Si system,
CALPHAD 35 (2011) 346-354.
A00334-253 Ni-Nb-Ti K. Santhy, K.C. Hari Kumar, Thermodynamic reassessment of Nb-Ni-Ti system
with order-disorder model, J. Alloys Cmpd. 619 (2015) 733-747.
A00335-254 Mn-Ni-Si B. Hu, Y. Du, J.J. Yuan, Z.F. Liu, Q.P. Wang, Thermodynamic reassessment of the
mn-ni-si system, J. Min. Metall. Sect. B Metall. 51 (2015) 125–132.
A00336-255 Fe-Mn-C D. Djurovic, B. Hallstedt, J. von Appen, R. Dronskowski, Thermodynamic assessment
of the Fe–Mn–C system, Calphad. 35 (2011) 479–491.
A00337-256 Ni-Mn C. Guo, Z. Du, Thermodynamic optimization of the Mn-Ni system,
Intermetallics. 13 (2005) 525–534.
A00362-265 Mn-C D. Djurovic, B. Hallstedt, J. von Appen, R. Dronskowski,
Thermodynamic assessment of the Mn-C system,
CALPHAD 34 (2010) 279-85.
A00368-271 Fe-Mn-Nb S.H. Liu, B. Hallstedt, D. Music, Y. Du,
Ab initio calculations and thermodynamic modeling of the Fe-Mn-Nb system,
CALPHAD 38 (2012) 43-58.
A00378-281 Cr-Fe-Nb A. Jacob, C. Schmetterer, A.V. Khvan, A. Kondatriev, D. Ivanov, B.Hallstedt,
Liquidus projection and thermodynamic modeling of Cr-Fe-Nb ternary system,
CALPHAD 54 (2016) 1-15.
A00381-284 Cr-Nb-Si A. Jacob, E. Povoden-Karadeniz, E. Kozeschnik,
The Cr-Nb-Si system: Improved thermodynamic modelling and its use
in simulation of Laves phase in steel,
CALPHAD. 56 (2017) 80–91.
A0000-286 FE-MO V.B. Rajkumar & K.C. Hary Kumar,
Thermodynamic modeling of the Fe-Mo system coupled with experiments
and ab initio calculations,
Journal of Alloys and Compounds 611 (2014) 303–312.
A00000-287 CR-Fe A. Jacob, E. Povoden-Karadeniz, E. Kozeschnik,
Revised thermodynamic description of the Fe-Cr system based
on an improved sublattice model of the sigma-phase.
CALPHAD 60 (2018) 16-28.
A00397-288 Cr-Fe-Mo-Ni-Mn A. Jacob, E. Povoden-Karadeniz,
Predictive computations of intermetallic sigma phase evolution in stainless steel.
I) Thermodynamic modeling of sigma phase in the Fe-Cr-Mn-Mo-Ni system,
Calphad 71 (2020) 101998.
A0000-289 C-Fe R. Naraghi, M. Selleby, J. Ågren,
Thermodynamics of stable and metastable structures in Fe-C system,
CALPHAD 46 (2014) 148–158.
A0000-290 Fe-Ni W. Xiong, H. Zhang, L. Vitos, M. Selleby,
Magnetic phase diagram of the Fe-Ni system,
Acta Mater. 59 (2011) 521–530.
A0000-291 Fe-Si S. Cui, I.H. Jung,
Critical reassessment of the Fe-Si system,
CALPHAD 56 (2017) 108–125.
A000-292 Al-Fe-Ni L. Zhang, J. Wang, Y. Du, R. Hu, P. Nash, X.G. Lu, C. Jiang,
Thermodynamic properties of the Al-Fe-Ni system acquired via a hybrid
approach combining calorimetry, first-principles and CALPHAD,
Acta Mater. 57 (2009) 5324–5341.
A000-293 T0_Fe-C-Mn-Ni-Cr-Si A. Jacob, E. Povoden-Karadeniz, P. Retzl, E. Kozeschnik,
Calphad Reassessment of low-temperature Gibbs energies of BCC and FCC in steel
for T0-temperature evaluation, Calphad. 81 (2023) 102531. doi:10.1016/j.calphad.2023.102531.
koze E. Kozeschnik, unpublished, earlier than 2009.
koze09 E. Kozeschnik, unpublished, 2009.
koze13 E. Kozeschnik, unpublished, 2013.
pov09 E. Povoden-Karadeniz, unpublished, 2009.
pov10 E. Povoden-Karadeniz, unpublished, 2010.
pov11 E. Povoden-Karadeniz, unpublished, 2011.
pov12 E. Povoden-Karadeniz, unpublished, 2012.
pov13 E. Povoden-Karadeniz, unpublished, 2013.
pov14 E. Povoden-Karadeniz, unpublished, 2014.
pov15 E. Povoden-Karadeniz, unpublished, 2015.
pov16 E. Povoden-Karadeniz, unpublished, 2016.
pov17 E. Povoden-Karadeniz, unpublished, 2017.
pov23 E. Povoden-Karadeniz, unpublished, 2023.
jac17 A. Jacob, unpublished, 2017.
jac18 A. Jacob, unpublished, 2018.
jac23 A. Jacob, unpublished, 2023.
jac24 A. Jacob, unpublished, 2024.